CN102556974B - 连续化制备五氟化碘的方法 - Google Patents
连续化制备五氟化碘的方法 Download PDFInfo
- Publication number
- CN102556974B CN102556974B CN 201010605409 CN201010605409A CN102556974B CN 102556974 B CN102556974 B CN 102556974B CN 201010605409 CN201010605409 CN 201010605409 CN 201010605409 A CN201010605409 A CN 201010605409A CN 102556974 B CN102556974 B CN 102556974B
- Authority
- CN
- China
- Prior art keywords
- iodine
- reaction
- pentafluoride
- open valve
- fluorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- CEBDXRXVGUQZJK-UHFFFAOYSA-N 2-methyl-1-benzofuran-7-carboxylic acid Chemical compound C1=CC(C(O)=O)=C2OC(C)=CC2=C1 CEBDXRXVGUQZJK-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 238000000034 method Methods 0.000 title claims abstract description 33
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 88
- 239000011630 iodine Substances 0.000 claims abstract description 88
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 88
- 238000006243 chemical reaction Methods 0.000 claims abstract description 68
- 239000007789 gas Substances 0.000 claims abstract description 52
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 32
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000011737 fluorine Substances 0.000 claims abstract description 32
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 32
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 17
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 16
- 239000003513 alkali Substances 0.000 claims abstract description 6
- 150000003839 salts Chemical class 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 6
- YPDSOAPSWYHANB-UHFFFAOYSA-N [N].[F] Chemical compound [N].[F] YPDSOAPSWYHANB-UHFFFAOYSA-N 0.000 claims description 16
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 5
- 238000010168 coupling process Methods 0.000 claims description 5
- 238000005859 coupling reaction Methods 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 230000001143 conditioned effect Effects 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 239000011775 sodium fluoride Substances 0.000 claims description 3
- 235000013024 sodium fluoride Nutrition 0.000 claims description 3
- 239000007788 liquid Substances 0.000 abstract description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 abstract description 2
- 238000002161 passivation Methods 0.000 abstract description 2
- 238000007747 plating Methods 0.000 abstract description 2
- 238000000746 purification Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000005935 Sulfuryl fluoride Substances 0.000 abstract 2
- OBTWBSRJZRCYQV-UHFFFAOYSA-N sulfuryl difluoride Chemical compound FS(F)(=O)=O OBTWBSRJZRCYQV-UHFFFAOYSA-N 0.000 abstract 2
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 238000000889 atomisation Methods 0.000 abstract 1
- 238000003541 multi-stage reaction Methods 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000003889 chemical engineering Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- XRURPHMPXJDCOO-UHFFFAOYSA-N iodine heptafluoride Chemical compound FI(F)(F)(F)(F)(F)F XRURPHMPXJDCOO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 201010605409 CN102556974B (zh) | 2010-12-27 | 2010-12-27 | 连续化制备五氟化碘的方法 |
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CN 201010605409 CN102556974B (zh) | 2010-12-27 | 2010-12-27 | 连续化制备五氟化碘的方法 |
Publications (2)
Publication Number | Publication Date |
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CN102556974A CN102556974A (zh) | 2012-07-11 |
CN102556974B true CN102556974B (zh) | 2013-09-04 |
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CN 201010605409 Expired - Fee Related CN102556974B (zh) | 2010-12-27 | 2010-12-27 | 连续化制备五氟化碘的方法 |
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CN (1) | CN102556974B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103449371B (zh) * | 2013-09-04 | 2015-03-18 | 核工业理化工程研究院华核新技术开发公司 | 一种提纯五氟化碘的工艺方法 |
CN105152988B (zh) * | 2015-08-13 | 2017-06-30 | 湖北卓熙氟化股份有限公司 | 一步法制备n‑氟代双苯磺酰亚胺的新工艺 |
CN105523522B (zh) * | 2015-12-08 | 2018-06-12 | 巨化集团技术中心 | 一种五氟化碘的制备方法 |
CN105854518B (zh) * | 2016-05-10 | 2018-06-12 | 杨皓 | 一种利用氮气与抽空结合的变压吸附脱碳装置动火前置换方法 |
CN105854517B (zh) * | 2016-05-10 | 2018-12-28 | 杨皓 | 一种利用氮气与抽空法结合的变压吸附脱碳装置开车前置换方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101214927A (zh) * | 2008-01-17 | 2008-07-09 | 核工业理化工程研究院华核新技术开发公司 | 五氟化碘的制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2098480A4 (en) * | 2006-10-20 | 2011-12-21 | Daikin Ind Ltd | PROCESS FOR PRODUCTION OF IODINE PENTAFLUORIDE |
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- 2010-12-27 CN CN 201010605409 patent/CN102556974B/zh not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101214927A (zh) * | 2008-01-17 | 2008-07-09 | 核工业理化工程研究院华核新技术开发公司 | 五氟化碘的制备方法 |
Non-Patent Citations (1)
Title |
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JP特开2010-285347A 2010.12.24 |
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Owner name: HUBEI ZHUOXI FLUORINATION TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: YINGCHENG CHANGJIANG FLUORINE CHEMICAL CO., LTD. Effective date: 20130115 |
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Effective date of registration: 20130115 Address after: 430043 Hubei Province in Qiaokou District of Wuhan city Gutian five road No. 17, room 216 Applicant after: Hubei Zhongke Boze New Materials Research Institute Applicant after: HUBEI ZHUOXI FLUORINATION TECHNOLOGY Co.,Ltd. Address before: 430043 Hubei Province in Qiaokou District of Wuhan city Gutian five road No. 17, room 216 Applicant before: Hubei Zhongke Boze New Materials Research Institute Applicant before: YINGCHENG CHANGJIANG FLUORINE CHEMICAL Co.,Ltd. |
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Address after: 430043 Hubei Province in Qiaokou District of Wuhan city Gutian five road No. 17, room 216 Patentee after: Hubei Zhongke Boze New Materials Research Institute Patentee after: HUBEI ZHUOXI FLUOROCHEMICAL Co.,Ltd. Address before: 430043 Hubei Province in Qiaokou District of Wuhan city Gutian five road No. 17, room 216 Patentee before: Hubei Zhongke Boze New Materials Research Institute Patentee before: HUBEI ZHUOXI FLUORINATION TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20190814 Address after: 432405, Xiaogan City, Hubei province should be No. 1 Changjiang River port development avenue Patentee after: HUBEI ZHUOXI FLUOROCHEMICAL Co.,Ltd. Address before: 430043 Hubei Province in Qiaokou District of Wuhan city Gutian five road No. 17, room 216 Co-patentee before: HUBEI ZHUOXI FLUOROCHEMICAL Co.,Ltd. Patentee before: Hubei Zhongke Boze New Materials Research Institute |
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