CN102633576A - Soil nutrient protective agent for preventing harm of acid rain - Google Patents

Soil nutrient protective agent for preventing harm of acid rain Download PDF

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CN102633576A
CN102633576A CN2012101293000A CN201210129300A CN102633576A CN 102633576 A CN102633576 A CN 102633576A CN 2012101293000 A CN2012101293000 A CN 2012101293000A CN 201210129300 A CN201210129300 A CN 201210129300A CN 102633576 A CN102633576 A CN 102633576A
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soil
acid rain
soil nutrient
protective agent
acid
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CN102633576B (en
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伊力塔
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Zhejiang A&F University ZAFU
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Abstract

The invention relates to a soil nutrient protective agent for preventing harm of acid rain, and belongs to the technical field of environmental protection. The soil nutrient protective agent comprises 53-78% of natural alkalescent water, 11-25% of nutrients, 6-17% of synergistic ingredients and 2-8% of penetrants. The soil nutrient protective agent for preventing harm of acid rain can improve yield and quality of crops and nursery stock, can provide nutrients for and improve soil, can improve fertilizer efficiency of the soil, can promote virtuous cycle of nutrient elements and can prevent phenomena such as soil hardening, nutrient elements loss and the like, thereby especially being applicable to be sprayed on soil at plant roots. When the soil nutrient protective agent is in use, the nutrients are uniformly released and are unlikely to run away; a plant can obtain effective supplement of the nutrients during the whole growing process; and at the same time, acidity of the acid rain is neutralized, so as to greatly reduce the damage on the soil by the acid rain, so that the plant can grow vigorously, and has a developed root system, luxuriant leaves and completely filled fruits. Obvious effects can be obtained if the protective agent is used over a long term. The soil nutrient protective agent provided by the invention has the characteristics of wide application range, simple processing method and low raw material cost, and is easy and convenient to store and transport and safe to use.

Description

A kind of soil nutrient protective material of anti-acid rain harm
Technical field
The invention belongs to environmental protection technical field, be specially a kind of soil nutrient protective material of anti-acid rain harm.
Background technology
Acid rain is current outstanding global environment problem, and is very big to the harm of the mankind and living environment.Usually call " acid rain " to the pH value less than the Atmospheric precipitation that 5.6 sleet or other modes form, " acid rain " correct title should be " acid deposition ", and it can be divided into " dry deposition " and " wet deposition " two big classes.When not raining, the atmosphere middle acid substance can be arrived ground " dry deposition " by vegetation absorption or gravity settling; When raining, the high-altitude raindrop absorb to comprise and wash away acidic substance when acidic substance are fallen then again and drop to ground " wet deposition ".The staple of acid precipitation middle acid substance is a sulfuric acid, nitric acid and hydrochloric acid.
Acid rain all brings for ball ecological environment and human social economy and seriously influences and destroy.It all brings serious harm to places of cultural interest such as soil, water body, forest, building, the scenic spots and historical sites, not only causes heavy economic losses, more jeopardizes human survival and development.Acid rain can make soil generation physicochemical property change.One of influence be acid rain land infiltrate soil after, make soil acidification, destroy the trophic structure of soil.Acid rain comes out plant nutrient drip washing from soil; Particularly positively charged ions such as Ca, Mg, Fe lose rapidly; So secular acid rain can make nutritive elements a large amount of in the soil by leaching loss; Cause the wretched insufficiency of nutritive element in the soil, thereby make soil become barren, influence the g and D of plant.Two of influence is landing of excessive acid rain; Cause the ability drop of soil microorganisms decomposing organic matter, influence effects such as the ammonification of soil microorganisms, nitrated, fixed nitrogen, the nitrogen that directly suppresses to be participated in by mikrobe decomposes, assimilation, with fixing; The final soil nutrient deliverability that reduces; Influencing the Nutrition and Metabolism of plant. acid rain accumulates the influence of soil, and soil also has certain surge