CN102875943B - Red semitransparent gluedots and preparation method thereof - Google Patents
Red semitransparent gluedots and preparation method thereof Download PDFInfo
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- CN102875943B CN102875943B CN201210138470.5A CN201210138470A CN102875943B CN 102875943 B CN102875943 B CN 102875943B CN 201210138470 A CN201210138470 A CN 201210138470A CN 102875943 B CN102875943 B CN 102875943B
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- water
- borax
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- nasal mucus
- redness
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Abstract
The invention relates to gluedots and a preparation method thereof. The preparation method for red semitransparent gluedots comprises the following steps of: mixing water and guar gum; adding sorbic acid, sodium benzoate, dilauryl thiodipropionate, propylene glycol and glycerol, and emulsifying in an emulsifying pot; adding Carbomer resin to obtain a glue solution; pouring the glue solution into a stirrer, adding amyl valerate, amyl butyrate, geranialdehyde, geranyl formate and 1-(4'-sulfo-1'-azobenzol)-2-naphthol-6,8-trisodium disulfonate, and blending; and adding prepared borax water. The red semitransparent gluedots have high stability and good transparency, are naturally antibacterial and have high antiaging, antioxidant and water retaining capacity, so that the red semitransparent gluedots have long service life which is 12-15 months commonly, have bright color and stable pigment without discoloration, and have the transparency of 50-60 percent.
Description
Technical field
The invention belongs to toy material field, particularly relate to a kind of nasal mucus glue and preparation method thereof.
Background technology
Nasal mucus glue is a kind of translucent thickness colloid, the colloid of its state between solid and liquid.Mainly for the preparation of the material of various nasal mucus glue toys, nasal mucus glue toy comprises for punishing and enchanting, the emerging toy of practical joke, and market outlook are wide, according to color, divide have redness, green, blueness and yellow multiple.Existing nasal mucus glue main component comprises water, guar gum, tripoly phosphate sodium STPP and pigment, existing this nasal mucus glue poor stability, and easy deterioration by oxidation, transparency is bad, and easy breed bacteria.In addition, because lack the component of water retention, make nasal mucus glue in use, easily dehydration is rotten, and work-ing life was short at 6～8 months lower work-ing life for normal temperature.The red pigments that wherein red nasal mucus glue adopts is industrial pigment, and not only color is not bright-coloured in nasal mucus glue for this red pigments, easily decolouring, and pigment state labile, and easily oxidation stain, also affects transparency.The translucent nasal mucus glue of existing redness transparency is between 30～40%.
Summary of the invention
The deficiency existing for above-mentioned nasal mucus glue, the object of this invention is to provide the translucent nasal mucus glue of a kind of redness, the translucent nasal mucus glue of this redness is a kind of good stability, has anti-old oxidation-resistance, transparency is good, can be naturally antibacterial and the nasal mucus glue material of long service life; Aspect color, the translucent nasal mucus glue of this redness is bright-colored, color stable.
Another object of the present invention is to provide the preparation method of the translucent nasal mucus glue of this redness.
In order to realize foregoing invention object, the present invention has adopted following technical scheme:
The translucent nasal mucus glue of redness, the translucent nasal mucus glue of this redness is made by following component by weight percentage:
Guar gum: 2～5%;
Borax: 7～13%;
1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt: 0.05～0.1%;
Sorbic Acid: 0.03～0.08%;
Sodium Benzoate: 0.01～0.03%;
Propylene glycol: 4～12%;
Glycerine: 1～7%;
Carbomer: 3～7%;
Tyox B: 0.08～0.15%;
Oil of apple: 0.008～0.013%;
Pentyl butyrate: 0.01～0.03%;
Citral: 0.01～0.03%;
Geranyl Formate: 0.005～0.012%;
Water: 70～80%;
The summation of above-mentioned all components percentage composition is 100%.
As preferably, the translucent nasal mucus glue of this redness is made by following component by weight percentage:
Guar gum: 3.5%;
Borax: 9%;
1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt: 0.07%;
Sorbic Acid: 0.05%;
Sodium Benzoate: 0.02%;
Propylene glycol: 7%;
Glycerine: 3%;
Carbomer: 5%;
Tyox B: 0.1%;
Oil of apple: 0.01%;
Pentyl butyrate: 0.02%;
Citral: 0.02%;
Geranyl Formate: 0.01%;
Water: 72.2%.
