CN102771493A - Fungicide composition containing prochloraz and imazalil, and application thereof - Google Patents
Fungicide composition containing prochloraz and imazalil, and application thereof Download PDFInfo
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- CN102771493A CN102771493A CN2011101192359A CN201110119235A CN102771493A CN 102771493 A CN102771493 A CN 102771493A CN 2011101192359 A CN2011101192359 A CN 2011101192359A CN 201110119235 A CN201110119235 A CN 201110119235A CN 102771493 A CN102771493 A CN 102771493A
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- prochloraz
- mixture
- down mould
- mould azoles
- agent
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Abstract
The invention relates to a fungicide composition containing prochloraz and imazalil, and application thereof. The fungicide composition is characterized by comprising the following components expressed in weight percentage: 8 to 60% of prochloraz, 2 to 30% of imazalil, 10 to 25% of an auxiliary agent and 20 to 80% a solvent or a filling material. Prochloraz and imazalil are compounded to form a pesticidal dosage form of missible oil, wettable powder, dispersible granule or a suspending agent. The fungicide composition containing prochloraz and imazalil can be used for prevention and treatment of a variety of fungal diseases of field crops, fruits, vegetables, turf and ornamental plants, especially applicable to prevention and treatment of apple canker. The fungicide composition provided by the invention has the advantages of a good control effect, long duration, an obvious synergistic effect after compounding of prochloraz and imazalil, capacity of achieving a better effect even when usage amount of each single agent is reduced, lower cost, environment friendliness and easy transport and storage.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, relating in particular to a kind of is the bactericidal composition and the application thereof of active component with Prochloraz with pressing down mould azoles.
Background technology
Prochloraz (Prochloraz), chemical name: N-propyl group-N-[2-(2,4, the 6-Trichlorophenoxy) ethyl]-1H-imidazoles-1-formamide, molecular formula: C
15H
16Cl
3N
3O
2, be the strongest active kind in the amino formyl imidazole class, inhale multiple actions such as conduction, prevention protection and treatment in having, be high-effective broad-spectrum fungicide, antistaling agent, ergosterol inhibitor, splendid to the multiple diseases preventive effect that sac fungi, imperfect fungus cause.Adaptable across the multiple fungal disease of control such as cereal, paddy rice, leguminous plant, fruit, vegetables Lay such as citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose; Leaf spot of peanut, vegetables anthracnose such as capsicum, eggplant, muskmelon, tomato, strawberry anthracnose; Bakanae disease of rice, rice blast, sclerotinia rot of colza, leaf spot, mushroom brown spot; Apple anthracnose, rot, pear scab etc.
Press down mould azoles (Imazalil), chemical name: (±) pi-allyl 1-(2,4 dichloro benzene base)-2-imidazoles-1-benzyl ethyl ether, molecular formula: C
14H
14C1
2N
2O, systemic fungicide all has preventive effect to many fungal diseases of attacking fruit, vegetables and ornamental plants, and Helminthosporium, Fusarium, Septoria fungi are had high activity.Can be used for preventing and treating the cereal disease, fruit is sprayed or floods, can prevent and treat rotting of results back fruit.Green grass or young crops, green mold bacterium to benzimidazoles such as resisting carbendazim, probenazoles have special efficacy.
A kind of pesticide active ingredient uses on same disease for a long time, repeatedly, and disease is developed immunity to drugs, thereby reduces drug effect; Increase use cost, prevent drug-fast generation, a kind of method is the new pesticide active ingredient of exploitation; But developed a kind of new pesticide active ingredient 5～10 years; Expensive more than one hundred million dollars obviously is very difficult, and will have the composite use of pesticide active ingredient of two kinds of different sterilization mechanisms of synergistic effect; Also can delay and administer the pesticide resistance of pathogen, increase preventive effect.Simultaneously, if adopt the high pesticide active ingredient of the low pesticide active ingredient of a kind of price and other a kind of price composite, can also reach the effect that reduces the agricultural chemicals use cost.
