CN102558619A - Rubber material with characteristics of bacterial resistance, fungi resistance and algae resistance, and preparation method thereof - Google Patents
Rubber material with characteristics of bacterial resistance, fungi resistance and algae resistance, and preparation method thereof Download PDFInfo
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- CN102558619A CN102558619A CN2011101763618A CN201110176361A CN102558619A CN 102558619 A CN102558619 A CN 102558619A CN 2011101763618 A CN2011101763618 A CN 2011101763618A CN 201110176361 A CN201110176361 A CN 201110176361A CN 102558619 A CN102558619 A CN 102558619A
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Abstract
The present invention relates to a rubber material with characteristics of bacterial resistance, fungi resistance and algae resistance, and a preparation method thereof. According to the present invention, the main rubber comprises natural rubber, styrene-butadiene rubber, ethylene-propylene-diene monomer rubber, chloroprene rubber, acrylonitrile-butadiene rubber, chlorosulfonated polyethylene rubber, chlorinated polyethylene, or a composition comprising any materials selected from natural rubber, styrene-butadiene rubber, ethylene-propylene-diene monomer rubber, chloroprene rubber, acrylonitrile-butadiene rubber, chlorosulfonated polyethylene rubber and chlorinated polyethylene, and further comprises carbendazim, N-octylisothiazolone, and diuron. With the novel rubber material and the preparation method thereof, the fungi breeding and the algae breeding on the rubber surface can be effectively inhibited, the intrinsic quality and the appearance quality of the product can be maintained, and the frequent cleaning is not required so as to save a large amount of manpower and material resources.
Description
Technical field
The present invention relates to a kind of antibiotic mildew-resistant algae-resistant elastomeric material and preparation method thereof.
Background technology
As everyone knows; The rubber dam that elastomeric material is made is a kind of hydraulic structure; The checkdam that water (gas) inflation forms; Can be used for flood control, irrigate, generating, supply water, usefulness that ecoscape is built in retaining tide and city, the rubber floor covering that the public place is laid is because no antibiotic mildew-resistant algae-resistant function (general more than 2 months) in use for some time, because a large amount of black mildew of the etch of mould appearance; The colorful rubber dam that is used to control flood, block water, administer beautifying city, river course ecotope is after operation for some time; A large amount of blackish green liver moss mildews appears in the surface; Destroyed rubber item interior molecules structure like this, made the product appearance downgrade, aging resistance reduces; Need often to clean, expended a large amount of human and material resources.
Summary of the invention
For addressing the above problem, thereby the present invention provides a kind of antibiotic mildew-resistant algae-resistant to keep its visual appearance and inner quality, thereby not needing often to clean has saved antibiotic mildew-resistant algae-resistant elastomeric material of a large amount of manpower and materials and preparation method thereof.
Antibiotic mildew-resistant algae-resistant elastomeric material of the present invention; Wherein, Main rubber comprises tree elastomer, styrene-butadiene rubber(SBR), terpolymer EP rubber, X 050, paracril, chlorosulfonated polyethylene rubber, chlorinatedpolyethylene or arbitrary combination wherein, it is characterized in that: also comprise derosal, N-octyl group RH-893 and Diuron Tech.
The preparation method of antibiotic mildew-resistant algae-resistant elastomeric material of the present invention, wherein,
1 >, mixing fusion or back mixing fusion: derosal, N-octyl group RH-893, three kinds of materials of Diuron Tech are joined in the elastomeric material sizing material by the formula rate fusion; Fusion is in closed rubber kneading machine or back mixing machine, to carry out; 50 ℃-110 ℃ of the temperature of sizing material are admixed time 5-10 minute during fusion.
2 >, roll, extrude compound slice: the rubber unvulcanizate that fusion is good extrudes on rubber calender or film forcing machine has certain width in (general 0.5-1.5 rice), the film that certain thickness (general 0.4-20mm) length is not limit.40 ℃-90 ℃ of the temperature that calendering is extruded.
3 >, sulfuration flat board or drum vulcanizer sulfuration: film is vulcanized on sulfuration flat board or drum vulcanizer, process work in-process sulfide film or adhesive plaster.140-160 ℃ of sulfuration process temperature.
4 >, blanking moulding: will vulcanizate film or adhesive plaster and promptly be made into the antibiotic mildew-resistant algae-resistant elastomeric material by size blanking, the moulding of stipulating.
Beneficial effect of the present invention is: the compound ligand that in used elastomeric material, adds three kinds of mould inhibitors, antiseptic-germicide, anti-algae agent makes it have the antibiotic mildew-resistant algae-resistant function; Its mechanism of action is through destroying the cell structure of mould and algae; Stop metabolism; The activity that reduces mould and algae prevents or mould fungus inhibition and algae grows and breeding, thereby keeps its visual appearance and performance, do not need frequent cleaning, saved a large amount of manpower and materials.
