CN101946798A - Binary natural chlorine dioxide disinfectant and preparation method thereof - Google Patents
Binary natural chlorine dioxide disinfectant and preparation method thereof Download PDFInfo
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- CN101946798A CN101946798A CN2010105014820A CN201010501482A CN101946798A CN 101946798 A CN101946798 A CN 101946798A CN 2010105014820 A CN2010105014820 A CN 2010105014820A CN 201010501482 A CN201010501482 A CN 201010501482A CN 101946798 A CN101946798 A CN 101946798A
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Abstract
The invention belongs to the technical field of disinfectant, particularly relating to a binary natural chlorine dioxide disinfectant and a preparation method thereof. The technical scheme is that the binary natural chlorine dioxide disinfectant comprises binary package component A and binary package component B, wherein, the binary package component A comprises the following components in parts by weight: 0.5-50 parts of chlorine dioxide parent, 0-15 parts of corrosion inhibitor and 0-15 parts of surfactant; and the binary package component B comprises the following components in parts by weight: 0.5-20 parts of excitant, 0.5-50 parts of neutral oxidant and 0.5-15 parts of synergist. The invention is beneficial to storage and transportation, is convenient to use and has low corrosivity.
Description
Technical field
The invention belongs to the disinfectant technical field, be specifically related to a kind of two yuan of neutral disinfection agent of chlorine dioxide and preparation method thereof.
Background technology
Chlorine dioxide be approve in the world the 4th generation disinfectant, classified as A1 level wide spectrum, efficient and safe disinfectant by the World Health Organization and the World Food Programme, have strong sterilization, sterilization, discoloration.Along with the success of chlorine dioxide exploitation and development, many industrialization developed country has carried out extensive studies and popularization to it.At present, the application of chlorine dioxide relates to industries such as water treatment, medical treatment, health, food processing, breed, papermaking, and it has a extensive future.
Chinese patent CA101176469A has proposed a chlorine dioxide generation structure that contains two yuan of packings of sodium chlorite and hydrochloric acid, change that packing has been avoided direct contact of chlorine dioxide matrix and activator and the problem that influences conversion ratio for its two yuan, but the activator of this system is a liquid hydrochloric acid, it is bigger that liquid takies volume, transportation, use inconvenience.
Chinese patent CN1238130A discloses a kind of preparation method of powdered CLO 2 disinfectant, the fabrication material package is drawn together sodium chlorite, solid acidifier and passivator, this preparation method's deficiency is the adding that does not relate to synergist, will the conversion ratio of chlorine dioxide in the reaction system be descended.
Chinese patent CN101124913A discloses a kind of preparation method of solid state one-element chlorine dioxide disinfectant, its disinfectant is made up of sodium chlorite, sodium peroxydisulfate, solid organic acid and solid filler, in this system because organic acid causes the chlorine dioxide disinfection liquid pH value that forms low a large amount of the adding, perishable metal.
Summary of the invention
The present invention is for solving the problems of the prior art, and a kind of storage, transportation and two yuan of neutral disinfection agent of chlorine dioxide easy to use and preparation method thereof are provided.
The present invention is achieved by the following technical solutions:
A kind of two yuan of neutral disinfection agent of chlorine dioxide, it comprises that two yuan are changed packing A component and B component, described A component comprises chlorine dioxide matrix 0.5～50, corrosion inhibiter 0～15, surfactant 0～15 by weight; Described B component comprises exciting agent 0.5～20, neutral oxidant 0.5～50, synergist 0.5～15 by weight.
Described chlorine dioxide matrix is a kind of or its mixture in sodium chlorite, potassium chlorite, magnesium chlorite, the barium chlorite; Described corrosion inhibiter is a kind of or its mixture in potassium chloride, potassium nitrate, sodium nitrate, sodium silicate, sodium molybdate, the sodium phosphate trimer; Described surfactant is a kind of or its mixture in lauryl sodium sulfate, neopelex, the poly-trisiloxanes powder of ethyoxyl modification; Described exciting agent is that citric acid, boric acid, tartaric acid, oxalic acid, hydrogen sulfate are received, a kind of or its mixture in the potassium acid sulfate; Described neutral oxidant is a kind of or its mixture in sodium peroxydisulfate, the potassium peroxydisulfate; Described synergist is a kind of or its mixture in sodium dichloro cyanurate, dichlord isocyanurice acid, calcium hypochlorite, the lithium hypochlorite.