Summary of the invention
The objective of the invention is to solve a kind of pesticide active ingredient of the prior art uses on same disease for a long time, repeatedly; Disease is developed immunity to drugs; Thereby the reduction drug effect, the problem of increase use cost provides a kind of contain Prochloraz and the bactericidal composition and the application that press down mould azoles; To overcome the above-mentioned defective that prior art exists, satisfy the needs in relevant field.The present invention designs a kind of Prochloraz and bactericidal composition that presses down mould azoles of containing, and it is characterized in that being made up of following constituent and percentage by weight:
Prochloraz 8～60%,
Press down mould azoles 2～30%,
Auxiliary agent 10～25%,
Solvent or filler 20～80%,
It is characterized in that: for Prochloraz with press down mould azoles and auxiliary agent and filler or solvent complex and become any formulation on the agricultural chemicals, preferred version is missible oil, wetting powder, dispersibility granula and suspending agent.It is characterized in that: described auxiliary agent comprises a kind of or its mixture in emulsifier, dispersant, wetting agent, disintegrant, antifreezing agent, antifoaming agent or the thickener.Described emulsifier is selected from a kind of or its mixture in APES, AEO, glycerine fatty acid APEO, phenethyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy polyethenoxy ether, castor oil ethylene oxide adduct, APES formaldehyde condensation products, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, calcium dodecyl benzene sulfonate, the neopelex; Described dispersant is selected from a kind of or its mixture in polycarboxylate, lignosulfonates, APES, APES formaldehyde condensation products sulphate, alkylnaphthalene sulfonate, alkylbenzenesulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, aliphatic amine polyoxyethylene ether or the aliphatic acid polyethenoxy ether; Described wetting agent is selected from a kind of or its mixture in neopelex, dodecyl sodium naphthalene sulfonate, dodecyl phenenyl sulfate, potassium oleate, enuatrol, dioctyl sodium sulfosuccinate, nekal, alkyl polyoxyethylene ether sulfonate, spaonin powder, silkworm excrement, the soapberry powder; Described disintegrant is selected from a kind of or its mixture in bentonite, urea, sodium bicarbonate, ammonium sulfate, sodium carbonate, citric acid or the aluminium chloride; Said antifreezing agent is selected from a kind of of ethylene glycol, propane diols, glycerine or urea or sodium chloride or its mixture; Said antifoaming agent is selected from a kind of or its mixture in silicone oil, organosilicon ketone, C8～C10 fatty alcohol, C8～C20 saturated fatty acid or the C8～C20 polyunsaturated fatty acid ester; Said thickener is selected from a kind of or its mixture in carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, sodium carboxymethyl starch, polyvinylpyrrolidone, xanthans or the polyvinyl alcohol Magnesiumaluminumsilicate.It is characterized in that: described filler comprises a kind of or its mixture in talcum powder, kaolin, potter's clay, diatomite, white carbon black, attapulgite, starch or the precipitated calcium carbonate.It is characterized in that: described solvent comprises a kind of or its mixture in methyl alcohol, ethanol, dimethyl formamide, dimethyl sulfoxide (DMSO), N-Methyl pyrrolidone, cyclohexanone, toluene, xylol, solvent naphtha, chloroform, the deionized water.The described application that contains Prochloraz and the bactericidal composition that presses down mould azoles is characterized in that: be used to prevent and treat the multiple fungal disease on field crop, fruit, vegetables, turf and the ornamental plants, be particularly useful for preventing and treating Valsa mali.Advantage of the present invention be bactericidal composition of the present invention compared with prior art, have the following advantages: 1, brand-new composite reagent, preventive effect is good, the lasting period is long.Prochloraz with press down mould azoles composite after, have obvious synergistic effect, the single agent consumption that reduces separately also can reach better effect; Thereby reduce Toxicity in Crops effect and the adverse effect of having avoided a large amount of medications to bring to environment; Cost is lower, its economic benefit and obvious social benefit, 2, in the bactericidal composition of the present invention the active ingredient Prochloraz with press down mould azoles and have different sterilization mechanisms; Compare with single agent, more should not develop immunity to drugs.
Prochloraz and the bactericidal composition that presses down mould azoles of containing of the present invention, for Prochloraz with press down mould azoles and known auxiliary agent and excipient and be re-dubbed any formulation on the agricultural chemicals, reasonable is missible oil, wetting powder, dispersibility granula and suspending agent.
