CN102675793B - Blue semitransparent magic gluedots and preparation method thereof - Google Patents
Blue semitransparent magic gluedots and preparation method thereof Download PDFInfo
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- CN102675793B CN102675793B CN2012101389198A CN201210138919A CN102675793B CN 102675793 B CN102675793 B CN 102675793B CN 2012101389198 A CN2012101389198 A CN 2012101389198A CN 201210138919 A CN201210138919 A CN 201210138919A CN 102675793 B CN102675793 B CN 102675793B
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- nasal mucus
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Abstract
The invention relates to blue semitransparent magic gluedots and a preparation method thereof. The blue semitransparent magic gluedots provided by the invention is formed in the following steps of: mixing water with guar gum; then adding benzoic acid, propionic acid, dilauryl thiodipropionate, propylene glycol and glycerol into an emulsion pot to be emulsified; then adding Carbomer resin to obtain glue solution; pouring the glue solution into a stirrer; then, adding amyl valerate, amyl butyrate, citral, geranyl formate and gardenia blue to mix and stir; and finally, adding modulated borax water to obtain the blue semitransparent magic gluedots. All in all, the blue semitransparent magic gluedots has the advantages of high stability, good transparency, strong anti-ageing, anti-oxidation and water-retention capability and long service life (which is about 12-15 months), and can naturally resist bacteria. On the aspect of the color, the blue semitransparent magic gluedots has the advantages of vivid color and stable pigment and is unlikely to change color, and the transparency of the magic gluedots is between 50% and 60%.
Description
Technical field
The invention belongs to the toy material field, particularly relate to a kind of nasal mucus glue and preparation method thereof.
Background technology
Nasal mucus glue is a kind of translucent thickness colloid, the colloid of its state between solid and liquid.Mainly for the preparation of the material of various nasal mucus glue toys, nasal mucus glue toy comprises be used to punishing and enchanting, the emerging toy of practical joke, and market outlook are wide, divide according to color blueness is arranged, redness, yellow and green multiple.Existing nasal mucus glue main component comprises water, guar gum, tripoly phosphate sodium STPP and pigment, existing this nasal mucus glue poor stability, and easy deterioration by oxidation, transparency is bad, and easy breed bacteria.In addition,, because lack the component of water retention, make nasal mucus glue in use, easily dehydration is rotten, and work-ing life was short at 6～8 months lower work-ing life for normal temperature.Wherein the blue pigment of blue nasal mucus glue employing is industrial pigment, and not only color is not bright-coloured in nasal mucus glue for this blue pigment, easily decolouring, and pigment state labile, and easily oxidation stain, also affect transparency.The translucent nasal mucus glue of existing blueness transparency is between 30～40%.
Summary of the invention
Deficiency for above-mentioned nasal mucus glue existence, the purpose of this invention is to provide the translucent nasal mucus glue of a kind of blueness, the translucent nasal mucus glue of this blueness is a kind of good stability, has anti-old oxidation-resistance, transparency is good, can be naturally antibiotic and the nasal mucus glue material of long service life; Aspect color, the translucent nasal mucus glue of this blueness is bright-colored, color stable.
Another object of the present invention is to provide the preparation method of the translucent nasal mucus glue of this blueness.
In order to realize the foregoing invention purpose, the present invention has adopted following technical scheme:
The translucent nasal mucus glue of a kind of blueness, should be made by following component by the translucent nasal mucus glue of blueness by weight percentage:
Guar gum: 2～5%;
Borax: 7～13%;
Gardenia blue: 0.05～0.1%;
Phenylformic acid: 0.03～0.08%;
Propionic acid: 0.01～0.03%;
Propylene glycol: 4～12%;
Glycerine: 1～7%;
Carbomer: 3～7%;
Tyox B: 0.08～0.15%;
Oil of apple: 0.008～0.013%;
Pentyl butyrate: 0.01～0.03%;
Citral: 0.01～0.03%;
Geranyl Formate: 0.005～0.012%;
Water: 70～80%;
The summation of above-mentioned all components percentage composition is 100%.
As preferably, should be made by following component by the translucent nasal mucus glue of blueness by weight percentage:
Guar gum: 3.5%;
Borax: 9%;
Gardenia blue: 0.07%;
Phenylformic acid: 0.05%;
Propionic acid: 0.02%;
Propylene glycol: 7%;
Glycerine: 3%;
Carbomer: 5%;
Tyox B: 0.1%;
Oil of apple: 0.01%;
Pentyl butyrate: 0.02%;
Citral: 0.02%;
Geranyl Formate: 0.01%;
Water: 72.2%.