A preparation method for the translucent nasal mucus glue of redness, this preparation method comprises the following steps:
(1) mix, water and guar gum are mixed and pours container for stirring into 10～20 minutes, form mixed solution;
(2) emulsification, pours above-mentioned mixed solution in emulsification pot into and stirs 5～10 minutes, then adds Sorbic Acid, Sodium Benzoate, Tyox B, propylene glycol and glycerine, the mixed solution in heating emulsification pot stirring and emulsifying pot; Until mixeding liquid temperature rises to 90～100 ℃ in emulsification pot, emulsification completely;
(3) glue liquid, then add carbomer to the good above-mentioned mixed solution of emulsification, stir 20～30 minutes, until transparent glue solution is even, glue is at this moment the thick liquid that transparency is high;
(4) modulation borax water, is first crushed into powder borax, then water and borax is mixed to join in warming pan, heats to 90 ℃ and constantly stirs, until borax powder is completely water-soluble, makes borax water heat preservation for standby use;
(5) paint and make finished product, the good transparent glue of emulsification pot internal modulation in step (3) is poured in stirrer, add oil of apple, pentyl butyrate, citral, Geranyl Formate and 1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt, stir 2～5 minutes, add again the borax solution modulating in step (4) to stir 5～10 minutes, the effect of borax water is to solidify, be about to the semi-solid glue that above-mentioned glue becomes thickness, make red translucent nasal mucus glue finished product;
As preferably, in described step (1), the weight ratio of water and guar gum is 6～8:1.
The translucent nasal mucus glue of redness of preparing by such scheme of the present invention, in stability, anti-always anti-oxidant, in transparency and water retention capacity, all have significantly and improve, glycerine and propylene glycol belong to wetting Agent for Printing Inks, so glycerine wherein, propylene glycol, borax and water combination make nasal mucus glue water retention capacity very good; Carbomer mixes with above-mentioned wetting Agent for Printing Inks, water and the guar gum mixed solution of comprising, and makes nasal mucus glue transparency high.The effect that borax also has water conservation and solidifies finished product in technological process, also as a kind of stablizer and antioxidant, stability is high simultaneously, and anti-old antioxidant effect is good.Tyox B is also a kind of oxidation inhibitor, its with include 1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6, the mixture of 8-disulfonic acid trisodium salt (red pigments), Sorbic Acid, Geranyl Formate is used in combination, the anti-old antioxidant effect of the translucent nasal mucus glue of redness that not only makes the present invention make further promotes, possesses antibacterial ability simultaneously, and aspect color, redness shows more bright-colouredly and is stable not easy to change.In a word, the translucent nasal mucus glue of this redness stability is high, and transparency is good, can be naturally antibacterial, and anti-old anti-oxidant strong with water retention capacity, thus make it long with the life-span, work-ing life is generally at 12～15 months; Aspect color, bright-colored, pigment is stable not easy to change, makes the transparency of nasal mucus glue between 50～60%.
Embodiment
By embodiment, the present invention to be done further to describe for example below.
Embodiment 1:
The translucent nasal mucus glue of redness, the translucent nasal mucus glue of this redness is made by following component by weight percentage:
Guar gum: 3.5%;
Borax: 9%;
1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt: 0.07%;
Sorbic Acid: 0.05%;
Sodium Benzoate: 0.02%;
Propylene glycol: 7%;
Glycerine: 3%;
Carbomer: 5%;
Tyox B: 0.1%;
Oil of apple: 0.01%;
Pentyl butyrate: 0.02%;
Citral: 0.02%;
Geranyl Formate: 0.01%;
Water: 72.2%.
The preparation method of the translucent nasal mucus glue of redness of above-mentioned raw materials percentage composition proportioning comprises the following steps:
(1) mix, water and guar gum are mixed and pours container for stirring into 10～20 minutes, form mixed solution, in this step, above-mentioned 72.2% water is not added completely, the weight ratio of water and guar gum is at 7:1, and water accounts for 24.5% of gross weight.
(2) emulsification, pours above-mentioned water and guar gum mixed solution in emulsification pot into and stirs 5～10 minutes, then add Sorbic Acid, Sodium Benzoate, Tyox B, propylene glycol and glycerine, the mixed solution in heating emulsification pot stirring and emulsifying pot; Until mixeding liquid temperature rises to 90～100 ℃ in emulsification pot, emulsification completely.
(3) glue liquid, then add carbomer to the good above-mentioned mixed solution of emulsification, stir 20～30 minutes, until transparent glue solution is even, glue is at this moment the thick liquid that transparency is high.
(4) modulation borax water, first borax is crushed into powder, again water and borax are mixed to join in warming pan, wherein water accounts for 47.7% of gross weight, borax accounts for 9% of gross weight, this water and borax are heated to 90 ℃ and constantly stirred, until borax powder is completely water-soluble, make borax water heat preservation for standby use.
(5) paint and make finished product, the good transparent glue of emulsification pot internal modulation in step (3) is poured in stirrer, add oil of apple, pentyl butyrate, citral, Geranyl Formate and 1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt, cover and stir cover and stir 2～5 minutes, add again the borax solution modulating in step (4), stir 5～10 minutes, the effect of borax water is to solidify, be about to the semi-solid glue that above-mentioned glue becomes thickness, thereby prepare red translucent nasal mucus glue finished product.