Embodiment
With embodiment content of the present invention is further described below, but the present invention is not limited thereto.
It is characterized in that forming by following constituent and percentage by weight:
Prochloraz 8～60%,
Press down mould azoles 2～30%,
Auxiliary agent 10～25%,
Solvent or filler 20～80%,
It is characterized in that: for Prochloraz with press down mould azoles and auxiliary agent and filler or solvent complex and become any formulation on the agricultural chemicals, preferred version is missible oil, wetting powder, dispersibility granula and suspending agent.It is characterized in that: described auxiliary agent comprises a kind of or its mixture in emulsifier, dispersant, wetting agent, disintegrant, antifreezing agent, antifoaming agent, the thickener.Described emulsifier is selected from a kind of or its mixture in APES, AEO, glycerine fatty acid APEO, phenethyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy polyethenoxy ether, castor oil ethylene oxide adduct, APES formaldehyde condensation products, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, calcium dodecyl benzene sulfonate, the neopelex;
Described dispersant is selected from a kind of or its mixture in polycarboxylate, lignosulfonates, APES, APES formaldehyde condensation products sulphate, alkylnaphthalene sulfonate, alkylbenzenesulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, aliphatic amine polyoxyethylene ether or the aliphatic acid polyethenoxy ether; Described wetting agent is selected from a kind of or its mixture in neopelex, dodecyl sodium naphthalene sulfonate, dodecyl phenenyl sulfate, potassium oleate, enuatrol, dioctyl sodium sulfosuccinate, nekal, alkyl polyoxyethylene ether sulfonate, spaonin powder, silkworm excrement, the soapberry powder; Described disintegrant is selected from a kind of or its mixture in bentonite, urea, sodium bicarbonate, ammonium sulfate, sodium carbonate, citric acid or the aluminium chloride; Said antifreezing agent is selected from a kind of of ethylene glycol, propane diols, glycerine or urea or sodium chloride or its mixture; Said antifoaming agent is selected from a kind of or its mixture in silicone oil, organosilicon ketone, C8～C10 fatty alcohol, C8～C20 saturated fatty acid or the C8～C20 polyunsaturated fatty acid ester; Said thickener is selected from a kind of or its mixture in carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, sodium carboxymethyl starch, polyvinylpyrrolidone, xanthans or the polyvinyl alcohol Magnesiumaluminumsilicate.It is characterized in that: described filler comprises a kind of or its mixture in talcum powder, kaolin, potter's clay, diatomite, white carbon black, attapulgite, starch or the precipitated calcium carbonate.It is characterized in that: described solvent comprises a kind of or its mixture in methyl alcohol, ethanol, dimethyl formamide, dimethyl sulfoxide (DMSO), N-Methyl pyrrolidone, cyclohexanone, toluene, xylol, solvent naphtha, chloroform, the deionized water.The described application that contains Prochloraz and the bactericidal composition that presses down mould azoles is characterized in that: be used to prevent and treat the multiple fungal disease on field crop, fruit, vegetables, turf and the ornamental plants, be particularly useful for preventing and treating Valsa mali.
Embodiment 1
Prescription: get
Mix, pulverize, obtain 15% Prochloraz and press down mould azoles wetting powder double centner through airslide disintegrating mill.
Embodiment 2
Prescription: get
Mix, pulverize, obtain 25% Prochloraz and press down mould azoles wetting powder double centner through airslide disintegrating mill.
Embodiment 3
Prescription: get
Mix, pulverize, obtain 45% Prochloraz and press down mould azoles wetting powder double centner through airslide disintegrating mill.
Embodiment 4
Prescription: get
Mix, pulverize, obtain 65% Prochloraz and press down mould azoles wetting powder double centner through airslide disintegrating mill.
Embodiment 5
Prescription: get
Mix, pulverize, obtain 70% Prochloraz and press down mould azoles wetting powder double centner through airslide disintegrating mill.
Embodiment 6
Prescription: get
Mix,, obtain 10% Prochloraz and press down mould azole suspending agent double centner through ball milling.
Embodiment 7
Prescription: get
Mix,, obtain 20% Prochloraz and press down mould azole suspending agent double centner through ball milling.
