CN102964824A - 一种玻璃纤维增韧尼龙料复配组合物的制备工艺 - Google Patents
一种玻璃纤维增韧尼龙料复配组合物的制备工艺 Download PDFInfo
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Abstract
本发明公开了一种玻璃纤维增韧尼龙料复配组合物的制备工艺,将所得改性尼龙PA66与PA66+30%GF等比例混匀后,得到的混合物经主喂料口加入双螺杆挤出机中,控制加工温度在250-270℃,螺杆转数在300-400rpm,熔融后挤出造粒即得到改性尼龙料产品。本发明解决了现有尼龙材料普遍耐高温性能差,强度低等性能缺陷,与其余原料复合,所得产品质量稳定,提高了生产效率,降低了生产成本,玻璃纤维增韧效果显著。
Description
技术领域
本发明涉及尼龙材料领域,确切地说是一种玻璃纤维增韧尼龙料复配组合物的制备工艺。
背景技术
由于尼龙具有很多的特性,因此,在汽车、电气设备、机械部构、交通器材、纺织、造纸机械等方面得到广泛应用。
随着汽车的小型化、电子电气设备的高性能化、机械设备轻量化的进程加快,对尼龙的需求将更高更大。特别是尼龙作为结构性材料,对其强度、耐热性、耐寒性等方面提出了很高的要求。尼龙的固有缺点也是限制其应用的重要因素,特别是对于PA6、PA66两大品种来说,与PA46、PAl2等品种比具有很强的价格优势,虽某些性能不能满足相关行业发展的要求。因此,必须针对某一应用领域,通过改性,提高其某些性能,来扩大其应用领域。 由于PA强极性的特点,吸湿性强,尺寸稳定性差,但可以通过改性来改善。
发明内容
为了缓解现有技术的不足和缺陷,本发明的目的在于提供一种玻璃纤维增韧尼龙料复配组合物的制备工艺。
上述目的通过以下方案实现:
一种玻璃纤维增韧尼龙料复配组合物的制备工艺,其特征在于,包括以下步骤:
(1)将尼龙PA66在95-100℃下干燥8-10小时;
(2)将3-5重量份膨胀蛭石粉、2-4重量份钾长石粉在450-500℃下烧损6-7小时,后研磨成纳米粉末,拌入相当于粉体重量2-4%的氯化石蜡搅拌均匀,烘干,粉碎成粉末,即得改性纳米矿物粉,得;
(3)取制备改性尼龙PA66所需原料中的除玻璃纤维以外各原料,按照重量份置于高混机中混合3-6min,得到的混合物经主喂料口加入双螺杆挤出机中,玻璃纤维从侧喂料口按重量份加入双螺杆挤出机,控制加工温度在255-265℃,螺杆转数在400-500rpm,熔融后挤出造粒即得到改性尼龙PA66;
所述的改性尼龙PA66由下述重量份的原料制得:尼龙PA66 65-70,双酚A型聚碳酸酯 10-15,改性纳米矿物粉5-9,聚己内酯3-5,硅油0.5-1,KH570 1-2,抗氧剂168 0.1-0.2,抗氧剂1010 0.5-0.8,玻璃纤维6-8,氧化聚乙烯蜡0.8-1,硬脂酸锌1-1.2,二苯胺0.1-0.2;
(4)将所得改性尼龙PA66与PA66+30%GF等比例混匀后,得到的混合物经主喂料口加入双螺杆挤出机中,控制加工温度在250-270℃,螺杆转数在300-400rpm,熔融后挤出造粒即得到改性尼龙料产品。
所述的一种玻璃纤维增韧尼龙料复配组合物的制备工艺,其特征在于:步骤(1)中干燥温度为100℃。
本发明的有益效果为:
本发明解决了现有尼龙材料普遍耐高温性能差,强度低等性能缺陷,与其余原料复合,所得产品质量稳定,提高了生产效率,降低了生产成本。玻璃纤维增韧效果显著。
具体实施方式
一种玻璃纤维增韧尼龙料复配组合物的制备工艺,包括以下步骤:
(1)将尼龙PA66在100℃下干燥10小时;
(2)将5重量份膨胀蛭石粉、4重量份钾长石粉在500℃下烧损7小时,后研磨成纳米粉末,拌入相当于粉体重量4%的氯化石蜡搅拌均匀,烘干,粉碎成粉末,即得改性纳米矿物粉,得;
(3)取制备改性尼龙PA66所需原料中的除玻璃纤维以外各原料,按照重量份置于高混机中混合3-6min,得到的混合物经主喂料口加入双螺杆挤出机中,玻璃纤维从侧喂料口按重量份加入双螺杆挤出机,控制加工温度在265℃,螺杆转数在400rpm,熔融后挤出造粒即得到改性尼龙PA66;
所述的改性尼龙PA66由下述重量份(kg)的原料制得:尼龙PA66 70,双酚A型聚碳酸酯 15,改性纳米矿物粉9,聚己内酯5,硅油1,KH570 2,抗氧剂168 0.2,抗氧剂1010 0.8,玻璃纤维8,氧化聚乙烯蜡1,硬脂酸锌1.2,二苯胺0.2;
(4)将所得改性尼龙PA66与PA66+30%GF等比例混匀后,得到的混合物经主喂料口加入双螺杆挤出机中,控制加工温度在270℃,螺杆转数在400rpm,熔融后挤出造粒即得到改性尼龙料产品。所述的玻璃纤维为无碱短切玻璃纤维,表面经过硅烷偶联剂处理。
本实施例注塑成型后所得产品的性能检测:
试验项目 | 测试方法 | 测试数据 |
拉伸强度 | ASTM D638 | 129 MPa |
弯曲强度 | ASTM D790 | 139.9MPa |
缺口冲击强度(23℃) | ASTM D256 | 91.6KJ/㎡ |
热变形温度 | ASTM D648 | 236℃ |
Claims (2)
1.一种玻璃纤维增韧尼龙料复配组合物的制备工艺,其特征在于,包括以下步骤:
(1)将尼龙PA66在95-100℃下干燥8-10小时;
