CN102558994A - Preparation method of liquid marble paint containing pearl pigment - Google Patents
Preparation method of liquid marble paint containing pearl pigment Download PDFInfo
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Abstract
The invention provides a preparation method of liquid marble paint containing pearl pigment, relating to a preparation method of marble paint. The invention solves the problems that the traditional liquid marble paint has single variety, low glossiness and poor decorative effect. The preparation method comprises the following steps of: preparing HG-1 aqueous solution; preparing protective colloid solution; preparing base paint; blending the base paint and water-based colour paste to obtain target coloured paint, then stirring the protective colloid solution and the target coloured paint and pelleting to obtain coloured paint particles; mixing silicone acrylic emulsion, alcohol ester 12, deionized water and propylene glycol to be uniform and adding the coloured paint particles and thickening agent, and stirring, thus the liquid marble paint containing the pearl pigment is obtained. By adopting the liquid marble paint containing the pearl pigment prepared by the invention, colour layering can be renewed according to mixing and matching in different colours, thus products are further diversified; coating and contrasting effects are stronger, colour is bright, patterns are diversified, the liquid marble paint is novel and unique, textures are rich, gloss is soft and colour and lustre are bright, real stone imitation degree is higher and reaches up to 95%, and the liquid marble paint containing the pearl pigment can substitute for natural stone.
Description
Technical field
The present invention relates to a kind of preparation method of marble paint.
Background technology
In order to beautify indoor environment, also buildings is protected simultaneously, generally all to decorate in the inside and the outside of building.In architectural process, embody lithotome effect attractive in appearance at present, often use lithotome or stone-like coating in order to reach.But lithotome can receive natural colour usually, decorate the influence of problems such as back figure line is inhomogeneous, and natural crystal also can receive the region restriction, and exploitation and processing is unusual difficulty all, makes its price very expensive.
Especially in decorative coveringn, silvery white pigment is used as gloss or effect pigment usually at many industrial circles.In order to reach the purpose of decoration; Denomination of invention is an Automotive paint compositions containing pearlescent pigments and dyes (application number: US4598020A; The applying date: on August 16th, 1985, open day: on July 1st, 1986) USP in announced a kind of pearly coating; Through adding pearly-lustre and other coloured pigment in thermoplastic resin and thermosetting resin, thereby produce colorful pearly coating.But this coating that includes pearly pigment is dispersed in base-material and the solution in the preparation process; Therefore the coating stereoeffect is not obvious; The pearly-lustre look is shown in the face that is coated with of decorating equably; Make the finishing effect of its construction stiff, stiff, and construction the time is easy to generate and sticks up the skin phenomenon, brings a lot of troubles to construction.
Liquid marble paint is as using wider a kind of finishing material at present, co-existed in together by the water-borne coatings of two kinds of not miscible two or more and forms, and a part is non-volatile component, comprising resin, pigment and filler etc.; Another part is a volatiles, comprises solvent, auxiliary agent etc.Through to different selection of pigment and combination, thereby produce colorful effect.But existing liquid marble paint exists kind single, the low problem that reaches the decorative effect difference of glossiness.
Summary of the invention
The present invention seeks to exist kind single in order to solve existing liquid marble paint, the low problem that reaches the decorative effect difference of glossiness, and a kind of preparation method who comprises the liquid marble paint of pearly pigment is provided.
The preparation method who comprises the liquid marble paint of pearly pigment carries out according to the following steps:
One, under the agitation condition of 850～1500r/min, by ratio of weight and the number of copies 3～15 parts HG-1 powder is joined in 85～97 parts the deionized water, obtain the HG-1 aqueous solution after stirring 20～50min;
Two, by ratio of weight and the number of copies 65～86.5 parts deionized water and 8.5～15 parts HD-7 are put into stirrer; The HG-1 aqueous solution that under the agitation condition of 300～700r/min, adds 5～20 parts then; Under the condition of 900～1450r/min, disperse 25～45min again, obtain protective colloid solution;
Three, by ratio of weight and the number of copies with 32～40 parts deionized water, 0.1～0.25 part multifunctional assistant and 0.6～0.9 part HG-1 aqueous solution; Under the condition of 850～1500r/min, stir 20～40min then; Add successively again 0.25～0.5 part the ammonium salt dispersion agent, 0.05～0.17 part the nonionic wetting agent, 0.15～0.35 part skimmer, 0.5～4 part the rutile titanium white powder, 0.5～20 part kaolin and 0.5～19 part pearly pigment and under 900～1450r/min condition, stir 20～35min; Adding 27～35 parts elastic emulsion and 0.2～0.4 part skimmer then continues to be stirred to still; The negatively charged ion wetting agent that adds 0.17～0.23 part again stirs 3～5min; The HG-1 aqueous solution that adds 0.6～0.9 part then stirs 8～18min; Add 0.07～0.18 part negatively charged ion wetting agent, 1.7～3.3 parts sterilant and 0.8～2.2 part thickening material again and stir 10～15min; The aqueous color paste that adds 0.08～0.23 part then stirs 10～15min, obtains base paint after leaving standstill 4h;
Four, by ratio of weight and the number of copies 30～70 parts base paint and 5～10 parts aqueous color paste mixing are accessed the target colored paint; Then 30～65 parts protective colloid solution and 35～70 parts target colored paint are stirred 5～30min under 300～1200r/min condition; Carry out granulation after 5～50 eye mesh screens, obtain the coloured enamel grain;
Five, by ratio of weight and the number of copies with 27～37 parts organosilicon crylic acid latex, 1.3～2.8 parts 12,15～19 parts of alcohol esters deionized water and 0.4～0.7 part the Ucar 35 mixing and adjust pH value to 8～9; Add 2.5～12 parts coloured enamel grain and 43～53 parts thickening material then; Under 100～500r/min condition, stir 5～25min, promptly accomplish the preparation of the liquid marble paint that comprises pearly pigment;
Wherein aqueous color paste adopts red iron oxide, Rutile type Titanium Dioxide, titanium ultramarine, yellow oxide of iron, iron oxide black or titanizing green in the step 3.