Embodiment 8
Prescription: get
Mix,, obtain 50% Prochloraz and press down mould azole suspending agent double centner through ball milling.
Embodiment 9
Prescription: get
Mix, after airslide disintegrating mill was pulverized, granulating and drying obtained 30% Prochloraz and presses down mould azoles dispersibility granula double centner.
Embodiment 10
Prescription: get
Mix, after airslide disintegrating mill was pulverized, granulating and drying obtained 50% Prochloraz and presses down mould azoles dispersibility granula double centner.
Embodiment 11
Prescription: get
After the dissolving, mix, obtain 10% Prochloraz and press down mould azoles missible oil double centner.
Embodiment 12
Prescription: get
After the dissolving, mix, obtain 20% Prochloraz and press down mould azoles missible oil double centner.
Embodiment 13
Prescription: get
After the dissolving, mix, obtain 40% Prochloraz and press down mould azoles missible oil double centner.
Be to utilize Prochloraz to be mixed to the toxicity test of apple canker below with pressing down mould azoles,
(1) medicament preparation
Prochloraz solution: accurately taking by weighing the 0.0100g weight concentration is the former medicine of 95% Prochloraz; Dissolve with the 0.2ml dimethyl formamide; Add the sterile water 94.8ml that contains 0.1% Tween 80 surfactant; Stir, be mixed with Prochloraz 100mg/L mother liquor, again with the sterile water that contains 0.1% Tween 80 surfactant be diluted to 50,10,5,2.5,1.25mg/L concentration is subsequent use.
Press down mould azoles solution: accurately take by weighing 0.0100g95% and press down the former medicine of mould azoles; Dissolve with the 0.2ml dimethyl formamide; Add the sterile water 94.8ml that contains 0.1% Tween 80 surfactant; Stir, be mixed with and press down mould azoles 100mg/L mother liquor, again with the sterile water that contains 0.1% Tween 80 surfactant be diluted to 50,10,5,2.5,1.25mg/L concentration is subsequent use.
Solution respectively is mixed: get 10,5,5,3 respectively, 3ml50mg/L presses down mould azoles solution; Add 10,10,20,18 respectively, process 50mg/L in the 24ml50mg/L Prochloraz solution and press down mould azoles: 1: 1,1: 2,1: 4,1: 6,1: 8 solution of Prochloraz, again with the sterile water that contains 0.1% Tween 80 surfactant be diluted to 10,5,2.5,1.25,0.625mg/L concentration is subsequent use.
Contrast solution: the 0.2ml dimethyl formamide adds the sterile water that 96ml contains 0.1% Tween 80 surfactant.(2) experimental technique: with reference to romaine lettuce standard method NY/T 1156.4-2006; Adopt the pastille medium therapy: the soup 3ml that gets each single agent and mixture series concentration; Add in the PDE medium of the 27ml that is cooled to 45 ℃, process the pastille culture medium flat plate of required final concentration.Get 6mm diameter mycelia piece from the Valsa mali colony edge of cultivating 4 days then, move on each serial pastille medium, mycelia faces down; Every processing repeats for 4 times, and the processing that does not contain medicament is as blank, and the biochemical incubator of the constant temperature that places 28 ℃ of experiments to establish is then cultivated; Measure colony diameter after 4 days; Adopt the SAS6.12 statistical software to analyze, calculate mycelial growth inhibition rate (%), obtain virulence regression equation, correlation coefficient (r) and 95% confidence interval (EC according to experimental data
50), with reference to NY/T 1156.6-2006, estimate the synergistic effect of pharmacy mix according to the co-toxicity coefficient method (CTC) of Sun&Johnson (1960), promptly CTC≤80 are antagonism, 80＜CTC＜120 summation actions, CTC>=120 synergistic effects.
(3) evaluation method and evaluation criterion
Prochloraz is with the toxicity test result who makes up apple canker sees table 1 but mould azoles and the two different proportion are mixed.Visible by table one, in 1: 1,1: 2,1: 4,1: 6 the combination that is mixed that presses down mould azoles and Prochloraz, apple canker is all showed synergistic effect, the most obvious to press down 1: 2 the combination synergistic effect that is mixed of mould azoles and Prochloraz especially.