The preparation method of the translucent nasal mucus glue of a kind of blueness, this preparation method comprises the following steps:
(1) mix, water and guar gum are mixed and poured container for stirring into 10～20 minutes, form mixed solution;
(2) emulsification, pour above-mentioned mixed solution in the emulsification pot into and stirred 5～10 minutes, then add phenylformic acid, propionic acid, Tyox B, propylene glycol and glycerine, the mixed solution in heating emulsification pot and stirring and emulsifying pot; Until in the emulsification pot, mixeding liquid temperature rises to 90～100 ℃, emulsification fully;
(3) glue liquid, then add carbomer to the good above-mentioned mixed solution of emulsification, stirred 20～30 minutes, until transparent glue solution is even, glue at this moment is the high thick liquid of transparency;
(4) the modulation borax water, first be crushed into powder borax, then water and borax be mixed to join in warming pan, heats to 90 ℃ and constantly stir, and, until borax powder is fully water-soluble, makes borax water and heat preservation for standby use;
(5) paint and make finished product, the good transparent glue of emulsification pot internal modulation in step (3) is poured in stirrer, add oil of apple, pentyl butyrate, citral, Geranyl Formate and gardenia blue, stirred 2～5 minutes, add again the borax solution that modulates in step (4) to stir 5～10 minutes, the effect of borax water is to solidify, and is about to above-mentioned glue and becomes the semi-solid glue of thickness, makes blue translucent nasal mucus glue finished product;
As preferably, in described step (1), the weight ratio of water and guar gum is 6～8:1.
Blue translucent nasal mucus glue by such scheme preparation of the present invention, in stability, anti-always anti-oxidant, all have on transparency and water retention capacity significantly and improve, glycerine and propylene glycol belong to wetting Agent for Printing Inks, so glycerine wherein, propylene glycol, borax and water combination make nasal mucus glue water retention capacity very good; Carbomer mixes with above-mentioned wetting Agent for Printing Inks, water and the guar gum mixed solution of comprising, and makes nasal mucus glue transparency high.Borax also has water conservation and solidifies finished product in technological process effect, also as a kind of stablizer and antioxidant, stability is high simultaneously, and anti-old antioxidant effect is good.Tyox B is also a kind of oxidation inhibitor, it is used in combination with the mixture that includes gardenia blue (blue pigment), phenylformic acid, Geranyl Formate, the anti-old antioxidant effect of the blue translucent nasal mucus glue that the present invention is made further promotes, possesses simultaneously antibacterial ability, and aspect color, blueness shows more bright-colouredly and is stable not easy to change.In a word, the translucent nasal mucus glue of this blueness stability is high, and transparency is good, can be naturally antibiotic, and anti-old anti-oxidant strong with water retention capacity, thus make it long with the life-span, work-ing life is generally at 12～15 months; Aspect color, bright-colored, pigment is stable not easy to change, makes the transparency of nasal mucus glue between 50～60%.
Embodiment
Below by embodiment, the present invention to be done further to describe for example.
Embodiment 1:
The translucent nasal mucus glue of a kind of blueness, should be made by following component by the translucent nasal mucus glue of blueness by weight percentage:
Guar gum: 3.5%;
Borax: 9%;
Gardenia blue: 0.07%;
Phenylformic acid: 0.05%;
Propionic acid: 0.02%;
Propylene glycol: 7%;
Glycerine: 3%;
Carbomer: 5%;
Tyox B: 0.1%;
Oil of apple: 0.01%;
Pentyl butyrate: 0.02%;
Citral: 0.02%;
Geranyl Formate: 0.01%;
Water: 72.2%.
The preparation method of the blue translucent nasal mucus glue of above-mentioned raw materials percentage composition proportioning comprises the following steps:
(1) mix, water and guar gum are mixed and poured container for stirring into 10～20 minutes, form mixed solution, in this step, above-mentioned 72.2% water is not added fully, the weight ratio of water and guar gum is at 7:1, and namely water accounts for 24.5% of gross weight.
(2) emulsification, pour above-mentioned water and guar gum mixed solution in the emulsification pot into and stirred 5～10 minutes, then add phenylformic acid, propionic acid, Tyox B, propylene glycol and glycerine, the mixed solution in heating emulsification pot and stirring and emulsifying pot; Until in the emulsification pot, mixeding liquid temperature rises to 90～100 ℃, emulsification fully.
(3) glue liquid, then add carbomer to the good above-mentioned mixed solution of emulsification, stirred 20～30 minutes, until transparent glue solution is even, glue at this moment is the high thick liquid of transparency.
(4) modulation borax water, first borax is crushed into powder, again water and borax are mixed to join in warming pan, namely wherein water accounts for 47.7% of gross weight, borax accounts for 9% of gross weight, this water and borax are heated to 90 ℃ and constantly stirred,, until borax powder is fully water-soluble, make borax water and heat preservation for standby use.
