CN102493234A - Reserving agent for washing jean garments and preparation method thereof - Google Patents
Reserving agent for washing jean garments and preparation method thereof Download PDFInfo
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- CN102493234A CN102493234A CN2011104350797A CN201110435079A CN102493234A CN 102493234 A CN102493234 A CN 102493234A CN 2011104350797 A CN2011104350797 A CN 2011104350797A CN 201110435079 A CN201110435079 A CN 201110435079A CN 102493234 A CN102493234 A CN 102493234A
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Abstract
The invention relates to the technical field of a reserving agent for washing, particular to the reserving agent for washing jean garments and a preparation method thereof. The reserving agent is generated by carrying out esterification reaction on polyether dicarboxylic acid and ethylene glycol serving as raw materials under the action of an acid catalyst, wherein the molar ratio of the polyether dicarboxylic acid and the ethylene glycol is 1:1; and the reserving agent is water-solubility macromolecule polyester. The reserving agent provided by the invention is a non-ionic surface active agent and is not combined with protein in the washing and fade-out treatment process of the jean garments, and therefore, the catalytic activity of the reserving agent can be remained, and the reserving effect has excellent back-staining resistant effect. The preparation method provided by the invention is simple in production process, is convenient for realizing large-scale production and has good production prospect and market application prospect.
Description
Technical field
The present invention relates to wash the resist agent technical field, resist agent of particularly a kind of jeans washing and preparation method thereof.
Background technology
Jean receives liking of consumers in general for a long time with its robust performance and the old outward appearance of natural mill always deeply.Along with people's back to nature phychology dense day by day in recent years particularly, jean has been not only doting on of the younger generation, and it is with its unique glamour, receives the liking of people of each ages.
When denim is made jean, need usually to divest the part dyestuff,, also given fabric unique style simultaneously to reach the old outward appearance of natural mill through returning old arrangement.The old arrangement of returning of cowboy's fabric is to utilize cellulase to the controllable degradation of cellulose fibre, makes the part fibrolysis, and bipseudoindoxyl dye is also by the friction of washing equipment and kneading action and come off thereupon, thereby reaches " threadbare sense " effect.
But in water-washing process, bipseudoindoxyl dye can return again from the aqueous solution and dye on denim and the annex fabric, causes on the denim profile of decorative pattern unintelligible, and third dimension is not strong, and blue background, gloomy outward appearance appear in fabric, and this phenomenon is called indigo staining.Indigo staining is the most obvious in the white portion performance of clothes, like the weft yarn of white and the bagging of white etc.Indigo staining has destroyed the third dimension and degree of rocketing of jeans, influences the appearance effect of denim, reduces the use value of denim.Along with cellulase to the popularizing of denim treatment technology, the denim washing is anti-to be returned the problem of dying and causes people's attention.
The method of returning the problem of dying that solves denim at present is in treatment fluid, to add suitable resist agent; Existing resist agent mainly is divided into anionic surfactant and cationic surface active agent; Anionic surfactant and cationic surface active agent can generate complex with protein and destroy the structure of protein; Make protein (cellulase) inactivation, reduce anti-the returning of resist agent widely and dye effect.
Need a kind of anti-resist agent that dyes effective jeans washing that returns in the market badly.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art, a kind of anti-resist agent that dyes effective jeans washing that returns is provided.
Another object of the present invention is to overcome the deficiency of prior art, a kind of preparation method of resist agent of jeans washing is provided, its production technology is simple, is convenient to realize large-scale production.
For realizing above-mentioned purpose, the present invention adopts following technical scheme.
A kind of resist agent of jeans washing, said resist agent is that polyethers dicarboxylic acids and the ethylene glycol of 1:1 is raw material with the mol ratio, under the effect of acidic catalyst, generates through esterification; Said resist agent is the water soluble polymer polyester.
