CN102766246B - 一种鞋材油墨用的水性聚氨酯树脂 - Google Patents
一种鞋材油墨用的水性聚氨酯树脂 Download PDFInfo
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- CN102766246B CN102766246B CN 201210279415 CN201210279415A CN102766246B CN 102766246 B CN102766246 B CN 102766246B CN 201210279415 CN201210279415 CN 201210279415 CN 201210279415 A CN201210279415 A CN 201210279415A CN 102766246 B CN102766246 B CN 102766246B
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- polyurethane resin
- waterborne polyurethane
- dibasic alcohol
- printing ink
- deionized water
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- 239000000463 material Substances 0.000 title claims abstract description 33
- 229920005749 polyurethane resin Polymers 0.000 title claims abstract description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000008367 deionised water Substances 0.000 claims abstract description 14
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 14
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical group CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 13
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical group O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims abstract description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005057 Hexamethylene diisocyanate Chemical group 0.000 claims abstract description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 8
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims abstract description 7
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical group OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims abstract description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical group CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 5
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000007639 printing Methods 0.000 claims description 28
- 150000002009 diols Chemical class 0.000 claims description 17
- 229920000728 polyester Polymers 0.000 claims description 16
- -1 Aminoethyl aminopropyl triethoxysilane 4 Butanone Chemical compound 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 239000000539 dimer Substances 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 230000035484 reaction time Effects 0.000 claims description 9
- DQFBYFPFKXHELB-UHFFFAOYSA-N Chalcone Natural products C=1C=CC=CC=1C(=O)C=CC1=CC=CC=C1 DQFBYFPFKXHELB-UHFFFAOYSA-N 0.000 claims description 8
- 235000005513 chalcones Nutrition 0.000 claims description 8
- 229960002725 isoflurane Drugs 0.000 claims description 8
- GUHRAJHKEBMTIG-UHFFFAOYSA-N [Na].NCCNC(C)S(=O)(=O)O Chemical compound [Na].NCCNC(C)S(=O)(=O)O GUHRAJHKEBMTIG-UHFFFAOYSA-N 0.000 claims description 7
- 229920003054 adipate polyester Polymers 0.000 claims description 7
- INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 4
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- 238000003756 stirring Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- AKANXUIAFDKRMU-UHFFFAOYSA-N 1-aminoethanesulfonic acid;sodium Chemical compound [Na].CC(N)S(O)(=O)=O AKANXUIAFDKRMU-UHFFFAOYSA-N 0.000 claims 1
- HJOVHMDZYOCNQW-UHFFFAOYSA-N Isophorone Natural products CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 239000000049 pigment Substances 0.000 abstract description 6
- 239000012948 isocyanate Substances 0.000 abstract description 5
- 239000005058 Isophorone diisocyanate Chemical group 0.000 abstract description 4
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical group CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005452 bending Methods 0.000 abstract description 3
- 150000002513 isocyanates Chemical class 0.000 abstract description 3
- 238000005259 measurement Methods 0.000 abstract 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 abstract 1
- WAWYSJFTGINOCE-UHFFFAOYSA-N 1-(2-aminoethylamino)ethanesulfonic acid Chemical group OS(=O)(=O)C(C)NCCN WAWYSJFTGINOCE-UHFFFAOYSA-N 0.000 abstract 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 239000004814 polyurethane Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 229920002635 polyurethane Polymers 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004970 Chain extender Substances 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000008520 organization Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001610 polycaprolactone Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 description 1
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002462 isocyano group Chemical group *[N+]#[C-] 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
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- 150000005846 sugar alcohols Polymers 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
Description
固含量 | 50% | 外观 | 乳白带蓝光 |
粘度 | 100-150mpas(25℃) | 抗拉强度 | 15Mpa |
断裂伸长度% | 600-700 | PH值 | 6.5-7.5 |
Claims (5)
Priority Applications (1)
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CN 201210279415 CN102766246B (zh) | 2012-08-07 | 2012-08-07 | 一种鞋材油墨用的水性聚氨酯树脂 |
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CN 201210279415 CN102766246B (zh) | 2012-08-07 | 2012-08-07 | 一种鞋材油墨用的水性聚氨酯树脂 |
Publications (2)
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CN102766246A CN102766246A (zh) | 2012-11-07 |
CN102766246B true CN102766246B (zh) | 2013-11-06 |
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Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103467695B (zh) * | 2013-09-03 | 2015-09-16 | 山东天庆科技发展有限公司 | 一种高疏水性、高耐黄变性皮革涂饰剂的制备方法 |
CN104499299B (zh) * | 2014-12-18 | 2016-11-16 | 陕西科技大学 | 一种用于绒面型超细纤维合成革的表面处理固色法 |
CN105038394A (zh) * | 2015-08-03 | 2015-11-11 | 中华制漆(深圳)有限公司 | 环保移印油墨及其制备方法和应用 |
CN106893065A (zh) * | 2015-12-21 | 2017-06-27 | 上海东大化学有限公司 | 一种固色用水性聚氨酯分散体、制备方法及其应用 |
US10829658B2 (en) * | 2016-07-20 | 2020-11-10 | Hewlett-Packard Development Company, L.P. | Inkjet ink set |
CN110177818B (zh) | 2017-02-27 | 2022-04-08 | 惠普发展公司,有限责任合伙企业 | 基于聚氨酯的粘合剂分散体 |
CN110198965B (zh) | 2017-02-27 | 2022-04-01 | 惠普发展公司,有限责任合伙企业 | 基于聚氨酯的粘合剂分散体 |
CN107141882B (zh) * | 2017-03-20 | 2022-03-25 | 江苏百瑞特新材料有限公司 | 一种水性油墨用水性聚氨酯树酯的合成方法 |
CN106986979A (zh) * | 2017-04-13 | 2017-07-28 | 合肥科天水性科技有限责任公司 | 一种阳离子芳香族水性聚氨酯同步扩链制备工艺 |
CN108329747A (zh) * | 2018-03-28 | 2018-07-27 | 深圳市美丽华科技股份有限公司 | 一种水性鞋材丝印油墨及其制备方法 |
CN110713808A (zh) * | 2018-07-13 | 2020-01-21 | 重庆韩拓科技有限公司 | 高固含量聚氨酯改性eva复合乳液及其制备方法 |
CN112143470B (zh) * | 2019-06-28 | 2023-02-03 | 中国石油化工股份有限公司 | 堵漏材料及其制备方法、堵漏剂 |
CN112341594B (zh) * | 2020-10-30 | 2022-08-09 | 西安工程大学 | 一种水性聚氨酯固色剂的制备方法 |
CN115505293B (zh) * | 2022-09-26 | 2023-04-25 | 三晃树脂(佛山)有限公司 | 一种鞋材油墨用聚氨酯及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1970626A (zh) * | 2006-11-01 | 2007-05-30 | 淄博奥德美高分子材料有限公司 | 水性聚氨酯氟硅改性高分子导电乳液 |
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2012
- 2012-08-07 CN CN 201210279415 patent/CN102766246B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1970626A (zh) * | 2006-11-01 | 2007-05-30 | 淄博奥德美高分子材料有限公司 | 水性聚氨酯氟硅改性高分子导电乳液 |
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