Embodiment
Antibiotic mildew-resistant algae-resistant elastomeric material of the present invention; Wherein, Main rubber comprises tree elastomer, styrene-butadiene rubber(SBR), terpolymer EP rubber, X 050, paracril, chlorosulfonated polyethylene rubber, chlorinatedpolyethylene or arbitrary combination wherein, derosal, N-octyl group RH-893 and Diuron Tech, at first, derosal, N-octyl group RH-893, three kinds of materials of Diuron Tech is joined in the rubber dam sizing material by the formula rate fusion; Fusion is in closed rubber kneading machine or back mixing machine, to carry out; The sizing material temperature is 50 ℃-110 ℃ during fusion, and blending time 5-10 minute, (wherein; The add-on of compound ligand accounts for the heavy 0.3%-0.5% of elastomeric material sizing material); Secondly, the rubber unvulcanizate that fusion is good extrudes on rubber calender or film forcing machine has certain width in (general 0.5-1.5 rice), the film that certain thickness (general 0.4-20mm) length is not limit.40 ℃-90 ℃ of the temperature that calendering is extruded once more, are vulcanized film on vulcanizing press, process work in-process sulfide film or adhesive plaster.140-160 ℃ of sulfuration process temperature, last, promptly be made into the antibiotic mildew-resistant algae-resistant elastomeric material with vulcanizating size blanking, the moulding of film or adhesive plaster by regulation.
Above embodiment describes preferred implementation of the present invention; Be not that scope of the present invention is limited; Design under the prerequisite of spirit not breaking away from the present invention; Various distortion and improvement that the common engineering technical personnel in this area make technical scheme of the present invention all should fall in the definite protection domain of claims of the present invention.
Claims (2)
1. antibiotic mildew-resistant algae-resistant elastomeric material; Its main rubber comprises tree elastomer, styrene-butadiene rubber(SBR), terpolymer EP rubber, X 050, paracril, chlorosulfonated polyethylene rubber, chlorinatedpolyethylene or arbitrary combination wherein, it is characterized in that: also comprise derosal, N-octyl group RH-893 and Diuron Tech.
2. the preparation method according to right 1 said antibiotic mildew-resistant algae-resistant elastomeric material is characterized in that, may further comprise the steps:
1 >, mixing fusion: derosal, N-octyl group RH-893, three kinds of materials of Diuron Tech are joined in the rubber size by the formula rate fusion; Fusion is in closed rubber kneading machine or back mixing machine, to carry out; 50 ℃-110 ℃ of the temperature of sizing material during fusion, blending time 5-10 minute.
2 >, roll, extrude compound slice: the rubber unvulcanizate that fusion is good extrudes on rubber calender or film forcing machine has certain width in (general 0.5-1.5 rice), film or adhesive plaster that certain thickness (general 0.4-20mm) length is not limit.40 ℃-90 ℃ of the temperature that calendering is extruded.
3 >, sulfuration flat board or drum vulcanizer sulfuration: film is vulcanized on sulfuration flat board or drum vulcanizer, process work in-process sulfide film or adhesive plaster.140-160 ℃ of sulfuration process temperature.
4 >, blanking moulding: will vulcanizate film or adhesive plaster and promptly be made into the antibiotic mildew-resistant algae-resistant elastomeric material by size blanking, the moulding of stipulating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101763618A CN102558619B (en) | 2011-06-28 | 2011-06-28 | Rubber material with characteristics of bacterial resistance, fungi resistance and algae resistance, and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101763618A CN102558619B (en) | 2011-06-28 | 2011-06-28 | Rubber material with characteristics of bacterial resistance, fungi resistance and algae resistance, and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102558619A true CN102558619A (en) | 2012-07-11 |
| CN102558619B CN102558619B (en) | 2013-11-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2011101763618A Expired - Fee Related CN102558619B (en) | 2011-06-28 | 2011-06-28 | Rubber material with characteristics of bacterial resistance, fungi resistance and algae resistance, and preparation method thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103866958A (en) * | 2014-03-13 | 2014-06-18 | 苏州市相城区明达复合材料厂 | Antibacterial rubber floor |
