CN103981714A - Clothing dye-resistant color fixative as well as preparation method and application of clothing dye-resistant color fixative - Google Patents
Clothing dye-resistant color fixative as well as preparation method and application of clothing dye-resistant color fixative Download PDFInfo
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- CN103981714A CN103981714A CN201410217181.3A CN201410217181A CN103981714A CN 103981714 A CN103981714 A CN 103981714A CN 201410217181 A CN201410217181 A CN 201410217181A CN 103981714 A CN103981714 A CN 103981714A
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- printing color
- color stabilizer
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Abstract
The invention provides a clothing dye-resistant color fixative. The dye-resistant color fixative is prepared by adopting a water-soluble high-molecular polymer, polyethylene glycol, organic phosphoric acid, sodium gluconate, potassium hydroxide, a preservative and water. The dye-resistant color fixative is characterized in that various matters in the components respectively play own roles and have a very good synergistic effect. The dye-resistant color fixative has the characteristics that dyeing resistance is achieved, the energy consumption is low, the use is convenient, and the clothes have stability in shape, no fiber falling, invariability in luster and color (color protecting) after using the color fixative, and the like when being cooperated with an ordinary washing agent. The invention further provides a preparation method and application of the clothing dye-resistant color fixative.
Description
Technical field
The present invention relates to chemical field, especially a kind of clothing resist printing color stabilizer and its preparation method and application.
Background technology
Clothing is colourful, and dyeing is different with material used causes in washing process the phenomenon of fading in various degree.In home laundry thing process, in the time that the clothing of different colours is put washing together, pigment above clothing can come off, because laundry water is alkalescence, pigment can dye above fabric again, causes mixing clothing string to dye, affect clean result, more seriously, greatly destroy quality and the class of product, this is undesirable in life at home.
Chinese patent CN1096051 discloses a kind of without phosphorus type liquid detergent capable of resisting cross talk and preparation method thereof.Wherein washing agent is by surfactant and inorganic formulated with organic additive and water.It is characterized in that in component, containing 1.6～4% glacial acetic acid, make pH value between 5～6.5.This washing agent, compared with plain edition washing powder, has without crossing extensive use of chemical fertilizer pollution, anti-colour contamination, low energy consumption, the feature such as easy to use.
Chinese patent CN1354244 discloses a kind of liquid detergent capable of resisting cross talk, and formula is made up of raw materials such as 6～40% surfactants, 0.1～10% anti-colour contamination high polymers, and properties of product are stable, anti-colour contamination successful.Its technical characteristics is to adopt surfactant 6～40%, the anti-colour contamination high polymers 0.1～10% such as anion, amphion, can add in addition the raw material such as cationic surfactant, washing assisant, makes product have the function of washing and anti-colour contamination.
Chinese patent CN102453620 discloses a kind of multifunctional laundry liquid, the percentage by weight composition of this liquid detergent comprises: anion surfactant 1%～50%, non-ionic surface active agent 1%～40%, high molecular polymer 0%～30%, disinfection sanitizer 0%～2%, fluorescent whitening agent 0%～0.5%, acid-base modifier: 0%～10%, biology enzyme: 0%～2%, 0%～0.5%, pigment 0%～0.0005%.Utilize high molecular polymer long-chain absorption, parcel dirt, there is removal stain, anti-colour contamination, realize the multi-functionals such as clean, submissive, antistatic, and be applicable to various clothings, bedding, towel etc.
What but these documents all related to is resist printing (colour contamination) washing agent, and they at least exist inferior position in cost, effect and operating aspect compared with clothing resist printing color stabilizer of the present invention.This area still needs that development and operation is simple, effect is excellent, cost is low, the resist printing color stabilizer of applied range.
Summary of the invention
The invention provides a kind of clothing resist printing color stabilizer, it comprises the component (by weight) with following content:
In a preferred embodiment, the invention provides a kind of clothing resist printing color stabilizer, it comprises the component (by weight) with following content:
In another preferred embodiment, the invention provides a kind of clothing resist printing color stabilizer, it comprises the component (by weight) with following content:
In still another preferred embodiment, the invention provides a kind of clothing resist printing color stabilizer, it comprises the component (by weight) with following content:
In one embodiment, the invention provides the preparation method of clothing resist printing color stabilizer, the method comprises
(1) accurate-metering deionized water is in reactor, and under agitation (600 revs/min) add gluconic acid sodium salt, polyethylene glycol, organic phosphoric acid (ATMP), potassium hydroxide, stirs more 10 minutes.
(2) whether under rapid stirring, (1500 revs/min) add the high molecular weight water soluble polymer having measured fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent also stirs and after 10 minutes, filters discharging packaging.
Clothing resist printing color stabilizer of the present invention is a kind of colourless extremely light yellow transparency liquid, is weak anionic, and density is 1.050 ± 0.1g/cm
3(20 DEG C), PH (stoste) is at 7 ± 1 (20 DEG C), can mix with arbitrary proportion with water and viscosity does not increase, all stable to hard water, salt, different PH and temperature.
