CN107624773A - A kind of composition pesticide and its application on preventing and treating moss - Google Patents

A kind of composition pesticide and its application on preventing and treating moss Download PDF

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Publication number
CN107624773A
CN107624773A CN201710991933.5A CN201710991933A CN107624773A CN 107624773 A CN107624773 A CN 107624773A CN 201710991933 A CN201710991933 A CN 201710991933A CN 107624773 A CN107624773 A CN 107624773A
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China
Prior art keywords
composition pesticide
moss
active component
application
active components
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CN201710991933.5A
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Chinese (zh)
Inventor
邓建华
陈曦
李锐
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Sichuan Guoguang Agrochemical Co Ltd
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Sichuan Guoguang Agrochemical Co Ltd
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Priority to CN201710991933.5A priority Critical patent/CN107624773A/en
Publication of CN107624773A publication Critical patent/CN107624773A/en
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Abstract

The present invention, which discloses a kind of composition pesticide and its application on preventing and treating moss, the composition pesticide, to be included:Active components A and active component B;The active components A is OIT, and the active component B is carbendazim;The active components A and the active component B weight ratio are 1:(0.1~10);The composition for preventing and controlling moss has obvious synergistic effect, and effect is good, quick, has slow releasing function, and continuation is good, reduces dosage, no poisoning, so as to reduce the influence to environment, is applied after being applicable to tea tree stump, can improve tea leaf quality.

Description

A kind of composition pesticide and its application on preventing and treating moss
Technical field
The present invention relates to technical field of pesticide, and in particular to a kind of composition pesticide and its application on preventing and treating moss.
Background technology
Influenceed by humiture, moss is easily grown on tea tree, wherein, relatively contained between late spring and early summer, summer developmental retardation, autumn Continued growth, winter taper off.And moss produces significant damage to growth of tea plant.1st, the photosynthesis and gas of plant are influenceed Exchange.The moss being grown on leaf will directly affect being normally carried out for leaf photosynthesis, so as to influence the normal life of plant It is long;And branch, the excessively vigorous moss of dry above growth also can be by hindering the absorption of branch, the gas exchanges of stem organization and light and shadow Branch or dry normal growth are rung, results even in the death of some sprigs.2nd, young sprout germination is influenceed.The moss being covered on branches and leaves If overstocked with lichen, leaf bud can be caused normally to sprout or postpone sprouting, promote the decline progress faster of tea tree.3、 Moss is that disease pest growth creates condition on tea tree, has aggravated the generation of tea place pest and disease damage.4th, the quality of tealeaves is reduced.On tealeaves The moss of dip-dye is difficult to peel off, and into tea product, reduces the quality of tea product.
Being usually used in preventing and treating the decoction of tea tree moss includes:Soda quick lime mixture, resin soap emulsifiable concentrate, lime sulfur, Bordeaux Liquid, ziram, ferrous sulfate and glyphosate.Wherein, soda quick lime mixture, resin soap emulsifiable concentrate, lime sulfur, Bordeaux mixture are alkali Property agricultural chemicals, the corrosion to tea tree is big, influences growth of tea plant, and can only be used in tea tree dormancy season;Ziram, ferrous sulfate activity Low, usage amount is big, and the lasting period is short;It is root characteristics that there is glyphosate interior suction to kill to tea tree, and the growth to tea tree is unfavorable.
The content of the invention
In view of this, the application this application provides a kind of composition pesticide and its on preventing and treating moss, the composition Preventing and treating moss has obvious synergistic effect, and effect is good, quick, has slow releasing function, and continuation is good, reduces dosage, nothing Poisoning, so as to reduce the influence to environment, applied after being applicable to tea tree stump, tea leaf quality can be improved.
To solve above technical problem, technical scheme provided by the invention is a kind of composition pesticide on preventing and treating moss Using the composition pesticide includes:Active components A and active component B;The active components A is OIT, the work Property composition B is carbendazim;The active components A and the active component B weight ratio are 1:(0.1~10).
