CN110105862A - A kind of spray painting major ingredient and rain and dew paint for button - Google Patents

A kind of spray painting major ingredient and rain and dew paint for button Download PDF

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Publication number
CN110105862A
CN110105862A CN201910501129.3A CN201910501129A CN110105862A CN 110105862 A CN110105862 A CN 110105862A CN 201910501129 A CN201910501129 A CN 201910501129A CN 110105862 A CN110105862 A CN 110105862A
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CN
China
Prior art keywords
spray painting
rain
button
major ingredient
agent
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Pending
Application number
CN201910501129.3A
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Chinese (zh)
Inventor
林强
郑吉林
卢静
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Zhejiang Weixing Industrial Development Co Ltd
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Zhejiang Weixing Industrial Development Co Ltd
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Priority to CN201910501129.3A priority Critical patent/CN110105862A/en
Publication of CN110105862A publication Critical patent/CN110105862A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The present invention provides a kind of spray painting major ingredients for button, comprising: the acrylic resin of 25~28wt%, the flexible polyurethane resin of 45~48wt%, the defoaming agent of 0.1~0.2wt%, the levelling agent of 0.4~0.6wt%, the mallear stria agent of 0.4~0.8wt%, balance of solvent.Present invention also provides the rain and dew paints including above-mentioned spray painting major ingredient.The application is in spray painting major ingredient by the way that above-mentioned auxiliary agent is added in acrylic resin and flexible polyurethane resin and controls its content; enhance the binding force of itself and button semi-finished product; enhance that button is wear-resisting, washable and solvent resistance simultaneously; and secondary spray protective paint processing is not needed; and can be realized the transparent color of preferable concave-convex sense skin texture and 100%, meet demand of the different clients to effect and service performance.