Table 1 Prochloraz with press down mould azoles and be mixed the toxicity test result of apple canker
Claims (7)
1. contain Prochloraz and the bactericidal composition that presses down mould azoles, it is characterized in that forming by following constituent and percentage by weight:
Prochloraz 8～60%,
Press down mould azoles 2～30%,
Auxiliary agent 10～25%,
Solvent or filler 20～80%.
2. Prochloraz and the bactericidal composition that presses down mould azoles of containing according to claim 1; It is characterized in that: for Prochloraz with press down mould azoles and auxiliary agent and filler or solvent complex and become any formulation on the agricultural chemicals, preferred version is missible oil, wetting powder, dispersibility granula and suspending agent.
3. Prochloraz and the bactericidal composition that presses down mould azoles of containing according to claim 1, it is characterized in that: described auxiliary agent comprises a kind of or its mixture in emulsifier, dispersant, wetting agent, disintegrant, antifreezing agent, antifoaming agent or the thickener.
4. Prochloraz and the bactericidal composition that presses down mould azoles of containing according to claim 3, it is characterized in that: described emulsifier is selected from a kind of or its mixture in APES, AEO, glycerine fatty acid APEO, phenethyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy polyethenoxy ether, castor oil ethylene oxide adduct, APES formaldehyde condensation products, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, calcium dodecyl benzene sulfonate, the neopelex;
Described dispersant is selected from a kind of or its mixture in polycarboxylate, lignosulfonates, APES, APES formaldehyde condensation products sulphate, alkylnaphthalene sulfonate, alkylbenzenesulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, aliphatic amine polyoxyethylene ether or the aliphatic acid polyethenoxy ether;
Described wetting agent is selected from a kind of or its mixture in neopelex, dodecyl sodium naphthalene sulfonate, dodecyl phenenyl sulfate, potassium oleate, enuatrol, dioctyl sodium sulfosuccinate, nekal, alkyl polyoxyethylene ether sulfonate, spaonin powder, silkworm excrement, the soapberry powder;
Described disintegrant is selected from a kind of or its mixture in bentonite, urea, sodium bicarbonate, ammonium sulfate, sodium carbonate, citric acid or the aluminium chloride;
Said antifreezing agent is selected from a kind of of ethylene glycol, propane diols, glycerine or urea or sodium chloride or its mixture;
Said antifoaming agent is selected from a kind of or its mixture in silicone oil, organosilicon ketone, C8～C10 fatty alcohol, C8～C20 saturated fatty acid or the C8～C20 polyunsaturated fatty acid ester;
Said thickener is selected from a kind of or its mixture in carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, sodium carboxymethyl starch, polyvinylpyrrolidone, xanthans or the polyvinyl alcohol Magnesiumaluminumsilicate.
5. Prochloraz and the bactericidal composition that presses down mould azoles of containing according to claim 1 is characterized in that: described filler comprises a kind of or its mixture in talcum powder, kaolin, potter's clay, diatomite, white carbon black, attapulgite, starch or the precipitated calcium carbonate.
6. Prochloraz and the bactericidal composition that presses down mould azoles of containing according to claim 1, it is characterized in that: described solvent comprises a kind of or its mixture in methyl alcohol, ethanol, dimethyl formamide, dimethyl sulfoxide (DMSO), N-Methyl pyrrolidone, cyclohexanone, toluene, xylol, solvent naphtha, chloroform, the deionized water.