Preferably, the moss is the moss on tea tree.
Preferably, the composition pesticide time of application is after the tea tree stump.
Preferably, the composition pesticide method of application is the active components A and the active component B methods of application are Apply or successively apply together.
Preferably, the active components A and the active component B methods of application are to apply together.
Preferably, the composition pesticide method of application be spraying, atomizing, dust, soak, spread fertilizer over the fields and pour it is middle one kind or It is a variety of.
Present invention also offers a kind of composition pesticide, the composition pesticide includes:Active components A and active component B; The active components A is OIT, and the active component B is carbendazim;The active components A and the active component B Weight ratio is 1:(0.1~10).
Preferably, the active components A and the active component B weight ratio are 1:(1~10).
Preferably, the active components A and the active component B weight ratio are 1:(1~5).
Preferably, the OIT is BIT, 2-n- octyl group -4- isothiazolines -3- Ketone, MIT, the one or more of 2- methyl-5-chloro -4- isothiazoline -3- ketone.
Preferably, the OIT is by MIT and 2- methyl-5-chloro -4- isothiazole Quinoline -3- ketone forms.
Preferably, the OIT is by MIT and 2- methyl-5-chloro -4- isothiazole Quinoline -3- ketone forms, the MIT and the 2- methyl-5-chloros -4- isothiazolines -3- ketone weight ratio For 1:3.
Preferably, it is calculated in mass percent, the active components A and described active component B are in the composition pesticide Middle content summation is 0.5%~70%.
Preferably, the composition pesticide also includes:Acceptable auxiliary material in Pesticide Science.
Preferably, the auxiliary material includes:Solvent, solid carrier.
Preferably, the auxiliary material also includes:Surfactant.
Preferably, surfactant for it is at least one selected from nonionic surfactant, cationic surfactant, it is cloudy from Sub- surfactant or amphoteric surfactant.
Preferably, the composition pesticide formulation is wettable powder, tablet, granule or dispersible oil-suspending agent.
Active components A is OIT:OIT is by the active part on isothiazoline ketone heterocyclic and bacterium Base in vivo protein on DNA molecular forms hydrogen bond, and is adsorbed on the cell of bacterium, plays the work of attack cells nucleophilic With so as to destroy intracellular DNA structure, making it lose replication capacity, lose relevant physiological, biochemical reaction and metabolism and live It is dynamic, key cell death of the OIT also by disconnecting liver moss protein.
Active component B is carbendazim:Carbendazim is high-efficiency low-toxicity systemic fungicide, has interior suction treatment and protective effect With the formation for disturbing spindle in sick cell mitogen, cell proper splitting is destroyed, and to people, animal, fish low toxicity.More bacterium Spirit does not have prevention effect to liver moss.
Compared with prior art, its detailed description is as follows by the application:
Composition pesticide provided by the invention is compounded using active components A OIT and active component B carbendazim, Weight proportion scope is 1:(0.1~10), active component B enhancing active components As prevent and treat the effect of the moss on tea tree, effect It is good, there are obvious synergistic effect, no poisoning;In the case of reaching identical preventive effect, compared with single dose, composition can reduce use Dose, so as to reduce the influence to environment.Meanwhile to reduce tea tree height, it is easy to harvest, at present, selects the fine hot weather extensively Clear and Bright after and enter to carry out tea tree stump before the winter, and composition pesticide provided by the invention can be applied in the period, dispenser 10 days It can show positive effect, after dispenser 30 days, prevention effect can reach more than 87.3%, after dispenser 70 days, prevention effect More than 86.92% can still be reached, rapid-action, effect is good and has lasting effect, and so as to reduce dosage, it is residual to reduce agricultural chemicals Stay, improve tea leaf quality.
Embodiment
In order that those skilled in the art more fully understands technical scheme, with reference to specific embodiment pair The present invention is described in further detail.
