A kind of agricultural bactericidal agent and preparation method thereof
Technical field
The invention belongs to bactericidal agent technical field, be specifically related to a kind of agricultural bactericidal agent and preparation method thereof.
Background technology
Present agricultural bactericidal agent major part is all sterilization pesticide, as organic phosphorus type disinfectant: kitazine, Ppyrazophos etc.; As organic sulfurcontaining fungicide: captan, folpet are first-class; As substituted beneze-group fungicides: thiophanate-methyl, metalaxyl, Wakil, Seedvax etc.; As heterocyclic nitrogen-group fungicide: triazolone, propiconazole, Isoprothiolane etc.; As antibiotics bactericide (containing medical): blasticidin-S, chloramphenicol etc., exist or fungicidal spectrum single, or easily develop immunity to drugs, or the shortcoming such as healing of focus is slow, sterilization effect is poor, and mostly poisonous, environment is had to pollution, harmful to people and animals, therefore, applying in agricultural production is all undesirable, and agricultural plant protection is in the urgent need to a kind of efficient, safe bactericide.
Summary of the invention
The present invention, for solving the problems of the prior art, provides a kind of agricultural bactericidal agent and preparation method thereof, and the bactericidal agent of the inventive method system is efficient, safety, and can not make virus, bacterium, fungi produce drug resistance.
For solving the problems of the technologies described above, the present invention is achieved by the following technical solutions:
An agricultural bactericidal agent, it comprises following material component by weight: oxidative disinfectant 20~60, extension agent 1~20, mould inhibitor 20~50, filler 10~30.
Described oxidative disinfectant is the calcium hypochlorite of sodium method production, a kind of or its mixture in sodium dichloro cyanurate; Described extension agent is a kind of or its mixture in the poly-trisiloxanes (silicone powder) of solid ethyoxyl modification, lauryl sodium sulfate; Described mould inhibitor is a kind of or its mixture in IPBC (IPBC), four hydration eight Boratexes, and described filler is a kind of or its mixture in anhydrous sodium sulfate, anhydrous magnesium sulfate, anhydrous magnesium chloride.
Preferably, described a kind of agricultural bactericidal agent, it comprises following material component by weight:
Oxidative disinfectant 30~50, extension agent 3~10, mould inhibitor 25~40, filler 15~25.
Preferably, described a kind of agricultural bactericidal agent, it comprises following material component by weight: the calcium hypochlorite 45 that sodium method is produced, the modification of solid ethyoxyl gathers trisiloxanes 7, four hydration eight Boratexes 28, anhydrous sodium sulfate 20.
The preparation method of above-mentioned a kind of agricultural bactericidal agent, it comprises the following steps:
By formula ratio, first take oxidative disinfectant, join in blender, then add formula ratio filler, mix, and then add mould inhibitor and the extension agent of formula ratio, mix, packing obtains product of the present invention.
Preferably, a kind of preparation method of agricultural bactericidal agent, the order number 20~80 of described oxidative disinfectant, extension agent, mould inhibitor; The order number of described filler is 80~120.
The present invention selects calcium hypochlorite that sodium method produces and sodium dichloro cyanurate as a oxidizing disinfect, they are a kind of efficient, wide spectrum, novel systemic bactericide, there is the extremely strong effect of killing livestock, they can produce hypochlorous acid in water, destroy the cell wall of bacterium, the permeability of cell membrane of bacterium is strengthened.Now, hypochlorous acid spreads rapidly, enters in bacterial body, with bacterioprotein, nucleic acid, enzyme etc., oxidation reaction occurs, thereby kills bacterium.Chlorion also can change the osmotic pressure of cell, makes cell inactivation and death.When 20ppm, sterilizing rate reaches 99.5%.Can kill various bacteriums, algae, fungi and germ, without pesticide resistance.
The present invention selects IPBC (IPBC), four hydration eight Boratexes as mould inhibitor, they are compounds of a kind of efficient killing fungus, germ, there is broad spectrum antibiotic activity, especially various moulds, saccharomycete are had to very strong inhibitory or killing effect, have higher-security.
The present invention has added filler, has guaranteed that product is stable, can not lump.
