CN102786176B - 一种催化裂化汽油碱渣综合利用方法 - Google Patents
一种催化裂化汽油碱渣综合利用方法 Download PDFInfo
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- CN102786176B CN102786176B CN 201210300639 CN201210300639A CN102786176B CN 102786176 B CN102786176 B CN 102786176B CN 201210300639 CN201210300639 CN 201210300639 CN 201210300639 A CN201210300639 A CN 201210300639A CN 102786176 B CN102786176 B CN 102786176B
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- oil
- sludge
- sodium sulfate
- acid sludge
- acid
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- 238000000034 method Methods 0.000 title claims abstract description 43
- 239000010802 sludge Substances 0.000 title claims abstract description 40
- 239000003502 gasoline Substances 0.000 title claims abstract description 24
- 238000004523 catalytic cracking Methods 0.000 title abstract description 3
- 239000002253 acid Substances 0.000 claims abstract description 51
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 27
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 25
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000005804 alkylation reaction Methods 0.000 claims abstract description 9
- 230000029936 alkylation Effects 0.000 claims abstract description 8
- 238000001704 evaporation Methods 0.000 claims abstract description 5
- 238000000926 separation method Methods 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 claims description 47
- 238000004821 distillation Methods 0.000 claims description 18
- 238000006386 neutralization reaction Methods 0.000 claims description 11
- 150000002989 phenols Chemical class 0.000 claims description 11
- 241000282326 Felis catus Species 0.000 claims description 5
- 238000002425 crystallisation Methods 0.000 claims description 4
- 230000008025 crystallization Effects 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052753 mercury Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 239000010687 lubricating oil Substances 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 2
- 238000006297 dehydration reaction Methods 0.000 claims description 2
- 239000003350 kerosene Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 230000003068 static effect Effects 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 9
- 239000013078 crystal Substances 0.000 abstract description 6
- 238000001953 recrystallisation Methods 0.000 abstract description 3
- 230000003472 neutralizing effect Effects 0.000 abstract description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 abstract 1
- 238000005292 vacuum distillation Methods 0.000 abstract 1
- 239000002699 waste material Substances 0.000 description 16
- 239000012071 phase Substances 0.000 description 10
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 229910052785 arsenic Inorganic materials 0.000 description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000007670 refining Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 235000010269 sulphur dioxide Nutrition 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- -1 small molecules sulfide Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- NESLWCLHZZISNB-UHFFFAOYSA-M sodium phenolate Chemical compound [Na+].[O-]C1=CC=CC=C1 NESLWCLHZZISNB-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 239000004291 sulphur dioxide Substances 0.000 description 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003674 animal food additive Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
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CN103589443B (zh) * | 2013-10-31 | 2015-09-09 | 唐山山岛石油化学有限公司 | 劣质有机废物的无公害提纯及高效利用方法 |
CN103893941B (zh) * | 2014-04-22 | 2016-05-04 | 山东腾跃化学危险废物研究处理有限公司 | 利用碱渣以废治废中和水解处理有机硅浆渣的方法 |
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GB2038868B (en) * | 1979-11-12 | 1982-09-22 | Waste Lubricating Oils Ltd | Method and apparatus for reprocessing waste oils |
CN1132899C (zh) * | 2000-07-24 | 2003-12-31 | 中国石油化工股份有限公司 | 酸渣、碱渣综合处理方法 |
CN1528863A (zh) * | 2003-09-26 | 2004-09-15 | 毅 赵 | 碱溶液中和酸渣破乳沉降分离生产重质燃料油的工艺方法 |
CN102351357B (zh) * | 2011-06-24 | 2012-10-17 | 扬州大学 | 含苯酚和硫酸钠废水的资源化利用和处理方法 |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CB03 | Change of inventor or designer information |
Inventor after: Xie Zhaoxin Inventor after: Zhang Xinglin Inventor after: Xu Dongmei Inventor after: Yang Linqing Inventor after: Mei Jiaozong Inventor after: Qin Jinlin Inventor after: Gan Liming Inventor after: Ma Wenjuan Inventor after: Bai Liang Inventor before: Xie Zhaoxin Inventor before: Yang Linqing Inventor before: Mei Jiaozong Inventor before: Gan Liming Inventor before: Qin Jinlin Inventor before: Ma Wenjuan |
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TR01 | Transfer of patent right |
Effective date of registration: 20231207 Address after: 730000 Jiuhe Village, Jiuhe Town, Anning District, Lanzhou City, Gansu Province Patentee after: LANZHOU KANGSHUN PETROCHEMICAL Co.,Ltd. Patentee after: Gansu ecological environment science design and Research Institute (Gansu Ecological Environment Planning Institute) Address before: 730060, 13th Floor, Changye Building, No. 129 Gongyuan Road, Xigu District, Lanzhou City, Gansu Province Patentee before: LANZHOU KANGSHUN PETROCHEMICAL Co.,Ltd. |
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CP03 | Change of name, title or address | ||
CP03 | Change of name, title or address |
Address after: 730000 No. 225, Yanerwan Road, Chengguan District, Lanzhou City, Gansu Province (Gansu Environmental Science and Technology Building) Patentee after: Gansu ecological environment science design and Research Institute (Gansu Ecological Environment Planning Institute) Patentee after: LANZHOU KANGSHUN PETROCHEMICAL Co.,Ltd. Address before: 730000 Jiuhe Village, Jiuhe Town, Anning District, Lanzhou City, Gansu Province Patentee before: LANZHOU KANGSHUN PETROCHEMICAL Co.,Ltd. Patentee before: Gansu ecological environment science design and Research Institute (Gansu Ecological Environment Planning Institute) |