capability to acid deposition, so after the several years, just the soil acidification phenomenon can occur.In addition, acid rain also produces remote effect to HUMAN HEALTH.Acid rain is washed away the poisonous metal in the soil and brings river, lake into, makes drinking water source contaminated on the one hand; On the other hand, these deleterious heavy metals such as mercury, lead, cadmium can deposit in the fish body, and the mankind are injured because of edible; Can bring out cancer and senile dementia, once more, the agricultural land soil acidifying; Make the harmful heavy metal that originally is secured in the soil mineralization thing, like mercury, cadmium, lead etc., stripping again; Then be grain, vegetables absorb and enrichment, poison and fall ill in human picked-up back.In a word, acid rain brings for ball ecological environment and seriously influences and destroy with human social economy, and many toxic substances are by the root absorption of plant; Poison root system; Kill root hair cell, make plant can not from soil, absorb moisture and nutrient, suppress growth, the growth of plant.Acid rain makes the river, and the water acidification in lake suppresses hydrobiological growth, breeding, even causes fry death by suffocation; Acid rain also kills the planktonic organism in the water, reduces the fish food source, makes aquatic ecosystem disorderly; Acid rain pollution river, lake and underground water, directly or indirectly harm humans is healthy.Acid rain directly injures through the drip washing to plant surface or through the soil consequential injury, acid rain is also lured the disease and pest outburst into, causes forest large stretch of dead.Acid rain has very strong corrosive nature to metal, building stones, timber, cement constructional material, and existing a lot of ancient buildings in the world and art of stone carving article are destroyed by acid rain.
From China's long term monitoring, the occurrence scope of acid precipitation has expansion trend.China's acid rain mainly is distributed in the areas to the south, the Changjiang river, just in time overlaps with the acid soil range of distribution, causes some places to occur soil acidification, nutrient leaching, phenomenon such as fertility descends, and vegetation is withered.Under field conditions (factors), soil extremely is difficult to reverse after the acidifying, if the acidifying of soil big area, consequence is with hardly imaginable.At present, aspect control acid rain, the biologist utilizes microbial desulfurization, has obtained good effect.The principle that how to meet in the future " watershed management " and " cleaner production " is explored a kind of promising treatment technology and the product that prevent acid rain harm, more and more receives the attention of countries in the world.
Summary of the invention
To the problems referred to above that exist in the prior art; The objective of the invention is to design the protectant technical scheme of soil nutrient that a kind of anti-acid rain harm is provided; It can effectively prevent soil acidification; The improve the soil loss of trophic structure, prevention soil mineral nutritive element reduces crop leaf look chlorosis or pigment and changes, and prevents that acid rain from destroying the crop cell homergy and causing too early fallen leaves.
The soil nutrient protective material of described a kind of anti-acid rain harm is characterized in that containing natural weak base water 53-78%, nutritive ingredient 11-25%, synergistic component 6-17%, permeate agent 2-8%; Described nutritive ingredient is one or more mixtures that have in urea, an ammonium nitrate, potassium primary phosphate, humate, saltpetre, manganous sulfate, sal epsom, sucrose, ammonium molybdate, nitrocalcite, copper sulfate, borax, boric acid, the Sodium orthomolybdate; Described synergistic component is one or more mixtures in methyl piperidine, VITMAIN B1, Wei ShengsuB2, Plant hormones regulators,gibberellins, phytokinin, vitamins C, jasmine acid esters, choline dichloride, yellow soda ash, maleic hydrazide, whole property element, ethephon, ammoniacal liquor, PP-333, the rare earth nitrate, and described permeate agent is one or more mixtures among azone, thionamic acid sodium, the alkali-resistant penetrant OEP-70.
The soil nutrient protective material of described a kind of anti-acid rain harm is characterized in that the content of natural weak base water is 55-75%, is preferably 59-72%.
The soil nutrient protective material of described a kind of anti-acid rain harm is characterized in that the content of nutritive ingredient is 13-23%, is preferably 15-20%.
The soil nutrient protective material of described a kind of anti-acid rain harm is characterized in that the content of synergistic component is 8-16%, is preferably 9-15%.
