CN102665897A - 具有接近优化位点的多金属催化剂的制备方法 - Google Patents

具有接近优化位点的多金属催化剂的制备方法 Download PDF

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Publication number
CN102665897A
CN102665897A CN2010800301225A CN201080030122A CN102665897A CN 102665897 A CN102665897 A CN 102665897A CN 2010800301225 A CN2010800301225 A CN 2010800301225A CN 201080030122 A CN201080030122 A CN 201080030122A CN 102665897 A CN102665897 A CN 102665897A
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China
Prior art keywords
preparation
catalyst
tin
phosphorus
metal
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CN2010800301225A
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English (en)
Chinese (zh)
Inventor
P.阿维尼尔
S.拉科贝
H.考弗里滋
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to CN201610819884.2A priority Critical patent/CN106423226B/zh
Publication of CN102665897A publication Critical patent/CN102665897A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6445—Antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1856—Phosphorus; Compounds thereof with iron group metals or platinum group metals with platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/24—Chlorinating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN2010800301225A 2009-07-01 2010-06-15 具有接近优化位点的多金属催化剂的制备方法 Pending CN102665897A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610819884.2A CN106423226B (zh) 2009-07-01 2010-06-15 具有接近优化位点的多金属催化剂的制备方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0903226A FR2947465B1 (fr) 2009-07-01 2009-07-01 Catalyseur multi-metallique presentant une proximite de sites optimisee
FR09/03.226 2009-07-01
PCT/FR2010/000443 WO2011012776A2 (fr) 2009-07-01 2010-06-15 Procede de preparation d'un catalyseur multi-métallique présentant une proximité de sites optimisée

Related Child Applications (1)

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CN201610819884.2A Division CN106423226B (zh) 2009-07-01 2010-06-15 具有接近优化位点的多金属催化剂的制备方法

Publications (1)

Publication Number Publication Date
CN102665897A true CN102665897A (zh) 2012-09-12

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CN2010800301225A Pending CN102665897A (zh) 2009-07-01 2010-06-15 具有接近优化位点的多金属催化剂的制备方法
CN201610819884.2A Active CN106423226B (zh) 2009-07-01 2010-06-15 具有接近优化位点的多金属催化剂的制备方法

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Country Link
US (2) US20120178979A1 (https=)
EP (1) EP2448670B1 (https=)
JP (1) JP5615917B2 (https=)
CN (2) CN102665897A (https=)
DK (1) DK2448670T3 (https=)
FR (1) FR2947465B1 (https=)
RU (1) RU2535206C2 (https=)
WO (1) WO2011012776A2 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104841425A (zh) * 2014-02-18 2015-08-19 中国石油化工股份有限公司 一种半再生催化重整催化剂及其制备方法
CN108040472A (zh) * 2015-07-24 2018-05-15 Ifp 新能源公司 掺杂有磷和镧系元素的多金属催化剂
CN111372680A (zh) * 2017-11-30 2020-07-03 Ifp 新能源公司 用磷和镱掺杂的多金属催化剂

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150133291A1 (en) * 2012-05-08 2015-05-14 Stc.Unm Hydrothermal Stability of Oxides With Carbon Coatings
FR3120076A1 (fr) 2021-02-22 2022-08-26 IFP Energies Nouvelles Procédé de production de composés aromatiques et/ou d’essences à partir d’une charge hydrocarbonée de type naphta
FR3123230A1 (fr) 2021-05-28 2022-12-02 IFP Energies Nouvelles Procédé de traitement à régénération continue de catalyseur d’une charge hydrocarbonée
FR3156335A1 (fr) * 2023-12-06 2025-06-13 Axens Catalyseur de reformage catalytique ayant une acidite optimisee

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4416804A (en) * 1981-11-23 1983-11-22 Uop Inc. Acidic multimetallic catalytic composite
US4522935A (en) * 1983-06-02 1985-06-11 Uop Inc. Platinum and indium-containing catalyst for reforming hydrocarbons
CN1655868A (zh) * 2002-05-22 2005-08-17 国际壳牌研究有限公司 含铋和磷的催化剂载体、由其制备的重整催化剂、其制备方法和石脑油重整方法
WO2008087273A2 (fr) * 2006-12-22 2008-07-24 Ifp Catalyseur bimetallique ou multi-metallique presentant un indice de bimetallicite et une capacite d'adsorption d'hydrogene optimises