Description

A kind of spray painting major ingredient and rain and dew paint for button
Technical field
The present invention relates to painting applications more particularly to a kind of spray painting major ingredients and rain and dew paint for button.
Background technique
Button-shaped is the long life haberdashery kept together.With the continuous improvement of quality of the life, button is by initially using Carry out the effect development of the left front of connecting clothing to have more artistry and dicoration in addition to keeping its original function, that is, a Propertyization effect.One good button can make clothes more perfect, play the role of crucial touch, so that clothes more adds Beauty.
In order to increase the aesthetics of button, staff generally carries out spray painting processing on the surface of button at present, to To the button of different-effect, more specifically, the technique of the button used in the prior art is general are as follows: semi-finished product button-ultrasonic wave Cleaning-drying-row's button-spray painting-drying-product inspection packaging.But the surface effect of button is single at present, the base shown It originally is flat and smooth surface effect;Integrally color is single after spraying for product, only Transparent color or blank color itself, and market is competing It is not strong to strive power, selectivity is not enough;Color is needed since existing spray painting material is mixed into using color matching in direct colored varnish superposition blank The product of system, and product colour is single in process of production, so that client generates visual fatigue, fashion to the product of solid color Property and collocation property it is insufficient.It is very necessary for providing a kind of button with three-dimensional rain and dew effect as a result, to meet fashion trend.
Summary of the invention
Present invention solves the technical problem that being to provide a kind of spray painting major ingredient for button, which is used for button The spraying of semi-finished product can make button have three-dimensional rain and dew effect, and water-fastness, dry cleaning resistance when button uses and wear-resisting also can be improved Property.
In view of this, this application provides a kind of spray painting major ingredients for button, comprising:
Preferably, the acrylic resin is BC/204 acrylic resin, and the flexible polyurethane resin is XH-PU316 Flexible polyurethane resin.
Preferably, the solvent is the diformazan prepared by ethyl acetate, isopropanol and heteroauxin according to mass ratio 2:1:1 Base formamide diluent.
Preferably, the defoaming agent is Defom5700 defoaming agent, and the levelling agent is Levelo1835 levelling agent, described Mallear stria agent is the agent of Moneng-6013 mallear stria.
Preferably, the content of the acrylic resin is 26~27wt%, and the content of the flexible polyurethane resin is 46 ~47wt%.
Preferably, the content of the mallear stria agent is 0.5~0.6wt%.
Present invention also provides a kind of rain and dew paint for button, including spray painting major ingredient, curing agent and diluent, the sprays Painting major ingredient is spray painting major ingredient described in above scheme.
It preferably, further include delustring slurry in the rain and dew paint.
Preferably, further include color essence pigment in the rain and dew paint, the color essence pigment be the rain and dew paint 0.1~ 10wt%.
Preferably, the mass ratio of the spray painting major ingredient, curing agent and diluent is (8~10): (4~5): (1~2).
This application provides a kind of spray painting major ingredients for button comprising: acrylic resin, flexible polyurethane resin, Defoaming agent, levelling agent, mallear stria agent and solvent;The application to spray paint film by the way that mallear stria agent is added in spray painting major ingredient In the forming process of button surface there is three-dimensional granular sensation to occur, three-dimensional rain and dew effect is presented;Acrylic resin and elasticity are poly- Main carriers of the urethane resin as spray painting major ingredient are the spray painting main film forming matter of major ingredient and coating film layer, and solvent is for dilute It releases and dissolves above-mentioned resin and reach viscosity appropriate, with the bite force of paint film and substrate after raising spraying, promote paint film and button Semi-finished product can be combined effectively and not separated, and finally meet washing, dry-cleaning test not delamination.Therefore, provided by the present application to be used for knob The spraying paint of button is used cooperatively by said components, so that its spraying for being used for button can make button have three-dimensional rain and dew effect Fruit, and improve water-fastness, dry cleaning resistance and wearability when button uses.
Detailed description of the invention
Fig. 1 is the button of transparent semi-gloss rain and dew effect prepared by the embodiment of the present invention 1;
Fig. 2 is the button of transparent light rain and dew effect prepared by the embodiment of the present invention 2;
Fig. 3 is the button of translucent rain and dew effect prepared by the embodiment of the present invention 3.
Specific embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still It should be appreciated that these descriptions are only further explanation the features and advantages of the present invention, rather than to the claims in the present invention Limitation.
For the single problem of button surface effect in the prior art, this application provides a kind of spray painting major ingredients, are painting A kind of rain and dew paint is additionally provided on the basis of major ingredient, which is used for the spraying on button surface, and button can be made to have three-dimensional rain Reveal effect.Specifically, the embodiment of the invention discloses a kind of spray painting major ingredients for button, comprising:
In the above-mentioned spray painting major ingredient for button provided by the present application, acrylic resin and flexible polyurethane resin conduct The flexible resin of spray painting major ingredient is the main carriers of spray painting major ingredient, and the spray painting main film forming matter of major ingredient and coating film layer. The content of the acrylic resin is 25~28wt%, and in a particular embodiment, the content of the thermosetting acrylic resin is 26wt%, 27wt% or 28wt%.The content of the flexible polyurethane resin is 45~48wt%, in a particular embodiment, institute The content for stating flexible polyurethane resin is 45wt%, 47wt% or 48wt%.In a particular embodiment, the acrylic resin is BC/204 acrylic resin, the flexible polyurethane resin are XH-PU316 polyurethane resin.