The soil nutrient protective material of described a kind of anti-acid rain harm is characterized in that the content of permeate agent is 3-7%, is preferably 4-6%.
The soil nutrient protective material of described a kind of anti-acid rain harm is characterized in that nutrition and protects soil to avoid acid rain destruction, improves the application in soil fertilizer efficiency and crop yield and the quality.
Described natural weak base water can be by directly buying on the market.
The soil nutrient protective material of above-mentioned a kind of anti-acid rain harm; Has the yield and quality that improves farm crop and nursery stock; Simultaneously its can nutrition, improve the soil, improve the soil fertilizer efficiency; Can promote the benign cycle of nutritive element, can keep soil from packing together and phenomenon such as nutritive element loss, be specially adapted to be sprayed on plant root soil and use.Support part even release in the use, be difficult for running off, in the plant whole growth process, can both obtain effectively supporting part replenishing; Neutralized the simultaneously acidity of acid rain has significantly reduced the destruction of acid rain to soil, makes the plant growing way vigorous; Well developed root system; The blade face is luxuriant, completely filled fruit, and the life-time service effect is remarkable.Its use range is wider, simple and convenient processing method, and raw materials cost is low, stores and transports easy, safe in utilization.
The percentage composition that relates in the present specification unless otherwise indicated, other the weight percentage that is pure substance.
Embodiment
Combine the embodiments of the invention and the test of pesticide effectiveness at present, further specify beneficial effect of the present invention.
Embodiment 1
In the 500L reaction kettle, drop into the natural weak base water of 295kg; Slowly drop into 20kg urea, 10kg an ammonium nitrate, 10kg potassium primary phosphate, 10kg humate, 10kg saltpetre, 10kg manganous sulfate, 10kg sal epsom, 10kg sucrose and 10kg Sodium orthomolybdate again; Stir; Drop into 5kg VITMAIN B1,5kg Wei ShengsuB2,5kg phytokinin, 5kg vitamins C, 5kg jasmine acid esters, 5kg choline dichloride, 5kg yellow soda ash, 5kg maleic hydrazide, the whole property element of 5kg, 5kg ethephon, 10kg ammoniacal liquor, 10kg PP-333 and 5kg rare earth nitrate again, stir, drop into 15kg azone and 15kg thionamic acid sodium at last; Mix all with, stirring half a hour the finished product.
Embodiment 2
In the 500L reaction kettle, drop into the natural weak base water of 360kg; Slowly drop into 7.5kg saltpetre, 7.5kg manganous sulfate, 7.5kg sal epsom, 7.5kg sucrose, 7.5kg ammonium molybdate, 7.5kg nitrocalcite, 7.5kg copper sulfate, 7.5kg borax, 7.5kg boric acid and 7.5kg Sodium orthomolybdate again; Stir; Drop into 2kg methyl piperidine, 5kg Plant hormones regulators,gibberellins, 5kg phytokinin, 5kg vitamins C, 3kg jasmine acid esters, 3kg choline dichloride, 3kg yellow soda ash, 3kg maleic hydrazide, the whole property element of 3kg, 3kg ethephon, 5kg ammoniacal liquor, 3kg PP-333 and 2kg rare earth nitrate again, stir, drop into the 20kg azone at last; Mix all with, stirring half a hour the finished product.
Embodiment 3
In the 500L reaction kettle, drop into the natural weak base water of 348kg; Slowly drop into 9kg urea, 9kg an ammonium nitrate, 9kg potassium primary phosphate, 9kg ammonium molybdate, 9kg nitrocalcite, 9kg copper sulfate, 9kg borax, 9kg boric acid and 8kg Sodium orthomolybdate again; Stir; Drop into 2kg methyl piperidine, 2kg VITMAIN B1,2kg Wei ShengsuB2,2kg Plant hormones regulators,gibberellins, 2kg phytokinin, 5kg jasmine acid esters, 5kg choline dichloride, 5kg yellow soda ash, 5kg maleic hydrazide, the whole property element of 3kg, 3kg ethephon, 3kg ammoniacal liquor, 3kg PP-333 and 8kg rare earth nitrate again; Stir; Drop into 11kg thionamic acid sodium and 11kg alkali-resistant penetrant OEP-70 at last, mix all with, stirring half a hour the finished product.
