CN105368216A - Environment-friendly water-based transparent primer and preparation method thereof - Google Patents
Environment-friendly water-based transparent primer and preparation method thereof Download PDFInfo
- Publication number
- CN105368216A CN105368216A CN201510945784.XA CN201510945784A CN105368216A CN 105368216 A CN105368216 A CN 105368216A CN 201510945784 A CN201510945784 A CN 201510945784A CN 105368216 A CN105368216 A CN 105368216A
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- water
- environment
- acrylic emulsion
- agent
- based transparent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention provides an environment-friendly water-based transparent primer. The primer is prepared from, by weight, 25-45% of fluorine-carbon modified acrylic emulsion, 15-25% of styrene-acrylic emulsion, 0.3-0.5% of wetting dispersant, 10-15% of talcum powder, 5-10% of water-based zinc stearate powder, 4-10% of a film forming auxiliary agent, 0.2-0.6% of thickener, 1-3% of an antifreezing agent, 0.3-0.6% of anticorrosion bactericide, 0.3-0.5% of a antifoaming agent, 0.3-0.5% of a flatting agent, 0.2-0.6% of a PH adjusting agent and 4-16% of water. The environment-friendly water-based transparent primer is good in color, transparency and glossiness and low in cost; a paint film of a product is short in drying time, good in transparency, high in glossiness and excellent in mechanical property; the invention further provides a preparation method of the transparent primer, the preparation method is simple in process, easy to operate and good in repeatability, and the product is short in production cycle, high in production efficiency and quite suitable for industrialized production.
Description
Technical field
The invention belongs to technical field of coatings, specifically, relate to a kind of environment-friendly water-based transparent priming and preparation method thereof.
Background technology
Along with the progress of science and technology and people are to the attention of living environment, coatings industry is moving towards environmental protection, Water-borne modification is carried out, for current overall situation, 2012, in succession issue and implement " children furniture general technical specifications ", administered regulations such as " Beijing's clean air action plan (the 2011-2015 Air Pollution Control measures) " of the industry pollutions such as furniture, strict restriction has been made to the pollutent volatilization of furniture.Can say, environment protection health has become the most basic demand that following furniture makes.
First furniture environmental protection must be material environment friendly, to volatilize most important material---furniture lacquer, being in most important status as affecting furniture pollutant.
Aqueous woodware paint, because of its less harmful and low stain, in the improvement of resource rational utilization and ecotope, has significant social benefit, the environmental consciousness that common people are more and more higher in addition, aqueous woodware paint is welcome the spring of high speed development.
But the defect that the aqueous priming paint ubiquity transparency is low, wettability is poor.
Summary of the invention
Instant invention overcomes shortcoming of the prior art, provide a kind of environment-friendly water-based transparent priming and preparation method thereof, environmental protection, firm, non-volatile, adhesion property is good, and its transparency is high, and wettability is good, applies simple and quick.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical solutions:
A kind of environment-friendly water-based transparent priming, comprises by weight percentage:
Fluorine-carbon modified ACRYLIC EMULSION 25-45%
Styrene-acrylic emulsion 15-25%
Ricinate 0.3-0.5%
Talcum powder 10-15%
Water-based zinc stearate powder 5-10%
Film coalescence aid 4-10%
Thickening material 0.2-0.6%
Frostproofer 1-3%
Anticorrosion and bactericidal agent 0.3-0.6%
Defoamer 0.3-0.5%
Flow agent 0.3-0.5%
PH conditioning agent 0.2-0.6%
Water 4-16%.
Further,
Described fluorine-carbon modified ACRYLIC EMULSION 35%
Styrene-acrylic emulsion 20%
Ricinate 0.4%
Talcum powder 12%
Water-based zinc stearate powder 8%
Film coalescence aid 8%
Thickening material 0.4%
Frostproofer 2%
Anticorrosion and bactericidal agent 0.5%
Defoamer 0.4%
Flow agent 0.4%
PH conditioning agent 0.4%
Water 12.5%.
Further, described fluorine-carbon modified ACRYLIC EMULSION is the fluorine-carbon modified ACRYLIC EMULSION of U.S. BNK8001, and described styrene-acrylic emulsion is the one in DSM waterborne styrene-acrylic emulsion.
Further, described thickening material is one in TT935, PUR32 or two kinds.
Further, described PH conditioning agent is AMP-95PH conditioning agent.
Further, described water-based zinc stearate powder is the TP800 of Dongguan Han Wei company.
Further, described film coalescence aid is propylene glycol phenylate.
Further, described defoamer is one or both the mixture in TEGO900, EFKA2022, EFKA2721, TEG0805.
Further, described flow agent is one or both the mixture in BYK323, TEG0450, BYK358.
Further, described Ricinate is the high molecular weight block copolymer masking liquid that BYK-190 contains pigment affinity groups, and described frostproofer is 1,2-PD, and described anticorrosion and bactericidal agent is isothiazolinone disinfecting agent ROCIMA623.