Preferably, described two yuan of neutral disinfection agent of chlorine dioxide, described A component is made up of the material of following parts by weight: chlorine dioxide matrix 10～40, corrosion inhibiter 3～10, surfactant 3～10; Described B component is made up of the material of following parts by weight: exciting agent 2～15, neutral oxidant 10～50, synergist 2～12.
Preferably, described two yuan of neutral disinfection agent of chlorine dioxide, described A component is made up of the material of following parts by weight: sodium chlorite 30, sodium nitrate 6, dodecylphosphoric acid sodium 5; Described B component is made up of the material of following parts by weight: citric acid 5, sodium peroxydisulfate 35, sodium dichloro cyanurate 6.
A kind of method for preparing two yuan of above-mentioned neutral disinfection agent of chlorine dioxide, specifically it may further comprise the steps:
A. take by weighing chlorine dioxide matrix, corrosion inhibiter, surfactant by formula ratio, mix, obtain the A component.
B. take by weighing exciting agent, neutral oxidant, synergist by formula ratio, mix, obtain the B component.
C. with the ratio packing in 1: 1 of A component and B component, A component that branch is installed and B component package and get final product.
The present invention compared with prior art has following significant advantage:
The present invention selects for use neutral oxidant persulfate and sodium chlorite reaction generation chlorine dioxide to prepare chlorine dioxide disinfection liquid, and adding exciting agent and synergist, can make persulfate and sodium chlorite fast reaction, reaction conversion ratio is improved, and the chlorine dioxide disinfection liquid that reaction generates is near neutral, and the corrosion inhibiter that adds, reduced the corrosivity of disinfectant greatly, also added surfactant in the prescription, can reduce surface tension, the raising penetration of solution, with the chlorine dioxide disinfection liquid Synergistic.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
A kind of two yuan of neutral disinfection agent of chlorine dioxide of the present invention, it comprises that two yuan are changed packing A component and B component, described A component comprises chlorine dioxide matrix 0.5～50, corrosion inhibiter 0～15, surfactant 0～15 by weight; Described B component comprises exciting agent 0.5～20, neutral oxidant 0.5～50, synergist 0.5～15 by weight; Described chlorine dioxide matrix is a kind of or its mixture in sodium chlorite, potassium chlorite, magnesium chlorite, the barium chlorite; Described corrosion inhibiter is a kind of or its mixture in potassium chloride, potassium nitrate, sodium nitrate, sodium silicate, sodium molybdate, the sodium phosphate trimer; Described surfactant is a kind of or its mixture in lauryl sodium sulfate, neopelex, the poly-trisiloxanes powder of ethyoxyl modification; Described exciting agent is that citric acid, boric acid, tartaric acid, oxalic acid, hydrogen sulfate are received, a kind of or its mixture in the potassium acid sulfate; Described neutral oxidant is a kind of or its mixture in sodium peroxydisulfate, the potassium peroxydisulfate; Described synergist is a kind of or its mixture in sodium dichloro cyanurate, dichlord isocyanurice acid, calcium hypochlorite, the lithium hypochlorite.
Two yuan of above-mentioned neutral disinfection agent of chlorine dioxide, described A component is made up of the material of following parts by weight: chlorine dioxide matrix 10～40, corrosion inhibiter 3～10, surfactant 3～10; Described B component is made up of the material of following parts by weight: exciting agent 2～15, neutral oxidant 10～50, synergist 2～12.
Prepare the method for described two yuan of neutral disinfection agent of chlorine dioxide, it may further comprise the steps:
A. take by weighing chlorine dioxide matrix, corrosion inhibiter, surfactant by formula ratio, mix, obtain the A component.