Embodiment 1
Wettable powder
The OIT is by MIT and 2- methyl-5-chloro -4- isothiazoline -3- ketone groups Into the MIT and the 2- methyl-5-chloros -4- isothiazolines -3- ketone weight ratio are 1:3.
Preparation method:Material is well mixed air-flow crushing.
Embodiment 2
Wettable powder
The OIT is by MIT and 2- methyl-5-chloro -4- isothiazoline -3- ketone groups Into the MIT and the 2- methyl-5-chloros -4- isothiazolines -3- ketone weight ratio are 1:3.System Preparation Method:Material is well mixed into air-flow crushing can discharge unlap.
Embodiment 3
Dispersible oil-suspending agent
The OIT is by MIT and 2- methyl-5-chloro -4- isothiazoline -3- ketone groups Into the MIT and the 2- methyl-5-chloros -4- isothiazolines -3- ketone weight ratio are 1:3.System Preparation Method:Material is mixed, is sanded in sand mill to D90It can be discharged unlap less than 5um.
Embodiment 4
Wettable powder
The OIT is 1,2- benzisothiazole-3-ketones.
Preparation method:Material is mixed into the unlap that can discharge.
Preparation method:Material is well mixed air-flow crushing to granularity and is less than 325 mesh, is discharged, unlap.
Embodiment 5
Tablet
The OIT is 2-n- octyl group -4- isothiazoline -3- ketone.
Preparation method:Material is mixed, crushes, remixes, tabletting is according to finished product.
Embodiment 6
Dispersible oil-suspending agent
The OIT is by MIT and 2- methyl-5-chloro -4- isothiazoline -3- ketone groups Into the MIT and the 2- methyl-5-chloros -4- isothiazolines -3- ketone weight ratio are 1:3.
Preparation method:Material is mixed, is sanded to D95 and is less than 5um discharging unlaps.
Embodiment 7
Granule
The OIT is by MIT and 2- methyl-5-chloro -4- isothiazoline -3- ketone groups Into the MIT and the 2- methyl-5-chloros -4- isothiazolines -3- ketone weight ratio are 1:3.System Preparation Method:OIT, carbendazim, alkylnaphthalene sulfonate, lignosulfonates, white carbon, attapulgite are well mixed It is crushed to D95 and is less than 5um.After polyvinylpyrrolidone is configured into 1% aqueous solution, the material that adds after crushing, mediate, It is granulated, dries, is screened into finished product unlap.
Embodiment 8
Effect experiment
1st, test material:Moss on tea tree.
2nd, experimental design:The processing of experimental design 13, and set blank control processing, to entering tea tree stump before the winter after Clear and Bright Afterwards, each processing is repeated 4 times, totally 56 cells, plot area 112m2, random district's groups arrangement.Per minizone every 20cm.Agricultural chemicals group Active components A is OIT in compound, active component B be to bacterium spirit, OIT by 2- methyl -4- isothiazolines - 3- ketone and 2- methyl-5-chloro -4- isothiazoline -3- ketone composition, the MIT and the 2- methyl - The chloro- 4- isothiazolines -3- ketone weight ratios of 5- are 1:3.
3rd, efficacy survey:30th day investigation drug effect after dispenser, by 0 (no moss), 1 (1%~10% slightly moss), 3 (11%~25% moss is somewhat green), 5 (26%~50% moss visual field is visible), 7 (51%~5% moss cakings), 9 (76% ~100% moss is covered with tea tree) level grade scale.Each cell chooses 5 points, and each point is in 0.4m2In the range of investigate record Each processing cell moss occurs series and compares calculating preventive effect.
4th, data statistic analysis:Analyzed using DPS6.55 (Duncan) statistical software.Calculated according to test data Go out to calculate preventive effect T1(%).
Preventive effect calculation formula:T=(C0-C1)/C0×100
In formula:T --- preventive effect %.