Wherein, said polyethers dicarboxylic acids is water-soluble dicarboxylic acids; Said polyethers dicarboxylic acids is pyromellitic dianhydride and the poly glycol monomethyl ether of 1:2 by mol ratio, carries out esterification and generates; Perhaps, said polyethers dicarboxylic acids is trimellitic anhydride and the poly glycol monomethyl ether of 1:1 by mol ratio, carries out esterification and generates.
Wherein, the molecular weight of said poly glycol monomethyl ether is 500～6000; Molecular weight through the control poly glycol monomethyl ether is regulated the water-soluble of resist agent and resist printing performance.
Wherein, the structural formula of said polyethers dicarboxylic acids is:
Perhaps
N=11～136 wherein.
Wherein, said acidic catalyst is any one or more than one the mixture in hydrochloric acid, oxalic acid, sulfuric acid, dithyl sulfate, halogenosulfonic acid and benzene sulfonic acid and the alkyl substituent thereof.
Wherein, the structural formula of said resist agent is:
Perhaps
N=11～136 wherein, p=10～100, m=10～100.
A kind of preparation method of resist agent of jeans washing, this preparation method's concrete steps are:
(1) preparation of polyethers dicarboxylic acids:
In temperature is 80 ~ 100 ℃ agitated reactor; Add a certain amount of xylene, with pyromellitic dianhydride and poly glycol monomethyl ether 1:2 adding in molar ratio agitated reactor, perhaps with trimellitic anhydride and poly glycol monomethyl ether 1:1 adding in molar ratio agitated reactor; Stir, until mixing; Under 100 ℃ of conditions, isothermal reaction 1 ~ 6 hour makes the polyethers dicarboxylic acids then;
The preparation feedback formula of polyethers dicarboxylic acids is:
(2) preparation of resist agent:
The adding mol ratio is that polyethers dicarboxylic acids and ethylene glycol, the weight of 1:1 is the acidic catalyst of 0.1 of overall reaction material～1 ‰, carries out esterification; Isothermal reaction is 20 ~ 80 minutes under 100 ℃ condition, is warmed up under 140 ~ 180 ℃ of conditions under the condition again, and esterification 2 ~ 5 hours treats that water yield reaches 90% when above of theoretical amount, and reaction finishes; Under this temperature, carry out decompression distillation 1 ~ 3 hour then, xylene is removed from product fully, obtain resist agent, promptly said water soluble polymer polyester;
The preparation feedback formula of resist agent is:
Perhaps
N=11～136 wherein, p=10～100, m=10～100.
Beneficial effect of the present invention is: the resist agent of a kind of jeans washing of the present invention, and said resist agent is that polyethers dicarboxylic acids and the ethylene glycol of 1:1 is raw material with the mol ratio, under the effect of acidic catalyst, generates through esterification; Said resist agent is the water soluble polymer polyester.
The resist agent of the jeans that the present invention relates to washing is nonionic surface active agent, returns in the old processing procedure not and protein bound in the jean washing, so can keep its catalytic activity, anti-the returning with excellence dyed effect.
The preparation method of the resist agent of the jeans washing that the present invention relates to, its production technology is simple, is convenient to realize large-scale production, has good prospect of production and market application foreground.
Description of drawings
Fig. 1 dyes the effect contrast figure for anti-the returning of the resist agent of embodiment 1 ~ 10 preparation.
The specific embodiment
With specific embodiment the present invention is further described below, but the present invention does not receive the qualification of following embodiment.
embodiment 1.
A kind of resist agent of jeans washing, its preparation method is following:
(1) preparation of polyethers dicarboxylic acids A1:
In temperature is 80 ℃ agitated reactor, add xylene 2L, be 500 poly glycol monomethyl ether 10kg adding agitated reactor with pyromellitic dianhydride 2.18kg and number-average molecular weight, mix.Isothermal reaction 6 hours under 100 ℃ of conditions then makes polyethers dicarboxylic acids A1.
