CN107836453A - A kind of Chinese prickly ash moss scavenger composition and its application - Google Patents
A kind of Chinese prickly ash moss scavenger composition and its application Download PDFInfo
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- CN107836453A CN107836453A CN201710962429.2A CN201710962429A CN107836453A CN 107836453 A CN107836453 A CN 107836453A CN 201710962429 A CN201710962429 A CN 201710962429A CN 107836453 A CN107836453 A CN 107836453A
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- Prior art keywords
- prickly ash
- chinese prickly
- moss
- scavenger composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
Abstract
The invention discloses a kind of Chinese prickly ash moss scavenger composition and its application, the Chinese prickly ash moss scavenger composition includes：Active components A and active component B, the A is isothiazolinone derivative, the B be selected from DMH, dibromo dimethyl hydantoin, dichloro-dimethyl Hai Ying, bromochlorodimethyl hydanton one or more, the active components A and the active component B weight ratio are 1:(0.1 15), for removing Chinese prickly ash trunk, leaf, the moss on garden mould.Technical scheme has haveed the function that compound synergic, while improves Chinese prickly ash yield.
Description
Technical field
The present invention relates to plant growth regulating field, specially a kind of Chinese prickly ash moss scavenger composition and its application.
Background technology
Chinese prickly ash is the distinctive woody oleiferous plants in China and spices seeds.At present China formed scale plantation have Si Chuanhan
The ground such as source, Chongqing Jiangjin, Hancheng Region, Shaanxi, Feng County, Shanxi Ruicheng, Gansu Wudu, Qin'an, Guizhou, Laiwu in Shandong province, Hebei She County
Area.In recent years, with agricultural restructuring, each department Chinese prickly ash industry has a larger development, and China's Chinese prickly ash planting scale is annual
With 20%-30% speed increase.Chinese prickly ash tree body moss, often occur in ground, limb, blade, obstructed medicine, fertilizer and tree
The contact of body, the utilization rate of medicine fertilizer is reduced, indirectly add fertilizer, the administration cost of medicine.Moss weakens the light of plant simultaneously
Cooperation is used, and is more easy to grow disease pest, is caused Growth status bad, tree vigo(u)r decline etc., has a strong impact on the yield and quality of Chinese prickly ash.
Preventing and treating Chinese prickly ash trunk, leaf and the medicament of garden mould moss mainly have containing Kocide SD, cuprous oxide, oxychlorination at present
Copper, copper sulphate agent, mineral oil, rosin acid sodium, S-Ethyl ethylthio sulfonate, ambam, Peracetic acid, chlorobromide isocyanuric acid, dichlord isocyanurice acid,
Lime, Bordeaux mixture etc..But copper agent only has certain inhibitory action to not serious moss, and killing effect is bad, compounding is tired
Difficulty, poisoning easily occurs using young fruit period during high temperature, can also stimulate mite to do harm to, mineral oil, ambam, rosin acid sodium make when temperature is high
Poisoning is produced with easy；Peracetic acid, chlorobromide isocyanuric acid sodium, sodium dichloro cyanurate, oxidisability is strong, has to human body stronger
Excitant, security risk are big；Lime, Bordeaux mixture alkalescence are strong, have corrosion risk to bark and leaf, after use, Chinese pricklyash length
Gesture is deteriorated.
In summary, existing moss scavenger has that drug effect is not strong, has poisoning, the shortcomings that influenceing Chinese prickly ash yield.
The content of the invention
In view of this, the application provides a kind of Chinese prickly ash moss scavenger composition and its application, for remove Chinese prickly ash trunk,
Moss on leaf, garden mould.Technical scheme has haveed the function that compound synergic, while improves Chinese prickly ash yield.
To solve above technical problem, technical scheme provided by the invention is that a kind of Chinese prickly ash moss scavenger composition is being gone
Except the application on Chinese prickly ash trunk, leaf, garden mould moss, the Chinese prickly ash moss scavenger composition includes：Active components A and activity
Composition B, the A are isothiazolinone derivative, and the B is selected from DMH, dibromo dimethyl hydantoin, dichloro diformazan
Ji Haiying, bromochlorodimethyl hydanton one or more, the active components A and the active component B weight ratio are 1:
(0.1-15)。
Preferably, effective application concentration of the composition is 1-100ppm, and Dressing date includes before Chinese prickly ash rudiment half
After the moon, leaf stretching period, secondary physiological fallen fruit phase, fruit growth period, autumn fruit picking, after fallen leaves 2/3, one is applied every time to twice, every time
Interval 10-15 days, application process include spraying, atomizing, dust, soak, spreading fertilizer over the fields, pouring.