Mallear stria agent is to be aided in spray painting major ingredient the filler that can generate concave-convex dot shape, can not be just after spraying spray painting major ingredient Chang Liuping is a kind of auxiliary agent of special efficacy at smooth film layer.In a particular embodiment, the mallear stria agent is Moneng- 6013 mallear stria agent.The content of the mallear stria agent is 0.4~0.8wt%, and in a particular embodiment, the content of the silica flour is 0.4wt%, 0.6wt%, 0.7wt% or 0.8wt%.
The defoaming agent and the levelling agent are the filler in spray painting major ingredient, and in a particular embodiment, the defoaming agent is Defom5700 defoaming agent, the levelling agent are Levelo1835 levelling agent.The content of the levelling agent is 0.4~0.6wt%, In a particular embodiment, the content of the levelling agent is 0.4wt%, 0.42wt%, 0.5wt% or 0.6wt%.The defoaming agent Content be 0.1~0.2wt%, in a particular embodiment, the content of the defoaming agent be 0.1wt%, 0.15wt% or 0.2wt%.
In spray painting major ingredient, the solvent is the necessary object of production spray painting major ingredient, to dilute and dissolution acrylic resin Reach required viscosity with flexible polyurethane resin, and can be improved the bite force of paint film Yu button semi-finished product, promotes paint film and knob Button semi-finished product can be combined effectively and not separated, and guarantee that button meets washing, dry-cleaning test department delamination.In a particular embodiment, institute Stating solvent is the dimethylformamide diluent prepared by ethyl acetate, isopropanol and heteroauxin according to mass ratio 2:1:1 (applying -4 glasss, 20 DEG C).
The preparation method of herein described spray painting major ingredient can directly mix all the components, can also be by acrylic acid tree Rouge, flexible polyurethane resin after mixing, add solvent, defoaming agent, levelling agent and mallear stria agent, and spray can be obtained through filtering Paint major ingredient;Spraying is in use, using stand-by in the paint special drum of filter screen filtration to Special seal.
The spray painting major ingredient of the application mentioned component interacts, and cooperates, component and content beyond the application are then painted Film will appear the ineffective problem of three-dimensional rain and dew, while demand is not achieved in film forming and film layer substrate binding force, there is test Fall film layer phenomenon.
Present invention also provides a kind of rain and dew paints for button comprising the spray painting major ingredient of above scheme, curing agent and Diluent.
Spray painting major ingredient provided by the present application needs to arrange in pairs or groups curing agent and diluent is used together, the spray painting major ingredient, described The mass ratio of curing agent and the diluent is (8~10): (4~5): (1~2);Rain and dew are imitated after then spraying beyond aforementioned proportion Fruit is bad, paint film will not drying and forming-film, and wash, dry-cleaning test there are pull-away phenomenons.The curing agent and the dilution Agent is auxiliary agent well known to those skilled in the art, is not particularly limited to this application.
If desired semi-gloss photometric stereo rain and dew paint effect is made, delustring slurry need to be added in rain and dew paint and is carried out at luminosity delustring Reason, then sprayed, then button surface reaches the rain and dew paint product of semi-gloss.
To realize that adding assorted color essence pigment color matching in edematus effect product, then rain and dew paint needs color, specifically Additive amount is 0.1~10wt%, stirs evenly to spray to button surface and reach and needs effect.
After obtaining rain and dew paint, then it can be used for painting in button surface of semi-finished, to form the knob of different-effect Button, detailed process are as follows: semi-finished product button-ultrasonic cleaning-drying-row's button-spray painting-drying-product inspection packaging;
It is handled during above-mentioned cleaning using ultrasonic cleaning process, three-dimensional rain and dew paint and button surface can be enhanced Binding force;
In semi-finished product button painting process, the spraying of semi-finished product button is realized by above-mentioned rain and dew paint combination method for paint spraying, May be implemented out 100% transparent effect and translucent coloured effect;The spraying method specifically: hand-held spray guns are used, Bore is 1.0~1.2MM, and spray pressure is 1.5~2 kilograms of air pressures, oil plant is installed, needed for alignment button surface is adjusted Fuel-displaced amount is sprayed on button surface, and effect embodies rain and dew effect to be achieved according to hand speed and fuel-displaced amount.
Before portioned product spraying rain and dew paint due to carry out it is radium-shine carve characters or paint, lettering and other effects processing, can by Carried out before spraying rain and dew paint it is radium-shine carve characters or pre-treatment, while color essence pigment can also be added in rain and dew paint, realize out and need wind The rain and dew paint effect button product of lattice;
By special three-dimensional rain and dew paint material technology, in conjunction with before spraying blank color matching, pattern, pearl effect variation with And the utilization of various surface treatment effects is wherein, forms the variation of multiple product background color and the effect Joker of rain and dew paint, makes button There are multi-effect texture and colors on surface.
For a further understanding of the present invention, below with reference to embodiment to the spray painting major ingredient provided by the present invention for button into Row is described in detail, and protection scope of the present invention is not limited by the following examples.
Embodiment 1
Flexible stereo rain and dew paint formula forms (wt%)
Flexible resin: acrylic resin liquid: 26%
Flexible polyurethane resin liquid: 45%;
Solvent: 28.08%;The dimethyl methyl prepared by ethyl acetate, isopropanol and heteroauxin according to mass ratio 2:1:1 Amide diluent;
Defom5700 defoaming agent: 0.1%;
1835 levelling agent of Levelo: 0.42%;
