CN102732125A - Aqueous epoxy resin anticorrosion coating - Google Patents
Aqueous epoxy resin anticorrosion coating Download PDFInfo
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- CN102732125A CN102732125A CN2011100892950A CN201110089295A CN102732125A CN 102732125 A CN102732125 A CN 102732125A CN 2011100892950 A CN2011100892950 A CN 2011100892950A CN 201110089295 A CN201110089295 A CN 201110089295A CN 102732125 A CN102732125 A CN 102732125A
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Abstract
An aqueous epoxy resin anticorrosion coating provided in the invention is a priming paint which comprises a component A and a component B, wherein the component A comprises, by weight, 10.2-11.4 parts of deionized water, 38.6-42.5 parts of an AB-EP-20 aqueous epoxy resin emulsion, 0.08-0.7 parts of a flash-rust inhibitor, and the like; and the component B comprises, by weight, 12.5-14.9 parts of an AB-HGA aqueous epoxy resin curing agent or 16.3-18.8 parts of a Cognis751 aqueous epoxy resin curing agent. The aqueous epoxy resin anticorrosion coating of the invention can also be a finish which comprises a component A and a component B, wherein the component A comprises, by weight, 8-10 parts of deionized water, 45-50 parts of an AB-EP-20 epoxy resin emulsion, and the like; and the component B comprises, by weight, 25.4-31.2 parts of an EU5173 aqueous epoxy resin curing agent containing 50% of a solid, or 16.5-19.5 parts of the AB-HGA aqueous epoxy resin curing agent. Compared with coatings prepared through the prior art, the coating of the invention does not contain expensive materials and organic solvents, and various technical indexes of the coating of the invention are completely qualified.
Description
Technical field
What the present invention relates to is a kind of water borne epoxy resin anticorrosive paint, belongs to technical field of coatings in the chemistry.
Background technology
With the synthesising macromolecule copolymer is the coating of filmogen, is used widely in all trades and professions, and wherein anti-corrosive paint of epoxy resin becomes indispensable product in production especially.But all to spray behind the organic solvent dissolution, the volatilization of organic solvent is contaminate environment not only for traditional anti-corrosive paint of epoxy resin, and the waste resource.Therefore, the exploitation of water borne epoxy resin anticorrosive paint and popularization become a kind of inevitable trend.Chinese invention patent ZL200710185212.1 " a kind of water corrosion-resistant epoxy paint and preparation method thereof " is arranged, and wherein coating is that " be made up of A, B two components, said A component is processed by following weight unit's matter: chitin epoxy resin latex 45 ~ 50; Red iron oxide 20 ~ 22; Rust-stabilising pigment 8 ~ 10; Talcum powder 8 ~ 10; Skimmer 0.25 ~ 0.35; Flow agent 0.25 ~ 0.35; The agent 0.35 ~ 0.45 of anti-sudden strain of a muscle rust; Deionized water 8 ~ 10; Said B component is processed by following weight unit's matter: polyamide 6 50 58 ~ 62; Alcohol ether organic solvent 38 ~ 42.Though " this water borne epoxy resin anticorrosive paint is main with water-soluble, wherein used expensive chitin, and in the B group, also be to use organic solvent, so on the price and the feature of environmental protection, still have certain gap.
Summary of the invention
To above-mentioned deficiency, technical problem to be solved by this invention is in water borne epoxy resin anticorrosive paint, how to be completely free of organic solvent and to avoid the use of expensive component, and a kind of suitable water borne epoxy resin anticorrosive paint is provided.