Embodiment 4
In the 500L reaction kettle, drop into the natural weak base water of 328kg; Slowly drop into 8.5kg urea, 8.5kg an ammonium nitrate, 8.5kg potassium primary phosphate, 8.5kg humate, 8.5kg sucrose, 8.5kg ammonium molybdate, 8.5kg nitrocalcite, 8.5kg copper sulfate, 8.5kg borax and 8.5kg Sodium orthomolybdate again; Stir; Drop into 5kg Plant hormones regulators,gibberellins, 5kg phytokinin, 5kg vitamins C, 5kg jasmine acid esters, 5kg choline dichloride, 5kg yellow soda ash, 5kg maleic hydrazide, the whole property element of 5kg, 5kg ethephon, 5kg ammoniacal liquor, 5kg PP-333 and 5kg rare earth nitrate again, stir, drop into 27kg thionamic acid sodium at last; Mix all with, stirring half a hour the finished product.
Embodiment 5
In the 500L reaction kettle, drop into the natural weak base water of 320kg; Slowly drop into 8kg urea, 8kg an ammonium nitrate, 8kg potassium primary phosphate, 8kg humate, 8kg saltpetre, 8kg manganous sulfate, 8kg sal epsom, 8kg sucrose, 8kg ammonium molybdate, 8kg nitrocalcite, 2.5kg copper sulfate, 2.5kg borax, 2.5kg boric acid and 2.5kg Sodium orthomolybdate again; Stir; Drop into 4kg methyl piperidine, 4kg VITMAIN B1,4kg Wei ShengsuB2,4kg Plant hormones regulators,gibberellins, 4kg phytokinin, 5kg vitamins C, 5kg jasmine acid esters, 5kg choline dichloride, 5kg yellow soda ash, 10kg ammoniacal liquor, 10kg PP-333 and 5kg rare earth nitrate again; Stir; Drop into 25kg alkali-resistant penetrant OEP-70 at last, mix all with, stirring half a hour the finished product.
Embodiment 6
In the 500L reaction kettle, drop into the natural weak base water of 306kg; Slowly drop into 10kg urea, 10kg an ammonium nitrate, 10kg potassium primary phosphate, 10kg humate, 10kg saltpetre, 10kg sucrose, 10kg ammonium molybdate, 10kg borax and 15kg Sodium orthomolybdate again; Stir; Drop into 6kg methyl piperidine, 6kg VITMAIN B1,6kg Wei ShengsuB2,6kg Plant hormones regulators,gibberellins, 6kg phytokinin, 5kg vitamins C, 5kg jasmine acid esters, 5kg choline dichloride, 5kg yellow soda ash, 10kg maleic hydrazide, the whole property element of 3kg, 3kg ethephon and 4kg rare earth nitrate again; Stir; Drop into 19kg thionamic acid sodium and 10kg alkali-resistant penetrant OEP-70 at last, mix all with, stirring half a hour the finished product.
Embodiment 7
In the 500L reaction kettle, drop into the natural weak base water of 319kg; Slowly drop into 9.8kg urea, 9.8kg potassium primary phosphate, 9.8kg manganous sulfate, 9.8kg sal epsom, 9.8kg sucrose, 9.8kg ammonium molybdate, 9.8kg nitrocalcite, 9.8kg copper sulfate, 9.8kg borax and 9.8kg boric acid again; Stir; Drop into 5kg methyl piperidine, 5kg VITMAIN B1,5kg Wei ShengsuB2,5kg Plant hormones regulators,gibberellins, 5kg vitamins C, 5kg jasmine acid esters, 5kg yellow soda ash, 5kg maleic hydrazide, the whole property element of 5kg, 5kg ethephon and 5kg ammoniacal liquor again, stir, drop into 8kg azone and 20kg alkali-resistant penetrant OEP-70 at last; Mix all with, stirring half a hour the finished product.