(5) paint and make finished product, the good transparent glue of emulsification pot internal modulation in step (3) is poured in stirrer, add oil of apple, pentyl butyrate, citral, Geranyl Formate and gardenia blue, cover and stir cover and stirred 2～5 minutes, add the borax solution that modulates in step (4) again, stirred 5～10 minutes, the effect of borax water is to solidify, be about to the semi-solid glue that above-mentioned glue becomes thickness, thereby prepare blue translucent nasal mucus glue finished product.
Above steps is all carried out under normal pressure, above-mentioned gross weight refers to the weight of blue translucent nasal mucus glue finished product.
In above-mentioned various components, glycerine and propylene glycol belong to wetting Agent for Printing Inks, and borax replaces existing tripoly phosphate sodium STPP, has both had water retention, is also a kind of stablizer, so glycerine wherein, propylene glycol, borax and water combination make nasal mucus glue water retention capacity very good.Carbomer mixes with above-mentioned wetting Agent for Printing Inks, water and the guar gum mixed solution of comprising, and makes nasal mucus glue transparency high.In addition, have borax or a kind of antioxidant of stabilizer function, under the effect of borax solution, the borax composition is evenly mixed wherein fully, make nasal mucus glue stability high, water-retentivity is strong, and anti-old antioxidant effect is good.Gardenia blue is a kind of natural blue pigment, water-solublely is blue, and temperature capacity is strong, but can only be blue under acid and neutrallty condition, especially under acidic conditions, is the blueness of distinctness in the water-soluble and propylene glycol solvent of gardenia blue.And above-mentioned phenylformic acid and propionic acid are sanitass, and mould, yeast and aerobic bacteria are all had restraining effect, and wherein the phenylformic acid of selecting and propionic acid are all acid sanitass, are intended to rot-resistant simultaneously, keep the bright-coloured nondiscoloration of blue pigment.Oil of apple, pentyl butyrate, citral and Geranyl Formate as essence can allow nasal mucus glue possess fruit aroma.Tyox B wherein and borax are all oxidation inhibitor, can prevent that gardenia blue is oxidized, affect the tone of product.In a word, on the prepared blue translucent nasal mucus glue final effect of this embodiment, have stability high, can be naturally antibiotic, anti-old anti-oxidant strong with water retention capacity, thus make it long with the life-span; Aspect color, bright-colored stable not easy to change simultaneously.
And the blue pigment gardenia blue in said components is replaced by other natural blue pigments, as also under acidic conditions painted blue pigment bath blue.The resistance toheat of bath indigo plant is poor, can decomposes in preparation process separates out protein and variable color finally causes the blue color of nasal mucus glue not bright-coloured, and the protein of separating out also affects the transparency of nasal mucus glue.Other components of the present invention such as the organic solvents such as glycerine and propylene glycol can damage bath indigo plant in addition, also can make nasal mucus glue color unstable, use for some time with regard to variable color.Therefore, the translucent effect of blueness of the present invention is not only and is relied on the gardenia blue of selecting in natural pigment, prior or by gardenia blue, coordinate with other components and realize, these components are to have selectivity and interdependence, are difficult for just being realized by simply alternative.
Embodiment 2
The translucent nasal mucus glue of a kind of blueness, should be made by following component by the translucent nasal mucus glue of blueness by weight percentage:
Guar gum: 5%;
Borax: 8%;
Gardenia blue: 0.05%;
Phenylformic acid: 0.04%;
Propionic acid: 0.03%;
Propylene glycol: 8%;
Glycerine: 1%;
Carbomer: 4%;
Tyox B: 0.12%;
Oil of apple: 0.008%;
Pentyl butyrate: 0.022%;
Citral: 0.025%;
Geranyl Formate: 0.005%;
Water: 73.7%.
In the preparation method of the blue translucent nasal mucus glue of above-mentioned raw materials percentage composition proportioning, the weight ratio of step (1) water and guar gum is at 6:1, and namely water accounts for 30% of gross weight, and all the other water all mix and add with borax in step (3).Other is identical with embodiment 1.
Embodiment 3
The translucent nasal mucus glue of a kind of blueness, should be made by following component by the translucent nasal mucus glue of blueness by weight percentage:
Guar gum: 2.5%;
Borax: 7%;
Gardenia blue: 0.08%;
Phenylformic acid: 0.06%;
Propionic acid: 0.03%;
Propylene glycol: 4%;
Glycerine: 6%;
Carbomer: 7%;
Tyox B: 0.09%;
Oil of apple: 0.008%;
Pentyl butyrate: 0.01%;
Citral: 0.013%;
Geranyl Formate: 0.009%;
Water: 73.2%.
