CN105668730A - Novel chlorine dioxide material for treating water and method for preparing novel chlorine dioxide material - Google Patents
Novel chlorine dioxide material for treating water and method for preparing novel chlorine dioxide material Download PDFInfo
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- CN105668730A CN105668730A CN201610165675.0A CN201610165675A CN105668730A CN 105668730 A CN105668730 A CN 105668730A CN 201610165675 A CN201610165675 A CN 201610165675A CN 105668730 A CN105668730 A CN 105668730A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/12—Halogens or halogen-containing compounds
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- Pest Control & Pesticides (AREA)
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- Agronomy & Crop Science (AREA)
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
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Abstract
The invention discloses a novel chlorine dioxide material for treating water. The novel chlorine dioxide material comprises 35-40 parts of sodium chlorite, 3-5 parts of potassium chlorate, 3-5 parts of benzoic acid, 2-3 parts of n-hexanoic acid, 4-6 parts of adipic acid, 1-2 parts of magnesium bicarbonate, 0.5-0.8 part of calcium bicarbonate, 0.1-0.3 part of dichloromethane, 1.5-1.8 parts of sodium dichloroisocyanurate, 1-2 parts of calcium oxide, 2-3 parts of starch, 0.5-0.8 part of dehydrated silicic acid, 0.5-0.8 part of lecithin, 0.6-0.7 part of sucrose fatty acid ester, 0.5-0.8 part of dextrin and 0.3-0.5 part of rosin. The novel chlorine dioxide material for treating the water has the advantages of good stability, convenience in use, high dissolving speed, activation efficiency and sterilization capacity, simplicity in manufacture and portability.
Description
Technical field
The present invention relates to a kind of dioxide peroxide water treatment novel material and its preparation method, belong to water treatment field.
Background technology
Dioxide peroxide is current safety generally acknowledged in the world, the sterilization of wide spectrum, fresh-keeping and reodorant, is the optimal substitute of chlorinated product, is widely used in developed country. The U.S., Canada, Japan, West Europe etc. have been ratified and have been recommended dioxide peroxide for the anti-corrosive fresh-keeping etc. of the sterilization of food, food-processing industry, pharmacy industry, hospital, public environment etc., deodorizing, mildew-resistant and food. Dioxide peroxide has also been classified as Al level security high effect disinfectants by the World Health Organization (WHO). For the generation of " three cause material " (cause abnormal, carcinogenic, mutagenesis) in control tap water, European and American developed countries wide popularization and application dioxide peroxide substitute the sterilization that chlorine carries out tap water. In recent years since, China also starts to pay attention to the promotion and application to dioxide peroxide, and it is that sterilizing agent and novel food product add that health ministry has also ratified dioxide peroxide. But owing to current stability chlorine dioxide product is mostly two-component packaging (being made up of stabilized chlorine chlorine solution and solid or liquid activating agent two portions), in use need again to be activated by sterilized stock solution with acidic activator, not only operate loaded down with trivial details. Operator are required height, transport, storage inconvenience; And activation efficiency lower (only reaching 10-15%), make the dioxide peroxide of nearly 85-90% because not having to activate and cannot use, cause the significant wastage of product, also substantially increase working concentration and the disinfection cost of product, seriously limit the widespread use of dioxide peroxide product.
Summary of the invention
In order to solve the above-mentioned defect that in prior art, dioxide peroxide product exists, the present invention provides a kind of dioxide peroxide water treatment novel material and its preparation method.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is as follows:
A kind of dioxide peroxide water treatment novel material, its raw material comprises following component: Textone 35-40 part, Potcrate 3-5 part, phenylformic acid 3-5 part, n-caproic acid 2-3 part, hexanodioic acid 4-6 part, Magnesium hydrogen carbonate 1-2 part, Calcium hydrogen carbonate 0.5-0.8 part, methylene dichloride 0.1-0.3 part, Surchlor GR 60 1.5-1.8 part, calcium oxide 1-2 part, starch 2-3 part, dehydration silicic acid 0.5-0.8 part, Yelkin TTS 0.5-0.8 part, sucrose fatty ester 0.6-0.7 part, dextrin 0.5-0.8 part and rosin 0.3-0.5 part, described part number is mass fraction.