The polyethylene glycol using in the present invention is Liquid Macrogol, PEG400, polyethylene glycol 500, Macrogol 600, polyethylene glycol 700, polyethylene glycol 800 or two or more mixture in them.Preferably use PEG400.
The high molecular weight water soluble polymer using in the present invention is cellulose, cellulose ether, such as methylcellulose, hydroxyethylmethyl-cellulose, hydroxypropyl methylcellulose, hydroxy butyl methyl cellulose, hydroxyethylcellulose, hydroxypropyl cellulose, hydroxybutyl cellulose, sodium carboxymethylcellulose etc., polyvinyl alcohol, polysaccharide is as amylopectin or pullulan, polyvinylpyrrolidone, alginic acid or its salt, sodium chondroitin sulfate, chondroitin heparin etc., or two or more mixture in them.Preferably pullulan or sodium chondroitin sulfate.
The preservative agent using in the present invention is Sodium Benzoate, potassium sorbate, isothiazolinone, P-hydroxybenzoic acid sodium, dimethyl hydantoin etc., or two or more mixture in them.
The present invention also provides a kind of clothing resist printing color stabilizer for preventing the purposes of clothing dyeing (altering look).
Clothing resist printing color stabilizer of the present invention has following characteristic and advantage:
● close dye-type polymer, without fiber-reactive
● the commute clothing that fades coordinates after this product washing one or two times, and clothing substantially no longer fades
● adsorb from clothing the dyestuff or the pigment that are dissolved in the water
● the dyestuff being dissolved into from clothing in water is retained in water, prevents that dyestuff is stained with (return dye) to returning of clothing
● resist printing process is not subject to the impact of PH
● resist printing process is not subject to the impact of salt (in washing powder and liquid detergent all containing more salt) concentration
● under normal temperature and high temperature, all there is good result
● all effective to the clothing that all quality are different with color
● outstanding dispersive property, has effectively prevented formation and the redeposition of deposition of dye
● resist printing color stabilizer can not make clothing fade, and washes rear sparkling cleanly, has certain dirt-removing power concurrently simultaneously
The invention solves the colouring problem while perplexing for a long time people's washing clothes, disclose a kind of clothing resist printing color stabilizer and preparation method thereof.This resist printing color stabilizer is formulated by high molecular weight water soluble polymer, polyethylene glycol, organic phosphoric acid, gluconic acid sodium salt, potassium hydroxide, preservative agent and water.It is characterized in that the various materials in component bring into play separately the effect of oneself and produce good cooperative effect.This resist printing color stabilizer and plain edition washing agent are used in conjunction with, have anti-dyeing, low energy consumption, easy to use and use after dimensionally stable, do not lose hair or feathers, the feature such as clothing gloss color constant (protecting look).
Although have severally about anti-colour contamination washing agent patent and one section of periodical research report domestic, commodity are not seen in market.Another its belongs to washing agent and the present invention is a kind of resist agent, without the property compared.Abroad (Germany) has a kind of anti-dyeing towel (" Beckman doctor " anti-dyeing towel) to apply abroad comparatively maturation, we test on year-on-year basis with " Beckman doctor " anti-dyeing towel by product, and this clothing resist printing color stabilizer successful is dominant.
Brief description of the drawings
Fig. 1 is the test effect comparison diagram of resist printing color stabilizer Piglet s colibacillosis I.
Fig. 2 is the product figure of " Beckman doctor " anti-dyeing towel.
Fig. 3 is the test effect comparison diagram of resist printing color stabilizer and " Beckman doctor " anti-dyeing towel Piglet s colibacillosis II.
Embodiment
Embodiment 1
Measure 23.5 parts by weight of deionized water in reactor, under agitation (600 revs/min) add gluconic acid sodium salt 7 weight portions, PEG400 42 weight portions, organic phosphoric acid 8 weight portions, potassium hydroxide 4 weight portions, stir more 10 minutes.Whether under rapid stirring, (1500 revs/min) add high molecular weight water soluble polymer hydroxyethylmethyl-cellulose 15 weight portions fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent Sodium Benzoate 0.5 weight portion also stirs and after 10 minutes, filters discharging packaging.
Embodiment 2
Measure 24.5 parts by weight of deionized water in reactor, under agitation (600 revs/min) add gluconic acid sodium salt 6 weight portions, PEG400 39 weight portions, organic phosphoric acid 8 weight portions, potassium hydroxide 4 weight portions, stir more 10 minutes.Whether under rapid stirring, (1500 revs/min) add high molecular weight water soluble polymer sodium carboxymethylcellulose 18 weight portions fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent Sodium Benzoate 0.5 weight portion also stirs and after 10 minutes, filters discharging packaging.