The present invention also provides a kind of Chinese prickly ash moss scavenger composition, and the composition is made up of A and B, and the A is different
Thiazolinone analog derivative, the B are selected from DMH, dibromo dimethyl hydantoin, dichloro-dimethyl Hai Ying, bromine chlorine diformazan
The one or more of base glycolylurea, the weight ratio of the A and B are 1:(0.1-15).
Preferably, the weight ratio of the A and B are 1:(0.5-5).
Preferably, the weight ratio of the A and B are 1:3.
Preferably, the A is MIT (MI) and 2- methyl-5-chloro -4- isothiazoline -3- ketone
(CMI) mixture.
Preferably, the B be selected from dibromo dimethyl hydantoin, dichloro-dimethyl Hai Ying, bromochlorodimethyl hydanton one kind or
It is several.
Preferably, the B is dibromo dimethyl hydantoin.
Preferably, according to above-mentioned Chinese prickly ash moss scavenger composition, be calculated in mass percent, the active components A and
Described active component B content summations in the plant growth regualting composition are 0.5%~70%.
Preferably, the plant growth regualting composition also includes：Acceptable auxiliary material in Pesticide Science.
It is more highly preferred to, the Chinese prickly ash moss scavenger combination dosage form is wettable powder, tablet, granule or can divided
Dissipate oil-suspending agent.
Moss is bryophyte, and bryophyte (Bryophyte) belongs to most low higher plant.Plant is without flower, nothing
Seed, it is simple in construction with sporogenesis, only comprising stem and leaf two parts, only flat thallus sometimes, without real root
And vascular bundle, the internal structure of plant is simple, rhizoid by unicellular or be made up of a row cell, no center pillar, only compared with
There is the cell mass of similar conducting tissue in advanced species.The cell of bryophyte is by cell membrane, cell membrane, cytoplasm, cell
Core forms.The cytoplasm of higher bryophyte includes cytoplasmic matrix and organelle.Organelle includes：Endoplasmic reticulum, line grain
Body, golgiosome, ribosomes, lysosome, chloroplaset, vacuole.The chemical composition of bryophyte cell is water (with reference to water and freedom
Water) 85-95%, protein 7-10%, lipid 1-2% nucleic acid (DNA 0.4%RNA 0.7%), other organic matter 0.4-1%,
Inorganic matter 1-1.6%.
OIT is heterocycle structural compounds, and common isothiazolinone compound has：1,2- benzisoxas
Thiazoline -3- ketone (BIT), 2-n- octyl group -4- isothiazoline -3- ketone (OIT), MIT (MIT),
5- chloro-2-methyl -4- isothiazole beautiful jade -3- ketone (CMIT).Their common feature is that strong antibacterial, application dose are small, compatible
Property is good, toxicity is low etc., all has very strong antibacterial action to various bacteria, fungi.This analog derivative have high efficiency, preferably
Compatibility, the wider pH scope of applications, can natural biology degraded the advantages that.
Isothiazolinone derivative prevent and kill off moss mechanism be mainly by the active part on isothiazoline ketone heterocyclic with
Moss cell membrane adsorbs, and then into cell body, hydrogen bond is formed with the base on DNA molecular, so as to destroy intracellular DNA's
Structure, it is lost replication capacity, lose relevant physiological, biochemical reaction and metabolic activity, OIT can also be by disconnected
Opening the one-level connecting key of moss cell protein makes cell death.
The amino reaction of protein, makes protein denaturation, loses life in formaldehyde and cell that DMH passes through sustained release
Reason activity, so as to have the function that to prevent and kill off moss.Halo DMH prevents and kill off moss principle in addition to formaldehyde is sustained, and also release is lived
Property halogen act on the cell membrane of microorganism, make the increase of its permeability, the protein in cell is spilt with nucleic acid, cell death；
Halogen atom can also act on DNA, be broken double-strand；And reactive halogen also there is oxidation to make important and sensitive enzyme
With disturbing moss cell metabolism, make moss dead.In hydantoin-based compound, evaluated from liver moss effect is killed, halo diformazan
Base glycolylurea is better than non-halogenated glycolylurea, and C5H6Br2N2O2 is better than BCDMH in halo DMH, and BCDMH is better than dichloro sea
Cause.
