CN102760579B - 染料敏化太阳能电池用氧化钛薄膜电极材料及其制备方法 - Google Patents
染料敏化太阳能电池用氧化钛薄膜电极材料及其制备方法 Download PDFInfo
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- CN102760579B CN102760579B CN201110109638.5A CN201110109638A CN102760579B CN 102760579 B CN102760579 B CN 102760579B CN 201110109638 A CN201110109638 A CN 201110109638A CN 102760579 B CN102760579 B CN 102760579B
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- electrode material
- film
- titanium oxide
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- 239000010409 thin film Substances 0.000 title claims abstract description 27
- 239000007772 electrode material Substances 0.000 title claims abstract description 26
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 18
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 title claims description 20
- 239000004408 titanium dioxide Substances 0.000 title description 2
- 239000004793 Polystyrene Substances 0.000 claims abstract description 57
- 229920002223 polystyrene Polymers 0.000 claims abstract description 55
- 239000013078 crystal Substances 0.000 claims abstract description 33
- 239000010408 film Substances 0.000 claims abstract description 25
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- 238000010438 heat treatment Methods 0.000 claims abstract description 18
- 239000011521 glass Substances 0.000 claims abstract description 17
- 239000002243 precursor Substances 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 36
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 25
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 22
- 238000004140 cleaning Methods 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- 238000010792 warming Methods 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
- 235000019394 potassium persulphate Nutrition 0.000 claims description 11
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 10
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 9
- 230000005611 electricity Effects 0.000 claims description 7
- -1 polyoxyethylene Polymers 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- 239000012298 atmosphere Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 4
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N butyl alcohol Substances CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 238000012360 testing method Methods 0.000 claims description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 2
- 206010070834 Sensitisation Diseases 0.000 claims description 2
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 2
- 230000008313 sensitization Effects 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 2
- 229910001887 tin oxide Inorganic materials 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000010936 titanium Substances 0.000 abstract description 6
- 238000000802 evaporation-induced self-assembly Methods 0.000 abstract description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 1
- 230000031700 light absorption Effects 0.000 abstract 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 18
- 238000004090 dissolution Methods 0.000 description 13
- 238000003756 stirring Methods 0.000 description 12
- 239000000975 dye Substances 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000008236 heating water Substances 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910003088 Ti−O−Ti Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000009916 joint effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Landscapes
- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
Abstract
Description
Claims (9)
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CN201110109638.5A CN102760579B (zh) | 2011-04-29 | 2011-04-29 | 染料敏化太阳能电池用氧化钛薄膜电极材料及其制备方法 |
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CN201110109638.5A CN102760579B (zh) | 2011-04-29 | 2011-04-29 | 染料敏化太阳能电池用氧化钛薄膜电极材料及其制备方法 |
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CN102760579A CN102760579A (zh) | 2012-10-31 |
CN102760579B true CN102760579B (zh) | 2015-04-01 |
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CN201110109638.5A Expired - Fee Related CN102760579B (zh) | 2011-04-29 | 2011-04-29 | 染料敏化太阳能电池用氧化钛薄膜电极材料及其制备方法 |
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CN103214611B (zh) * | 2013-05-14 | 2014-12-24 | 西华大学 | 一种自带模板剂的单分散型纳米致孔剂的制备方法 |
CN105762286B (zh) * | 2016-02-26 | 2018-11-27 | 上海科技大学 | 反蛋白石结构钙钛矿薄膜及相应太阳能电池的制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008115055A (ja) * | 2006-11-07 | 2008-05-22 | Electric Power Dev Co Ltd | 酸化チタン膜、酸化チタン膜電極膜構造および色素増感太陽電池 |
CN101323504A (zh) * | 2008-06-13 | 2008-12-17 | 天津大学 | 大孔-介孔纳米晶二氧化钛薄膜的制备方法 |
CN101503211A (zh) * | 2008-02-04 | 2009-08-12 | 中国科学院合肥物质科学研究院 | 二氧化钛纳米孔阵列薄膜及其制备方法 |
CN101508417A (zh) * | 2009-03-19 | 2009-08-19 | 浙江大学 | 一种双层纳米结构锐钛矿二氧化钛光电薄膜及其制备方法 |
JP2011009119A (ja) * | 2009-06-26 | 2011-01-13 | Toyo Seikan Kaisha Ltd | 色素増感型太陽電池に使用される電極 |
-
2011
- 2011-04-29 CN CN201110109638.5A patent/CN102760579B/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008115055A (ja) * | 2006-11-07 | 2008-05-22 | Electric Power Dev Co Ltd | 酸化チタン膜、酸化チタン膜電極膜構造および色素増感太陽電池 |
CN101503211A (zh) * | 2008-02-04 | 2009-08-12 | 中国科学院合肥物质科学研究院 | 二氧化钛纳米孔阵列薄膜及其制备方法 |
CN101323504A (zh) * | 2008-06-13 | 2008-12-17 | 天津大学 | 大孔-介孔纳米晶二氧化钛薄膜的制备方法 |
CN101508417A (zh) * | 2009-03-19 | 2009-08-19 | 浙江大学 | 一种双层纳米结构锐钛矿二氧化钛光电薄膜及其制备方法 |
JP2011009119A (ja) * | 2009-06-26 | 2011-01-13 | Toyo Seikan Kaisha Ltd | 色素増感型太陽電池に使用される電極 |
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CN102760579A (zh) | 2012-10-31 |
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Address after: 100190 No. two, No. 1, North Haidian District, Beijing, Zhongguancun Patentee after: Institute of Process Engineering, Chinese Academy of Sciences Patentee after: Foshan Gaoming District (Chinese Academy of Sciences) New Material Industry Research Institute Address before: 100190 No. two, No. 1, North Haidian District, Beijing, Zhongguancun Patentee before: Institute of Process Engineering, Chinese Academy of Sciences Patentee before: FOSHAN GAOMING (CAS) CENTER FOR NEW MATERIALS |
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Effective date of registration: 20230309 Address after: 100190 north two street, Zhongguancun, Haidian District, Beijing, 1 Patentee after: Institute of Process Engineering, Chinese Academy of Sciences Address before: 100190 No. two, No. 1, North Haidian District, Beijing, Zhongguancun Patentee before: Institute of Process Engineering, Chinese Academy of Sciences Patentee before: Foshan Gaoming District (Chinese Academy of Sciences) New Material Industry Research Institute |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150401 |