Water borne epoxy resin anticorrosive paint provided by the invention; Divide priming paint and finish paint; Wherein priming paint is made up of A, B two components, and said A component is made up of following substances in parts by weight: deionized water 10.2 ~ 11.4, contain solid 60% AB-EP-20 aqueous epoxy resin emulsion 38.6 ~ 42.5, dispersion agent 0.5 ~ 0.8, skimmer 0.3 ~ 0.5, wetting agent 0.5 ~ 0.8, flow agent 0.3 ~ 0.4, thickening material 0.4 ~ 0.5, Rutile type Titanium Dioxide 13.6 ~ 15.3, aluminium triphosphate 10.5 ~ 12.5, process white 2.7 ~ 4.3, pigment 0.08 ~ 0.7, talcum powder 2.0 ~ 2.7, mica powder 5.5 ~ 6.6, anti-ly dodge rust agent 0.3 ~ 0.5; Said B component is made up of following substances in parts by weight: peaceful 751 aqueous epoxy resin curing agents 16.3 ~ 18.8 of AB-HGA aqueous epoxy resin curing agent 12.5 ~ 14.9 or section.
Said dispersion agent is made up of following substances in parts by weight: SN-5029 dispersion agent 0.1 ~ 0.3,3204 dispersion agents 0.1 ~ 0.3, BYK-346 dispersion agent 0.05 ~ 0.2.
Said pigment is made up of following substances in parts by weight: high-carbon black pigment 0.04 ~ 0.07, medium chrome yellow medium yellow 0.03 ~ 0.6, pthalocyanine blue 0.01 ~ 0.03.
Said skimmer is made up of following substances in parts by weight: A-10 skimmer 0.1 ~ 0.3, SN-1311 skimmer 0 ~ 0.2.
Also has aerosil 0.3 ~ 0.6 weight part in the said priming paint A component.
Water borne epoxy resin anticorrosive paint provided by the invention, said priming paint A component is made up of following substances in parts by weight: deionized water 13.38, contain solid 60% AB-EP-20 aqueous epoxy resin emulsion 42.45, SN-5029 dispersion agent 0.30,3204 dispersion agents 0.30, BYK-346 dispersion agent 0.20, A-10 skimmer 0.30, SN-1311 skimmer 0.20, PE-100 wetting agent 0.30, RM-2020 flow agent 0.40, PU-40 thickening material 0.50, Rutile type Titanium Dioxide 18.9, APW-II aluminium triphosphate 12.50, process white (400 order) 4.30, high-carbon black pigment 0.05, medium chrome yellow medium yellow 0.60,1510BS pthalocyanine blue 0.02, talcum powder (325 order) 2.70, mica powder 7.60, A-200 aerosil 0.60, anti-ly dodge rust agent 0.50; Said B component is made up of following substances in parts by weight: peaceful 751 aqueous epoxy resin curing agents 18.8 of AB-HGA aqueous epoxy resin curing agent 14.9 or section.
Water borne epoxy resin anticorrosive paint provided by the invention; Divide priming paint and finish paint; Wherein finish paint is made up of A, B two components, and said A component is made up of following substances in parts by weight: deionized water 8 ~ 10, contain solid 65% AB-EP-20 epoxy resin latex 45 ~ 50, dispersion agent 0.4 ~ 0.6, skimmer 0.1 ~ 0.3, flow agent 0.1 ~ 0.3, thickening material 0.3 ~ 0.5, Rutile type Titanium Dioxide 18 ~ 24, aluminium triphosphate 5.5 ~ 8.6, process white 1 ~ 2, organic amino 0.1 ~ 0.2, Ucar 35 0.8 ~ 1.5, alcohol ester 12 ~ 2.0; Said B component is made up of following substances in parts by weight: contain solid 50% EU5173 aqueous epoxy resin curing agent 25.4 ~ 31.2 or AB-HGA aqueous epoxy resin curing agent 16.5 ~ 19.5.
Said dispersion agent is made up of following substances in parts by weight: SN-5029 dispersion agent 0.05 ~ 0.2,3204 dispersion agents 0.05 ~ 0.2, BYK-346 dispersion agent 0.2 ~ 0.4.