The present invention prepares the liquid marble paint that gained comprises pearly pigment, and appearance of different color is realized on its surface, has more characteristic, outward appearance is more beautiful, and the weather resistance of paint film all improves a lot with resistance to soiling, and paint film is thinner, weight and bear all very light.Through the mixing and the proportioning of different colours, can make gradation sense surface again, thereby make further variation of product.
The present invention prepares the liquid marble paint that gained comprises pearly pigment, and to be coated with contrast effect stronger for dress, has that color is lucid and lively, pattern is various, new and original a, rich texture, the fresh feature of the age such as gloss is soft, color and luster is beautiful; Emulation stone degree is higher, up to 95%, can replace lithotome; Can according to requirement of client; Make not of uniform size, the effect that texture is different, thus make it reach the ideal decorative effect.
The present invention prepares the liquid marble paint that gained comprises pearly pigment and has good anti-stain characteristic, weathering resistance and abrasion resistance; Can brush applied range at the surface and the position of Any shape; The construction simple and fast, the starting material that use all adopt international environmental protection standard, and cost is reasonable, has very high quality guarantee.
Embodiment
Technical scheme of the present invention is not limited to following cited embodiment, also comprises the arbitrary combination between each embodiment.
The specific embodiment one: the preparation method that present embodiment comprises the liquid marble paint of pearlescent pigment carries out according to the following steps: one, under the stirring condition of 850～1500r/min; By ratio of weight and the number of copies 3～15 parts HG-1 powder is joined in 85～97 parts the deionized water, obtain the HG-1 aqueous solution after stirring 20～50min;
Two, by ratio of weight and the number of copies 65～86.5 parts deionized water and 8.5～15 parts HD-7 are put into stirrer; The HG-1 aqueous solution that under the agitation condition of 300～700r/min, adds 5～20 parts then; Under the condition of 900～1450r/min, disperse 25～45min again, obtain protective colloid solution;
Three, by ratio of weight and the number of copies with 32～40 parts deionized water, 0.1～0.25 part multifunctional assistant and 0.6～0.9 part HG-1 aqueous solution; Under the condition of 850～1500r/min, stir 20～40min then; Add successively again 0.25～0.5 part the ammonium salt dispersion agent, 0.05～0.17 part the nonionic wetting agent, 0.15～0.35 part skimmer, 0.5～4 part the rutile titanium white powder, 0.5～20 part kaolin and 0.5～19 part pearly pigment and under 900～1450r/min condition, stir 20～35min; Adding 27～35 parts elastic emulsion and 0.2～0.4 part skimmer then continues to be stirred to still; The negatively charged ion wetting agent that adds 0.17～0.23 part again stirs 3～5min; The HG-1 aqueous solution that adds 0.6～0.9 part then stirs 8～18min; Add 0.07～0.18 part negatively charged ion wetting agent, 1.7～3.3 parts sterilant and 0.8～2.2 part thickening material again and stir 10～15min; The aqueous color paste that adds 0.08～0.23 part then stirs 10～15min, obtains base paint after leaving standstill 4h;
Four, by ratio of weight and the number of copies 30～70 parts base paint and 5～10 parts aqueous color paste mixing are accessed the target colored paint; Then 30～65 parts protective colloid solution and 35～70 parts target colored paint are stirred 5～30min under 300～1200r/min condition; Carry out granulation after 5～50 eye mesh screens, obtain the coloured enamel grain;
Five, by ratio of weight and the number of copies with 27～37 parts organosilicon crylic acid latex, 1.3～2.8 parts 12,15～19 parts of alcohol esters deionized water and 0.4～0.7 part the Ucar 35 mixing and adjust pH value to 8～9; Add 2.5～12 parts coloured enamel grain and 43～53 parts thickening material then; Under 100～500r/min condition, stir 5～25min, promptly accomplish the preparation of the liquid marble paint that comprises pearly pigment;
Wherein aqueous color paste adopts red iron oxide, Rutile type Titanium Dioxide, titanium ultramarine, yellow oxide of iron, iron oxide black or titanizing green in the step 3.