In the present invention, isothiazolinone derivative and DMH, dibromo dimethyl hydantoin, dichloro-dimethyl sea
English, bromochlorodimethyl hydanton have synergistic function on tea tree moss is killed, and the two is administered simultaneously, and it is thin to add moss first
The permeability of after birth, isothiazolinone derivative is adsorbable on cell membrane, guiding the attack to cell, and then makes in cell
Protein spilt with nucleic acid compositions；And isothiazolinone derivative can also directly act on moss with hydantoin-based compound
Amino in protein component in cell, with its structure reacts, and triggers one-level connection to build fracture, causes the change of protein
Property；Isothiazolinone derivative can act on hydantoin halides class compound with the intracellular DNA of moss simultaneously, be formed extra
Hydrogen bond so that the fracture of former DNA molecular double-strand hydrogen bond, it is lost replication capacity, lose relevant physiological, biochemical reaction, cause
The stopping of metabolic activity；Reactive halogen also there is oxidation to make enzyme important and sensitive in moss metabolic pathway in hydantoin halides
With the metabolism of interference moss cell from another point of view.Above-mentioned composition is applied to Chinese prickly ash trunk, leaf, on garden mould, can be cooperateed with
Moss is removed, excludes moss to the obstruction of Chinese prickly ash growth course so that Chinese prickly ash tree body, branches and leaves and the fertile contact with sunlight of medicine are more
Fully, meanwhile, the composition in this programme, belong to micromolecular compound, different from copper class preparation of the prior art, applying
In the range of, do not have poisoning to Chinese prickly ash, finally substantially increase the yield of Chinese prickly ash on the contrary, while because of its biodegradable, to ring
Border and human body are also friendly harmless.
Embodiment
In order that those skilled in the art more fully understands the technical scheme of invention, with reference to embodiment pair
The present invention is described in further detail.
Preventing and treating Chinese prickly ash trunk, leaf and the medicament of garden mould moss mainly have containing Kocide SD, cuprous oxide, oxychlorination at present
Copper, copper sulphate agent, mineral oil, rosin acid sodium, S-Ethyl ethylthio sulfonate, ambam, Peracetic acid, chlorobromide isocyanuric acid, dichlord isocyanurice acid,
Lime, Bordeaux mixture etc..And foregoing moss scavenger has that drug effect is not strong, there is poisoning, the shortcomings that influenceing Chinese prickly ash yield.
Glycolylurea is the general name of a kind of compound, and their parent is all 5 penta azacyclos containing methyl substituents
Compound, i.e. 5,5- dimethyl hydantoins (5,5-dimethy lhy dantoin), its chemical name are 5,5- dimethyl -2,
4- imidazolinediones, it is commonly called as 5,5- DMHs, abbreviation DMH.DMH ring structure is more stable, but the H on N atoms is very
Vivaciously, it can be substituted by a variety of groups and form derivative not of the same race.Hydantoin halides are the H being connected on DMH rings with N atoms by halogen
A kind of compound of plain atom substitution.
OIT belongs to heterocyclic organic compounds, and its derivative refers to by other materials be substituted on 2,4 and 5
The compound formed.Conventional derivative has the chloro- 4- isothiazole of MIT (MI), 2- methyl -5-
Quinoline -3- ketone (CMI), 1,2- benzisothiazole-3-ketones (BIT), 2-n- octyl group -4- isothiazoline -3- ketone (OIT), 2- methyl -
4- isothiazoline -3- ketone (MIT), 5- chloro-2-methyl -4- isothiazole beautiful jade -3- ketone (CMIT), two chloro- N- octyl groups -4- isothiazole
Quinoline -3- ketone DCOIT, butyl BIT BBIT, methyl BIT MBIT, normal-butyl benzisothiazole
Ketone OBIT etc., and the mixture of said derivative.
Isothiazolinone derivative and hydantoin-based compound are combined in the present invention, can be from different passages
Trigger the death of moss, reach the purpose that compound synergic removes moss, also, the composition of this programme is biodegradable small
Molecular compound, Environmental insults are had no adverse effects, Chinese prickly ash body is not caused damage, while moss is effectively removed,
The yield of Chinese prickly ash can also be improved, achieves unexpected technique effect.
0.1-90% active component can be included in the composition of the present invention by weight percentage；Preferably, it is described
By weight percentage 0.5-70% active component is included in composition；It is more highly preferred to, is included in the composition by weight
Measure the active component of percentages 1-50%；Highly preferred, the composition includes by weight percentage 5.5-45%
Active component.Sum it up, active component isothiazolinone derivative and hydantoin-based compound class compound in the present invention
Effective application concentration of combination is 1-100ppm, and preferably valid density is 5.5ppm-80ppm, is more highly preferred to 10-50ppm, most
For preferred 20-30ppm, above-mentioned weight proportion is adjusted according to required preparation type, can be direct when meeting valid density
Using if active component percentage by weight is too high, it is desirable to using being preceding diluted with water to Valid concentration.