(2)将3-5重量份膨胀蛭石粉、2-4重量份钾长石粉在450-500℃下烧损6-7小时,后研磨成纳米粉末,拌入相当于粉体重量2-4%的氯化石蜡搅拌均匀,烘干,粉碎成粉末,即得改性纳米矿物粉;
(3)取制备改性尼龙PA66所需原料中的除玻璃纤维以外各原料,按照重量份置于高混机中混合3-6min,得到的混合物经主喂料口加入双螺杆挤出机中,玻璃纤维从侧喂料口按重量份加入双螺杆挤出机,控制加工温度在255-265℃,螺杆转数在400-500rpm,熔融后挤出造粒即得到改性尼龙PA66;
所述的改性尼龙PA66由下述重量份的原料制得:尼龙PA66 65-70,双酚A型聚碳酸酯 10-15,改性纳米矿物粉5-9,聚己内酯3-5,硅油0.5-1,KH570 1-2,抗氧剂168 0.1-0.2,抗氧剂1010 0.5-0.8,玻璃纤维6-8,氧化聚乙烯蜡0.8-1,硬脂酸锌1-1.2,二苯胺0.1-0.2;
(4)将所得改性尼龙PA66与PA66+30%GF等比例混匀后,得到的混合物经主喂料口加入双螺杆挤出机中,控制加工温度在250-270℃,螺杆转数在300-400rpm,熔融后挤出造粒即得到改性尼龙料产品。
2.根据权利要求1所述的一种玻璃纤维增韧尼龙料复配组合物的制备工艺,其特征在于:步骤(1)中干燥温度为100℃。
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102993705A (zh) * | 2012-10-19 | 2013-03-27 | 芜湖市鑫海橡塑制品有限责任公司 | 一种汽车油管内层用耐油尼龙pa12材料及其制备方法 |
CN103834165A (zh) * | 2013-11-21 | 2014-06-04 | 安徽师范大学 | 一种汽车塑料件用陶瓷粉改性尼龙66材料 |
CN104830028A (zh) * | 2015-05-27 | 2015-08-12 | 陕西科技大学 | 一种提高尼龙6纤维增强复合材料界面结合强度的方法 |
CN107400354A (zh) * | 2017-07-17 | 2017-11-28 | 宁波市鄞州红岩汽配厂 | 一种汽车散热器出水室 |
CN112592585A (zh) * | 2020-12-11 | 2021-04-02 | 山东非金属材料研究所 | 一种耐低温低吸水低膨胀改性尼龙材料及其制备方法 |
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US4546147A (en) * | 1982-11-10 | 1985-10-08 | Monsanto Company | Compositions of nylon and elastomers |
CN101987917A (zh) * | 2009-07-30 | 2011-03-23 | 现代自动车株式会社 | 导电性聚酰胺复合组合物和使用其的燃料输送管 |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US4546147A (en) * | 1982-11-10 | 1985-10-08 | Monsanto Company | Compositions of nylon and elastomers |
CN101987917A (zh) * | 2009-07-30 | 2011-03-23 | 现代自动车株式会社 | 导电性聚酰胺复合组合物和使用其的燃料输送管 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102993705A (zh) * | 2012-10-19 | 2013-03-27 | 芜湖市鑫海橡塑制品有限责任公司 | 一种汽车油管内层用耐油尼龙pa12材料及其制备方法 |
CN103834165A (zh) * | 2013-11-21 | 2014-06-04 | 安徽师范大学 | 一种汽车塑料件用陶瓷粉改性尼龙66材料 |
CN103834165B (zh) * | 2013-11-21 | 2016-04-27 | 安徽师范大学 | 一种汽车塑料件用陶瓷粉改性尼龙66材料 |
CN104830028A (zh) * | 2015-05-27 | 2015-08-12 | 陕西科技大学 | 一种提高尼龙6纤维增强复合材料界面结合强度的方法 |
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CN107400354B (zh) * | 2017-07-17 | 2020-02-18 | 宁波市鄞州红岩汽配厂 | 一种汽车散热器出水室 |
CN112592585A (zh) * | 2020-12-11 | 2021-04-02 | 山东非金属材料研究所 | 一种耐低温低吸水低膨胀改性尼龙材料及其制备方法 |
CN115477844A (zh) * | 2020-12-11 | 2022-12-16 | 山东非金属材料研究所 | 一种耐低温低吸水低膨胀改性尼龙材料及其制备方法 |
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