Used HG-1 powder in this embodiment: buy from the Deidro Deluxe, Shanghai Ltd, model is HG-1;
HG-7: buy from the Deidro Deluxe, Shanghai Ltd, model is HG-7;
Multifunctional assistant: buy the perseverance space chemical industry ltd from Guangzhou, model is AMP-95;
The ammonium salt dispersion agent is one or more the mixture (when the ammonium salt dispersion agent is formed for two or more material by arbitrarily than mixing) among the WP-19 that produces of shellfish specialization worker ltd, WP-5040, the WP-5060;
The nonionic wetting agent: buy from Japanese. Nuo Puke, model is DS-200;
The rutile titanium white powder: buy from Nanjing Titanium Dioxide Chemical Co., Ltd., model is NR-950;
Kaolin: buy from Tangshan. Madison, model are CMP-80;
Pearly pigment: buy the excellent graceful special dyeing and printing auxiliary ltd from Hangzhou, model is for needing decide according to color;
Elastic emulsion: life reaches chemical industry ltd from Nantong in purchase, and model is S-07;
Skimmer is W-090, the W-092 that the modest company of moral produces, the mixture of one or more among the H-436 of Haichuan Company, the Defoamer 121 (pressing when skimmer is formed for two or more material arbitrarily than mixing);
The negatively charged ion wetting agent: buy the field chemistry ltd that rubs from Shanghai, model is OT-75;
Sterilant: buy from the U.S.. ROHM AND HAAS, model are LSE;
Thickening material: buy from shellfish specialization worker ltd, model is one or more the mixture (when thickening material is formed for two or more material by arbitrarily than mixing) among ATW-01, ATW-06, ATW-60, the ATW-2000;
Aqueous color paste: buy the dyeing Science and Technology Ltd. of pausing again from Shanghai, model needs according to color and decides;
Organosilicon crylic acid latex: buy from Qingzhou shellfish specialization worker ltd, model is GK-503.
Protective colloid solution is transparent or semitransparent shape in this embodiment step 2.
Embodiment two: this embodiment and embodiment one are different be in the step 1 under the agitation condition of 1000r/min, by ratio of weight and the number of copies 5 parts HG-1 powder is joined in 95 parts the deionized water, obtain the HG-1 aqueous solution after stirring 30min.Other step and parameter are identical with embodiment one.
Embodiment three: what this embodiment was different with embodiment one or two is by ratio of weight and the number of copies 70 parts deionized water and 10 parts HD-7 to be put into stirrer in the step 2; The HG-1 aqueous solution that under the agitation condition of 500r/min, adds 10 parts then disperses 30min again under the condition of 1250r/min.Other step and parameter are identical with embodiment one or two.
Embodiment four: this embodiment is different with one of embodiment one to three be in the step 3 by ratio of weight and the number of copies with 35 parts deionized water, 0.2 part multifunctional assistant and 0.8 part HG-1 aqueous solution, under the condition of 1200r/min, stir 30min then.Other step and parameter are identical with one of embodiment one to three.
Embodiment five: this embodiment is different with one of embodiment one to four be add successively again in the step 3 0.4 part the ammonium salt dispersion agent, 0.1 part the nonionic wetting agent, 0.2 part skimmer, 2 parts the rutile titanium white powder, 10 parts kaolin and 10 parts pearly pigment and under the 1350r/min condition, stir 30min.Other step and parameter are identical with one of embodiment one to four.
Embodiment six: this embodiment is different with one of embodiment one to five is to add 30 parts elastic emulsion in the step 3 then and 0.3 part skimmer continues to be stirred to still; The negatively charged ion wetting agent that adds 0.2 part again stirs 4min, and the HG-1 aqueous solution that adds 0.8 part then stirs 15min.Other step and parameter are identical with one of embodiment one to five.
Embodiment seven: what this embodiment was different with one of embodiment one to six is to add 0.12 part negatively charged ion wetting agent, 2.5 parts sterilant and 1.5 parts thickening material in the step 3 again to stir 12min, and the aqueous color paste that adds 0.15 part then stirs 12min.Other step and parameter are identical with one of embodiment one to six.