The preparation of Chinese prickly ash moss scavenger composition of the present invention refers to the mode with routine, using in formulation technology
The adjuvant of generally use, it is processed into required preparation.Formulation and the type of composition are mutually suitable, according to crop object and dispenser ring
Border selects application process, such as spraying, atomizing, dusts, soaks, spreads fertilizer over the fields or pours.Dressing date can Chinese prickly ash rudiment first half of the month,
After leaf stretching period, secondary physiological fallen fruit phase, fruit growth period, autumn fruit picking, after fallen leaves 2/3, one is applied every time to twice, per minor tick
10-15 days.Preparation is adopted to be prepared in a known manner, such as by by composition and described auxiliary agent, typically solvent or solid
Body supported homogeneous mixture and/or grinding, also additionally it can carry out preparation of preparation using surfactant.The reality of solvent and solid carrier
Example is described in Liu Bulin chief editors'《Formulations of pesticide process technology》In the second edition (Chemical Industry Press, 1998) second.It is suitable
The surface active cpd of conjunction refers to there is good emulsification, disperse and the nonionic of wettability, cation, anion and/or
Amphoteric surfactant and surfactant mixture.Suitable nonionic, cation, anion and/or amophoteric surface active
The example of agent is listed in Liu Bulin chief editors'《Formulations of pesticide process technology》The second edition (Chemical Industry Press, 1998) the 3rd
In.
Above-mentioned elaborating for the present invention, is the embodiment of the present invention below.
In embodiment, during non-specified otherwise, OIT refers to MIT (MI) and 2- first
The mixture of the chloro- 4- isothiazolines -3- ketone (CMI) of base -5-, usual CMI: MI=3: 1, but be not construed as limiting the invention.
Embodiment one
Preparation method：Material is well mixed air-flow crushing.
Embodiment two
Preparation method：Material is well mixed into air-flow crushing can discharge unlap.
Embodiment three
Preparation method：Material is mixed, is sanded in horizontal sand mill to D90It can be discharged unlap less than 5um.
Example IV
Preparation method：By AEO, tristyryl phenol APEO formaldehyde condensation products phosphate, silicon
Sour magnalium, xanthans, organic silicon defoamer and water are stirred into aqueous phase, under agitation by OIT, dibromo two
Methyl hydantoin adds aqueous phase, is stirred into premix, premix is sanded to D in horizontal sand mill90Less than 5um, you can
Discharging packaging.
Embodiment five
Colby equations determine effect experiment
1st, test material：Moss on Chinese prickly ash
2nd, experimental design：13 processing of experimental design, and blank control processing is set, each processing is repeated 4 times, totally 56 small
Area, plot area 112m2, random district's groups arrangement.Per minizone every 20cm.
3rd, efficacy survey：30th day investigation drug effect after dispenser, by 0 (no moss), 1 (1%~10% slightly moss), 3
(11%~25% moss is somewhat green), 5 (26%~50% moss visual field is visible), 7 (51%~5% moss cakings), 9 (76%
~100% moss is covered with Chinese prickly ash) level grade scale.Each cell chooses 5 points, and each point is in 0.4m2In the range of investigate record
Each processing cell moss occurs series and compares calculating preventive effect.
4th, data statistic analysis：Analyzed using DPS6.55 (Duncan) statistical software.Calculated according to test data
Go out to calculate preventive effect T.
Preventive effect calculation formula：T=(C0-C1)/C0 × 100
In formula：T --- preventive effect %.
The average series of C0 --- blank district.
The average series of C1 --- chemicals treatment district.
5th, evaluation method：Obtained using Colby formula and prevent and kill off rate E (%) after theory is used with.Practical measurement it is mixed after
Deliberated index T compared with the theory index E that Colby formula are drawn, actual value be more than theoretical value 12% be Synergistic
Effect, actual value is more than effect for addition of the difference between 0% -12% of theoretical value, and actual value is less than theoretical value
For antagonism.
Colby formula：E=x+y-xy/100；X, y is actually to prevent and kill off rate obtained by alone each component respectively.
6th, measurement result
1 single medicine of table or composition are applied to the result of the test of Chinese prickly ash moss
Experiment shows：Dibromo dimethyl hydantoin is applied together with OIT, and it is fine to prevent and kill off the effect of Chinese prickly ash moss,
The two mass ratio is 1：There is compound synergic effect, 1 in the range of (0.1-15)：Synergistic effect is more preferably when 3.