| CN104017282A (en) * | 2014-05-06 | 2014-09-03 | 天长市远洋船舶设备有限公司 | Marine high-strength aging-resistant rubber material |
| CN104403151A (en) * | 2014-12-22 | 2015-03-11 | 孙宝林 | Elastic rubber floorboard |
| CN104494032A (en) * | 2014-12-22 | 2015-04-08 | 孙宝林 | Preparation method of elastic rubber floor |
| CN104804251A (en) * | 2015-04-27 | 2015-07-29 | 安徽美祥实业有限公司 | Antibacterial and antistatic rubber floor |
| CN104927124A (en) * | 2015-05-29 | 2015-09-23 | 安徽同丰橡塑工业有限公司 | Antibacterial antistatic and wear-resistant rubber floor |
| CN105694158A (en) * | 2016-03-29 | 2016-06-22 | 无锡智谷锐拓技术服务有限公司 | Preparation method of anti-mildew rubber |
| CN105885294A (en) * | 2016-06-15 | 2016-08-24 | 苏州锦腾电子科技有限公司 | Packaging material for electronic product and preparation method of packaging material |
| CN105968459A (en) * | 2016-05-16 | 2016-09-28 | 天津纽威特橡胶制品股份有限公司 | Bacteriostatic rubber floorboard for stadium |
| CN107502072A (en) * | 2017-09-12 | 2017-12-22 | 滁州远方车船装备工程有限公司 | A kind of preparation method of the rubber floor covering with antibacterial bacteriostatic effect |
| CN107624773A (en) * | 2017-10-17 | 2018-01-26 | 四川国光农化股份有限公司 | A kind of composition pesticide and its application on preventing and treating moss |
| CN107915881A (en) * | 2017-12-27 | 2018-04-17 | 安徽微威环保科技有限公司 | A kind of heat conduction antibacterial rubber material |
| CN108586785A (en) * | 2018-04-18 | 2018-09-28 | 合肥易美特建材有限公司 | A kind of novel rubber floor and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6149927A (en) * | 1997-08-14 | 2000-11-21 | Rohm And Haas Company | Solid biocidal compositions |
| US20100240800A1 (en) * | 2009-03-20 | 2010-09-23 | Dash Multi-Corp | Biocidal elastomeric compositions and methods of making the same |
-
2011
- 2011-06-28 CN CN2011101763618A patent/CN102558619B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6149927A (en) * | 1997-08-14 | 2000-11-21 | Rohm And Haas Company | Solid biocidal compositions |
| US20100240800A1 (en) * | 2009-03-20 | 2010-09-23 | Dash Multi-Corp | Biocidal elastomeric compositions and methods of making the same |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103866958A (en) * | 2014-03-13 | 2014-06-18 | 苏州市相城区明达复合材料厂 | Antibacterial rubber floor |
| CN104017282A (en) * | 2014-05-06 | 2014-09-03 | 天长市远洋船舶设备有限公司 | Marine high-strength aging-resistant rubber material |
| CN104403151A (en) * | 2014-12-22 | 2015-03-11 | 孙宝林 | Elastic rubber floorboard |
| CN104494032A (en) * | 2014-12-22 | 2015-04-08 | 孙宝林 | Preparation method of elastic rubber floor |
| CN104804251A (en) * | 2015-04-27 | 2015-07-29 | 安徽美祥实业有限公司 | Antibacterial and antistatic rubber floor |
| CN104927124A (en) * | 2015-05-29 | 2015-09-23 | 安徽同丰橡塑工业有限公司 | Antibacterial antistatic and wear-resistant rubber floor |
| CN105694158A (en) * | 2016-03-29 | 2016-06-22 | 无锡智谷锐拓技术服务有限公司 | Preparation method of anti-mildew rubber |
| CN105968459A (en) * | 2016-05-16 | 2016-09-28 | 天津纽威特橡胶制品股份有限公司 | Bacteriostatic rubber floorboard for stadium |
| CN105885294A (en) * | 2016-06-15 | 2016-08-24 | 苏州锦腾电子科技有限公司 | Packaging material for electronic product and preparation method of packaging material |
| CN107502072A (en) * | 2017-09-12 | 2017-12-22 | 滁州远方车船装备工程有限公司 | A kind of preparation method of the rubber floor covering with antibacterial bacteriostatic effect |
| CN107624773A (en) * | 2017-10-17 | 2018-01-26 | 四川国光农化股份有限公司 | A kind of composition pesticide and its application on preventing and treating moss |
| CN107915881A (en) * | 2017-12-27 | 2018-04-17 | 安徽微威环保科技有限公司 | A kind of heat conduction antibacterial rubber material |
| CN108586785A (en) * | 2018-04-18 | 2018-09-28 | 合肥易美特建材有限公司 | A kind of novel rubber floor and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102558619B (en) | 2013-11-13 |
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Inventor after: Liu Zhengguo Inventor after: Sun Jingping Inventor after: Cui Baocheng Inventor after: Zhou Zhengmin Inventor after: Wang Jiahui Inventor before: Liu Zhengguo Inventor before: Sun Jingping Inventor before: Cui Baocheng |
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Free format text: CORRECT: INVENTOR; FROM: LIU ZHENGGUO SUN JINGPING CUI BAOCHENG TO: LIU ZHENGGUO SUN JINGPING CUI BAOCHENG ZHOU ZHENGMIN WANG JIAHUI |
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Granted publication date: 20131113 Termination date: 20180628 |