Embodiment eight: what this embodiment was different with one of embodiment one to seven is that step 4 accesses the target colored paint with 50 parts base paint and 8 parts aqueous color paste mixing by ratio of weight and the number of copies; Then 50 parts protective colloid solution and 50 parts target colored paint are stirred 20min under the 1000r/min condition, carry out granulation after 30 eye mesh screens.Other step and parameter are identical with one of embodiment one to seven.
Embodiment nine: this embodiment is different with one of embodiment one to eight is that aqueous color paste adopts in green two kinds, three kinds or four kinds of red iron oxide, Rutile type Titanium Dioxide, titanium ultramarine, yellow oxide of iron, iron oxide black, titanizing in the step 4.Other step and parameter are identical with one of embodiment one to eight.
Aqueous color paste adopts red iron oxide and Rutile type Titanium Dioxide in this embodiment, according to ratio of weight and number 50 parts red iron oxide and 50 parts Rutile type Titanium Dioxide is mixed then, obtains brown tone;
Aqueous color paste adopts red iron oxide, Rutile type Titanium Dioxide and titanium ultramarine, according to ratio of weight and number 30 parts red iron oxide, 40 parts Rutile type Titanium Dioxide and 30 parts titanium ultramarine is mixed then, obtains purple tone;
Aqueous color paste adopts Rutile type Titanium Dioxide and titanium ultramarine, according to ratio of weight and number 70 parts Rutile type Titanium Dioxide and 30 parts titanium ultramarine is mixed then, obtains light blue tone;
Aqueous color paste adopts Rutile type Titanium Dioxide, titanium ultramarine and yellow oxide of iron, according to ratio of weight and number 30 parts Rutile type Titanium Dioxide, 35 parts titanium ultramarine and 35 parts yellow oxide of iron is mixed green tone in the acquisition then;
Aqueous color paste adopts yellow oxide of iron, iron oxide black and titanizing green, according to ratio of weight and number 20 parts Rutile type Titanium Dioxide, 20 parts titanium ultramarine and 60 parts yellow oxide of iron is mixed then, obtains the darkcyan tone;
Aqueous color paste adopts red iron oxide, Rutile type Titanium Dioxide, yellow oxide of iron and iron oxide black; According to ratio of weight and number 30 parts red iron oxide, 20 parts Rutile type Titanium Dioxide, 30 parts yellow oxide of iron and 20 parts iron oxide black are mixed then, obtain the taupe brown tone.
Embodiment ten: this embodiment is different with one of embodiment one to nine be in the step 5 by ratio of weight and the number of copies with 35 parts organosilicon crylic acid latex, 2 parts 12,16 parts of alcohol esters deionized water and 0.5 part the Ucar 35 mixing and adjust pH value to 8.5; Add 5 parts coloured enamel grain and 48 parts thickening material then, under the 300r/min condition, stir 15min.Other step and parameter are identical with one of embodiment formula one to nine.
Embodiment 1
The preparation method who comprises the liquid marble paint of pearly pigment carries out according to the following steps: one, under the agitation condition of 1200r/min, by ratio of weight and the number of copies 10 parts HG-1 powder is joined in 90 parts the deionized water, obtain the HG-1 aqueous solution after stirring 40min;
Two, by ratio of weight and the number of copies 80 parts deionized water and 12 parts HD-7 are put into stirrer, under the agitation condition of 500r/min, add 15 parts the HG-1 aqueous solution then, under the condition of 1250r/min, disperse 30min again, obtain protective colloid solution;
Three, by ratio of weight and the number of copies with 38 parts deionized water, 0.2 part multifunctional assistant and 0.7 part HG-1 aqueous solution; Under the condition of 1200r/min, stir 30min then; Add successively again 0.3 part the ammonium salt dispersion agent, 0.1 part the nonionic wetting agent, 0.2 part skimmer, 2 parts the rutile titanium white powder, 10 parts kaolin and 10 parts pearly pigment and under the 1250r/min condition, stir 30min; Adding 30 parts elastic emulsion and 0.3 part skimmer then continues to be stirred to still; The negatively charged ion wetting agent that adds 0.2 part again stirs 4min, and the HG-1 aqueous solution that adds 0.8 part then stirs 15min, adds 0.1 part negatively charged ion wetting agent, 2 parts sterilant and 1.5 parts thickening material again and stirs 15min; The aqueous color paste that adds 0.2 part then stirs 15min, obtains base paint after leaving standstill 4h;
Four, by ratio of weight and the number of copies 50 parts base paint and 8 parts aqueous color paste mixing are accessed the target colored paint; Then 50 parts protective colloid solution and 40 parts target colored paint are stirred 20min under the 1000r/min condition; Carry out granulation after 25 eye mesh screens, obtain the coloured enamel grain;
Five, by ratio of weight and the number of copies with 32 parts organosilicon crylic acid latex, 2 parts 12,16 parts of alcohol esters deionized water and 0.5 part the Ucar 35 mixing and adjust pH value to 8; Add 6 parts coloured enamel grain and 48 parts thickening material then; Under the 400r/min condition, stir 15min, promptly accomplish the preparation of the liquid marble paint that comprises pearly pigment;
Wherein aqueous color paste adopts red iron oxide, Rutile type Titanium Dioxide, titanium ultramarine, yellow oxide of iron, iron oxide black or titanizing green in the step 3.