(2) preparation of resist agent C1:
Polyethers dicarboxylic acids A1 12.18kg, ethylene glycol 62g, dithyl sulfate 1.3g carry out esterification, and isothermal reaction is 60 minutes under 100 ℃ of conditions, are warmed up under 180 ℃ of conditions esterification then 5 hours, and water yield reaches 17.5g, and reaction finishes.Under this temperature, carry out decompression distillation 1 hour then, xylene is removed from agitated reactor fully, obtain resist agent C1, i.e. the water soluble polymer polyester.
This resist agent is white waxy solid, and is water-soluble, has obviously anti-returning and dye effect.
embodiment 2.
A kind of resist agent of jeans washing, its preparation method is following:
(1) preparation of polyethers dicarboxylic acids A2:
In temperature is 85 ℃ agitated reactor, add xylene 2.5L, be 1000 poly glycol monomethyl ether 20kg adding agitated reactor with pyromellitic dianhydride 2.18kg and number-average molecular weight, mix.Isothermal reaction 5.5 hours under 100 ℃ of conditions then makes polyethers dicarboxylic acids A2.
(2) preparation of resist agent C2:
Polyethers dicarboxylic acids A2 22.18kg, ethylene glycol 62g, p-methyl benzenesulfonic acid 2.3g carry out esterification, and isothermal reaction is 50 minutes under 100 ℃ of conditions, are warmed up under 170 ℃ of conditions esterification then 4 hours, and water yield reaches 17.2g, and reaction finishes.Under this temperature, carry out decompression distillation 2.5 hours then, xylene is removed from agitated reactor fully, obtain resist agent C2, i.e. the water soluble polymer polyester.
This resist agent is white waxy solid, and is water-soluble, has obviously anti-returning and dye effect.
embodiment 3.
A kind of resist agent of jeans washing, its preparation method is following:
(1) preparation of polyethers dicarboxylic acids A3:
In temperature is 90 ℃ agitated reactor, add xylene 3L, be 2000 poly glycol monomethyl ether 40kg adding agitated reactor with pyromellitic dianhydride 2.18kg and number-average molecular weight, mix.Isothermal reaction 3.5 hours under 100 ℃ of conditions then makes polyethers dicarboxylic acids A3.
(2) preparation of resist agent C3:
Polyethers dicarboxylic acids A3 42.18kg, ethylene glycol 62g, hydrochloric acid 5.0g carry out esterification, and isothermal reaction is 40 minutes under 100 ℃ of conditions, are warmed up under 160 ℃ of conditions esterification then 2.5 hours, and water yield reaches 16.8g, and reaction finishes.Under this temperature, carry out decompression distillation 2.5 hours then, xylene is removed from agitated reactor fully, obtain resist agent C3, i.e. the water soluble polymer polyester.
This resist agent is white waxy solid, and is water-soluble, has obviously anti-returning and dye effect.
embodiment 4.
A kind of resist agent of jeans washing, its preparation method is following:
(1) preparation of polyethers dicarboxylic acids A4:
In temperature is 95 ℃ agitated reactor, add xylene 3.5L, be 4000 poly glycol monomethyl ether 80kg adding agitated reactor with pyromellitic dianhydride 2.18kg and number-average molecular weight, mix.Isothermal reaction 2 hours under 100 ℃ of conditions then makes polyethers dicarboxylic acids A4.
(2) preparation of resist agent C4:
Polyethers dicarboxylic acids A4 82.18kg, ethylene glycol 62g, chlorosulfonic acid 8.5g carry out esterification, and isothermal reaction is 20 minutes under 100 ℃ of conditions, are warmed up under 150 ℃ of conditions esterification then 3 hours, and water yield reaches 16.5g, and reaction finishes.Under this temperature, carry out decompression distillation 2.5 hours then, xylene is removed from agitated reactor fully, obtain resist agent C4, i.e. the water soluble polymer polyester.
This resist agent is white waxy solid, and is water-soluble, has obviously anti-returning and dye effect.
embodiment 5.
