CN102746130B - 用于生产甲基异丁基酮的低压一步气相方法 - Google Patents

用于生产甲基异丁基酮的低压一步气相方法 Download PDF

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Publication number
CN102746130B
CN102746130B CN201110439952.XA CN201110439952A CN102746130B CN 102746130 B CN102746130 B CN 102746130B CN 201110439952 A CN201110439952 A CN 201110439952A CN 102746130 B CN102746130 B CN 102746130B
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acetone
hydrogen
pressure
reactor
gas phase
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Expired - Fee Related
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CN201110439952.XA
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Chinese (zh)
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CN102746130A (zh
Inventor
阿布杜尔拉曼·A·阿尔-拉比阿
阿卜杜拉阿齐兹·A·巴加巴斯
阿克莫多夫·瓦吉夫·莫利克
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King Abdulaziz City for Science and Technology KACST
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King Abdulaziz City for Science and Technology KACST
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/73—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6522—Chromium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201110439952.XA 2011-04-20 2011-12-23 用于生产甲基异丁基酮的低压一步气相方法 Expired - Fee Related CN102746130B (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201113091089A 2011-04-20 2011-04-20
US13/091,089 2011-04-20
US13/154,475 US8101805B2 (en) 2011-04-20 2011-06-07 Low pressure one-step gas-phase process for production of methyl isobutyl ketone
US13/154,475 2011-06-07

Publications (2)

Publication Number Publication Date
CN102746130A CN102746130A (zh) 2012-10-24
CN102746130B true CN102746130B (zh) 2015-08-26

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Country Status (4)

Country Link
US (1) US8101805B2 (enExample)
EP (1) EP2532642B1 (enExample)
JP (1) JP2012254967A (enExample)
CN (1) CN102746130B (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8858659B2 (en) 2010-02-02 2014-10-14 Celanese International Corporation Processes for producing denatured ethanol
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8101805B2 (en) * 2011-04-20 2012-01-24 King Abdulaziz City for Science and Technology (KACST) Low pressure one-step gas-phase process for production of methyl isobutyl ketone
US20130035517A1 (en) * 2011-08-03 2013-02-07 Celanese International Corporation Production of alcohols
IT201600106503A1 (it) 2016-10-21 2018-04-21 Conser Spa Piazzale Ezio Tarantelli 100 00144 Roma / It Processo di produzione di metil isobutil chetone da acetone e relativo impianto di produzione
CN108084008B (zh) * 2016-11-19 2020-10-27 中国石油化工股份有限公司 一种丙酮一步法合成甲基异丁基酮工艺的开工方法
CN106669564B (zh) * 2017-03-21 2018-09-28 河北东华舰化工有限公司 一种氯乙酸反应釜事故应急处理系统
CN110105183A (zh) * 2019-05-31 2019-08-09 宁波镇洋化工发展有限公司 丙酮一步法合成mibk装置紧急停车方法及丙酮合成mibk方法
CN112745207B (zh) * 2019-10-31 2022-08-12 中国石油化工股份有限公司 一种丙酮一步法生产甲基异丁基酮的方法
CN112745196B (zh) * 2019-10-31 2023-02-03 中国石油化工股份有限公司 丙酮制备甲基异丁基酮和异丙醇的方法及装置

Citations (5)

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US3953517A (en) * 1967-09-08 1976-04-27 Veba-Chemie Aktiengesellschaft Process for preparing methyl isobutyl ketone and catalyst
US5059724A (en) * 1988-09-02 1991-10-22 Industrial Technology Research Institute Preparation of methyl isobutyl ketone
US5495055A (en) * 1994-08-12 1996-02-27 Arco Chemical Technology, L.P. Acetone hydrogenation using a supported ruthenium catalyst
CN101712606A (zh) * 2009-11-24 2010-05-26 沈阳化工学院 丙酮联产甲基异丁基酮和二异丁基酮的工艺方法
US7951976B1 (en) * 2010-08-15 2011-05-31 King Abdulaziz City for Science and Technology (KACST) Synthesizing and utilizing novel nano crystalline zinc chromate supported nano palladium catalyst

