CN102644094B - 一种熔盐电解制备Al-Mg-Tb三元合金的方法 - Google Patents
一种熔盐电解制备Al-Mg-Tb三元合金的方法 Download PDFInfo
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- CN102644094B CN102644094B CN201210122563.9A CN201210122563A CN102644094B CN 102644094 B CN102644094 B CN 102644094B CN 201210122563 A CN201210122563 A CN 201210122563A CN 102644094 B CN102644094 B CN 102644094B
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- electrolysis
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- ternary alloy
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- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 50
- 229910002058 ternary alloy Inorganic materials 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims abstract description 22
- 150000003839 salts Chemical class 0.000 title claims abstract description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 30
- 229910052751 metal Inorganic materials 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims abstract description 18
- 229910052771 Terbium Inorganic materials 0.000 claims abstract description 16
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 15
- 239000011780 sodium chloride Substances 0.000 claims abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 13
- 239000010439 graphite Substances 0.000 claims abstract description 13
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 12
- 239000011733 molybdenum Substances 0.000 claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 7
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 4
- 229910016569 AlF 3 Inorganic materials 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- GWYXTVGANSBRNB-UHFFFAOYSA-N terbium(iii) oxide Chemical compound O=[Tb]O[Tb]=O GWYXTVGANSBRNB-UHFFFAOYSA-N 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 11
- 239000004411 aluminium Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 abstract description 25
- 239000000956 alloy Substances 0.000 abstract description 25
- 239000011777 magnesium Substances 0.000 abstract description 14
- 229910052749 magnesium Inorganic materials 0.000 abstract description 13
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 12
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 abstract description 8
- 150000002910 rare earth metals Chemical class 0.000 abstract description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 abstract 2
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 2
- 239000001103 potassium chloride Substances 0.000 abstract 2
- 230000007547 defect Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229910003451 terbium oxide Inorganic materials 0.000 abstract 1
- SCRZPWWVSXWCMC-UHFFFAOYSA-N terbium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Tb+3].[Tb+3] SCRZPWWVSXWCMC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 description 9
- 239000010431 corundum Substances 0.000 description 9
- 230000018044 dehydration Effects 0.000 description 9
- 238000006297 dehydration reaction Methods 0.000 description 9
- -1 aluminium-magnesium rare earth Chemical class 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910018134 Al-Mg Inorganic materials 0.000 description 3
- 229910018467 Al—Mg Inorganic materials 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 3
- 229910001371 Er alloy Inorganic materials 0.000 description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910000765 intermetallic Inorganic materials 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 229910000861 Mg alloy Inorganic materials 0.000 description 2
- 229910001122 Mischmetal Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 229910000905 alloy phase Inorganic materials 0.000 description 2
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910001051 Magnalium Inorganic materials 0.000 description 1
- WLLURKMCNUGIRG-UHFFFAOYSA-N alumane;cerium Chemical compound [AlH3].[Ce] WLLURKMCNUGIRG-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 229910021652 non-ferrous alloy Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
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- Electrolytic Production Of Metals (AREA)
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CN102644094B true CN102644094B (zh) | 2014-08-06 |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN102912382B (zh) * | 2012-10-26 | 2015-09-30 | 哈尔滨工程大学 | 一种在氟氯化物熔盐体系中电解制备铝-镁合金的方法 |
CN102995067B (zh) * | 2012-10-30 | 2015-09-30 | 哈尔滨工程大学 | 一种熔盐电解制备铝镁钕合金的方法 |
CN103060852B (zh) * | 2013-01-18 | 2015-02-25 | 哈尔滨工程大学 | 一种熔盐电解制备Mg-Mn-La三元合金的方法 |
CN103132108B (zh) * | 2013-03-14 | 2015-05-27 | 哈尔滨工程大学 | 熔盐体系中电解制备耐热镁铝钕合金的方法 |
CN109440150B (zh) * | 2018-12-10 | 2021-01-29 | 沈阳大学 | 一种室温电沉积制备铝镁镧合金膜的方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101285143A (zh) * | 2008-05-30 | 2008-10-15 | 哈尔滨工程大学 | 一种熔盐电解制备镁锂镝合金的方法 |
CN101302593A (zh) * | 2008-06-04 | 2008-11-12 | 哈尔滨工程大学 | 镁锂钬合金、镁锂钬合金的熔盐电解制备方法及装置 |
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CN101285143A (zh) * | 2008-05-30 | 2008-10-15 | 哈尔滨工程大学 | 一种熔盐电解制备镁锂镝合金的方法 |
CN101302593A (zh) * | 2008-06-04 | 2008-11-12 | 哈尔滨工程大学 | 镁锂钬合金、镁锂钬合金的熔盐电解制备方法及装置 |
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