In order to improve decontamination, the sterilizing ability of products obtained therefrom further, the raw material of dioxide peroxide water treatment novel material also comprises: bicarbonate of ammonia 1-1.5 part, and described part number is mass fraction.
In order to ensure the activity of products obtained therefrom further, the raw material of dioxide peroxide water treatment novel material also comprises: Vltra tears 0.2-0.3 part, and described part number is mass fraction.
In order to ensure that product is to the wetting property of object and perviousness further, the raw material of dioxide peroxide water treatment novel material also comprises: trihydroxy ethylamine oleate soap 0.1-0.3 part, and described part number is mass fraction.
In order to further ensure that product is to the wetting property of object and perviousness, the raw material of dioxide peroxide water treatment novel material also comprises: stearic acid 0.2-0.3 part, and described part number is mass fraction.
In order to be convenient to formed product further, and not affecting the use properties of product, the raw material of dioxide peroxide water treatment novel material also comprises: water glass 0.1-0.3 part, and described part number is mass fraction.
In order to further be convenient to formed product, and not affecting the use properties of product, the raw material of dioxide peroxide water treatment novel material also comprises: carboxymethyl cellulose 0.3-0.5 part, and described part number is mass fraction.
As a kind of preferred version of the application, the raw material of dioxide peroxide water treatment novel material comprises following component: Textone 38 parts, 4 parts, Potcrate, 4 parts, phenylformic acid, n-caproic acid 2.5 parts, hexanodioic acid 5 parts, Magnesium hydrogen carbonate 1.5 parts, Calcium hydrogen carbonate 0.6 part, 1.2 parts, bicarbonate of ammonia, methylene dichloride 0.2 part, Surchlor GR 60 1.7 parts, 1.5 parts, calcium oxide, starch 2.5 parts, dehydration silicic acid 0.7 part, Vltra tears 0.2 part, 0.6 part, Yelkin TTS, sucrose fatty ester 0.6 part, trihydroxy ethylamine oleate soap 0.2 part, stearic acid 0.3 part, 0.6 part, dextrin, rosin 0.4 part, water glass 0.2 part and carboxymethyl cellulose 0.4 part, described part number is mass fraction.
The preparation method of the application's dioxide peroxide water treatment novel material, comprises the following steps that order connects:
A, Textone, Potcrate, Yelkin TTS and sucrose fatty ester are heated up with the speed of 5/min while stirring, when temperature reaches 65-70 DEG C, it is incubated 40-45 minute;
B, by methylene dichloride, Surchlor GR 60, dextrin and rosin when 45-50 DEG C, be uniformly mixed 20-25 minute;
C, steps A gained material and step B gained material are mixed even;
D, calcium oxide, starch, dehydration silicic acid, Magnesium hydrogen carbonate and Calcium hydrogen carbonate and step C gained material are mixed even;
E, phenylformic acid, n-caproic acid and hexanodioic acid and step D gained material are mixed even, then temperature be 20-25 DEG C, humidity be 23%-26% environment under, compressing tablet, packaging.
Above-mentioned preparation method, if the feed composition of dioxide peroxide water treatment novel material also comprises: trihydroxy ethylamine oleate soap, stearic acid, water glass, carboxymethyl cellulose, Vltra tears and bicarbonate of ammonia, then trihydroxy ethylamine oleate soap stirs intensification with stearic acid together with the raw material of steps A; Water glass is uniformly mixed together with the raw material in step B with carboxymethyl cellulose; Vltra tears mixes even with bicarbonate of ammonia together with the material of step D.
The technology that the present invention does not mention is all with reference to prior art.
Dioxide peroxide water treatment novel material good stability of the present invention, it may also be useful to convenient, dissolution rate is fast, activation efficiency height, sterilizing ability are strong, and makes simple, easy to carry.
Embodiment
In order to understand the present invention better, illustrate the content of the present invention further below in conjunction with embodiment, but the content of the present invention is not only confined to the following examples.