Moneng-6013 mallear stria agent: 0.4%;
By the semi-finished product button being prepared successively carry out ultrasonic cleaning, drying, row buckle, ingredient, spray painting, drying and It examines, obtains finished product button;Wherein spray painting includes rain and dew paint major ingredient, curing agent and the diluent of said ratio, three's mass ratio For 10:4:1;
Spraying rain and dew paint performance test is carried out to semi-finished product product surface, additive color essence pigment and other effects in the spray colored varnish and paint It is tested, surface effect is as shown in Figure 1, meet quality standard.
Product is through water-fastness: GB/T 3921;Textile color stability tests 4 grades of color fastness to washing or more, paint layer without fall off, Color is without discoloration;
Dry cleaning resistance: GB/T 5771;Textile color stability tests 4 grades of colour fasteness to dry cleaning or more, paint layer without fall off, color Without discoloration;
Resistance to ironing: 150 DEG C, 10 seconds, product surface paint layer was without peeling, and frosting phenomenon, color are without staining;
The above standard testing, product surface is whole not to go out abrasion and paint layer obscission, and total quality meets auxiliary material product Professional standard appearance and surface are smooth bright and clean without unfilled corner, flash, film layer, and performance is water-fastness, dry-clean, ironing film layer does not send out wrinkle, rises The quality standards such as skin.Much larger than common spray painting class product abrasivity and paint especially on the number that resistance to home laundry is continuously machine-washed Layer fastness, common product 5 times, rain and dew paint product 10 times.
Embodiment 2
Flexible stereo rain and dew paint formula forms (wt%)
Flexible resin: acrylic resin liquid: 27%;
Flexible polyurethane resin liquid: 47%;
Solvent: 24.75%;The dimethyl methyl prepared by ethyl acetate, isopropanol and heteroauxin according to mass ratio 2:1:1 Amide diluent;
Defom5700 defoaming agent: 0.15%;
1835 levelling agent of Levelo: 0.5%;
Moneng-6013 mallear stria agent: 0.6%;
By the semi-finished product button being prepared successively carry out ultrasonic cleaning, drying, row buckle, ingredient, spray painting, drying and It examines, obtains finished product button;Wherein spray painting includes rain and dew paint major ingredient, curing agent and the diluent of said ratio, three's mass ratio For 8:4:1.5;
Spraying rain and dew paint performance test is carried out to semi-finished product product surface, additive color essence pigment and other effects in the spray colored varnish and paint It is tested, surface effect is as shown in Fig. 2, meet quality standard.
Product is through water-fastness: GB/T 3921;Textile color stability tests 4 grades of color fastness to washing or more, paint layer without fall off, Color is without discoloration;
Dry cleaning resistance: GB/T 5771;Textile color stability tests 4 grades of colour fasteness to dry cleaning or more, paint layer without fall off, color Without discoloration;
Resistance to ironing: 150 DEG C, 10 seconds, product surface paint layer was without peeling, and frosting phenomenon, color are without staining;
The above standard testing, product surface is whole not to go out abrasion and paint layer obscission, and total quality meets auxiliary material product Professional standard appearance and surface are smooth bright and clean without unfilled corner, flash, film layer, and performance is water-fastness, dry-clean, ironing film layer does not send out wrinkle, rises The quality standards such as skin.Much larger than common spray painting class product abrasivity and paint especially on the number that resistance to home laundry is continuously machine-washed Layer fastness: common product 5 times, rain and dew paint product 10 times.
Embodiment 3
Flexible stereo rain and dew paint formula forms (wt%)
Flexible resin: acrylic resin liquid: 28%;
Flexible polyurethane resin liquid: 48%;
Solvent: 22.4%;The dimethyl methyl prepared by ethyl acetate, isopropanol and heteroauxin according to mass ratio 2:1:1 Amide diluent;
Defom5700 defoaming agent: 0.2%;
1835 levelling agent of Levelo: 0.6%;
Moneng-6013 mallear stria agent: 0.8%;
By the semi-finished product button being prepared successively carry out ultrasonic cleaning, drying, row buckle, ingredient, spray painting, drying and It examines, obtains finished product button;Wherein spray painting includes rain and dew paint major ingredient, curing agent and the diluent of said ratio, three's mass ratio For 10:4:2;
Spraying rain and dew paint performance test is carried out to semi-finished product product surface, additive color essence pigment and other effects in the spray colored varnish and paint It is tested, surface effect meets quality standard as shown in Figure 3.
Product is through water-fastness: GB/T 3921;Textile color stability tests 4 grades of color fastness to washing or more, paint layer without fall off, Color is without discoloration;
Dry cleaning resistance: GB/T 5771;Textile color stability tests 4 grades of colour fasteness to dry cleaning or more, paint layer without fall off, color Without discoloration;
Resistance to ironing: 150 DEG C, 10 seconds, product surface paint layer was without peeling, and frosting phenomenon, color are without staining;
The above standard testing, product surface is whole not to go out abrasion and paint layer obscission, and total quality meets auxiliary material product Professional standard appearance and surface are smooth bright and clean without unfilled corner, flash, film layer, and performance is water-fastness, dry-clean, ironing film layer does not send out wrinkle, rises The quality standards such as skin.Much larger than common spray painting class product abrasivity and paint especially on the number that resistance to home laundry is continuously machine-washed Layer fastness: common product 5 times, rain and dew paint product 10 times.
The above description of the embodiment is only used to help understand the method for the present invention and its core ideas.It should be pointed out that pair For those skilled in the art, without departing from the principle of the present invention, the present invention can also be carried out Some improvements and modifications, these improvements and modifications also fall within the scope of protection of the claims of the present invention.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one The widest scope of cause.

