CN105368215A - Environment-friendly water-based transparent matte clear finish paint and preparation method thereof - Google Patents
Environment-friendly water-based transparent matte clear finish paint and preparation method thereof Download PDFInfo
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- CN105368215A CN105368215A CN201510945734.1A CN201510945734A CN105368215A CN 105368215 A CN105368215 A CN 105368215A CN 201510945734 A CN201510945734 A CN 201510945734A CN 105368215 A CN105368215 A CN 105368215A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides environment-friendly water-based transparent matte clear finish paint. The environment-friendly water-based transparent matte clear finish paint is prepared from, by weight, 35%-50% of fluorocarbon modified acrylic emulsion, 20%-30% of styrene-acrylic emulsion, 0.3%-0.5% of wetting and dispersing agent, 1%-6% of matte powder, 4%-9% of coalescing agent, 0.3%-0.4% of thickening agent, 1%-3% of antifreezing agent, 0.3%-0.5% of anticorrosion and bactericidal agent, 0.3%-0.5% of antifoaming agent, 0.3%-0.5% of flatting agent, 0.2%-0.6% of PH modifier and 4%-16% of water. The environment-friendly water-based transparent matte clear finish paint is high in adhesive force and hardness, resistant to high temperature, good in chemical resistance, high in yellowing resistance and easy to spray, and meets the environment-friendly requirements of customers for high environment friendliness, low smells and low pollution.
Description
Technical field
The invention belongs to technical field of coatings, specifically, relate to environment-friendly water-based transparent matte varnish and preparation method thereof.
Background technology
Modern life furniture, in the life of people, is more and more paid attention to.Along with reform and opening-up is over 30 years, the prosperity development of furniture industry, wood lacquer coating supporting with it also gets a promotion further.In order to better represent the natural speciality such as texture, lines of wood furniture itself, requirement is also improved to the decoration of coating, product requirement is also proposed to the various aspects of performance such as the transparency, levelling property, planeness, guarantor's light tint retention of paint film, simultaneously to furniture transport, store, use, in servicing operations paint film easily scratch, the aspect such as wearing and tearing, it is also proposed new requirement.
Water-based matte varnish is a kind of woodenware paint vehicle of high comprehensive performance, is widely used in wood decoration, after conventional products joins paint construction, because of ordinary resin emulsion self-characteristic, degree of crosslinking cannot design too high, and hardness is difficult to rise, and snappiness also rises along with hardness and is deteriorated.
Summary of the invention
Instant invention overcomes shortcoming of the prior art, provide a kind of environment-friendly water-based transparent matte varnish and preparation method thereof, its hardness is high, long service life, caters to the demand that improve constantly of current people to furniture coating specification.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical solutions:
Environment-friendly water-based transparent matte varnish, comprises by weight percentage:
Fluorine-carbon modified ACRYLIC EMULSION 35-50%
Styrene-acrylic emulsion 20-30%
Ricinate 0.3-0.5%
Dumb light powder 1-6%
Film coalescence aid 4-9%
Thickening material 0.3-0.4%
Frostproofer 1-3%
Anticorrosion and bactericidal agent 0.3-0.5%
Defoamer 0.3-0.5%
Flow agent 0.3-0.5%
PH conditioning agent 0.2-0.6%
Water 4-16%.
Further, comprise by weight percentage:
Fluorine-carbon modified ACRYLIC EMULSION 41%
Styrene-acrylic emulsion 28%
Ricinate 0.4%
Dumb light powder 5%
Film coalescence aid 7%
Thickening material 0.35%
Frostproofer 2.5%
Anticorrosion and bactericidal agent 0.45%
Defoamer 0.4%
Flow agent 0.4%
PH conditioning agent 0.5%
Water 14%.
Further, described fluorine-carbon modified ACRYLIC EMULSION is the fluorine-carbon modified ACRYLIC EMULSION of U.S. BNK8001, and described styrene-acrylic emulsion is the one in DSM waterborne styrene-acrylic emulsion.
Further, described Ricinate is the high molecular weight block copolymer solution that BYK-190 contains pigment affinity groups.
Further, described dumb light powder is silicon-dioxide dumb light powder, is Grace C803, Degussa OK520, the one in Degussa TS100 or two kinds.
Further, described film coalescence aid is propylene glycol phenylate.
Further, described thickening material is one in TT935, PUR32 or two kinds.
Further, described frostproofer is 1,2-PD.
Further, described anticorrosion and bactericidal agent is isothiazolinone disinfecting agent ROCIMA623, and described PH conditioning agent is AMP-95PH conditioning agent.
The preparation method of described environment-friendly water-based transparent matte varnish, comprises the following steps:
A) fluorine-carbon modified ACRYLIC EMULSION and styrene-acrylic emulsion are added agitator to stir;
B) add Ricinate and defoamer again while stirring, stir 8-10min;
C) add after dumb light powder is stirred to uniform state while stirring again, carry out high speed dispersion 15-25min, make fineness be less than 25 μm;
D) continue to stir, add film coalescence aid, thickening material, frostproofer, anticorrosion and bactericidal agent, defoamer, flow agent, PH conditioning agent, then add water and be stirred to uniform state, then detect, to be detected qualified after, carry out discharging, packaging.