7. according to each described application that contains Prochloraz and the bactericidal composition that presses down mould azoles in the claim 1 to 6; It is characterized in that: be used to prevent and treat the multiple fungal disease on field crop, fruit, vegetables, turf and the ornamental plants, be particularly useful for preventing and treating Valsa mali.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101192359A CN102771493A (en) | 2011-05-10 | 2011-05-10 | Fungicide composition containing prochloraz and imazalil, and application thereof |
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|---|---|---|---|
| CN2011101192359A CN102771493A (en) | 2011-05-10 | 2011-05-10 | Fungicide composition containing prochloraz and imazalil, and application thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103918657A (en) * | 2014-04-11 | 2014-07-16 | 山东省烟台市农业科学研究院 | Fungicidal composite for preventing and controlling apple diseases and application of fungicidal composite |
| CN104798794A (en) * | 2015-04-21 | 2015-07-29 | 山东省烟台市农业科学研究院 | Captan and imazalil compound composition and application thereof |
| CN104839220A (en) * | 2015-05-12 | 2015-08-19 | 柳州市耕青科技有限公司 | Special anti-rot agent for succulent echeveria desmetiana |
| CN104839219A (en) * | 2015-05-12 | 2015-08-19 | 柳州市耕青科技有限公司 | Special anti-rot agent for succulent pelargonium odoratissimum |
| CN104855426A (en) * | 2015-05-12 | 2015-08-26 | 柳州市耕青科技有限公司 | Special rot resistant agent for succulent ball cactus |
| CN104872179A (en) * | 2015-05-12 | 2015-09-02 | 柳州市耕青科技有限公司 | Special rot-resistant agent for succulent plant crassula obliqua |
| CN104886142A (en) * | 2015-05-12 | 2015-09-09 | 柳州市耕青科技有限公司 | Dedicated rot-resistant agent for succulent plant pachyphytum 'Blue Haze' |
| CN104920445A (en) * | 2015-05-12 | 2015-09-23 | 柳州市耕青科技有限公司 | Succulent lithops special-purposed anti-rot agent |
| CN105076130A (en) * | 2015-08-14 | 2015-11-25 | 浙江海正化工股份有限公司 | Compound emulsifier for pesticide emulsifiable oil |
| CN105994373A (en) * | 2016-05-14 | 2016-10-12 | 广东中迅农科股份有限公司 | Application technology of targeted microbubbles to sterilization emulsion in water |
| CN112120021A (en) * | 2020-09-30 | 2020-12-25 | 浙江农林大学 | Compound type slow-release algae removal microcapsule and preparation method thereof |
| CN108283215B (en) * | 2018-02-07 | 2021-03-19 | 中国农业大学 | Dispersible solid preparation for fruit preservation and application thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103918657A (en) * | 2014-04-11 | 2014-07-16 | 山东省烟台市农业科学研究院 | Fungicidal composite for preventing and controlling apple diseases and application of fungicidal composite |
| CN104798794A (en) * | 2015-04-21 | 2015-07-29 | 山东省烟台市农业科学研究院 | Captan and imazalil compound composition and application thereof |
| CN104839220A (en) * | 2015-05-12 | 2015-08-19 | 柳州市耕青科技有限公司 | Special anti-rot agent for succulent echeveria desmetiana |
| CN104839219A (en) * | 2015-05-12 | 2015-08-19 | 柳州市耕青科技有限公司 | Special anti-rot agent for succulent pelargonium odoratissimum |
| CN104855426A (en) * | 2015-05-12 | 2015-08-26 | 柳州市耕青科技有限公司 | Special rot resistant agent for succulent ball cactus |
| CN104872179A (en) * | 2015-05-12 | 2015-09-02 | 柳州市耕青科技有限公司 | Special rot-resistant agent for succulent plant crassula obliqua |
| CN104886142A (en) * | 2015-05-12 | 2015-09-09 | 柳州市耕青科技有限公司 | Dedicated rot-resistant agent for succulent plant pachyphytum 'Blue Haze' |
| CN104920445A (en) * | 2015-05-12 | 2015-09-23 | 柳州市耕青科技有限公司 | Succulent lithops special-purposed anti-rot agent |
| CN105076130A (en) * | 2015-08-14 | 2015-11-25 | 浙江海正化工股份有限公司 | Compound emulsifier for pesticide emulsifiable oil |
| CN105994373A (en) * | 2016-05-14 | 2016-10-12 | 广东中迅农科股份有限公司 | Application technology of targeted microbubbles to sterilization emulsion in water |
| CN108283215B (en) * | 2018-02-07 | 2021-03-19 | 中国农业大学 | Dispersible solid preparation for fruit preservation and application thereof |
| CN112120021A (en) * | 2020-09-30 | 2020-12-25 | 浙江农林大学 | Compound type slow-release algae removal microcapsule and preparation method thereof |
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Application publication date: 20121114 |