Water borne epoxy resin anticorrosive paint provided by the invention, said finish paint A component is made up of following substances in parts by weight: deionized water 9.60, contain solid 65% AB-EP-20 epoxy resin latex 50.00, SN-5029 dispersion agent 0.20,3204 dispersion agents 0.10, BYK-346 dispersion agent 0.30, A-10 skimmer 0.30, RM-2020 flow agent 0.30, RM-8W thickening material 0.50, rutile-type type white titanium pigment 25.00, APW-II aluminium triphosphate 8.00, process white 2.00, organic amino 0.20, Ucar 35 1.50, alcohol ester 12; Said B component is made up of following substances in parts by weight: contain solid 50% EU5173 aqueous epoxy resin curing agent 31.2 or AB-HGA aqueous epoxy resin curing agent 19.5.
Water borne epoxy resin anticorrosive paint provided by the invention compared with prior art, does not contain expensive material and organic solvent, and visible from data shown in the following table, each item technical indicator of the present invention is qualified fully.
Embodiment
1, a kind of water borne epoxy resin anticorrosive paint divides priming paint and finish paint.
Priming paint A component is made up of following substances in parts by weight: deionized water 10.2, contain solid 60% AB-EP-20 aqueous epoxy resin emulsion 38.6, dispersion agent 0.5, skimmer 0.3, wetting agent 0.5, flow agent 0.3, thickening material 0.4, Rutile type Titanium Dioxide 13.6, aluminium triphosphate 10.5, process white 2.7, pigment 0.08, talcum powder 2.0, mica powder 5.5, anti-ly dodge rust agent 0.3; Priming paint B component is AB-HGA aqueous epoxy resin curing agent 12.5 weight parts.
Finish paint is made up of following substances in parts by weight the A component: deionized water 8, contain solid 65% AB-EP-20 epoxy resin latex 45, dispersion agent 0.4, skimmer 0.1, flow agent 0.1, thickening material 0.3, Rutile type Titanium Dioxide 18, aluminium triphosphate 5.5, process white 1, organic amino 0.1, Ucar 35 0.8, alcohol ester 12; Finish paint B component is to contain solid 50% EU5173 aqueous epoxy resin curing agent 25.4 weight parts.
2, a kind of water borne epoxy resin anticorrosive paint divides priming paint and finish paint.
Priming paint A component is made up of following substances in parts by weight: deionized water 10.6, contain solid 60% AB-EP-20 aqueous epoxy resin emulsion 40, dispersion agent 0.6, skimmer 0.4, wetting agent 0.7, flow agent 0.4, thickening material 0.5, Rutile type Titanium Dioxide 14.6, aluminium triphosphate 11.5, process white 3.5, pigment 0.5, talcum powder 2.3, mica powder 5.9, anti-ly dodge rust agent 0.4; Priming paint B component is section's peaceful 751 aqueous epoxy resin curing agents 17 weight parts.
Finish paint is made up of following substances in parts by weight the A component: deionized water 9, contain solid 65% AB-EP-20 epoxy resin latex 46, dispersion agent 0.5, skimmer 0.2, flow agent 0.2, thickening material 0.4, Rutile type Titanium Dioxide 22, aluminium triphosphate 7, process white 1.5, organic amino 0.1, Ucar 35 1.1, alcohol ester 12; Finish paint B component is AB-HGA aqueous epoxy resin curing agent 18 weight parts.
3, in last two examples in the priming paint A group dispersion agent generation to form by following substances in parts by weight: SN-5029 dispersion agent 0.2,3204 dispersion agents 0.2, BYK-346 dispersion agent 0.2.Dispersion agent is made up of following substances in parts by weight in the finish paint A group: SN-5029 dispersion agent 0.1,3204 dispersion agents 0.2, BYK-346 dispersion agent 0.2.
In pigment generation, is to be made up of following substances in parts by weight in the priming paint A group: high-carbon black pigment 0.06, medium chrome yellow medium yellow 0. 3, pthalocyanine blue 0.2.
In skimmer generation, is with A-10 skimmer 0.2 weight part in the priming paint A group.In skimmer generation, is with A-10 skimmer 0.2 weight part in the finish paint A group.