Claims (10)

1. a kind of spray painting major ingredient for button, comprising:
2. spray painting major ingredient according to claim 1, which is characterized in that the acrylic resin is BC/204 acrylic acid tree Rouge, the flexible polyurethane resin are XH-PU316 flexible polyurethane resin.
3. spray painting major ingredient according to claim 1, which is characterized in that the solvent is by ethyl acetate, isopropanol and Yin The dimethylformamide diluent that indolylbutyric acid is prepared according to mass ratio 2:1:1.
4. spray painting major ingredient according to claim 1, which is characterized in that the defoaming agent is Defom5700 defoaming agent, described Levelling agent is Levelo1835 levelling agent, and the mallear stria agent is the agent of Moneng-6013 mallear stria.
5. spray painting major ingredient according to claim 1, which is characterized in that the content of the acrylic resin be 26~ 27wt%, the content of the flexible polyurethane resin are 46~47wt%.
6. spray painting major ingredient according to claim 1, which is characterized in that the content of the mallear stria agent is 0.5~0.6wt%.
7. a kind of rain and dew paint for button, including spray painting major ingredient, curing agent and diluent, the spray painting major ingredient are claim 1~6 described in any item spray painting major ingredients.
8. rain and dew paint according to claim 7, which is characterized in that further include delustring slurry in the rain and dew paint.
9. rain and dew paint according to claim 7, which is characterized in that further include color essence pigment, the color in the rain and dew paint Smart pigment is 0.1~10wt% of the rain and dew paint.
10. rain and dew paint according to claim 7, which is characterized in that the quality of the spray painting major ingredient, curing agent and diluent Than for (8~10): (4~5): (1~2).
CN201910501129.3A 2019-06-11 2019-06-11 A kind of spray painting major ingredient and rain and dew paint for button Pending CN110105862A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910501129.3A CN110105862A (en) 2019-06-11 2019-06-11 A kind of spray painting major ingredient and rain and dew paint for button

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Application Number Priority Date Filing Date Title
CN201910501129.3A CN110105862A (en) 2019-06-11 2019-06-11 A kind of spray painting major ingredient and rain and dew paint for button

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Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114907758A (en) * 2022-05-17 2022-08-16 浙江伟星实业发展股份有限公司 Napagi dermatoglyph paint and preparation method and application thereof

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CN101210129A (en) * 2006-12-30 2008-07-02 比亚迪股份有限公司 Crackle lacquer, preparing method thereof and spraying method for the same
CN102212302A (en) * 2011-05-10 2011-10-12 深圳市天健涂料科技开发有限公司 3D painting, method for preparing same and construction process
CN103194144A (en) * 2013-04-18 2013-07-10 广东溢达纺织有限公司 Button with hammer effect and preparation method of button
CN107556898A (en) * 2017-09-30 2018-01-09 浙江伟星实业发展股份有限公司 A kind of button finish paint, skin texture imitate stone button and preparation method thereof
CN107793903A (en) * 2017-09-26 2018-03-13 中车青岛四方机车车辆股份有限公司 A kind of coating composition and its application for being used to repair rubber floor covering cloth
CN109233588A (en) * 2017-05-09 2019-01-18 德莱特恩环保涂料(北京)有限公司 A kind of double-component waterborne polyurethane finish compositions and paint base composition, and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101210129A (en) * 2006-12-30 2008-07-02 比亚迪股份有限公司 Crackle lacquer, preparing method thereof and spraying method for the same
CN102212302A (en) * 2011-05-10 2011-10-12 深圳市天健涂料科技开发有限公司 3D painting, method for preparing same and construction process
CN103194144A (en) * 2013-04-18 2013-07-10 广东溢达纺织有限公司 Button with hammer effect and preparation method of button
CN109233588A (en) * 2017-05-09 2019-01-18 德莱特恩环保涂料(北京)有限公司 A kind of double-component waterborne polyurethane finish compositions and paint base composition, and preparation method thereof
CN107793903A (en) * 2017-09-26 2018-03-13 中车青岛四方机车车辆股份有限公司 A kind of coating composition and its application for being used to repair rubber floor covering cloth
CN107556898A (en) * 2017-09-30 2018-01-09 浙江伟星实业发展股份有限公司 A kind of button finish paint, skin texture imitate stone button and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114907758A (en) * 2022-05-17 2022-08-16 浙江伟星实业发展股份有限公司 Napagi dermatoglyph paint and preparation method and application thereof

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Application publication date: 20190809

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