Embodiment 1
The raw material of a kind of dioxide peroxide water treatment novel material comprises following component: Textone 38 parts, 4 parts, Potcrate, 4 parts, phenylformic acid, n-caproic acid 2.5 parts, hexanodioic acid 5 parts, Magnesium hydrogen carbonate 1.5 parts, Calcium hydrogen carbonate 0.6 part, 1.2 parts, bicarbonate of ammonia, methylene dichloride 0.2 part, Surchlor GR 60 1.7 parts, 1.5 parts, calcium oxide, starch 2.5 parts, dehydration silicic acid 0.7 part, Vltra tears 0.2 part, 0.6 part, Yelkin TTS, sucrose fatty ester 0.6 part, trihydroxy ethylamine oleate soap 0.2 part, stearic acid 0.3 part, 0.6 part, dextrin, rosin 0.4 part, water glass 0.2 part and carboxymethyl cellulose 0.4 part, described part number is mass fraction.
The preparation method of above-mentioned dioxide peroxide water treatment novel material, comprises the following steps that order connects:
A, Textone, Potcrate, Yelkin TTS, sucrose fatty ester, trihydroxy ethylamine oleate soap and stearic acid are heated up with the speed of 5/min while stirring, when temperature reaches 65-70 DEG C, it is incubated 40-45 minute;
B, by methylene dichloride, Surchlor GR 60, dextrin, rosin, water glass and carboxymethyl cellulose when 45-50 DEG C, be uniformly mixed 20-25 minute;
C, steps A gained material and step B gained material are mixed even;
D, calcium oxide, starch, dehydration silicic acid, Magnesium hydrogen carbonate, Calcium hydrogen carbonate, Vltra tears and bicarbonate of ammonia and step C gained material are mixed even;
E, phenylformic acid, n-caproic acid and hexanodioic acid and step D gained material are mixed even, then temperature be 20-25 DEG C, humidity be 23%-26% environment under, compressing tablet, packaging.
Embodiment 2
The raw material of a kind of dioxide peroxide water treatment novel material comprises following component: Textone 35 parts, 3 parts, Potcrate, 3 parts, phenylformic acid, n-caproic acid 2 parts, hexanodioic acid 4 parts, Magnesium hydrogen carbonate 1 part, Calcium hydrogen carbonate 0.5 part, methylene dichloride 0.1 part, Surchlor GR 60 1.5 parts, 1 part, calcium oxide, starch 2 parts, dehydration silicic acid 0.5 part, 0.5 part, Yelkin TTS, sucrose fatty ester 0.6 part, 0.5 part, dextrin, rosin 0.3 part, 1 part, bicarbonate of ammonia, Vltra tears 0.2 part, trihydroxy ethylamine oleate soap 0.1 part, stearic acid 0.2 part, water glass 0.1 part and carboxymethyl cellulose 0.3 part, described part number is mass fraction.
The preparation method of above-mentioned dioxide peroxide water treatment novel material, comprises the following steps that order connects:
A, Textone, Potcrate, Yelkin TTS, sucrose fatty ester, trihydroxy ethylamine oleate soap and stearic acid are heated up with the speed of 5/min while stirring, when temperature reaches 65-70 DEG C, it is incubated 40 minutes;
B, by methylene dichloride, Surchlor GR 60, dextrin, rosin, water glass and carboxymethyl cellulose when 45-50 DEG C, be uniformly mixed 20 minutes;
C, steps A gained material and step B gained material are mixed even;
D, calcium oxide, starch, dehydration silicic acid, Magnesium hydrogen carbonate, Calcium hydrogen carbonate, Vltra tears and bicarbonate of ammonia and step C gained material are mixed even;
E, phenylformic acid, n-caproic acid and hexanodioic acid and step D gained material are mixed even, then temperature be 20-25 DEG C, humidity be 23%-26% environment under, compressing tablet, packaging.