4, increase with aerosil 0.5 weight part in the priming paint A component in last three examples.
5, a kind of water borne epoxy resin anticorrosive paint divides priming paint and finish paint.
Priming paint A component is made up of following substances in parts by weight: deionized water 13.38; Contain solid 60% AB-EP-20 aqueous epoxy resin emulsion 42.45; SN-5029 dispersion agent 0.30; 3204 dispersion agents 0.30; BYK-346 dispersion agent 0.20; A-10 skimmer 0.30; SN-1311 skimmer 0.20; PE-100 wetting agent 0.30; RM-2020 flow agent 0.40; PU-40 thickening material 0.50; Rutile type Titanium Dioxide 18.9; APW-II aluminium triphosphate 12.50; Process white (400 order) 4.30; High-carbon black pigment 0.05; Medium chrome yellow medium yellow 0.60; 1510BS pthalocyanine blue 0.02; Talcum powder (325 order) 2.70; Mica powder 7.60; A-200 aerosil 0.60; The agent 0.50 of anti-sudden strain of a muscle rust; Said B component is AB-HGA aqueous epoxy resin curing agent 14.9 weight parts.
Finish paint A component is made up of following substances in parts by weight: deionized water 9.60, contain solid 65% AB-EP-20 epoxy resin latex 50.00, SN-5029 dispersion agent 0.20,3204 dispersion agents 0.10, BYK-346 dispersion agent 0.30, A-10 skimmer 0.30, RM-2020 flow agent 0.30, RM-8W thickening material 0.50, rutile-type type white titanium pigment 25.00, APW-II aluminium triphosphate 8.00, process white 2.00, organic amino 0.20, Ucar 35 1.50, alcohol ester 12; Said B component is AB-HGA aqueous epoxy resin curing agent 19.5 weight parts.
6, priming paint B group is section's peaceful 751 aqueous epoxy resin curing agents 18.8 weight parts in the last example, and finish paint B group is 50% EU5173 aqueous epoxy resin curing agent 31.2 weight parts.
Claims (9)
1. water borne epoxy resin anticorrosive paint; Divide priming paint and finish paint; It is characterized in that priming paint is made up of A, B two components, said A component is made up of following substances in parts by weight: deionized water 10.2 ~ 11.4, contain solid 60% AB-EP-20 aqueous epoxy resin emulsion 38.6 ~ 42.5, dispersion agent 0.5 ~ 0.8, skimmer 0.3 ~ 0.5, wetting agent 0.5 ~ 0.8, flow agent 0.3 ~ 0.4, thickening material 0.4 ~ 0.5, Rutile type Titanium Dioxide 13.6 ~ 15.3, aluminium triphosphate 10.5 ~ 12.5, process white 2.7 ~ 4.3, pigment 0.08 ~ 0.7, talcum powder 2.0 ~ 2.7, mica powder 5.5 ~ 6.6, anti-ly dodge rust agent 0.3 ~ 0.5; Said B component is made up of following substances in parts by weight: peaceful 751 aqueous epoxy resin curing agents 16.3 ~ 18.8 of AB-HGA aqueous epoxy resin curing agent 12.5 ~ 14.9 or section.
2. water borne epoxy resin anticorrosive paint as claimed in claim 1 is characterized in that said dispersion agent is made up of following substances in parts by weight: SN-5029 dispersion agent 0.1 ~ 0.3,3204 dispersion agents 0.1 ~ 0.3, BYK-346 dispersion agent 0.05 ~ 0.2.
3. water borne epoxy resin anticorrosive paint as claimed in claim 1 is characterized in that said pigment is made up of following substances in parts by weight: high-carbon black pigment 0.04 ~ 0.07, medium chrome yellow medium yellow 0.03 ~ 0.6, pthalocyanine blue 0.01 ~ 0.03.
4. water borne epoxy resin anticorrosive paint as claimed in claim 1 is characterized in that said skimmer is made up of following substances in parts by weight: A-10 skimmer 0.1 ~ 0.3, SN-1311 skimmer 0 ~ 0.2.
