CN102504463B - 改性碳酸钙及其制备方法 - Google Patents
改性碳酸钙及其制备方法 Download PDFInfo
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- CN102504463B CN102504463B CN 201110316221 CN201110316221A CN102504463B CN 102504463 B CN102504463 B CN 102504463B CN 201110316221 CN201110316221 CN 201110316221 CN 201110316221 A CN201110316221 A CN 201110316221A CN 102504463 B CN102504463 B CN 102504463B
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- calcium carbonate
- parts
- modified calcium
- powder
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 title claims abstract description 77
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 27
- 239000000843 powder Substances 0.000 claims abstract description 22
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 15
- -1 polyethylene Polymers 0.000 claims abstract description 13
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 7
- 239000004698 Polyethylene Substances 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010445 mica Substances 0.000 claims abstract description 7
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 7
- 229920000573 polyethylene Polymers 0.000 claims abstract description 7
- 239000011734 sodium Substances 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000000126 substance Substances 0.000 claims description 11
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 6
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 6
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 239000002956 ash Substances 0.000 claims description 6
- 229940077388 benzenesulfonate Drugs 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 abstract description 22
- 239000004033 plastic Substances 0.000 abstract description 22
- 238000000034 method Methods 0.000 abstract description 7
- 229920000642 polymer Polymers 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 4
- 239000002861 polymer material Substances 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 150000004996 alkyl benzenes Chemical class 0.000 abstract 1
- 229910021485 fumed silica Inorganic materials 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- 239000010902 straw Substances 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- 239000002912 waste gas Substances 0.000 abstract 1
- 239000002351 wastewater Substances 0.000 abstract 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 27
- 239000004800 polyvinyl chloride Substances 0.000 description 26
- 235000010216 calcium carbonate Nutrition 0.000 description 23
- 239000002245 particle Substances 0.000 description 19
- 238000012986 modification Methods 0.000 description 17
- 230000004048 modification Effects 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- 238000012545 processing Methods 0.000 description 10
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 7
- 239000004609 Impact Modifier Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 5
- 150000001669 calcium Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000003607 modifier Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 101100412856 Mus musculus Rhod gene Proteins 0.000 description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 206010047289 Ventricular extrasystoles Diseases 0.000 description 1
- LCJHLOJKAAQLQW-UHFFFAOYSA-N acetic acid;ethane Chemical compound CC.CC(O)=O LCJHLOJKAAQLQW-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
名称 | 最大扭矩/N.m | 平衡扭矩/N.m | 塑化时间/S | 熔融温度/℃ |
普通CaCO3 | 37.4 | 25.0 | 150 | 187 |
改性CaCO3 | 34.3 | 24.2 | 116 | 182 |
名称 | 屈服强度/Mpa | 断裂强度/Mpa | 断裂伸长率/% | 杨氏模量/Mpa |
普通CaCO3 | 50.835 | 21.364 | 46.569 | 2666.59 |
改性CaCO3 | 53.882 | 44.556 | 103.360 | 2740.27 |
名称 | 屈服强度/Mpa | 断裂强度/Mpa | 断裂伸长率/% | 杨氏模量/Mpa |
普通CaCO3 | 7.09 | 6.91 | 48.7 | 75.7 |
改性CaCO3 | 4.61 | 7.65 | 109.2 | 64.5 |
Claims (2)
Priority Applications (1)
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CN 201110316221 CN102504463B (zh) | 2011-10-18 | 2011-10-18 | 改性碳酸钙及其制备方法 |
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CN 201110316221 CN102504463B (zh) | 2011-10-18 | 2011-10-18 | 改性碳酸钙及其制备方法 |
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CN102504463A CN102504463A (zh) | 2012-06-20 |
CN102504463B true CN102504463B (zh) | 2013-09-11 |
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CN 201110316221 Expired - Fee Related CN102504463B (zh) | 2011-10-18 | 2011-10-18 | 改性碳酸钙及其制备方法 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103408972B (zh) * | 2013-07-03 | 2015-04-22 | 青阳县永诚钙业有限责任公司 | 一种高光泽空调外壳用改性碳酸钙及其制备方法 |
CN103408971B (zh) * | 2013-07-03 | 2015-04-22 | 青阳县恒源化工原料有限责任公司 | 一种抗老化油漆-乳胶漆用改性碳酸钙及其制备方法 |
CN104119623A (zh) * | 2014-07-02 | 2014-10-29 | 合肥和安机械制造有限公司 | 一种汽车线束护套材料用改性碳酸钙及其制备方法 |
CN104497637A (zh) * | 2014-12-16 | 2015-04-08 | 湖北羿廷化工科技有限公司 | 改性碳酸钙及其制备方法 |
CN104945788A (zh) * | 2015-07-28 | 2015-09-30 | 苏州荣昌复合材料有限公司 | 一种改性CaCO3-PVC复合材料的制备方法 |
CN105061957B (zh) * | 2015-08-21 | 2017-05-03 | 武汉工程大学 | 改性碳酸钙填充聚四氟乙烯复合材料的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1515632A (zh) * | 2003-08-26 | 2004-07-28 | 武汉理工大学 | 一种无机-有机高分子复合粒子的制备方法和专用设备 |
JP2005126561A (ja) * | 2003-10-23 | 2005-05-19 | Dainichi Giken Kogyo Kk | 多機能性塗料用組成物 |
EP1557442A1 (de) * | 2004-01-23 | 2005-07-27 | SOLVAY (Société Anonyme) | Verfahren zur Oberflächenbehandlung von gefälltem Calciumcarbonat |
CN101704961A (zh) * | 2009-11-04 | 2010-05-12 | 池州市金艺超细粉有限公司 | 一种塑料加工功能助剂及其制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08231760A (ja) * | 1995-02-28 | 1996-09-10 | Nittetsu Mining Co Ltd | 表面改質重質炭酸カルシウム及び当該炭酸カルシウムを配合した塩化ビニル系樹脂組成物 |
-
2011
- 2011-10-18 CN CN 201110316221 patent/CN102504463B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1515632A (zh) * | 2003-08-26 | 2004-07-28 | 武汉理工大学 | 一种无机-有机高分子复合粒子的制备方法和专用设备 |
JP2005126561A (ja) * | 2003-10-23 | 2005-05-19 | Dainichi Giken Kogyo Kk | 多機能性塗料用組成物 |
EP1557442A1 (de) * | 2004-01-23 | 2005-07-27 | SOLVAY (Société Anonyme) | Verfahren zur Oberflächenbehandlung von gefälltem Calciumcarbonat |
CN101704961A (zh) * | 2009-11-04 | 2010-05-12 | 池州市金艺超细粉有限公司 | 一种塑料加工功能助剂及其制备方法 |
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CN102504463A (zh) | 2012-06-20 |
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