Above steps is all carried out under normal pressure, and above-mentioned gross weight refers to the weight of red translucent nasal mucus glue finished product.
In above-mentioned various components, glycerine and propylene glycol belong to wetting Agent for Printing Inks, and borax replaces existing tripoly phosphate sodium STPP, have both had water retention, are also a kind of stablizers, so glycerine wherein, propylene glycol, borax and water combination make nasal mucus glue water retention capacity very good.Carbomer mixes with above-mentioned wetting Agent for Printing Inks, water and the guar gum mixed solution of comprising, and makes nasal mucus glue transparency high.In addition, have borax or a kind of antioxidant of stabilizer function, under the effect of borax solution, borax composition is evenly mixed wherein fully, make nasal mucus glue stability high, water-retentivity is strong, and anti-old antioxidant effect is good.1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt is a kind of natural red pigments, another name is carmine, English name Ponceau, water-soluble taking on a red color, maximum absorption wavelength 508 ± 2nm is heat-resisting, but can only under solutions of weak acidity, keep bright-coloured redness, meet alkali browning look.And above-mentioned Sorbic Acid and Sodium Benzoate are sanitass, mould, yeast and aerobic bacteria are all had to restraining effect, the Sorbic Acid of selecting is wherein exactly acid sanitas, is intended to rot-resistant simultaneously, keeps the bright-coloured nondiscoloration of red pigments.Similarly, as the oil of apple of essence, pentyl butyrate, each component of citral and Geranyl Formate, can not only allow nasal mucus glue possess fruit aroma, and Geranyl Formate wherein also has the effect that regulates mixture solutions of weak acidity, and protection is held pigment and is stablized nondiscoloration.Above-mentioned Sorbic Acid stink slightly with irritating, and in air, long-term placement is easily oxidized painted.Oil of apple wherein, pentyl butyrate, citral and Geranyl Formate can be removed its pungent odour as essence, and Tyox B wherein and borax are all oxidation inhibitor, can prevent that Sorbic Acid is oxidized, affect the color of product.In a word, on the prepared translucent nasal mucus glue of the redness final effect of this embodiment, there is stability high, can be naturally antibacterial, anti-old anti-oxidant strong with water retention capacity, thus make it long with the life-span; Aspect color, bright-colored stable not easy to change, transparency is 54% simultaneously.
And by red pigments 1-(4 '-sulfo group-1 in said components '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt is replaced by other natural red pigments, repeat above-mentioned embodiment, the transparency of the nasal mucus glue of preparation can be reduced to below 50%, if another name is 2,4,5,7-tetra-sulphur fluorescent yellows, the red scarlet pigment of English name Erythrosine joins the translucent nasal mucus glue of the redness of preparing in other components, and not only redness is not bright-coloured, and use for some time color partially blue unstable, make the transparency of nasal mucus glue 40%; Sorghum Pigment as by name in English, major ingredient is that the red sorghum pigment of apigenin (5.74 '-trihydroxyflavone) and quercimeritrin (Quercetin-7-glucoside) joins the translucent nasal mucus glue of the redness of preparing in other components color and is reddish brown, dimness is not bright-coloured, and the transparency of nasal mucus glue is 32%.
Embodiment 2
The translucent nasal mucus glue of redness, the translucent nasal mucus glue of this redness is made by following component by weight percentage:
Guar gum: 5%;
Borax: 8%;
1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt: 0.05%;
Sorbic Acid: 0.04%;
Sodium Benzoate: 0.03%;
Propylene glycol: 8%;
Glycerine: 1%;
Carbomer: 4%;
Tyox B: 0.12%;
Oil of apple: 0.008%;
Pentyl butyrate: 0.022%;
Citral: 0.025%;
Geranyl Formate: 0.005%;
Water: 73.7%.
In the preparation method of the translucent nasal mucus glue of redness of above-mentioned raw materials percentage composition proportioning, the weight ratio of step (1) water and guar gum is at 6:1, and water accounts for 30% of gross weight, and all the other water all mix and add with borax in step (3).Other is identical with embodiment 1.
Embodiment 3
The translucent nasal mucus glue of redness, the translucent nasal mucus glue of this redness is made by following component by weight percentage:
Guar gum: 2.5%;
Borax: 7%;
1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt: 0.08%;
Sorbic Acid: 0.06%;
Sodium Benzoate: 0.03%;
Propylene glycol: 4%;
Glycerine: 6%;
Carbomer: 7%;
Tyox B: 0.09%;
Oil of apple: 0.008%;
Pentyl butyrate: 0.01%;
Citral: 0.013%;
Geranyl Formate: 0.009%;
Water: 73.2%.