Used HG-1 powder in the present embodiment: buy from the Deidro Deluxe, Shanghai Ltd, model is HG-1;
HG-7: buy from the Deidro Deluxe, Shanghai Ltd, model is HG-7;
Multifunctional assistant: buy the perseverance space chemical industry ltd from Guangzhou, model is AMP-95;
The ammonium salt dispersion agent is the WP-19 that shellfish specialization worker ltd produces;
The nonionic wetting agent: buy from Japanese. Nuo Puke, model is DS-200;
The rutile titanium white powder: buy from Nanjing Titanium Dioxide Chemical Co., Ltd., model is NR-950;
Kaolin: buy from Tangshan. Madison, model are CMP-80;
Pearly pigment: buy the excellent graceful special dyeing and printing auxiliary ltd from Hangzhou, model is for needing decide according to color;
Elastic emulsion: life reaches chemical industry ltd from Nantong in purchase, and model is S-07;
Skimmer is the W-090 that the modest company of moral produces;
The negatively charged ion wetting agent: buy the field chemistry ltd that rubs from Shanghai, model is OT-75;
Sterilant: buy from the U.S.. ROHM AND HAAS, model are LSE;
Thickening material: buy from shellfish specialization worker ltd, model is ATW-01;
Aqueous color paste: buy the dyeing Science and Technology Ltd. of pausing again from Shanghai, model needs according to color and decides;
Organosilicon crylic acid latex: buy from Qingzhou shellfish specialization worker ltd, model is GK-503.
Aqueous color paste adopts Rutile type Titanium Dioxide in the present embodiment step 3.
Aqueous color paste adopts red iron oxide and Rutile type Titanium Dioxide in the present embodiment step 4, according to ratio of weight and number 50 parts red iron oxide and 50 parts Rutile type Titanium Dioxide is mixed then, obtains brown tone.
The present embodiment gained comprises the liquid marble paint of pearly pigment; Through detecting; It is no abnormal and 48h is no abnormal that water tolerance, alkali resistance detected result are respectively 96h; The abrasion resistance detected result is 1000 times, all meets or exceeds standard GB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ", GB/T 9779-2006 " Multi wall architectural coatings ".To artificial weathering ageing resistance's detected result is that 1000h efflorescence result is 0 grade, and the variable color detected result is that 1 grade, 1000h variable color are 2 grades for the 600h variable color, all National standard GB/T 9755-2001 " exterior wall coating material of synthetic resin emulsion ".
The present embodiment gained comprises the liquid marble paint of pearly pigment, and through detecting, the content of VOC is 34g/L; Well below the 200g/L of national standard, and, has accessibility for storage and transportation because VOC content is low; Use had security; Use usually to be sprayed by spray gun, spray pressure is 3～5.5kg/cm2, and the spraying mouthful distance from metope is 30～40cm.
Embodiment 2
Aqueous color paste adopts red iron oxide in the present embodiment step 3;
Aqueous color paste adopts red iron oxide, Rutile type Titanium Dioxide and titanium ultramarine in the present embodiment step 4, according to ratio of weight and number 30 parts red iron oxide, 40 parts Rutile type Titanium Dioxide and 30 parts titanium ultramarine is mixed then, obtains purple tone;
Other step is all identical with embodiment 1 with parameter.
The present embodiment gained comprises the liquid marble paint of pearly pigment; Through detecting; It is no abnormal and 48h is no abnormal that water tolerance, alkali resistance detected result are respectively 96h; The abrasion resistance detected result is 1000 times, all meets or exceeds standard GB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ", GB/T 9779-2006 " Multi wall architectural coatings ".To artificial weathering ageing resistance's detected result is that 1000h efflorescence result is 0 grade, and the variable color detected result is that 1 grade, 1000h variable color are 2 grades for the 600h variable color, all National standard GB/T 9755-2001 " exterior wall coating material of synthetic resin emulsion ".