C0--- the average series of blank district.
C1--- the average series of chemicals treatment district.
5th, evaluation method:Obtained using Colby formula and prevent and kill off rate E after theory is used with1(%).Practical measurement it is mixed after Deliberated index T1The theory index E that (%) is drawn with Colby formula1(%) compares, and the difference of actual value and theoretical value is more than 10% effect for Synergistic, actual value and the difference of theoretical value between ± 10% for the effect that is added, it is actual The difference of value T (%) and theoretical value less than -10% for antagonism.
Colby formula:E=X+Y-XY/100;X, Y is actually to prevent and kill off rate obtained by alone each component respectively.
1 single medicine of table or composition are applied to the result of the test of moss
Above test data shows:OIT single dose application preventing and treating moss effect is poor, and carbendazim single dose is without obvious anti- Moss effect is controlled, OIT and carbendazim compounding weight ratio are 1:(0.1~10) application preventing and treating moss, has Synergistic Effect, effect are good;Weight ratio is 1:(1~10), it is better;Weight ratio is 1:(1~8), it is better;Weight ratio is 1:5, Best results, meanwhile, concentration is low, and into environment, release chemical substance is few, environment-friendly;Namely active components A and activity Composition B ratios are 1:(0.1~10) application preventing and treating moss, has synergistic function;Preferably, weight ratio is 1:(1~10);More Preferably, weight ratio is 1:(1~8);Most preferably, weight ratio is 1:5.
Embodiment 9
1st, test material:Moss on tea tree.
2nd, experimental design:The processing of experimental design 7, and set blank control processing, to entering tea tree stump before the winter after Clear and Bright Afterwards, each processing is repeated 4 times, totally 36 cells, plot area 32m2, random district's groups arrangement.Per minizone every 20cm;7 processing Respectively 1 single dose treatment group and 6 compositions-treated groups, single dose treatment group 1 are the processing of 100ppm carbendazim single dose;Composition Treatment group 1~6 is the processing mixed with 100ppm carbendazim of 20ppm OITs, wherein, OIT is respectively composition 1 is made up of MIT and 2- methyl-5-chloro -4- isothiazoline -3- ketone with carbendazim, the 2- first Base -4- isothiazoline -3- ketone and the 2- methyl-5-chloros -4- isothiazolines -3- ketone weight ratio are 1:3;Composition 2 is by 1,2- Benzisothiazole-3-ketone and 2-n- octyl group -4- isothiazoline -3- ketone form with carbendazim, and 1, the 2- benzisothiazoles - 3- ketone and the 2-n- octyl groups -4- isothiazolines -3- ketone weight ratio are 1:3;Composition 3 is by MIT Formed with carbendazim;Composition 4 is made up of 2- methyl-5-chloro -4- isothiazoline -3- ketone with carbendazim;Composition 5 is by 1,2- benzene And isothiazoline -3- ketone forms with carbendazim;Composition 6 is made up of 2-n- octyl group -4- isothiazoline -3- ketone with carbendazim.
3rd, efficacy survey:By 0 (no moss), 1 (1%~10% slightly moss), 3 (11%~25% moss is somewhat green), 5 (26%~50% moss visual field is visible), 7 (51%~5% moss cakings), 9 (76%~100% moss is covered with tea tree) fractions Level standard.Each cell chooses 5 points, and each point is in 0.4m2In the range of investigation record each processing cell moss occur series with Compare calculating preventive effect.
4th, data statistic analysis:Analyzed using DPS6.55 (Duncan) statistical software.Calculated according to test data Go out to calculate preventive effect T (%).
Preventive effect calculation formula:T=(C0-C1)/C0×100
In formula:T --- preventive effect %.
C0--- the average series of blank district.
C1--- the average series of chemicals treatment district.
5th, measurement result:It is shown in Table 2.