5. like claim 1 or 2 or 3 or 4 described water borne epoxy resin anticorrosive paints, it is characterized in that also having aerosil 0.3 ~ 0.6 weight part in the said priming paint A component.
6. water borne epoxy resin anticorrosive paint as claimed in claim 5 is characterized in that said priming paint A component is made up of following substances in parts by weight: deionized water 13.38, contain solid 60% AB-EP-20 aqueous epoxy resin emulsion 42.45, SN-5029 dispersion agent 0.30,3204 dispersion agents 0.30, BYK-346 dispersion agent 0.20, A-10 skimmer 0.30, SN-1311 skimmer 0.20, PE-100 wetting agent 0.30, RM-2020 flow agent 0.40, PU-40 thickening material 0.50, Rutile type Titanium Dioxide 18.9, APW-II aluminium triphosphate 12.50, process white (400 order) 4.30, high-carbon black pigment 0.05, medium chrome yellow medium yellow 0.60,1510BS pthalocyanine blue 0.02, talcum powder (325 order) 2.70, mica powder 7.60, A-200 aerosil 0.60, anti-ly dodge rust agent 0.50; Said B component is made up of following substances in parts by weight: peaceful 751 aqueous epoxy resin curing agents 18.8 of AB-HGA aqueous epoxy resin curing agent 14.9 or section.
7. water borne epoxy resin anticorrosive paint as claimed in claim 5; It is characterized in that finish paint is made up of A, B two components, said A component is made up of following substances in parts by weight: deionized water 8 ~ 10, contain solid 65% AB-EP-20 epoxy resin latex 45 ~ 50, dispersion agent 0.4 ~ 0.6, skimmer 0.1 ~ 0.3, flow agent 0.1 ~ 0.3, thickening material 0.3 ~ 0.5, Rutile type Titanium Dioxide 18 ~ 24, aluminium triphosphate 5.5 ~ 8.6, process white 1 ~ 2, organic amino 0.1 ~ 0.2, Ucar 35 0.8 ~ 1.5, alcohol ester 12 ~ 2.0; Said B component is made up of following substances in parts by weight: contain solid 50% EU5173 aqueous epoxy resin curing agent 25.4 ~ 31.2 or AB-HGA aqueous epoxy resin curing agent 16.5 ~ 19.5.
8. water borne epoxy resin anticorrosive paint as claimed in claim 7 is characterized in that said dispersion agent is made up of following substances in parts by weight: SN-5029 dispersion agent 0.05 ~ 0.2,3204 dispersion agents 0.05 ~ 0.2, BYK-346 dispersion agent 0.2 ~ 0.4.
9. water borne epoxy resin anticorrosive paint as claimed in claim 8; It is characterized in that water borne epoxy resin anticorrosive paint, said finish paint A component is made up of following substances in parts by weight: deionized water 9.60, contain solid 65% AB-EP-20 epoxy resin latex 50.00, SN-5029 dispersion agent 0.20,3204 dispersion agents 0.10, BYK-346 dispersion agent 0.30, A-10 skimmer 0.30, RM-2020 flow agent 0.30, RM-8W thickening material 0.50, rutile-type type white titanium pigment 25.00, APW-II aluminium triphosphate 8.00, process white 2.00, organic amino 0.20, Ucar 35 1.50, alcohol ester 12; Said B component is made up of following substances in parts by weight: contain solid 50% EU5173 aqueous epoxy resin curing agent 31.2 or AB-HGA aqueous epoxy resin curing agent 19.5.
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Address after: 316100 marine industrial park, Shenjiamen street, Zhoushan, Zhejiang, Putuo District Patentee after: ZHEJIANG FEIJING NEW MATERIAL TECHNOLOGY CO., LTD. Address before: 316100 marine industrial park, Shenjiamen street, Zhoushan, Zhejiang, Putuo District Patentee before: Zhejiang Feijing Paint Co., Ltd. |