B. take by weighing exciting agent, neutral oxidant, synergist by formula ratio, mix, obtain the B component.
C. with the ratio packing in 1: 1 of A component and B component, A component that branch is installed and B component package and get final product.
Manufacturing process: take by weighing chlorine dioxide matrix, corrosion inhibiter, surfactant by formula ratio, mix, packing in proportion obtains the A component; Take by weighing exciting agent, neutral oxidant, synergist by formula ratio, mix, packing in proportion obtains the B component, and the A component and the B component that then branch are installed package.
Embodiment 1
The A component contains sodium chlorite 30kg, sodium nitrate 6kg, lauryl sodium sulfate 5kg; The B component contains citric acid 5kg, sodium peroxydisulfate 35kg, sodium dichloro cyanurate 6kg.
Embodiment 2
The A component contains magnesium chlorite 10kg, sodium silicate 3kg, neopelex 8kg; The B component contains tartaric acid 10kg, potassium peroxydisulfate 10kg, calcium hypochlorite 2kg.
Embodiment 3
The A component contains potassium chlorite 40kg, potassium chloride 12kg, dodecylphosphoric acid sodium 5kg; The B component contains hydrogen sulfate and receives 15kg, sodium peroxydisulfate 45kg, lithium hypochlorite 12kg.
Claims (4)
1. two yuan of neutral disinfection agent of chlorine dioxide is characterized in that it comprises that two yuan are changed packing A component and B component, and described A component comprises chlorine dioxide matrix 0.5～50, corrosion inhibiter 0～15, surfactant 0～15 by weight; Described B component comprises exciting agent 0.5～20, neutral oxidant 0.5～50, synergist 0.5～15 by weight;
Described chlorine dioxide matrix is a kind of or its mixture in sodium chlorite, potassium chlorite, magnesium chlorite, the barium chlorite; Described corrosion inhibiter is a kind of or its mixture in potassium chloride, potassium nitrate, sodium nitrate, sodium silicate, sodium molybdate, the sodium phosphate trimer; Described surfactant is a kind of or its mixture in lauryl sodium sulfate, neopelex, the poly-trisiloxanes powder of ethyoxyl modification; Described exciting agent is that citric acid, boric acid, tartaric acid, oxalic acid, hydrogen sulfate are received, a kind of or its mixture in the potassium acid sulfate; Described neutral oxidant is a kind of or its mixture in sodium peroxydisulfate, the potassium peroxydisulfate; Described synergist is a kind of or its mixture in sodium dichloro cyanurate, dichlord isocyanurice acid, calcium hypochlorite, the lithium hypochlorite.
2. two yuan of neutral disinfection agent of chlorine dioxide as claimed in claim 1 is characterized in that, described A component is made up of the material of following parts by weight: chlorine dioxide matrix 10～40, corrosion inhibiter 3～10, surfactant 3～10; Described B component is made up of the material of following parts by weight: exciting agent 2～15, neutral oxidant 10～50, synergist 2～12.
3. two yuan of neutral disinfection agent of chlorine dioxide as claimed in claim 1 is characterized in that, described A component is made up of the material of following parts by weight: sodium chlorite 30, sodium nitrate 6, dodecylphosphoric acid sodium 5; Described B component is made up of the material of following parts by weight: citric acid 5, sodium peroxydisulfate 35, sodium dichloro cyanurate 6.
4. method for preparing claim 1 or 2 or 3 described two yuan of neutral disinfection agent of chlorine dioxide is characterized in that it may further comprise the steps:
A. take by weighing chlorine dioxide matrix, corrosion inhibiter, surfactant by formula ratio, mix, obtain the A component;
B. take by weighing exciting agent, neutral oxidant, synergist by formula ratio, mix, obtain the B component;
C. with the ratio packing in 1: 1 of A component and B component, A component that branch is installed and B component package and get final product.