2 single medicine of table or composition are applied to the result of the test of moss
Upper test data shows:Active component B single doses do not have preventing and treating moss effect, and the application preventing and treating of active components A single dose is blue or green Tongue effect is poor, and short using duration of efficacy after tea tree stump to entering before the winter after the Clear and Bright of the fine hot weather;
And active components A is applied together with active component B, preventing and treating moss onset time can be shortened, improve preventing and treating moss Effect, slow releasing function is shown, improve lasting effect, dose can be reduced, reduce cost, environment-friendly, no poisoning.
Embodiment 10
1st, test material:Moss on tea tree.
2nd, experimental design:The processing of experimental design 3, and set blank control processing, to entering tea tree stump before the winter after Clear and Bright Afterwards, each processing is repeated 4 times, totally 16 cells, plot area 32m2, random district's groups arrangement.Per minizone every 20cm;7 processing Respectively 1 single dose treatment group and 6 compositions-treated groups, treatment group A~C use 20ppm OITs and 100ppm The mixed processing of carbendazim, treatment group A is 20ppm OITs and 100ppm carbendazim;Treatment group A is different first to apply 20ppm Thiazolinone, apply 100ppm carbendazim afterwards;Treatment group A applies 20ppm isothiazolines afterwards first to apply 100ppm carbendazim Ketone;OIT is made up of MIT and 2- methyl-5-chloro -4- isothiazoline -3- ketone, the 2- Methyl -4- isothiazoline -3- ketone and the 2- methyl-5-chloros -4- isothiazolines -3- ketone weight ratio are 1:3.
3rd, efficacy survey:By 0 (no moss), 1 (1%~10% slightly moss), 3 (11%~25% moss is somewhat green), 5 (26%~50% moss visual field is visible), 7 (51%~5% moss cakings), 9 (76%~100% moss is covered with tea tree) fractions Level standard.Each cell chooses 5 points, and each point is in 0.4m2In the range of investigation record each processing cell moss occur series with Compare calculating preventive effect.
4th, data statistic analysis:Analyzed using DPS6.55 (Duncan) statistical software.Calculated according to test data Go out to calculate preventive effect T (%).
Preventive effect calculation formula:T=(C0-C1)/C0×100
In formula:T --- preventive effect %.
C0--- the average series of blank district.
C1--- the average series of chemicals treatment district.
5th, measurement result:It is shown in Table 3.
Table 3
Upper test data shows:Composition pesticide method of application provided by the invention is the active components A and the work Property composition B methods of application to apply or successively apply together;Preferably, the active components A and the active component B administration sides Formula is to apply together.
It the above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair The limitation of the present invention, protection scope of the present invention should be defined by claim limited range.For the art For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change Enter and retouch and also should be regarded as protection scope of the present invention.

Claims (10)

1. a kind of application of composition pesticide on preventing and treating moss, the composition pesticide include:Active components A and active component B;The active components A is OIT, and the active component B is carbendazim;The active components A and the active component B weight ratio is 1:(0.1~10).
2. application according to claim 1, it is characterised in that the moss is the moss on tea tree.
3. application according to claim 2, it is characterised in that the composition pesticide time of application is the tea tree stump Afterwards.
4. application according to claim 2, it is characterised in that the composition pesticide method of application is the active component A and the active component B methods of application are applied for administration together or successively.
5. a kind of composition pesticide, it is characterised in that the composition pesticide includes:Active components A and active component B;It is described Active components A is OIT, and the active component B is carbendazim;The active components A and the active component B weight Than for 1:(0.1~10).
6. composition pesticide according to claim 5, it is characterised in that the active components A and active component B weights Amount is than being 1:(1~10).
7. composition pesticide according to claim 5, it is characterised in that the OIT is 1,2- benzisothiazoles Quinoline -3- ketone, 2-n- octyl group -4- isothiazoline -3- ketone, MIT, 2- methyl-5-chloro -4- isothiazole The one or more of quinoline -3- ketone.