In the preparation method of the translucent nasal mucus glue of redness of above-mentioned raw materials percentage composition proportioning, the weight ratio of step (1) water and guar gum is at 8:1, and water accounts for 20% of gross weight, and all the other water all mix and add with borax in step (3).Other is identical with embodiment 1.
The partial properties contrast table of the translucent nasal mucus glue of existing redness and above-described embodiment 1,2,3 below
Claims (3)
1. the translucent nasal mucus glue of redness, is characterized in that the translucent nasal mucus glue of this redness is made by following component by weight percentage:
Guar gum: 2～5%;
Borax: 7～13%;
1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt: 0.05～0.1%;
Sorbic Acid: 0.03～0.08%;
Sodium Benzoate: 0.01～0.03%;
Propylene glycol: 4～12%;
Glycerine: 1～7%;
Carbomer: 3～7%;
Tyox B: 0.08～0.15%;
Oil of apple: 0.008～0.013%;
Pentyl butyrate: 0.01～0.03%;
Citral: 0.01～0.03%;
Geranyl Formate: 0.005～0.012%;
Water: 70～80%;
Above-mentioned all components percentage composition sum is 100%.
2. the translucent nasal mucus glue of a kind of redness according to claim 1, is characterized in that this redness nasal mucus glue is made by following component by weight percentage:
Guar gum: 3.5%;
Borax: 9%;
1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt: 0.07%;
Sorbic Acid: 0.05%;
Sodium Benzoate: 0.02%;
Propylene glycol: 7%;
Glycerine: 3%;
Carbomer: 5%;
Tyox B: 0.1%;
Oil of apple: 0.01%;
Pentyl butyrate: 0.02%;
Citral: 0.02%;
Geranyl Formate: 0.01%;
Water: 72.2%.
3. a preparation method for the translucent nasal mucus glue of redness as claimed in claim 1, is characterized in that the method comprises the following steps:
(1) mix, water and guar gum are mixed and pours container for stirring into 10～20 minutes, form mixed solution, the weight ratio of water and guar gum is 6～8:1;
(2) emulsification, pours above-mentioned mixed solution in emulsification pot into and stirs 5～10 minutes, then adds Sorbic Acid, Sodium Benzoate, Tyox B, propylene glycol and glycerine, the mixed solution in heating emulsification pot stirring and emulsifying pot; Until mixeding liquid temperature rises to 90～100 ℃ in emulsification pot, emulsification completely;
(3) glue liquid, then add carbomer to the good above-mentioned mixed solution of emulsification, stir 20-30 minute, until transparent glue solution is even;
(4) modulation borax water, is first crushed into powder borax, then water and borax is mixed to join in warming pan, heats to 90 ℃ and constantly stirs, until borax powder is completely water-soluble, makes borax water heat preservation for standby use;
(5) paint and make finished product, the good transparent glue of emulsification pot internal modulation in step (3) is poured in stirrer, add oil of apple, pentyl butyrate, citral, Geranyl Formate and 1-(4 '-sulfo group-1 '-nitrogen benzide)-beta naphthal-6,8-disulfonic acid trisodium salt, stir 2～5 minutes, add again the borax water modulating in step (4), stir 5～10 minutes, make red translucent nasal mucus glue finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210138470.5A CN102875943B (en) | 2012-05-04 | 2012-05-04 | Red semitransparent gluedots and preparation method thereof |
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| CN201210138470.5A CN102875943B (en) | 2012-05-04 | 2012-05-04 | Red semitransparent gluedots and preparation method thereof |
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| CN102875943B true CN102875943B (en) | 2014-03-05 |
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| CN114479202A (en) * | 2022-03-05 | 2022-05-13 | 丽妍塑料(惠州)有限公司 | Binkou water and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007038855A1 (en) * | 2005-10-04 | 2007-04-12 | Sigmacon Medical Products Corporation | Medical gel |
| CN101525458A (en) * | 2008-11-17 | 2009-09-09 | 稂武忠 | Lava |
| CN102321443A (en) * | 2011-09-15 | 2012-01-18 | 宋仕良 | Environmental protection type transparent solid glue and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001078750A1 (en) * | 2000-04-17 | 2001-10-25 | Care Technologies, Inc. | Lice remover composition |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007038855A1 (en) * | 2005-10-04 | 2007-04-12 | Sigmacon Medical Products Corporation | Medical gel |
| CN101525458A (en) * | 2008-11-17 | 2009-09-09 | 稂武忠 | Lava |
| CN102321443A (en) * | 2011-09-15 | 2012-01-18 | 宋仕良 | Environmental protection type transparent solid glue and preparation method thereof |
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