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| CN2010105014820A CN101946798A (en) | 2010-10-11 | 2010-10-11 | Binary natural chlorine dioxide disinfectant and preparation method thereof |
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| CN2010105014820A CN101946798A (en) | 2010-10-11 | 2010-10-11 | Binary natural chlorine dioxide disinfectant and preparation method thereof |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102250600A (en) * | 2011-05-06 | 2011-11-23 | 河北科技大学 | Composite block remover for removing polymer blockage of oilfields |
| CN102283246A (en) * | 2011-05-30 | 2011-12-21 | 石家庄科大绿源科技发展有限公司 | Solid chlorine dioxide effervescent tablet and preparation method thereof |
| CN102318644A (en) * | 2011-06-09 | 2012-01-18 | 中国科学院化学研究所 | Method for preparing material slowly releasing chlorine dioxide and application thereof |
| CN102379309A (en) * | 2011-07-27 | 2012-03-21 | 中北大学 | Binary-packaged reactive chlorine dioxide tablet and preparation method thereof |
| CN102613240A (en) * | 2012-03-12 | 2012-08-01 | 河北科技大学 | Agricultural bactericidal agent and preparation method thereof |
| CN102960365A (en) * | 2011-12-31 | 2013-03-13 | 邵鹏飞 | Electrolyzed oxidizing sterilizing water with low corrosiveness and preparation method thereof |
| CN103875709A (en) * | 2014-04-01 | 2014-06-25 | 青岛市中心医院 | Swimming pool sterilizing agent and preparation method thereof |
| CN104585232A (en) * | 2015-01-28 | 2015-05-06 | 威海百克环保工程有限公司 | Compound disinfection powder for disinfecting hospital and aquaculture wastewater |
| CN105191979A (en) * | 2014-06-10 | 2015-12-30 | 李菠 | Powder for oxidizing and infecting drinking water and preparation method thereof |
| CN105668730A (en) * | 2016-03-22 | 2016-06-15 | 江苏祥豪实业有限公司 | Novel chlorine dioxide material for treating water and method for preparing novel chlorine dioxide material |
| CN106675797A (en) * | 2016-12-26 | 2017-05-17 | 李心 | Chlorine-containing compound disinfectant detergent and preparation method thereof |
| CN108211754A (en) * | 2018-02-02 | 2018-06-29 | 环境保护部华南环境科学研究所 | A kind of flue gas pollutant absorbent and its application |
| CN108849968A (en) * | 2018-04-23 | 2018-11-23 | 开封联昌药业有限公司 | Chlorine dioxide binary liquid disinfectant and preparation method thereof |
| CN110684605A (en) * | 2019-11-18 | 2020-01-14 | 青岛立见诊断技术发展中心 | Nucleic acid remover |
| CN111264518A (en) * | 2020-03-23 | 2020-06-12 | 郑吉宏 | Chlorine dioxide composition with bactericidal effect |
| CN111298178A (en) * | 2020-03-03 | 2020-06-19 | 江苏龙蟠科技股份有限公司 | Chlorine dioxide refrigerator bacteriostatic deodorant and preparation method thereof |
| CN111466406A (en) * | 2020-04-29 | 2020-07-31 | 北京青鸿福科技有限公司 | Contact type binary chlorine dioxide slow-release gel and preparation method thereof |
| CN112880108A (en) * | 2021-02-03 | 2021-06-01 | 深圳市南门科技有限公司 | Multifunctional intelligent sterilizing machine for new coronavirus and application thereof |
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| CN1293540A (en) * | 1999-02-26 | 2001-05-02 | 崔永成 | Weak acidic disinfectant |
| CN101228868A (en) * | 2008-02-27 | 2008-07-30 | 河北科技大学 | Unitary solid chlorine dioxide effervescent tablet and preparation method thereof |
| CN101233851A (en) * | 2008-02-22 | 2008-08-06 | 中国检验检疫科学研究院 | Disinfection effervescence tablet capable of continuously generating high oxidation-reduction potential |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1293540A (en) * | 1999-02-26 | 2001-05-02 | 崔永成 | Weak acidic disinfectant |