Embodiment 3
The raw material of a kind of dioxide peroxide water treatment novel material comprises following component: Textone 40 parts, 5 parts, Potcrate, 5 parts, phenylformic acid, n-caproic acid 3 parts, hexanodioic acid 6 parts, Magnesium hydrogen carbonate 2 parts, Calcium hydrogen carbonate 0.8 part, methylene dichloride 0.3 part, Surchlor GR 60 1.8 parts, 2 parts, calcium oxide, starch 3 parts, dehydration silicic acid 0.8 part, 0.8 part, Yelkin TTS, sucrose fatty ester 0.7 part, 0.8 part, dextrin, rosin 0.5 part, 1.5 parts, bicarbonate of ammonia, Vltra tears 0.3 part, trihydroxy ethylamine oleate soap 0.3 part, stearic acid 0.2-0.3 part, water glass 0.3 part and carboxymethyl cellulose 0.5 part, described part number is mass fraction.
The preparation method of above-mentioned dioxide peroxide water treatment novel material, comprises the following steps that order connects:
A, Textone, Potcrate, Yelkin TTS, sucrose fatty ester, trihydroxy ethylamine oleate soap and stearic acid are heated up with the speed of 5/min while stirring, when temperature reaches 65-70 DEG C, it is incubated 40-45 minute;
B, by methylene dichloride, Surchlor GR 60, dextrin, rosin, water glass and carboxymethyl cellulose when 45-50 DEG C, be uniformly mixed 20-25 minute;
C, steps A gained material and step B gained material are mixed even;
D, calcium oxide, starch, dehydration silicic acid, Magnesium hydrogen carbonate, Calcium hydrogen carbonate, Vltra tears and bicarbonate of ammonia and step C gained material are mixed even;
E, phenylformic acid, n-caproic acid and hexanodioic acid and step D gained material are mixed even, then temperature be 20-25 DEG C, humidity be 23%-26% environment under, compressing tablet, packaging.
Manufactured tablet is in 80 DEG C of baking ovens, and relative humidity is not less than 75%, places 21 days, and the rate of descent of chlorine dioxide content is respectively: embodiment 1,1.2%, embodiment 2,1.5%, embodiment 3,1.4%. The detection method of the application's chlorine dioxide content is the patent of 200810054571 with reference to application number.
The various embodiments described above gained dioxide peroxide water treatment novel material is soluble in water, and discharges rapidly dioxide peroxide, and all dissolves in 7 minutes completely; The actual burst size of dioxide peroxide reaches more than the 90% of theoretical burst size;
Using each embodiment gained dioxide peroxide water treatment novel material to be dissolved in (4g/L) after same batch of taken outdoors water, leave standstill 20 minutes, detect after filtering throw out, partial results is as follows:
Total coli group: non-detection (being 15000CFU/mL before using).
Heat-resisting coliform: non-detection (being 8000CFU/mL before using).
Colon bacillus: non-detection (being 3500CFU/mL before using).
Colourity: embodiment 1 is 4 degree, embodiment 2 is 6 degree, and embodiment 3 is 5 degree (being 22 degree) before use.
Opacity: embodiment 1 is 1 degree, embodiment 2 is 1 degree, and embodiment 3 is 1 degree (being 8 degree) before use.
Plumbous: embodiment 1 is 0.0003mg/L, and embodiment 2 is 0.0004mg/L, embodiment 3 is 0.0005mg/L (being 0.81mg/L before using).
Claims (10)
1. a dioxide peroxide water treatment novel material, it is characterized in that: its raw material comprises following component: Textone 35-40 part, Potcrate 3-5 part, phenylformic acid 3-5 part, n-caproic acid 2-3 part, hexanodioic acid 4-6 part, Magnesium hydrogen carbonate 1-2 part, Calcium hydrogen carbonate 0.5-0.8 part, methylene dichloride 0.1-0.3 part, Surchlor GR 60 1.5-1.8 part, calcium oxide 1-2 part, starch 2-3 part, dehydration silicic acid 0.5-0.8 part, Yelkin TTS 0.5-0.8 part, sucrose fatty ester 0.6-0.7 part, dextrin 0.5-0.8 part and rosin 0.3-0.5 part, described part number is mass fraction.
2. dioxide peroxide water treatment novel material as claimed in claim 1, it is characterised in that: its raw material also comprises: bicarbonate of ammonia 1-1.5 part, and described part number is mass fraction.
3. dioxide peroxide water treatment novel material as claimed in claim 1 or 2, it is characterised in that: its raw material also comprises:
Hydroxyl third
Ylmethyl Mierocrystalline cellulose 0.2-0.3 part, described part number is mass fraction.