Embodiment 8
In the 500L reaction kettle, drop into the natural weak base water of 355kg; Slowly drop into 7.7kg an ammonium nitrate, 7.7kg potassium primary phosphate, 7.7kg humate, 7.7kg saltpetre, 7.7kg manganous sulfate, 7.7kg sal epsom, 7.7kg ammonium molybdate, 7.7kg nitrocalcite, 7.7kg copper sulfate and 7.7kg Sodium orthomolybdate again; Stir; Drop into 7kg methyl piperidine, 4kg VITMAIN B1,4kg Plant hormones regulators,gibberellins, 4kg phytokinin, 4kg jasmine acid esters, 4kg choline dichloride, 4kg yellow soda ash, 4kg maleic hydrazide, the whole property element of 4kg, 4kg PP-333 and 4kg rare earth nitrate again; Stir; Drop into 7kg azone, 7kg thionamic acid sodium and 7kg alkali-resistant penetrant OEP-70 at last, mix all with, stirring half a hour the finished product.
Below through the protectant drug effect of the test above-mentioned soil nutrient of explanation.
Figure 251599DEST_PATH_IMAGE001
Table 1 shows: embodiment 1-8 is to red bayberry, mulberries, and the single fruit weight average of oranges and tangerines has gaining effect preferably, and embodiment 1 is superior to embodiment 2, and embodiment 4 is superior to embodiment 3, and embodiment 5 is superior to embodiment 6, embodiment, 8 are superior to embodiment 7.
The test effect that table 2 embodiment 1-8 grows corn jointing stage root growth (spraying is handled)
Handle Lateral root quantity (bar) Root system fresh weight (g)
Embodiment 1 29 21.6
Embodiment 2 30 25.3
Embodiment 3 28 22.1
Embodiment 4 27 21.4
Embodiment 5 31 24.7
Embodiment 6 28 21.6
Embodiment 7 26 20.5
Embodiment 8 28 22.8
CK (clear water) 16 15.7
Table 2 shows: embodiment 1-8 grows corn jointing stage root growth and all has facilitation effect preferably, and embodiment 2 is superior to embodiment 1, and embodiment 3 is superior to embodiment 4, and embodiment 5 is superior to embodiment 6, and embodiment 8 is superior to embodiment 7.
Table 3 embodiment 1-8 is to the quality test result (spraying is handled) of apple
Handle Edible rate (%) Pericarp thick (cm) Soluble solid (%) Total reducing sugar (%)
Embodiment 1 89.63 0.09 11.5 14.66
Embodiment 2 88.15 0.07 12.4 13.73
Embodiment 3 87.37 0.07 12.1 13.95
Embodiment 4 88.12 0.09 11.8 14.33
Embodiment 5 87.92 0.10 11.2 12.67
Embodiment 6 85.98 0.08 12.6 12.58
Embodiment 7 87.35 0.06 11.3 13.21
Embodiment 8 88.64 0.08 11.6 13.56
CK (clear water) 71.26 0.15 15.8 10.33
Table 3 shows: embodiment 1-8 all has synergistic effect preferably to apple quality, and embodiment 1 is superior to embodiment 2, and embodiment 4 is superior to embodiment 3, and embodiment 5 is superior to embodiment 6, and embodiment 8 is superior to embodiment 7.

Claims (5)

1. the soil nutrient protective material of an anti-acid rain harm is characterized in that containing the following material of weight percentage: natural weak base water 53-78%, nutritive ingredient 11-25%, synergistic component 6-17%, permeate agent 2-8%; Described nutritive ingredient is one or more mixtures that have in urea, an ammonium nitrate, potassium primary phosphate, humate, saltpetre, manganous sulfate, sal epsom, sucrose, ammonium molybdate, nitrocalcite, copper sulfate, borax, boric acid, the Sodium orthomolybdate; Described synergistic component is one or more mixtures in methyl piperidine, VITMAIN B1, Wei ShengsuB2, Plant hormones regulators,gibberellins, phytokinin, vitamins C, jasmine acid esters, choline dichloride, yellow soda ash, maleic hydrazide, whole property element, ethephon, ammoniacal liquor, PP-333, the rare earth nitrate, and described permeate agent is one or more mixtures among azone, thionamic acid sodium, the alkali-resistant penetrant OEP-70.