| CN101233851A (en) * | 2008-02-22 | 2008-08-06 | 中国检验检疫科学研究院 | Disinfection effervescence tablet capable of continuously generating high oxidation-reduction potential |
| CN101228868A (en) * | 2008-02-27 | 2008-07-30 | 河北科技大学 | Unitary solid chlorine dioxide effervescent tablet and preparation method thereof |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102250600A (en) * | 2011-05-06 | 2011-11-23 | 河北科技大学 | Composite block remover for removing polymer blockage of oilfields |
| CN102250600B (en) * | 2011-05-06 | 2013-05-29 | 河北科技大学 | Composite block remover for removing polymer blockage of oilfields |
| CN102283246A (en) * | 2011-05-30 | 2011-12-21 | 石家庄科大绿源科技发展有限公司 | Solid chlorine dioxide effervescent tablet and preparation method thereof |
| CN102283246B (en) * | 2011-05-30 | 2013-07-31 | 石家庄科大绿源科技发展有限公司 | Solid chlorine dioxide effervescent tablet and preparation method thereof |
| CN102318644A (en) * | 2011-06-09 | 2012-01-18 | 中国科学院化学研究所 | Method for preparing material slowly releasing chlorine dioxide and application thereof |
| CN102318644B (en) * | 2011-06-09 | 2013-10-09 | 中国科学院化学研究所 | Method for preparing material slowly releasing chlorine dioxide and application thereof |
| CN102379309A (en) * | 2011-07-27 | 2012-03-21 | 中北大学 | Binary-packaged reactive chlorine dioxide tablet and preparation method thereof |
| CN102379309B (en) * | 2011-07-27 | 2013-05-22 | 中北大学 | Binary-packaged reactive chlorine dioxide tablet and preparation method thereof |
| CN102960365A (en) * | 2011-12-31 | 2013-03-13 | 邵鹏飞 | Electrolyzed oxidizing sterilizing water with low corrosiveness and preparation method thereof |
| CN102613240A (en) * | 2012-03-12 | 2012-08-01 | 河北科技大学 | Agricultural bactericidal agent and preparation method thereof |
| CN103875709A (en) * | 2014-04-01 | 2014-06-25 | 青岛市中心医院 | Swimming pool sterilizing agent and preparation method thereof |
| CN105191979A (en) * | 2014-06-10 | 2015-12-30 | 李菠 | Powder for oxidizing and infecting drinking water and preparation method thereof |
| CN104585232A (en) * | 2015-01-28 | 2015-05-06 | 威海百克环保工程有限公司 | Compound disinfection powder for disinfecting hospital and aquaculture wastewater |
| CN105668730A (en) * | 2016-03-22 | 2016-06-15 | 江苏祥豪实业有限公司 | Novel chlorine dioxide material for treating water and method for preparing novel chlorine dioxide material |
| CN106675797A (en) * | 2016-12-26 | 2017-05-17 | 李心 | Chlorine-containing compound disinfectant detergent and preparation method thereof |
| CN108211754A (en) * | 2018-02-02 | 2018-06-29 | 环境保护部华南环境科学研究所 | A kind of flue gas pollutant absorbent and its application |
| CN108849968A (en) * | 2018-04-23 | 2018-11-23 | 开封联昌药业有限公司 | Chlorine dioxide binary liquid disinfectant and preparation method thereof |
| CN110684605A (en) * | 2019-11-18 | 2020-01-14 | 青岛立见诊断技术发展中心 | Nucleic acid remover |
| CN110684605B (en) * | 2019-11-18 | 2021-08-10 | 青岛立见生物科技有限公司 | Nucleic acid remover |
| CN111298178A (en) * | 2020-03-03 | 2020-06-19 | 江苏龙蟠科技股份有限公司 | Chlorine dioxide refrigerator bacteriostatic deodorant and preparation method thereof |
| CN111264518A (en) * | 2020-03-23 | 2020-06-12 | 郑吉宏 | Chlorine dioxide composition with bactericidal effect |
| CN111466406A (en) * | 2020-04-29 | 2020-07-31 | 北京青鸿福科技有限公司 | Contact type binary chlorine dioxide slow-release gel and preparation method thereof |
| CN112880108A (en) * | 2021-02-03 | 2021-06-01 | 深圳市南门科技有限公司 | Multifunctional intelligent sterilizing machine for new coronavirus and application thereof |
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Application publication date: 20110119 |