Embodiment six
Implement Chinese prickly ash simulation experiments in Hongya and the Chinese prickly ash planting base of Meishan (the second annual bearing after grafting).
1. experimental design：3 processing of experimental design, and blank control processing is set, each processing is repeated 5 times, totally 20 trees.
2. amount of increase in production calculation formula：P=(M1-M0)/M0 × 100
In formula：P --- amount of increase in production %.
M0 --- blank district average product.
M1 --- chemicals treatment district average product.
Experiment shows：OIT is applied together with dibromo dimethyl hydantoin, and compared with single dose, composition can improve
Chinese prickly ash moss preventive effect is prevented and kill off, shows as the increase of Chinese prickly ash yield.
It the above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair
The limitation of the present invention, protection scope of the present invention should be defined by claim limited range.For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change
Enter and retouch and also should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of application of Chinese prickly ash moss scavenger composition on removal Chinese prickly ash trunk, leaf, garden mould moss, the Chinese prickly ash are blue or green
Tongue scavenger composition includes：Active components A and active component B, the A are isothiazolinone derivative, the B be selected from
DMH, dibromo dimethyl hydantoin, dichloro-dimethyl Hai Ying, the one or more of bromochlorodimethyl hydanton, the activity
Composition A and the active component B weight ratio are 1:(0.1-15).
A kind of 2. application according to claim 1, it is characterised in that effective application concentration of the composition is 1-
100ppm, Dressing date include Chinese prickly ash rudiment first half of the month, leaf stretching period, secondary physiological fallen fruit phase, fruit growth period, autumn fruit picking
Afterwards, after fallen leaves 2/3, one is applied every time to twice, every minor tick 10-15 days, application process includes spraying, atomizing, dusts, moistens
It is wet, spread fertilizer over the fields, pour.
3. a kind of Chinese prickly ash moss scavenger composition, it is characterised in that the composition is made up of A and B, and the A is isothiazole
Quinoline ketones derivant, the B are selected from DMH, dibromo dimethyl hydantoin, dichloro-dimethyl Hai Ying, bromine Chlorodimethyl sea
The one or more of cause, the weight ratio of the A and B are 1:(0.1-15).
4. Chinese prickly ash moss scavenger composition according to claim 3, it is characterised in that the weight ratio of the A and B are 1:
(0.5-5)。
5. Chinese prickly ash moss scavenger composition according to claim 4, it is characterised in that the A is the different thiophenes of 2- methyl -4-
The mixture of oxazoline -3- ketone (MI) and 2- methyl-5-chloro -4- isothiazoline -3- ketone (CMI).
6. Chinese prickly ash moss scavenger composition according to claim 5, it is characterised in that the B is selected from dibromo dimethyl
Glycolylurea, dichloro-dimethyl Hai Ying, the one or more of bromochlorodimethyl hydanton.
7. Chinese prickly ash moss scavenger composition according to claim 6, it is characterised in that the B is dibromo dimethyl sea
Cause.
8. Chinese prickly ash moss scavenger composition according to claim 7, it is characterised in that it is calculated in mass percent, it is described
Active components A and described active component B the content summation in the plant growth regualting composition are 0.5%-70%.
9. Chinese prickly ash moss scavenger composition according to claim 8, it is characterised in that the plant growth regulating combination
Thing also includes：Acceptable auxiliary material in Pesticide Science.
10. Chinese prickly ash moss scavenger composition according to claim 9, it is characterised in that the Chinese prickly ash moss scavenger
Combination dosage form includes wettable powder, tablet, granule, dispersible oil-suspending agent, suspension aqua.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108849976A (en) * | 2017-11-15 | 2018-11-23 | 上海屹屹环境科技有限公司 | A kind of environment-friendly type Biocidal algae-killing agent |
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| CN101695300A (en) * | 2009-10-27 | 2010-04-21 | 南京工业大学 | Slow-release type composite sterilization algicide and preparation method |
| CN104222105A (en) * | 2014-08-13 | 2014-12-24 | 武汉新大地环保材料有限公司 | Compound preservative containing dimethyl 1,3-bis(hydroxymethyl)-5,5-dimethylimidazolidine-2,4-dione and preparation method thereof |
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| CN108849976A (en) * | 2017-11-15 | 2018-11-23 | 上海屹屹环境科技有限公司 | A kind of environment-friendly type Biocidal algae-killing agent |
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