The present invention also adds extension agent, makes the product can be even when spraying, and has penetration, has avoided local concentration excessive, and plant is produced to poisoning.
Product of the present invention is done to accelerated stability test (accelerated stability test condition is: 37 ℃ of temperature, humidity 75%, 90 days time), its effective content rate of descent is less than 10%, result of the test shows, product stability of the present invention is higher, and the shelf-life was over 2 years.
The present invention compared with prior art has following significant advantage:
(1) oxidative disinfectant bactericide sterilizing wide spectrum, efficient, safety.
(2) can not develop immunity to drugs.
(3) environmental protection, basic noresidue, harmless.
(4) make simply, cheap.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further details:
An agricultural bactericidal agent, it comprises following material component by weight: oxidative disinfectant 20~60, extension agent 1~20, mould inhibitor 20~50, filler 10~30.
Described oxidative disinfectant is the calcium hypochlorite of sodium method production, a kind of or its mixture in sodium dichloro cyanurate; Described extension agent is a kind of or its mixture in the poly-trisiloxanes (silicone powder) of solid ethyoxyl modification, lauryl sodium sulfate; Described mould inhibitor is a kind of or its mixture in IPBC (IPBC), four hydration eight Boratexes, and described filler is a kind of or its mixture in anhydrous sodium sulfate, anhydrous magnesium sulfate, anhydrous magnesium chloride.
Preferably, described a kind of agricultural bactericidal agent, it comprises following material component by weight: oxidative disinfectant 30~50, extension agent 3~10, mould inhibitor 25~40, filler 15~25.
Preferably, described a kind of agricultural bactericidal agent, it comprises following material component by weight: the calcium hypochlorite 45 that sodium method is produced, the modification of solid ethyoxyl gathers trisiloxanes 7, four hydration eight Boratexes 28, anhydrous sodium sulfate 20.
The preparation method of above-mentioned a kind of agricultural bactericidal agent, it comprises the following steps:
By formula ratio, first take oxidative disinfectant, join in blender, then add formula ratio filler, mix, and then add mould inhibitor and the extension agent of formula ratio, mix, packing obtains product of the present invention.
Preferably, a kind of preparation method of agricultural bactericidal agent, described oxidative disinfectant, extension agent, mould inhibitor, order number 20~80; The order number of described filler is 80~120.
This product in use, can add 10~30g product in 15kg water according to actual conditions, mixes, and sprays, and when disease is serious, can use by dosage.
Embodiment 1
The calcium hypochlorite 45kg that sodium method is produced
The modification of solid ethyoxyl gathers trisiloxanes 7kg
Four hydration eight Boratex 28kg
Anhydrous sodium sulfate 20kg
Embodiment 2
The calcium hypochlorite 30kg that sodium method is produced
Lauryl sodium sulfate 4kg
Four hydration eight Boratex 25kg
Anhydrous magnesium sulfate 15kg
Embodiment 3
Sodium dichloro cyanurate 50kg
The modification of solid ethyoxyl gathers trisiloxanes 10kg
IPBC 38kg
Anhydrous sodium sulfate 25kg
Embodiment 4
The calcium hypochlorite 21kg that sodium method is produced
Lauryl sodium sulfate 2kg
Four hydration eight Boratex 21kg
Anhydrous magnesium sulfate 11kg
Embodiment 5
Sodium dichloro cyanurate 60kg
The modification of solid ethyoxyl gathers trisiloxanes 19kg
IPBC 48kg
Anhydrous magnesium chloride 28kg
Embodiment 6
The calcium hypochlorite 40kg that sodium method is produced
The modification of solid ethyoxyl gathers trisiloxanes 6kg
Four hydration eight Boratex 30kg
Anhydrous sodium sulfate 22kg
Embodiment 7
The calcium hypochlorite 35kg that sodium method is produced
Lauryl sodium sulfate 8kg
Four hydration eight Boratex 27kg
Anhydrous sodium sulfate 18kg
It should be noted that, protection scope of the present invention is not limited to the embodiment of foregoing description, and technical solution of the present invention can be carried out the allotment of various ratios according to actual needs, with the various conversion of equivalence of the present invention all among protection scope of the present invention.