Compared with prior art, the invention has the beneficial effects as follows:
The environment-friendly water-based transparent matte varnish of one of the present invention, comprise by weight percentage: fluorine-carbon modified ACRYLIC EMULSION 35-50%, styrene-acrylic emulsion 20-30%, Ricinate 0.3-0.5%, dumb light powder 1-6%, film coalescence aid 4-9%, thickening material 0.3-0.4%, frostproofer 1-3%, anticorrosion and bactericidal agent 0.3-0.5%, defoamer 0.3-0.5%, flow agent 0.3-0.5%, PH conditioning agent 0.2-0.6%, water 4-16%, its strong adhesion, hardness is high, high temperature resistant, chemical resistant properties is good, high color inhibition, easy spraying, meet human consumer's high-environmental, low smell, oligosaprobic environmental requirement.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein is only for instruction and explanation of the present invention, is not intended to limit the present invention.
Embodiment 1:
The environment-friendly water-based transparent matte varnish of one of the present invention, fluorine-carbon modified ACRYLIC EMULSION 41%, styrene-acrylic emulsion 28%, Ricinate 0.4%, dumb light powder 5%, film coalescence aid 7%, thickening material 0.35%, frostproofer 2.5%, anticorrosion and bactericidal agent 0.45%, defoamer 0.4%, flow agent 0.4%, PH conditioning agent 0.5%, water 14%.
Ricinate is the high molecular weight block copolymer solution that BYK-190 contains pigment affinity groups, and dumb light powder is silicon-dioxide dumb light powder, and film coalescence aid is propylene glycol phenylate, thickening material is TT935, frostproofer is 1,2-PD, and anticorrosion and bactericidal agent is isothiazolinone disinfecting agent ROCIMA623.
The preparation method of environment-friendly water-based transparent matte varnish, comprises the following steps:
A) fluorine-carbon modified ACRYLIC EMULSION and styrene-acrylic emulsion are added agitator to stir;
B) add Ricinate and defoamer again while stirring, stir 8-10min;
C) add after dumb light powder is stirred to uniform state while stirring again, carry out high speed dispersion 15-25min, make fineness be less than 25 μm;
D) continue to stir, add film coalescence aid, thickening material, frostproofer, anticorrosion and bactericidal agent, defoamer, flow agent, PH conditioning agent, then add water and be stirred to uniform state, then detect, to be detected qualified after, carry out discharging, packaging.
Embodiment 2:
Environment-friendly water-based transparent matte varnish described in the present embodiment, fluorine-carbon modified ACRYLIC EMULSION 45%, styrene-acrylic emulsion 25%, Ricinate 0.35%, dumb light powder 6%, film coalescence aid 8%, thickening material 0.3%, frostproofer 2%, anticorrosion and bactericidal agent 0.35%, defoamer 0.35%, flow agent 0.35%, PH conditioning agent 0.3%, water 12%.
Last it is noted that these are only the preferred embodiments of the present invention; be not limited to the present invention; although with reference to embodiment to invention has been detailed description; for a person skilled in the art; it still can be modified to the technical scheme described in foregoing embodiments; or equivalent replacement is carried out to wherein portion of techniques feature; but it is within the spirit and principles in the present invention all; any amendment of doing, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. an environment-friendly water-based transparent matte varnish, is characterized in that: comprise by weight percentage:
Fluorine-carbon modified ACRYLIC EMULSION 35-50%
Styrene-acrylic emulsion 20-30%
Ricinate 0.3-0.5%
Dumb light powder 1-6%
Film coalescence aid 4-9%
Thickening material 0.3-0.4%
Frostproofer 1-3%
Anticorrosion and bactericidal agent 0.3-0.5%
Defoamer 0.3-0.5%
Flow agent 0.3-0.5%
PH conditioning agent 0.2-0.6%
Water 4-16%.
2. a kind of environment-friendly water-based transparent matte varnish according to claim 1, is characterized in that: comprise by weight percentage:
Fluorine-carbon modified ACRYLIC EMULSION 41%
Styrene-acrylic emulsion 28%
Ricinate 0.4%
Dumb light powder 5%
Film coalescence aid 7%
Thickening material 0.35%
Frostproofer 2.5%
Anticorrosion and bactericidal agent 0.45%
Defoamer 0.4%
Flow agent 0.4%
PH conditioning agent 0.5%
Water 14%.
3. a kind of environment-friendly water-based transparent matte varnish according to claim 1, it is characterized in that: described fluorine-carbon modified ACRYLIC EMULSION is the fluorine-carbon modified ACRYLIC EMULSION of U.S. BNK8001, and described styrene-acrylic emulsion is the one in DSM waterborne styrene-acrylic emulsion.
4. a kind of environment-friendly water-based transparent matte varnish according to claim 1, is characterized in that: described Ricinate is the high molecular weight block copolymer solution that BYK-190 contains pigment affinity groups.