A preparation method for environment-friendly water-based transparent priming, comprises the following steps:
A) fluorine-carbon modified ACRYLIC EMULSION and styrene-acrylic emulsion are added agitator to stir;
B adds Ricinate and defoamer while stirring again, stirs 8-10min;
C) add water-based zinc stearate powder while stirring again, after 1250 order talcum powder are stirred to uniform state, carry out high speed dispersion 15-25min, make fineness be less than 25 μm;
D) continue to stir, add film coalescence aid, thickening material, frostproofer, anticorrosion and bactericidal agent, defoamer, flow agent, PH conditioning agent, then add water and be stirred to uniform state, then detect, to be detected qualified after, carry out discharging, packaging.
Compared with prior art, the invention has the beneficial effects as follows:
The color of a kind of environment-friendly water-based transparent priming of the present invention, transparency and glossiness are good, and cost is low; The product drying varniss time is short simultaneously, and transparency is good, and glossiness is high, and has excellent mechanical property; Present invention also offers the preparation method of described transparent priming, its technique is simple, processing ease and reproducible, and life cycle of the product is short, and production efficiency is high, is suitable for very much carrying out industrialization production.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein is only for instruction and explanation of the present invention, is not intended to limit the present invention.
Embodiment 1:
A kind of environment-friendly water-based transparent priming described in the present embodiment, comprises by weight percentage: fluorine-carbon modified ACRYLIC EMULSION 35%, styrene-acrylic emulsion 20%, Ricinate 0.4%, talcum powder 12%, water-based zinc stearate powder 8%, film coalescence aid 8%, thickening material 0.4%, frostproofer 2%, anticorrosion and bactericidal agent 0.5%, defoamer 0.4%, flow agent 0.4%, PH conditioning agent 0.4%, water 12.5%.
Fluorine-carbon modified ACRYLIC EMULSION is the fluorine-carbon modified ACRYLIC EMULSION of U.S. BNK8001, and styrene-acrylic emulsion is the one in DSM waterborne styrene-acrylic emulsion.
Thickening material is TT935.
PH conditioning agent is AMP-95PH conditioning agent.
Film coalescence aid is propylene glycol phenylate.
Water-based zinc stearate powder is the TP800 of Dongguan Han Wei company.
Defoamer is TEGO900.
Flow agent is BYK323.
Ricinate is the high molecular weight block copolymer masking liquid that BYK-190 contains pigment affinity groups, and frostproofer is 1,2-PD, and anticorrosion and bactericidal agent is isothiazolinone disinfecting agent ROCIMA623.
A preparation method for environment-friendly water-based transparent priming, comprises the following steps:
A) fluorine-carbon modified ACRYLIC EMULSION and styrene-acrylic emulsion are added agitator to stir;
B adds Ricinate and defoamer while stirring again, stirs 8-10min;
C) add after 1250 order talcum powder are stirred to uniform state while stirring again, carry out high speed dispersion 15-25min, make fineness be less than 25 μm;
D) continue to stir, add water-based zinc stearate, film coalescence aid, thickening material, frostproofer, anticorrosion and bactericidal agent, defoamer, flow agent, PH conditioning agent, then add water and be stirred to uniform state, then detect, to be detected qualified after, carry out discharging, packaging.
Embodiment 2:
A kind of environment-friendly water-based transparent priming described in the present embodiment, comprises by weight percentage: fluorine-carbon modified ACRYLIC EMULSION 40%, styrene-acrylic emulsion 22%, Ricinate 0.35%, talcum powder 14%, water-based zinc stearate powder 6%, film coalescence aid 7%, thickening material 0.5%, frostproofer 2.5%, anticorrosion and bactericidal agent 0.45%, defoamer 0.35%, flow agent 0.35%, PH conditioning agent 0.5%, water 6%.
Last it is noted that these are only the preferred embodiments of the present invention; be not limited to the present invention; although with reference to embodiment to invention has been detailed description; for a person skilled in the art; it still can be modified to the technical scheme described in foregoing embodiments; or equivalent replacement is carried out to wherein portion of techniques feature; but it is within the spirit and principles in the present invention all; any amendment of doing, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. an environment-friendly water-based transparent priming, is characterized in that, comprises by weight percentage:
Fluorine-carbon modified ACRYLIC EMULSION 25-45%
Styrene-acrylic emulsion 15-25%
Ricinate 0.3-0.5%
Talcum powder 10-15%
Water-based zinc stearate powder 5-10%
Film coalescence aid 4-10%
Thickening material 0.2-0.6%
Frostproofer 1-3%
Anticorrosion and bactericidal agent 0.3-0.6%
Defoamer 0.3-0.5%
Flow agent 0.3-0.5%
PH conditioning agent 0.2-0.6%
Water 4-16%.