In the preparation method of the blue translucent nasal mucus glue of above-mentioned raw materials percentage composition proportioning, the weight ratio of step (1) water and guar gum is at 8:1, and namely water accounts for 20% of gross weight, and all the other water all mix and add with borax in step (3).Other is identical with embodiment 1.
Below existing blue translucent nasal mucus glue and above-described embodiment 1,2,3 partial properties contrast table
Claims (3)
1. translucent nasal mucus glue of blueness is characterized in that should being made by following component by the translucent nasal mucus glue of blueness by weight percentage:
Guar gum: 2～5%;
Borax: 7～13%;
Gardenia blue: 0.05～0.1%;
Phenylformic acid: 0.03～0.08%;
Propionic acid: 0.01～0.03%;
Propylene glycol: 4～12%;
Glycerine: 1～7%;
Carbomer: 3～7%;
Tyox B: 0.08～0.15%;
Oil of apple: 0.008～0.013%;
Pentyl butyrate: 0.01～0.03%;
Citral: 0.01～0.03%;
Geranyl Formate: 0.005～0.012%;
Water: 70～80%;
Above-mentioned all components percentage composition sum is 100%.
2. the translucent nasal mucus glue of a kind of blueness according to claim 1 is characterized in that should being made by following component by blueness nasal mucus glue by weight percentage:
Guar gum: 3.5%;
Borax: 9%;
Gardenia blue: 0.07%;
Phenylformic acid: 0.05%;
Propionic acid: 0.02%;
Propylene glycol: 7%;
Glycerine: 3%;
Carbomer: 5%;
Tyox B: 0.1%;
Oil of apple: 0.01%;
Pentyl butyrate: 0.02%;
Citral: 0.02%;
Geranyl Formate: 0.01%;
Water: 72.2%.
3. the preparation method of the translucent nasal mucus glue of blueness as claimed in claim 1 is characterized in that the method comprises the following steps:
(1) mix, water and guar gum are mixed and poured container for stirring into 10～20 minutes, form mixed solution;
(2) emulsification, pour above-mentioned mixed solution in the emulsification pot into and stirred 5～10 minutes, then add phenylformic acid, propionic acid, Tyox B, propylene glycol and glycerine, the mixed solution in heating emulsification pot and stirring and emulsifying pot; Until in the emulsification pot, mixeding liquid temperature rises to 90～100 ℃, emulsification fully;
(3) glue liquid, then add carbomer to the good above-mentioned mixed solution of emulsification, stir 20-30 minute, until transparent glue solution is even;
(4) the modulation borax water, first be crushed into powder borax, then water and borax be mixed to join in warming pan, heats to 90 ℃ and constantly stir, and, until borax powder is fully water-soluble, makes borax water and heat preservation for standby use;
(5) paint and make finished product, the good transparent glue of emulsification pot internal modulation in step (3) is poured in stirrer, add oil of apple, pentyl butyrate, citral, Geranyl Formate and gardenia blue, stirred 2～5 minutes, add again the borax water that modulates in step (4), stirred 5～10 minutes, and made blue translucent nasal mucus glue finished product; In described step (1), the weight ratio of water and guar gum is 6～8:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101389198A CN102675793B (en) | 2012-05-04 | 2012-05-04 | Blue semitransparent magic gluedots and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012101389198A CN102675793B (en) | 2012-05-04 | 2012-05-04 | Blue semitransparent magic gluedots and preparation method thereof |
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| CN102675793A CN102675793A (en) | 2012-09-19 |
| CN102675793B true CN102675793B (en) | 2013-11-13 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| AU2001251640A1 (en) * | 2000-04-17 | 2001-10-30 | Care Technologies, Inc | Lice remover composition |
| WO2007038855A1 (en) * | 2005-10-04 | 2007-04-12 | Sigmacon Medical Products Corporation | Medical gel |
| CN101525458A (en) * | 2008-11-17 | 2009-09-09 | 稂武忠 | Lava |
| CN102321443B (en) * | 2011-09-15 | 2013-04-17 | 江苏兴达文具集团有限公司 | Environmental protection type transparent solid glue and preparation method thereof |
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Effective date of registration: 20160811 Address after: 301, room 3, building 50, 322000 Yi Road, thick city street, Yiwu, Zhejiang Patentee after: Chen Junhua Address before: 322200 Zhejiang city of Jinhua Province Huang Town Pujiang County Parkway Park No. 67 Patentee before: Pujiang Xinping Import & Export Co.,Ltd. |
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Granted publication date: 20131113 |
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