4. dioxide peroxide water treatment novel material as claimed in claim 1 or 2, it is characterised in that: its raw material also comprises:
Three second
Hydramine oleate soap 0.1-0.3 part, described part number is mass fraction.
5. dioxide peroxide water treatment novel material as claimed in claim 1 or 2, it is characterised in that: its raw material also comprises:
Stearic
Acid 0.2-0.3 part, described part number is mass fraction.
6. dioxide peroxide water treatment novel material as claimed in claim 1 or 2, it is characterised in that: its raw material also comprises:
Silicic acid
Sodium 0.1-0.3 part, described part number is mass fraction.
7. dioxide peroxide water treatment novel material as claimed in claim 1 or 2, it is characterised in that: its raw material also comprises:
Carboxylic first
Base Mierocrystalline cellulose 0.3-0.5 part, described part number is mass fraction.
8. dioxide peroxide water treatment novel material as claimed in claim 1 or 2, it is characterized in that: its raw material comprises following component: Textone 38 parts, 4 parts, Potcrate, 4 parts, phenylformic acid, n-caproic acid 2.5 parts, hexanodioic acid 5 parts, Magnesium hydrogen carbonate 1.5 parts, Calcium hydrogen carbonate 0.6 part, 1.2 parts, bicarbonate of ammonia, methylene dichloride 0.2 part, Surchlor GR 60 1.7 parts, 1.5 parts, calcium oxide, starch 2.5 parts, dehydration silicic acid 0.7 part, Vltra tears 0.2 part, 0.6 part, Yelkin TTS, sucrose fatty ester 0.6 part, trihydroxy ethylamine oleate soap 0.2 part, stearic acid 0.3 part, 0.6 part, dextrin, rosin 0.4 part, water glass 0.2 part and carboxymethyl cellulose 0.4 part, described part number is mass fraction.
9. the preparation method of dioxide peroxide water treatment novel material described in claim 1-8 any one, it is characterised in that: comprise the following steps that order connects:
A, Textone, Potcrate, Yelkin TTS and sucrose fatty ester are heated up with the speed of 5/min while stirring, when temperature reaches 65-70 DEG C, it is incubated 40-45 minute;
B, by methylene dichloride, Surchlor GR 60, dextrin and rosin when 45-50 DEG C, be uniformly mixed 20-25 minute;
C, steps A gained material and step B gained material are mixed even;
D, calcium oxide, starch, dehydration silicic acid, Magnesium hydrogen carbonate and Calcium hydrogen carbonate and step C gained material are mixed even;
E, phenylformic acid, n-caproic acid and hexanodioic acid and step D gained material are mixed even, then temperature be 20-25 DEG C, humidity be 23%-26% environment under, compressing tablet, packaging.
10. preparation method as claimed in claim 9, it is characterized in that: if the feed composition of dioxide peroxide water treatment novel material also comprises: trihydroxy ethylamine oleate soap, stearic acid, water glass, carboxymethyl cellulose, Vltra tears and bicarbonate of ammonia, then trihydroxy ethylamine oleate soap stirs intensification with stearic acid together with the raw material of steps A; Water glass is uniformly mixed together with the raw material in step B with carboxymethyl cellulose; Vltra tears mixes even with bicarbonate of ammonia together with the material of step D.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610165675.0A CN105668730A (en) | 2016-03-22 | 2016-03-22 | Novel chlorine dioxide material for treating water and method for preparing novel chlorine dioxide material |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610165675.0A CN105668730A (en) | 2016-03-22 | 2016-03-22 | Novel chlorine dioxide material for treating water and method for preparing novel chlorine dioxide material |