8. composition pesticide according to claim 5, it is characterised in that the composition pesticide also includes:In Pesticide Science Acceptable auxiliary material.
9. composition pesticide according to claim 5, it is characterised in that be calculated in mass percent, the active components A and Described active component B content summations in the composition pesticide are 0.5%~70%.
10. composition pesticide according to claim 5, it is characterised in that the composition pesticide formulation is wettable powder Agent, tablet, granule or dispersible oil-suspending agent.
CN201710991933.5A 2017-10-17 2017-10-17 A kind of composition pesticide and its application on preventing and treating moss Pending CN107624773A (en)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5185357A (en) * 1990-02-26 1993-02-09 Shinto Paint Co., Ltd. Industrial antifungal composition
JP2003055116A (en) * 2001-08-10 2003-02-26 Takeda Chem Ind Ltd Industrial microbicident composition
JP2003146814A (en) * 2001-11-13 2003-05-21 Shoei Kagaku Kk Antibacterial, antiseptic, antifungal agent for industry and its antibacterial, antiseptic, antifungal method
CN101531836A (en) * 2009-04-13 2009-09-16 杭州中富彩化工新材料有限公司 Formula of environment-friendly type aqueous color paste for leather and coating as well as manufacturing method thereof
CN102558619A (en) * 2011-06-28 2012-07-11 北京东光橡塑制品有限公司 Rubber material with characteristics of bacterial resistance, fungi resistance and algae resistance, and preparation method thereof
CN103468132A (en) * 2013-09-25 2013-12-25 北京国电富通科技发展有限责任公司 Moss-prevention anti-contamination-flashover coatings and preparation method thereof
CN103975948A (en) * 2014-06-10 2014-08-13 山东瑞爱特环保科技有限公司 Biocide-algaecide for circulating water and preparation method thereof
CN105418044A (en) * 2014-09-16 2016-03-23 北新集团建材股份有限公司 Mildewproof thistle board and preparation method thereof
CN105773764A (en) * 2014-12-24 2016-07-20 党庆风 Wood water-soluble anticorrosion bactericide
CN106497063A (en) * 2016-10-20 2017-03-15 清华大学深圳研究生院 A kind of kill the antibacterial silicone rubber insulation material of algae and preparation method

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5185357A (en) * 1990-02-26 1993-02-09 Shinto Paint Co., Ltd. Industrial antifungal composition
JP2003055116A (en) * 2001-08-10 2003-02-26 Takeda Chem Ind Ltd Industrial microbicident composition
JP2003146814A (en) * 2001-11-13 2003-05-21 Shoei Kagaku Kk Antibacterial, antiseptic, antifungal agent for industry and its antibacterial, antiseptic, antifungal method
CN101531836A (en) * 2009-04-13 2009-09-16 杭州中富彩化工新材料有限公司 Formula of environment-friendly type aqueous color paste for leather and coating as well as manufacturing method thereof
CN102558619A (en) * 2011-06-28 2012-07-11 北京东光橡塑制品有限公司 Rubber material with characteristics of bacterial resistance, fungi resistance and algae resistance, and preparation method thereof
CN103468132A (en) * 2013-09-25 2013-12-25 北京国电富通科技发展有限责任公司 Moss-prevention anti-contamination-flashover coatings and preparation method thereof
CN103975948A (en) * 2014-06-10 2014-08-13 山东瑞爱特环保科技有限公司 Biocide-algaecide for circulating water and preparation method thereof
CN105418044A (en) * 2014-09-16 2016-03-23 北新集团建材股份有限公司 Mildewproof thistle board and preparation method thereof
CN105773764A (en) * 2014-12-24 2016-07-20 党庆风 Wood water-soluble anticorrosion bactericide
CN106497063A (en) * 2016-10-20 2017-03-15 清华大学深圳研究生院 A kind of kill the antibacterial silicone rubber insulation material of algae and preparation method

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Application publication date: 20180126