5. a kind of environment-friendly water-based transparent matte varnish according to claim 1, it is characterized in that: described dumb light powder is silicon-dioxide dumb light powder, is Grace C803, Degussa OK520, the one in Degussa TS100 or two kinds.
6. a kind of environment-friendly water-based transparent matte varnish according to claim 1, is characterized in that: described film coalescence aid is propylene glycol phenylate.
7. a kind of environment-friendly water-based transparent matte varnish according to claim 1, is characterized in that: described thickening material is one in TT935, PUR32 or two kinds.
8. a kind of environment-friendly water-based transparent matte varnish according to claim 1, is characterized in that: described frostproofer is 1,2-PD.
9. a kind of environment-friendly water-based transparent matte varnish according to claim 1, it is characterized in that, described anticorrosion and bactericidal agent is isothiazolinone disinfecting agent ROCIMA623, and described PH conditioning agent is AMP-95PH conditioning agent.
10. a kind of preparation method of environment-friendly water-based transparent matte varnish according to any one of claim 1 to 9, is characterized in that, comprise the following steps:
A) fluorine-carbon modified ACRYLIC EMULSION and styrene-acrylic emulsion are added agitator to stir;
B) add Ricinate and defoamer again while stirring, stir 8-10min;
C) add after dumb light powder is stirred to uniform state while stirring again, carry out high speed dispersion 15-25min, make fineness be less than 25 μm;
D) continue to stir, add film coalescence aid, thickening material, frostproofer, anticorrosion and bactericidal agent, defoamer, flow agent, PH conditioning agent, then add water and be stirred to uniform state, then detect, to be detected qualified after, carry out discharging, packaging.
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| CN201510945734.1A CN105368215B (en) | 2015-12-16 | 2015-12-16 | A kind of environment-friendly water-based transparent matte varnish and preparation method thereof |
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| CN201510945734.1A CN105368215B (en) | 2015-12-16 | 2015-12-16 | A kind of environment-friendly water-based transparent matte varnish and preparation method thereof |
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| CN105368215B CN105368215B (en) | 2017-04-05 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022214A (en) * | 2017-04-18 | 2017-08-08 | 杭州迎宾松装饰材料有限公司 | A kind of matte varnish |
| CN107325611A (en) * | 2017-06-28 | 2017-11-07 | 安徽慕曼德家具有限公司 | A kind of furniture anticorrosive paint additive |
| CN107573793A (en) * | 2017-10-10 | 2018-01-12 | 佛山市三水区白坭镇巨财红木厂 | A kind of preparation method of high adhesion force mahogany furniture coating |
| CN108864850A (en) * | 2018-06-28 | 2018-11-23 | 湖南梅山轩红木家具有限公司 | Transparency protected paint and preparation method thereof for classic furniture |
| CN113512325A (en) * | 2021-04-30 | 2021-10-19 | 东莞大宝化工制品有限公司 | Water-based fluorocarbon matte coating and preparation method thereof |
| CN115960501A (en) * | 2022-11-03 | 2023-04-14 | 上海君子兰新材料股份有限公司 | Water-based door and window varnish and preparation method thereof |
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|---|---|---|---|---|
| CN101333348A (en) * | 2008-07-02 | 2008-12-31 | 大连海事大学 | Non-toxic anti-pollution paint for sea and method for preparing same |
| CN104130650A (en) * | 2014-07-25 | 2014-11-05 | 佛山市高明福隆斯新材料科技有限公司 | Environmentally-friendly white flat lacquer for furniture and preparation method thereof |
-
2015
- 2015-12-16 CN CN201510945734.1A patent/CN105368215B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333348A (en) * | 2008-07-02 | 2008-12-31 | 大连海事大学 | Non-toxic anti-pollution paint for sea and method for preparing same |
| CN104130650A (en) * | 2014-07-25 | 2014-11-05 | 佛山市高明福隆斯新材料科技有限公司 | Environmentally-friendly white flat lacquer for furniture and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022214A (en) * | 2017-04-18 | 2017-08-08 | 杭州迎宾松装饰材料有限公司 | A kind of matte varnish |
| CN107325611A (en) * | 2017-06-28 | 2017-11-07 | 安徽慕曼德家具有限公司 | A kind of furniture anticorrosive paint additive |
| CN107573793A (en) * | 2017-10-10 | 2018-01-12 | 佛山市三水区白坭镇巨财红木厂 | A kind of preparation method of high adhesion force mahogany furniture coating |
| CN108864850A (en) * | 2018-06-28 | 2018-11-23 | 湖南梅山轩红木家具有限公司 | Transparency protected paint and preparation method thereof for classic furniture |
| CN113512325A (en) * | 2021-04-30 | 2021-10-19 | 东莞大宝化工制品有限公司 | Water-based fluorocarbon matte coating and preparation method thereof |
| CN115960501A (en) * | 2022-11-03 | 2023-04-14 | 上海君子兰新材料股份有限公司 | Water-based door and window varnish and preparation method thereof |
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| CN105368215B (en) | 2017-04-05 |
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