2. a kind of environment-friendly water-based transparent priming according to claim 1, is characterized in that,
Described fluorine-carbon modified ACRYLIC EMULSION 35%
Styrene-acrylic emulsion 20%
Ricinate 0.4%
Talcum powder 12%
Water-based zinc stearate powder 8%
Film coalescence aid 8%
Thickening material 0.4%
Frostproofer 2%
Anticorrosion and bactericidal agent 0.5%
Defoamer 0.4%
Flow agent 0.4%
PH conditioning agent 0.4%
Water 12.5%.
3. a kind of environment-friendly water-based transparent priming according to claim 1, it is characterized in that, described fluorine-carbon modified ACRYLIC EMULSION is the fluorine-carbon modified ACRYLIC EMULSION of U.S. BNK8001, and described styrene-acrylic emulsion is the one in DSM waterborne styrene-acrylic emulsion.
4. a kind of environment-friendly water-based transparent priming according to claim 1, is characterized in that, described thickening material is one in TT935, PUR32 or two kinds.
5. a kind of environment-friendly water-based transparent priming according to claim 1, it is characterized in that, described water-based zinc stearate powder is the TP800 of Dongguan Han Wei company.
6. a kind of environment-friendly water-based transparent priming according to claim 1, it is characterized in that, described PH conditioning agent is AMP-95PH conditioning agent, and described film coalescence aid is propylene glycol phenylate.
7. a kind of environment-friendly water-based transparent priming according to claim 1, it is characterized in that, described defoamer is one or both the mixture in TEGO900, EFKA2022, EFKA2721, TEG0805.
8. a kind of environment-friendly water-based transparent priming according to claim 1, it is characterized in that, described flow agent is one or both the mixture in BYK323, TEG0450, BYK358.
9. a kind of environment-friendly water-based transparent priming according to claim 1, it is characterized in that, described Ricinate is the high molecular weight block copolymer masking liquid that BYK-190 contains pigment affinity groups, and described frostproofer is 1,2-propylene glycol, described anticorrosion and bactericidal agent is isothiazolinone disinfecting agent ROCIMA623.
10. a kind of preparation method of environment-friendly water-based transparent priming according to any one of claim 1 to 9, is characterized in that, comprise the following steps:
A) fluorine-carbon modified ACRYLIC EMULSION and styrene-acrylic emulsion are added agitator to stir;
B) add Ricinate and defoamer again while stirring, stir 8-10min;
C) add water-based zinc stearate powder while stirring again, after 1250 order talcum powder are stirred to uniform state, carry out high speed dispersion 15-25min, make fineness be less than 25 μm;
D) continue to stir, add film coalescence aid, thickening material, frostproofer, anticorrosion and bactericidal agent, defoamer, flow agent, PH conditioning agent, then add water and be stirred to uniform state, then detect, to be detected qualified after, carry out discharging, packaging.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510945784.XA CN105368216B (en) | 2015-12-16 | 2015-12-16 | A kind of environment-friendly water-based transparent priming and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510945784.XA CN105368216B (en) | 2015-12-16 | 2015-12-16 | A kind of environment-friendly water-based transparent priming and preparation method thereof |
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| CN105368216A true CN105368216A (en) | 2016-03-02 |
| CN105368216B CN105368216B (en) | 2017-04-05 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106967364A (en) * | 2017-04-19 | 2017-07-21 | 东莞市泰发化工有限公司 | A kind of new-type waterborne edge sealing priming paint |
| CN110700526A (en) * | 2019-10-16 | 2020-01-17 | 江苏久诺建材科技股份有限公司 | Construction method for spraying stone-like paint on dry hanging plate surface of outer wall |
| CN112795246A (en) * | 2021-01-15 | 2021-05-14 | 湖州和悦新材料科技股份有限公司 | Water-based fluorocarbon outdoor paint and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333348A (en) * | 2008-07-02 | 2008-12-31 | 大连海事大学 | Non-toxic anti-pollution paint for sea and method for preparing same |
| CN103450751A (en) * | 2013-08-22 | 2013-12-18 | 吴江市物华五金制品有限公司 | Antibacterial wet-wiping-resistant interior wall coating |
-
2015
- 2015-12-16 CN CN201510945784.XA patent/CN105368216B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333348A (en) * | 2008-07-02 | 2008-12-31 | 大连海事大学 | Non-toxic anti-pollution paint for sea and method for preparing same |
| CN103450751A (en) * | 2013-08-22 | 2013-12-18 | 吴江市物华五金制品有限公司 | Antibacterial wet-wiping-resistant interior wall coating |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106967364A (en) * | 2017-04-19 | 2017-07-21 | 东莞市泰发化工有限公司 | A kind of new-type waterborne edge sealing priming paint |
| CN110700526A (en) * | 2019-10-16 | 2020-01-17 | 江苏久诺建材科技股份有限公司 | Construction method for spraying stone-like paint on dry hanging plate surface of outer wall |
| CN112795246A (en) * | 2021-01-15 | 2021-05-14 | 湖州和悦新材料科技股份有限公司 | Water-based fluorocarbon outdoor paint and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN105368216B (en) | 2017-04-05 |
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