The present embodiment gained comprises the liquid marble paint of pearly pigment, and through detecting, the content of VOC is 38g/L; Well below the 200g/L of national standard, and, has accessibility for storage and transportation because VOC content is low; Use had security; Use usually to be sprayed by spray gun, spray pressure is 3～5.5kg/cm2, and the spraying mouthful distance from metope is 30～40cm.
Embodiment 3
Aqueous color paste adopts Rutile type Titanium Dioxide in the present embodiment step 3;
Aqueous color paste adopts Rutile type Titanium Dioxide and titanium ultramarine in the present embodiment step 4, according to ratio of weight and number 70 parts Rutile type Titanium Dioxide and 30 parts titanium ultramarine is mixed then, obtains light blue tone;
Other step is all identical with embodiment 1 with parameter.
The present embodiment gained comprises the liquid marble paint of pearly pigment; Through detecting; It is no abnormal and 48h is no abnormal that water tolerance, alkali resistance detected result are respectively 96h; The abrasion resistance detected result is 1000 times, all meets or exceeds standard GB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ", GB/T 9779-2006 " Multi wall architectural coatings ".To artificial weathering ageing resistance's detected result is that 1000h efflorescence result is 0 grade, and the variable color detected result is that 1 grade, 1000h variable color are 2 grades for the 600h variable color, all National standard GB/T 9755-2001 " exterior wall coating material of synthetic resin emulsion ".
The present embodiment gained comprises the liquid marble paint of pearly pigment, and through detecting, the content of VOC is 43g/L; Well below the 200g/L of national standard, and, has accessibility for storage and transportation because VOC content is low; Use had security; Use usually to be sprayed by spray gun, spray pressure is 3～5.5kg/cm2, and the spraying mouthful distance from metope is 30～40cm.
Embodiment 4
Aqueous color paste adopts the titanium ultramarine in the present embodiment step 3;
Aqueous color paste adopts Rutile type Titanium Dioxide, titanium ultramarine and yellow oxide of iron in the present embodiment step 4, according to ratio of weight and number 30 parts Rutile type Titanium Dioxide, 35 parts titanium ultramarine and 35 parts yellow oxide of iron is mixed green tone in the acquisition then;
Other step is all identical with embodiment 1 with parameter.
The present embodiment gained comprises the liquid marble paint of pearly pigment; Through detecting; It is no abnormal and 48h is no abnormal that water tolerance, alkali resistance detected result are respectively 96h; The abrasion resistance detected result is 1000 times, all meets or exceeds standard GB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ", GB/T 9779-2006 " Multi wall architectural coatings ".To artificial weathering ageing resistance's detected result is that 1000h efflorescence result is 0 grade, and the variable color detected result is that 1 grade, 1000h variable color are 2 grades for the 600h variable color, all National standard GB/T 9755-2001 " exterior wall coating material of synthetic resin emulsion ".
The present embodiment gained comprises the liquid marble paint of pearly pigment, and through detecting, the content of VOC is 47g/L; Well below the 200g/L of national standard, and, has accessibility for storage and transportation because VOC content is low; Use had security; Use usually to be sprayed by spray gun, spray pressure is 3～5.5kg/cm2, and the spraying mouthful distance from metope is 30～40cm.
Embodiment 5
It is green that aqueous color paste adopts titanizing in the present embodiment step 3;
It is green that aqueous color paste adopts yellow oxide of iron, iron oxide black and titanizing in the present embodiment step 4, according to ratio of weight and number 20 parts Rutile type Titanium Dioxide, 20 parts titanium ultramarine and 60 parts yellow oxide of iron mixed then, obtains the darkcyan tone;
Other step is all identical with embodiment 1 with parameter.
The present embodiment gained comprises the liquid marble paint of pearly pigment; Through detecting; It is no abnormal and 48h is no abnormal that water tolerance, alkali resistance detected result are respectively 96h; The abrasion resistance detected result is 1000 times, all meets or exceeds standard GB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ", GB/T 9779-2006 " Multi wall architectural coatings ".To artificial weathering ageing resistance's detected result is that 1000h efflorescence result is 0 grade, and the variable color detected result is that 1 grade, 1000h variable color are 2 grades for the 600h variable color, all National standard GB/T 9755-2001 " exterior wall coating material of synthetic resin emulsion ".
The present embodiment gained comprises the liquid marble paint of pearly pigment, and through detecting, the content of VOC is 50g/L; Well below the 200g/L of national standard, and, has accessibility for storage and transportation because VOC content is low; Use had security; Use usually to be sprayed by spray gun, spray pressure is 3～5.5kg/cm2, and the spraying mouthful distance from metope is 30～40cm.