A kind of resist agent of jeans washing, its preparation method is following:
(1) preparation of polyethers dicarboxylic acids A5:
In temperature is 100 ℃ agitated reactor, add xylene 4L, be 6000 poly glycol monomethyl ether 120kg adding agitated reactor with pyromellitic dianhydride 2.18kg and number-average molecular weight, mix.Isothermal reaction 1 hour under 100 ℃ of conditions then makes polyethers dicarboxylic acids A5.
(2) preparation of resist agent C5:
Polyethers dicarboxylic acids A5 122.18kg, ethylene glycol 62g, sulfuric acid 15g carry out esterification, and isothermal reaction is 80 minutes under 100 ℃ of conditions, are warmed up under 140 ℃ of conditions esterification then 5 hours, and water yield reaches 16.6g, and reaction finishes.Under this temperature, carry out decompression distillation 3 hours then, xylene is removed from agitated reactor fully, obtain resist agent C5, i.e. the water soluble polymer polyester.
This resist agent is white waxy solid, and is water-soluble, has obviously anti-returning and dye effect.
embodiment 6.
A kind of resist agent of jeans washing, its preparation method is following:
(1) preparation of polyethers dicarboxylic acids B1:
In temperature is 80 ℃ agitated reactor, add xylene 1.5L, be 500 poly glycol monomethyl ether 5kg adding agitated reactor with trimellitic anhydride 1.92kg and number-average molecular weight, mix.Isothermal reaction 6 hours under 100 ℃ of conditions then makes polyethers dicarboxylic acids B1.
(2) preparation of resist agent C6:
Polyethers dicarboxylic acids B1 6.92kg, ethylene glycol 62g, oxalic acid 2.0g carry out esterification, and isothermal reaction is 60 minutes under 100 ℃ of conditions, are warmed up under 160 ℃ of conditions esterification then 3 hours, and water yield reaches 17.3g, and reaction finishes.Under this temperature, carry out decompression distillation 2 hours then, xylene is removed from agitated reactor fully, obtain resist agent C6, i.e. the water soluble polymer polyester.
This resist agent is white waxy solid, and is water-soluble, has obviously anti-returning and dye effect.
embodiment 7.
A kind of resist agent of jeans washing, its preparation method is following:
(1) preparation of polyethers dicarboxylic acids B2:
In temperature is 85 ℃ agitated reactor, add xylene 2L, be 1000 poly glycol monomethyl ether 10kg adding agitated reactor with trimellitic anhydride 1.92kg and number-average molecular weight, mix.Isothermal reaction 5 hours under 100 ℃ of conditions then makes polyethers dicarboxylic acids B2.
(2) preparation of resist agent C7:
Polyethers dicarboxylic acids B2 11.92kg, ethylene glycol 62g, dimethyl suflfate 2.5g carry out esterification, and isothermal reaction is 50 minutes under 100 ℃ of conditions, are warmed up under 180 ℃ of conditions esterification then 2 hours, and water yield reaches 17.2g, and reaction finishes.Under this temperature, carry out decompression distillation 2 hours then, xylene is removed from agitated reactor fully, obtain resist agent C7, i.e. the water soluble polymer polyester.
This resist agent is white waxy solid, and is water-soluble, has obviously anti-returning and dye effect.
embodiment 8.
A kind of resist agent of jeans washing, its preparation method is following:
(1) preparation of polyethers dicarboxylic acids B3:
In temperature is 90 ℃ agitated reactor, add xylene 2.5L, be 2000 poly glycol monomethyl ether 20kg adding agitated reactor with trimellitic anhydride 1.92kg and number-average molecular weight, mix.Isothermal reaction 3.5 hours under 100 ℃ of conditions then makes polyethers dicarboxylic acids B3.
(2) preparation of resist agent C8:
Polyethers dicarboxylic acids B3 21.92kg, ethylene glycol 62g, sulfuric acid 1.5g, p-methyl benzenesulfonic acid 2.5g
Carry out esterification, isothermal reaction is 40 minutes under 100 ℃ of conditions, is warmed up under 140 ℃ of conditions esterification then 5 hours, and water yield reaches 16.5g, and reaction finishes.Under this temperature, carry out decompression distillation 3 hours then, xylene is removed from agitated reactor fully, obtain resist agent C8, i.e. the water soluble polymer polyester.