2. like the soil nutrient protective material of right 1 described a kind of anti-acid rain harm, it is characterized in that the content of natural weak base water is 55-75%, be preferably 59-72%.
3. like the soil nutrient protective material of right 1 described a kind of anti-acid rain harm, it is characterized in that the content of nutritive ingredient is 13-23%, be preferably 15-20%.
4. like the soil nutrient protective material of right 1 described a kind of anti-acid rain harm, it is characterized in that the content of synergistic component is 8-16%, be preferably 9-15%.
5. like the soil nutrient protective material of right 1 described a kind of anti-acid rain harm, it is characterized in that the content of permeate agent is 3-7%, be preferably 4-6%.
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CN102823587A (en) * 2012-09-05 2012-12-19 浙江省柑桔研究所 Safe degradation liquid for residue paclobutrazol in red bayberry plant bodies and use method of safe degradation liquid
CN103026820A (en) * 2013-01-06 2013-04-10 诸卫平 Application of folium isatidis decoction in neutralizing acidity of acid rain as well as improving and treating acidified soil
CN105061094A (en) * 2015-09-09 2015-11-18 四川国光农化股份有限公司 Pesticide and fertilizer composition as well as application and preparation thereof
CN105315063A (en) * 2014-08-19 2016-02-10 杨凌德尔生物科技有限公司 Vitamin multifunctional water-soluble fertilizer
CN105638269A (en) * 2016-01-07 2016-06-08 南京农业大学 Soybean acid rain reliever, application thereof and method for increasing soybean yield under stress of acid rain
CN106007993A (en) * 2016-05-27 2016-10-12 安徽云锦农业科技发展有限公司 Seedling coated fertilizer capable of resisting acid rain erosion
CN107162729A (en) * 2017-05-25 2017-09-15 兰溪市沉默生物科技有限公司 A kind of soil conditioner for improving plant survival rate and preparation method thereof
CN114456005A (en) * 2022-02-23 2022-05-10 兴安盟博源化学有限公司 Special humic acid foliar fertilizer for rice as well as preparation method and use method thereof

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CN102823587A (en) * 2012-09-05 2012-12-19 浙江省柑桔研究所 Safe degradation liquid for residue paclobutrazol in red bayberry plant bodies and use method of safe degradation liquid
CN103026820A (en) * 2013-01-06 2013-04-10 诸卫平 Application of folium isatidis decoction in neutralizing acidity of acid rain as well as improving and treating acidified soil
CN103026820B (en) * 2013-01-06 2015-01-21 诸卫平 Application of folium isatidis decoction in neutralizing acidity of acid rain as well as improving and treating acidified soil
CN105315063A (en) * 2014-08-19 2016-02-10 杨凌德尔生物科技有限公司 Vitamin multifunctional water-soluble fertilizer
CN105061094A (en) * 2015-09-09 2015-11-18 四川国光农化股份有限公司 Pesticide and fertilizer composition as well as application and preparation thereof
CN105061094B (en) * 2015-09-09 2018-05-11 四川国光农化股份有限公司 A kind of medicine fertilizer composition and its application, preparation
CN105638269A (en) * 2016-01-07 2016-06-08 南京农业大学 Soybean acid rain reliever, application thereof and method for increasing soybean yield under stress of acid rain
CN106007993A (en) * 2016-05-27 2016-10-12 安徽云锦农业科技发展有限公司 Seedling coated fertilizer capable of resisting acid rain erosion
CN107162729A (en) * 2017-05-25 2017-09-15 兰溪市沉默生物科技有限公司 A kind of soil conditioner for improving plant survival rate and preparation method thereof
CN114456005A (en) * 2022-02-23 2022-05-10 兴安盟博源化学有限公司 Special humic acid foliar fertilizer for rice as well as preparation method and use method thereof

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