Embodiment 6
Aqueous color paste adopts Rutile type Titanium Dioxide in the present embodiment step 3;
Aqueous color paste adopts red iron oxide, Rutile type Titanium Dioxide, yellow oxide of iron and iron oxide black in the present embodiment step 4; According to ratio of weight and number 30 parts red iron oxide, 20 parts Rutile type Titanium Dioxide, 30 parts yellow oxide of iron and 20 parts iron oxide black are mixed then, obtain the taupe brown tone.
Other step is all identical with embodiment 1 with parameter.
The present embodiment gained comprises the liquid marble paint of pearly pigment; Through detecting; It is no abnormal and 48h is no abnormal that water tolerance, alkali resistance detected result are respectively 96h; The abrasion resistance detected result is 1000 times, all meets or exceeds standard GB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ", GB/T 9779-2006 " Multi wall architectural coatings ".To artificial weathering ageing resistance's detected result is that 1000h efflorescence result is 0 grade, and the variable color detected result is that 1 grade, 1000h variable color are 2 grades for the 600h variable color, all National standard GB/T 9755-2001 " exterior wall coating material of synthetic resin emulsion ".
The present embodiment gained comprises the liquid marble paint of pearly pigment, and through detecting, the content of VOC is 51g/L; Well below the 200g/L of national standard, and, has accessibility for storage and transportation because VOC content is low; Use had security; Use usually to be sprayed by spray gun, spray pressure is 3～5.5kg/cm2, and the spraying mouthful distance from metope is 30～40cm.
Claims (10)
1. preparation method who comprises the liquid marble paint of pearly pigment; The preparation method who it is characterized in that comprising the liquid marble paint of pearly pigment carries out according to the following steps: one, under the agitation condition of 850～1500r/min; By ratio of weight and the number of copies 3～15 parts HG-1 powder is joined in 85～97 parts the deionized water, obtain the HG-1 aqueous solution after stirring 20～50min;
Two, by ratio of weight and the number of copies 65～86.5 parts deionized water and 8.5～15 parts HD-7 are put into stirrer; The HG-1 aqueous solution that under the agitation condition of 300～700r/min, adds 5～20 parts then; Under the condition of 900～1450r/min, disperse 25～45min again, obtain protective colloid solution;
Three, by ratio of weight and the number of copies with 32～40 parts deionized water, 0.1～0.25 part multifunctional assistant and 0.6～0.9 part HG-1 aqueous solution; Under the condition of 850～1500r/min, stir 20～40min then; Add successively again 0.25～0.5 part the ammonium salt dispersion agent, 0.05～0.17 part the nonionic wetting agent, 0.15～0.35 part skimmer, 0.5～4 part the rutile titanium white powder, 0.5～20 part kaolin and 0.5～19 part pearly pigment and under 900～1450r/min condition, stir 20～35min; Adding 27～35 parts elastic emulsion and 0.2～0.4 part skimmer then continues to be stirred to still; The negatively charged ion wetting agent that adds 0.17～0.23 part again stirs 3～5min; The HG-1 aqueous solution that adds 0.6～0.9 part then stirs 8～18min; Add 0.07～0.18 part negatively charged ion wetting agent, 1.7～3.3 parts sterilant and 0.8～2.2 part thickening material again and stir 10～15min; The aqueous color paste that adds 0.08～0.23 part then stirs 10～15min, obtains base paint after leaving standstill 4h;
Four, by ratio of weight and the number of copies 30～70 parts base paint and 5～10 parts aqueous color paste mixing are accessed the target colored paint; Then 30～65 parts protective colloid solution and 35～70 parts target colored paint are stirred 5～30min under 300～1200r/min condition; Carry out granulation after 5～50 eye mesh screens, obtain the coloured enamel grain;
Five, by ratio of weight and the number of copies with 27～37 parts organosilicon crylic acid latex, 1.3～2.8 parts 12,15～19 parts of alcohol esters deionized water and 0.4～0.7 part the Ucar 35 mixing and adjust pH value to 8～9; Add 2.5～12 parts coloured enamel grain and 43～53 parts thickening material then; Under 100～500r/min condition, stir 5～25min, promptly accomplish the preparation of the liquid marble paint that comprises pearly pigment;
Wherein aqueous color paste adopts red iron oxide, Rutile type Titanium Dioxide, titanium ultramarine, yellow oxide of iron, iron oxide black or titanizing green in the step 3.
2. a kind of preparation method who comprises the liquid marble paint of pearly pigment according to claim 1; It is characterized in that in the step 1 under the agitation condition of 1000r/min; By ratio of weight and the number of copies 5 parts HG-1 powder is joined in 95 parts the deionized water, obtain the HG-1 aqueous solution after stirring 30min.
3. a kind of preparation method who comprises the liquid marble paint of pearly pigment according to claim 2; It is characterized in that by ratio of weight and the number of copies 70 parts deionized water and 10 parts HD-7 being put into stirrer in the step 2; The HG-1 aqueous solution that under the agitation condition of 500r/min, adds 10 parts then disperses 30min again under the condition of 1250r/min.