This resist agent is white waxy solid, and is water-soluble, has obviously anti-returning and dye effect.
embodiment 9.
A kind of resist agent of jeans washing, its preparation method is following:
(1) preparation of polyethers dicarboxylic acids B4:
In temperature is 95 ℃ agitated reactor, add xylene 3L, with trimellitic anhydride 1.92kg
With number-average molecular weight be that 4000 poly glycol monomethyl ether 40kg adds agitated reactor, mix.Isothermal reaction 2 hours under 100 ℃ of conditions then makes polyethers dicarboxylic acids B4.
(2) preparation of resist agent C9:
Polyethers dicarboxylic acids B4 41.92kg, ethylene glycol 62g, hydrochloric acid 2.5g, chlorosulfonic acid 2.5g carry out esterification, and isothermal reaction is 30 minutes under 100 ℃ of conditions, are warmed up under 150 ℃ of conditions esterification then 4 hours, and water yield reaches 16.7g, and reaction finishes.Under this temperature, carry out decompression distillation 2.5 hours then, xylene is removed from agitated reactor fully, obtain resist agent C9, i.e. the water soluble polymer polyester.
This resist agent is white waxy solid, and is water-soluble, has obviously anti-returning and dye effect.
embodiment 10.
A kind of resist agent of jeans washing, its preparation method is following:
(1) preparation of polyethers dicarboxylic acids B5:
In temperature is 100 ℃ agitated reactor, add xylene 3.5L, be 6000 poly glycol monomethyl ether 60kg adding agitated reactor with trimellitic anhydride 1.92kg and number-average molecular weight, mix.Isothermal reaction 1 hour under 100 ℃ of conditions then makes polyethers dicarboxylic acids B5.
(2) preparation of resist agent C10:
Polyethers dicarboxylic acids B5 61.92kg, ethylene glycol 62g, p-methyl benzenesulfonic acid 8g carry out esterification, and isothermal reaction is 80 minutes under 100 ℃ of conditions, are warmed up under 170 ℃ of conditions esterification then 3 hours, and water yield reaches 16.9g, and reaction finishes.Under this temperature, carry out decompression distillation 3 hours then, xylene is removed from agitated reactor fully, obtain resist agent C10, i.e. the water soluble polymer polyester.
This resist agent is white waxy solid, and is water-soluble, has obviously anti-returning and dye effect.
The resist agent of embodiment 1 ~ embodiment 10 preparation gained prevented returning dye measure of merit.
(1) staining experiment
Equipment: wash water plate machine; Cloth: 7 * 7 indigo jean trousers plates (containing white textile cloth), 5; Raw material: neutral cellulase 6 g, buffer 23 g, polyester polyethers 2 g, water consumption 40 kg; Wash water: temperature: 50 ℃, the time: 120 minutes.
(2) mensuration of K/S value
Indigo staining degree is to represent with the K/S value of the textile calico in staining test back.At indigo maximum absorption wavelength 660 nm places, the colour photometer determination data of same sample is calculated, get the mean value of 5 test results, the K/S value is low more, anti-ly returns that to dye effect good more.
Resist agent C1～C10 anti-returns dyes the measure of merit result and sees Fig. 1.
The above only is preferred embodiment of the present invention, so all equivalences of doing according to the described structure of patent claim of the present invention, characteristic and principle change or modify, includes in patent claim of the present invention.
Claims (10)
1. the resist agent of jeans washing, it is characterized in that: said resist agent is that polyethers dicarboxylic acids and the ethylene glycol of 1:1 is raw material with the mol ratio, under the effect of acidic catalyst, generates through esterification; Said resist agent is the water soluble polymer polyester.
2. the resist agent of a kind of jeans washing according to claim 1 is characterized in that: said acidic catalyst is any one or more than one the mixture in hydrochloric acid, oxalic acid, sulfuric acid, dithyl sulfate, halogenosulfonic acid and benzene sulfonic acid and the alkyl substituent thereof.