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2814599A (en) 1953-04-17 1957-11-26 Kellogg M W Co Group iii metal compound promoted platinum or palladium catalyst
US2890167A (en) 1953-11-16 1959-06-09 Universal Oil Prod Co Conversion process using a phosphoruscontaining platinum group metal catalyst
US3706815A (en) 1971-05-24 1972-12-19 Union Oil Co Chelated metal-polyphosphoric acid catalysts,method of preparation and isomerization process utilizing the same
US4016068A (en) * 1974-06-21 1977-04-05 Uop Inc. Catalytic reforming with an activated bimetallic catalytic composite
US4367137A (en) 1980-12-04 1983-01-04 Uop Inc. Hydrocarbon conversion with an acidic multimetallic catalytic composite
US4426279A (en) 1981-11-23 1984-01-17 Uop Inc. Reforming hydrocarbons with a platinum group- and phosphorus-containing catalyst
US4463104A (en) 1981-11-23 1984-07-31 Uop Inc. Platinum group and phosphorus containing catalyst composition for hydrocarbon conversion
US4487848A (en) * 1983-06-02 1984-12-11 Uop Inc. Indium-containing catalyst for reforming hydrocarbons
US5858908A (en) * 1997-04-17 1999-01-12 Uop Llc Selective multimetallic-multigradient reforming catalyst
CN1384175A (zh) * 2001-04-28 2002-12-11 中国石油化工股份有限公司 含铂、锡的多金属重整催化剂及其制备与应用
RU2004137503A (ru) * 2002-05-22 2005-05-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Висмут- и фосфорсодержащие катализаторы риформинга, способ их приготовления и способ риформинга нефти
FR2840548B1 (fr) 2002-06-07 2005-03-18 Inst Francais Du Petrole Lit homogene de catalyseur et procede de transformation d'hydrocarbures en composes aromatiques avec ledit lit
US20070215523A1 (en) * 2002-12-10 2007-09-20 Moser Mark D Dilute phosphorus incorporation into a naphtha reforming catalyst
CN100338189C (zh) * 2004-05-14 2007-09-19 中国石油化工股份有限公司 一种铂、锡系重整催化剂的制备方法
US7449423B2 (en) * 2005-01-14 2008-11-11 Headwaters Technology Innovation, Llc Heat treatment of anchored nanocatalysts in a non-zero oxidation state and catalysts made by such method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4416804A (en) * 1981-11-23 1983-11-22 Uop Inc. Acidic multimetallic catalytic composite
US4522935A (en) * 1983-06-02 1985-06-11 Uop Inc. Platinum and indium-containing catalyst for reforming hydrocarbons
CN1655868A (zh) * 2002-05-22 2005-08-17 国际壳牌研究有限公司 含铋和磷的催化剂载体、由其制备的重整催化剂、其制备方法和石脑油重整方法
WO2008087273A2 (fr) * 2006-12-22 2008-07-24 Ifp Catalyseur bimetallique ou multi-metallique presentant un indice de bimetallicite et une capacite d'adsorption d'hydrogene optimises

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104841425A (zh) * 2014-02-18 2015-08-19 中国石油化工股份有限公司 一种半再生催化重整催化剂及其制备方法
CN108040472A (zh) * 2015-07-24 2018-05-15 Ifp 新能源公司 掺杂有磷和镧系元素的多金属催化剂
CN108040472B (zh) * 2015-07-24 2021-06-11 Ifp 新能源公司 掺杂有磷和镧系元素的多金属催化剂
CN111372680A (zh) * 2017-11-30 2020-07-03 Ifp 新能源公司 用磷和镱掺杂的多金属催化剂

Also Published As

Publication number Publication date
JP5615917B2 (ja) 2014-10-29
RU2535206C2 (ru) 2014-12-10
DK2448670T3 (en) 2016-01-11
FR2947465A1 (fr) 2011-01-07
EP2448670A2 (fr) 2012-05-09
CN106423226B (zh) 2022-09-27
WO2011012776A3 (fr) 2011-11-17
US20120178979A1 (en) 2012-07-12
JP2012531306A (ja) 2012-12-10
CN106423226A (zh) 2017-02-22
US20170252726A1 (en) 2017-09-07
FR2947465B1 (fr) 2012-05-11
EP2448670B1 (fr) 2015-09-23
WO2011012776A2 (fr) 2011-02-03
RU2012103328A (ru) 2013-08-10

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