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CH526494A (de) * 1967-09-08 1972-08-15 Veba Chemie Ag Verfahren zur Herstellung von Methylisobutylketon
GB1268518A (en) * 1968-10-12 1972-03-29 Sumitomo Chemical Co Method for production of methyl isobutyl ketone
DE2525506C2 (de) * 1975-06-07 1983-09-15 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung eines Nickel und/oder Kobalt und Zinkoxid enthaltenden Katalysators
DE2625541A1 (de) * 1976-06-05 1977-12-22 Basf Ag Verfahren zur herstellung einer zink und nickel oder kobalt enthaltenden kontaktmasse
US4163696A (en) * 1978-06-07 1979-08-07 Arthur G. Mckee & Company Distillation process for recovery of methyl isobutyl ketone
JPS61200939A (ja) * 1985-03-01 1986-09-05 コンシグリオ・ナチオナ−レ・デレ・リケルケ 高級脂肪族ケトンの一段製造方法
JPH0737410B2 (ja) * 1986-10-13 1995-04-26 三菱化学株式会社 メチルイソブチルケトンの製造方法
WO1999065851A1 (en) * 1997-06-18 1999-12-23 Catalytic Distillation Technologies Production of mibk using catalytic distillation technology
ZA200107297B (en) * 2000-09-15 2002-03-11 Catalytic Distillation Tech Production of methyl isobutyl ketone.
US6566292B2 (en) * 2001-03-27 2003-05-20 Council Of Scientific And Industrial Research Process for the enhancement of the cycle life of a zinc-chromium based catalyst in the synthesis of 2-methylpyrazine
JP4092538B2 (ja) * 2001-11-20 2008-05-28 三菱瓦斯化学株式会社 水素含有ガスの製造法
CN101351435B (zh) * 2005-12-14 2012-04-11 Sasol技术股份有限公司 用于生产提纯的甲基异丁基酮的方法和装置
BRPI0619729A2 (pt) * 2005-12-14 2011-10-11 Sasol Tech Pty Ltd método e aparelho para produção de metil isobutil cetona purificada
FR2930550B1 (fr) * 2008-04-23 2010-04-23 Rhodia Poliamida E Especialidades Ltda Procede d'optimisation de production de cetones ou aldehydes
US8101805B2 (en) * 2011-04-20 2012-01-24 King Abdulaziz City for Science and Technology (KACST) Low pressure one-step gas-phase process for production of methyl isobutyl ketone

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3953517A (en) * 1967-09-08 1976-04-27 Veba-Chemie Aktiengesellschaft Process for preparing methyl isobutyl ketone and catalyst
US5059724A (en) * 1988-09-02 1991-10-22 Industrial Technology Research Institute Preparation of methyl isobutyl ketone
US5495055A (en) * 1994-08-12 1996-02-27 Arco Chemical Technology, L.P. Acetone hydrogenation using a supported ruthenium catalyst
CN101712606A (zh) * 2009-11-24 2010-05-26 沈阳化工学院 丙酮联产甲基异丁基酮和二异丁基酮的工艺方法
US7951976B1 (en) * 2010-08-15 2011-05-31 King Abdulaziz City for Science and Technology (KACST) Synthesizing and utilizing novel nano crystalline zinc chromate supported nano palladium catalyst

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
One-step synthesis of methyl isobutyl ketone from acetone catalysedby Pd supported on ZnII–CrIII mixed oxide;Elena F. Kozhevnikova.,et al;<J of Catalysis>;20060118(第238期);286-292 *
Pd supported on ZnII–CrIII mixed oxide as a catalyst for one-step synthesis of methyl isobutyl ketone;Fahd Al-Wadaani.,et al;<J of Catalysis>;20080527(第257期);199-205 *

Also Published As

Publication number Publication date
EP2532642B1 (en) 2017-01-25
EP2532642A2 (en) 2012-12-12
CN102746130A (zh) 2012-10-24
JP2012254967A (ja) 2012-12-27
US20110237837A1 (en) 2011-09-29
EP2532642A3 (en) 2013-11-13
US8101805B2 (en) 2012-01-24

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