3. the resist agent of a kind of jeans washing according to claim 1; It is characterized in that: said polyethers dicarboxylic acids is water-soluble dicarboxylic acids; Said polyethers dicarboxylic acids is pyromellitic dianhydride and the poly glycol monomethyl ether of 1:2 by mol ratio, carries out esterification and generates; The structural formula of said polyethers dicarboxylic acids is:
?，
N=11～136 wherein.
4. the resist agent of a kind of jeans washing according to claim 3, it is characterized in that: the molecular weight of said poly glycol monomethyl ether is 500～6000.
5. the resist agent of a kind of jeans washing according to claim 4, it is characterized in that: the structural formula of said resist agent is:
N=11～136 wherein, p=10～100.
6. the preparation method of the resist agent of the described a kind of jeans washing of claim 3, it is characterized in that: this preparation method's concrete steps are:
(1) preparation of polyethers dicarboxylic acids:
In temperature is 80 ~ 100 ℃ agitated reactor, add a certain amount of xylene, with pyromellitic dianhydride and poly glycol monomethyl ether in molar ratio 1:2 add agitated reactor, stir, until mixing; Under 100 ℃ of conditions, isothermal reaction 1 ~ 6 hour makes the polyethers dicarboxylic acids then;
The preparation feedback formula of polyethers dicarboxylic acids is:
(2) preparation of resist agent:
The adding mol ratio is that polyethers dicarboxylic acids and ethylene glycol, the weight of 1:1 is the acidic catalyst of 0.1 of overall reaction material～1 ‰, carries out esterification; Isothermal reaction is 20 ~ 80 minutes under 100 ℃ condition, is warmed up under 140 ~ 180 ℃ of conditions under the condition again, and esterification 2 ~ 5 hours treats that water yield reaches 90% when above of theoretical amount, and reaction finishes; Under this temperature, carry out decompression distillation 1 ~ 3 hour then, xylene is removed from product fully, obtain resist agent, promptly said water soluble polymer polyester;
The preparation feedback formula of resist agent is:
。
7. the resist agent of a kind of jeans washing according to claim 1; It is characterized in that: said polyethers dicarboxylic acids is water-soluble dicarboxylic acids; Said polyethers dicarboxylic acids is trimellitic anhydride and the poly glycol monomethyl ether of 1:1 by mol ratio, carries out esterification and generates;
The structural formula of said polyethers dicarboxylic acids is:
N=11～136 wherein.
8. the resist agent of a kind of jeans washing according to claim 7, it is characterized in that: the molecular weight of said poly glycol monomethyl ether is 500～6000.
9. the resist agent of a kind of jeans washing according to claim 7, it is characterized in that: the structural formula of said resist agent is:
N=11～136 wherein, m=10～100.