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Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2355197A (en) * | 1999-04-27 | 2001-04-18 | Medichem Internat Ltd | A dry powder/solid formulation for dissolving in water and subsequent use as a chlorine releasing sterilant |
| US6432322B1 (en) * | 2000-02-02 | 2002-08-13 | Engelhard Corporation | Massive bodies for producing highly converted solutions of chlorine dioxde |
| CN1582661A (en) * | 2003-08-21 | 2005-02-23 | 兰州金陵石化有限责任公司 | Solid chlorine dioxide anti septic |
| CN101124914A (en) * | 2007-10-03 | 2008-02-20 | 胡银安 | Mixing disinfectant containing chlorine dioxide and preparing process thereof |
| CN101228868A (en) * | 2008-02-27 | 2008-07-30 | 河北科技大学 | Unitary solid chlorine dioxide effervescent tablet and preparation method thereof |
| CN101773144A (en) * | 2010-01-19 | 2010-07-14 | 青岛大学 | Solid chlorine sterilization algicide and preparation method thereof |
| CN101946798A (en) * | 2010-10-11 | 2011-01-19 | 河北科技大学 | Binary natural chlorine dioxide disinfectant and preparation method thereof |
| KR20110074402A (en) * | 2009-12-24 | 2011-06-30 | 글로엔엠(주) | Composition for producting chlorine dioside |
| CN102246819A (en) * | 2011-05-19 | 2011-11-23 | 成都阳光生物科技有限责任公司 | Instant chlorine dioxide effervescent tablet and preparation method thereof |
| CN102687728A (en) * | 2012-06-07 | 2012-09-26 | 安徽省黄淮兽药有限公司 | Chlorine dioxide tablet disinfectant and preparation method of chlorine dioxide tablet disinfectant |
| CN103493843A (en) * | 2013-09-10 | 2014-01-08 | 昆明双玖消毒药业有限公司 | Production formula for neutral chlorine dioxide powder (unitary package) |
| CN105165891A (en) * | 2015-09-22 | 2015-12-23 | 上海普吉生物科技有限公司 | Chlorine dioxide tablet disinfector and preparing method thereof |
| CN105174412A (en) * | 2015-09-21 | 2015-12-23 | 江苏祥豪实业有限公司 | Water treatment agent and preparing method thereof |
-
2016
- 2016-03-22 CN CN201610165675.0A patent/CN105668730A/en active Pending
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2355197A (en) * | 1999-04-27 | 2001-04-18 | Medichem Internat Ltd | A dry powder/solid formulation for dissolving in water and subsequent use as a chlorine releasing sterilant |
| US6432322B1 (en) * | 2000-02-02 | 2002-08-13 | Engelhard Corporation | Massive bodies for producing highly converted solutions of chlorine dioxde |
| CN1582661A (en) * | 2003-08-21 | 2005-02-23 | 兰州金陵石化有限责任公司 | Solid chlorine dioxide anti septic |
| CN101124914A (en) * | 2007-10-03 | 2008-02-20 | 胡银安 | Mixing disinfectant containing chlorine dioxide and preparing process thereof |
| CN101228868A (en) * | 2008-02-27 | 2008-07-30 | 河北科技大学 | Unitary solid chlorine dioxide effervescent tablet and preparation method thereof |
| KR20110074402A (en) * | 2009-12-24 | 2011-06-30 | 글로엔엠(주) | Composition for producting chlorine dioside |
| CN101773144A (en) * | 2010-01-19 | 2010-07-14 | 青岛大学 | Solid chlorine sterilization algicide and preparation method thereof |
| CN101946798A (en) * | 2010-10-11 | 2011-01-19 | 河北科技大学 | Binary natural chlorine dioxide disinfectant and preparation method thereof |
| CN102246819A (en) * | 2011-05-19 | 2011-11-23 | 成都阳光生物科技有限责任公司 | Instant chlorine dioxide effervescent tablet and preparation method thereof |
| CN102687728A (en) * | 2012-06-07 | 2012-09-26 | 安徽省黄淮兽药有限公司 | Chlorine dioxide tablet disinfectant and preparation method of chlorine dioxide tablet disinfectant |
| CN103493843A (en) * | 2013-09-10 | 2014-01-08 | 昆明双玖消毒药业有限公司 | Production formula for neutral chlorine dioxide powder (unitary package) |
| CN105174412A (en) * | 2015-09-21 | 2015-12-23 | 江苏祥豪实业有限公司 | Water treatment agent and preparing method thereof |
| CN105165891A (en) * | 2015-09-22 | 2015-12-23 | 上海普吉生物科技有限公司 | Chlorine dioxide tablet disinfector and preparing method thereof |
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