4. a kind of preparation method who comprises the liquid marble paint of pearly pigment according to claim 3; It is characterized in that in the step 3 under the condition of 1200r/min, stirring 30min then by ratio of weight and the number of copies with 35 parts deionized water, 0.2 part multifunctional assistant and 0.8 part HG-1 aqueous solution.
5. a kind of preparation method who comprises the liquid marble paint of pearly pigment according to claim 4, it is characterized in that adding successively again in the step 3 0.4 part the ammonium salt dispersion agent, 0.1 part the nonionic wetting agent, 0.2 part skimmer, 2 parts the rutile titanium white powder, 10 parts kaolin and 10 parts pearly pigment and under the 1350r/min condition, stir 30min.
6. a kind of preparation method who comprises the liquid marble paint of pearly pigment according to claim 5; It is characterized in that adding 30 parts elastic emulsion in the step 3 then and 0.3 part skimmer continues to be stirred to still; The negatively charged ion wetting agent that adds 0.2 part again stirs 4min, and the HG-1 aqueous solution that adds 0.8 part then stirs 15min.
7. a kind of preparation method who comprises the liquid marble paint of pearly pigment according to claim 6; It is characterized in that adding in the step 3 0.12 part negatively charged ion wetting agent, 2.5 parts sterilant and 1.5 parts thickening material again and stir 12min, the aqueous color paste that adds 0.15 part then stirs 12min.
8. a kind of preparation method who comprises the liquid marble paint of pearly pigment according to claim 7; It is characterized in that step 4 accesses the target colored paint with 50 parts base paint and 8 parts aqueous color paste mixing by ratio of weight and the number of copies; Then 50 parts protective colloid solution and 50 parts target colored paint are stirred 20min under the 1000r/min condition, carry out granulation after 30 eye mesh screens.
9. a kind of preparation method who comprises the liquid marble paint of pearly pigment according to claim 8 is characterized in that aqueous color paste in the step 4 adopts in green two kinds, three kinds or four kinds of red iron oxide, Rutile type Titanium Dioxide, titanium ultramarine, yellow oxide of iron, iron oxide black, titanizing.
10. a kind of preparation method who comprises the liquid marble paint of pearly pigment according to claim 9; It is characterized in that in the step 5 by ratio of weight and the number of copies with 35 parts organosilicon crylic acid latex, 2 parts 12,16 parts of alcohol esters deionized water and 0.5 part the Ucar 35 mixing and adjust pH value to 8.5; Add 5 parts coloured enamel grain and 48 parts thickening material then, under the 300r/min condition, stir 15min.
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Cited By (6)
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| CN102732118A (en) * | 2012-07-17 | 2012-10-17 | 东莞大宝化工制品有限公司 | Aqueous artificial granite paint for furniture and preparation method thereof |
| CN104263164A (en) * | 2013-11-20 | 2015-01-07 | 漳州水之采环保科技有限公司 | Novel color-changing iridescent wall coating |
| CN105649293A (en) * | 2016-01-12 | 2016-06-08 | 黄河科技学院 | Water-based integrated plate and manufacturing technology thereof |
| CN106280826A (en) * | 2016-08-31 | 2017-01-04 | 铃鹿复合建材（上海）有限公司 | A kind of art opalescent lacquers and preparation method thereof |
| CN106854388A (en) * | 2016-12-19 | 2017-06-16 | 钦州市高新技术产业服务中心 | A kind of paint and preparation method for stone material |
| CN107629609A (en) * | 2016-07-12 | 2018-01-26 | 张明岩 | A kind of marble paint |
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| CN102732118A (en) * | 2012-07-17 | 2012-10-17 | 东莞大宝化工制品有限公司 | Aqueous artificial granite paint for furniture and preparation method thereof |
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| CN104263164A (en) * | 2013-11-20 | 2015-01-07 | 漳州水之采环保科技有限公司 | Novel color-changing iridescent wall coating |
| CN105649293A (en) * | 2016-01-12 | 2016-06-08 | 黄河科技学院 | Water-based integrated plate and manufacturing technology thereof |
| CN107629609A (en) * | 2016-07-12 | 2018-01-26 | 张明岩 | A kind of marble paint |
| CN106280826A (en) * | 2016-08-31 | 2017-01-04 | 铃鹿复合建材（上海）有限公司 | A kind of art opalescent lacquers and preparation method thereof |
| CN106854388A (en) * | 2016-12-19 | 2017-06-16 | 钦州市高新技术产业服务中心 | A kind of paint and preparation method for stone material |
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| CN102558994B (en) | 2013-11-06 |
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