10. the preparation method of the resist agent of the described a kind of jeans washing of claim 7, it is characterized in that: this preparation method's concrete steps are:
(1) preparation of polyethers dicarboxylic acids:
In temperature is 80 ~ 100 ℃ agitated reactor, add a certain amount of xylene, with trimellitic anhydride and poly glycol monomethyl ether in molar ratio 1:1 add agitated reactor, stir, until mixing; Under 100 ℃ of conditions, isothermal reaction 1 ~ 6 hour makes the polyethers dicarboxylic acids then;
The preparation feedback formula of polyethers dicarboxylic acids is:
(2) preparation of resist agent:
The adding mol ratio is that polyethers dicarboxylic acids and ethylene glycol, the weight of 1:1 is the acidic catalyst of 0.1 of overall reaction material～1 ‰, carries out esterification; Isothermal reaction is 20 ~ 80 minutes under 100 ℃ condition, is warmed up under 140 ~ 180 ℃ of conditions under the condition again, and esterification 2 ~ 5 hours treats that water yield reaches 90% when above of theoretical amount, and reaction finishes; Under this temperature, carry out decompression distillation 1 ~ 3 hour then, xylene is removed from product fully, obtain resist agent, promptly said water soluble polymer polyester;
The preparation feedback formula of resist agent is:
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| CN103981714A (en) * | 2014-05-21 | 2014-08-13 | 佛山市邦孚新材料科技有限公司 | Clothing dye-resistant color fixative as well as preparation method and application of clothing dye-resistant color fixative |
| CN107299547A (en) * | 2017-08-16 | 2017-10-27 | 纤化（上海）生物化工股份有限公司 | A kind of high-performance environment-friendly resist printing powder washed for cowboy's ferment |
| CN108265539A (en) * | 2018-02-26 | 2018-07-10 | 杭州小橙工业设计有限公司 | A kind of anti-transfection reagent prepares production line automatically |
| CN108385417A (en) * | 2018-02-26 | 2018-08-10 | 杭州小橙工业设计有限公司 | A kind of resist printing preparation process thereof implementation system |
| CN108396560A (en) * | 2018-03-07 | 2018-08-14 | 广州市德鹏新材料科技有限公司 | A kind of preparation method of resist agent |
| CN111118936A (en) * | 2020-01-03 | 2020-05-08 | 湖南金全立生物科技股份有限公司 | Multifunctional green environment-friendly dye-proofing agent and preparation method thereof |
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| CN112411207A (en) * | 2020-11-16 | 2021-02-26 | 临清三和纺织集团有限公司 | Reactive dye anti-dyeing agent and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4417686A1 (en) * | 1994-05-20 | 1995-11-23 | Henkel Kgaa | Polyester(s) with soil release properties in washing and cleaning agents |
| WO1999067350A1 (en) * | 1998-06-22 | 1999-12-29 | Seydel Research, Inc. | Prevention of dye redeposition in fabric washing processes |
| EP0907703B1 (en) * | 1996-05-03 | 2002-06-26 | The Procter & Gamble Company | Detergent compositions comprising modified polyamines as dye transfer inhibitors |
| CN1890361A (en) * | 2003-12-10 | 2007-01-03 | 萨索尔德国股份有限公司 | Method for preventing or minimizing color deposits using polyesters |
-
2011
- 2011-12-22 CN CN 201110435079 patent/CN102493234B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4417686A1 (en) * | 1994-05-20 | 1995-11-23 | Henkel Kgaa | Polyester(s) with soil release properties in washing and cleaning agents |
| EP0907703B1 (en) * | 1996-05-03 | 2002-06-26 | The Procter & Gamble Company | Detergent compositions comprising modified polyamines as dye transfer inhibitors |
| WO1999067350A1 (en) * | 1998-06-22 | 1999-12-29 | Seydel Research, Inc. | Prevention of dye redeposition in fabric washing processes |
| CN1890361A (en) * | 2003-12-10 | 2007-01-03 | 萨索尔德国股份有限公司 | Method for preventing or minimizing color deposits using polyesters |
Cited By (14)
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|---|---|---|---|---|
| CN103981714B (en) * | 2014-05-21 | 2016-06-08 | 佛山市邦孚新材料科技有限公司 | Medicated clothing resist printing colour fixative and its preparation method and application |
| CN103981714A (en) * | 2014-05-21 | 2014-08-13 | 佛山市邦孚新材料科技有限公司 | Clothing dye-resistant color fixative as well as preparation method and application of clothing dye-resistant color fixative |
| CN107299547A (en) * | 2017-08-16 | 2017-10-27 | 纤化（上海）生物化工股份有限公司 | A kind of high-performance environment-friendly resist printing powder washed for cowboy's ferment |
| CN108265539B (en) * | 2018-02-26 | 2020-09-11 | 杭州小橙工业设计有限公司 | Automatic preparation production line of dye-resistant reagent |
| CN108265539A (en) * | 2018-02-26 | 2018-07-10 | 杭州小橙工业设计有限公司 | A kind of anti-transfection reagent prepares production line automatically |
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