Embodiment 3
Measure 23.5 parts by weight of deionized water in reactor, under agitation (600 revs/min) add gluconic acid sodium salt 7 weight portions, Macrogol 600 42 weight portions, organic phosphoric acid 8 weight portions, potassium hydroxide 4 weight portions, stir more 10 minutes.Whether under rapid stirring, (1500 revs/min) add high molecular weight water soluble polymer polyvinyl alcohol 15 weight portions fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent potassium sorbate 0.5 weight portion also stirs and after 10 minutes, filters discharging packaging.
Embodiment 4
Measure 24.5 parts by weight of deionized water in reactor, under agitation (600 revs/min) add gluconic acid sodium salt 6 weight portions, Macrogol 600 39 weight portions, organic phosphoric acid 8 weight portions, potassium hydroxide 4 weight portions, stir more 10 minutes.Whether under rapid stirring, (1500 revs/min) add high molecular weight water soluble polymer pullulan 18 weight portions fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent potassium sorbate 0.5 weight portion also stirs and after 10 minutes, filters discharging packaging.
Embodiment 5
Measure 27.5 parts by weight of deionized water in reactor, under agitation (600 revs/min) add gluconic acid sodium salt 8 weight portions, PEG400 40 weight portions, organic phosphoric acid 8 weight portions, potassium hydroxide 4 weight portions, stir more 10 minutes.Whether under rapid stirring, (1500 revs/min) add high molecular weight water soluble polymer polyvinylpyrrolidone 12 weight portions fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent isothiazolinone 0.5 weight portion also stirs and after 10 minutes, filters discharging packaging.
Embodiment 6
Measure 27.5 parts by weight of deionized water in reactor, under agitation (600 revs/min) add gluconic acid sodium salt 8 weight portions, PEG400 40 weight portions, organic phosphoric acid 8 weight portions, potassium hydroxide 4 weight portions, stir more 10 minutes.Whether under rapid stirring, (1500 revs/min) add high molecular weight water soluble polymer alginates 12 weight portions fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent P-hydroxybenzoic acid sodium 0.5 weight portion also stirs and after 10 minutes, filters discharging packaging.
Embodiment 7
Measure 27.5 parts by weight of deionized water in reactor, under agitation (600 revs/min) add gluconic acid sodium salt 8 weight portions, Macrogol 600 40 weight portions, organic phosphoric acid 8 weight portions, potassium hydroxide 4 weight portions, stir more 10 minutes.Whether under rapid stirring, (1500 revs/min) add high molecular weight water soluble polymer sodium chondroitin sulfate 12 weight portions fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent P-hydroxybenzoic acid sodium 0.5 weight portion also stirs and after 10 minutes, filters discharging packaging.
Embodiment 8
Measure 27.5 parts by weight of deionized water in reactor, under agitation (600 revs/min) add gluconic acid sodium salt 8 weight portions, PEG400 40 weight portions, organic phosphoric acid 8 weight portions, potassium hydroxide 4 weight portions, stir more 10 minutes.Whether under rapid stirring, (1500 revs/min) add high molecular weight water soluble polymer chondroitin heparin 12 weight portions fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent dimethyl hydantoin 0.5 weight portion also stirs and after 10 minutes, filters discharging packaging.
Embodiment 9
Measure 27.5 parts by weight of deionized water in reactor, under agitation (600 revs/min) add gluconic acid sodium salt 8 weight portions, PEG400 40 weight portions, organic phosphoric acid 8 weight portions, potassium hydroxide 4 weight portions, stir more 10 minutes.Whether under rapid stirring, (1500 revs/min) add high molecular weight water soluble polymer pullulan 12 weight portions fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent dimethyl hydantoin 0.5 weight portion also stirs and after 10 minutes, filters discharging packaging.
Resist printing color stabilizer Piglet s colibacillosis I
One, test apparatus
Two, test method
1. respectively at respectively adding 100ml running water in A, B beaker (200ml);
2. (1) adds 4 grams of regular powders in A beaker, stirs with glass bar;
(2) in B beaker, add 4 grams of regular powders and 10 milliliters of resist printing color stabilizers, stir with another glass bar;
3. in A beaker, put into 1 white pure cotton cloth (A) and 2 painting cloths; In like manner in B beaker, put into 1 white pure cotton cloth (B) and 2 painting cloths, constantly stir with glass bar, cloth is immersed in the aqueous solution completely, timing simultaneously;
4. after approximately three to five minutes, outwell the aqueous solution, take out painting cloth, respectively add 100ml running water in A, B beaker, after fully stirring with glass bar, take out white pure cotton cloth A, B, extract water;
5. even up A, B cloth, contrast color.
Three, result of the test
A, B cloth detect by an unaided eye.As shown in Fig. 1 result, A cloth and B cloth have obvious aberration, and B cloth is almost without staining, illustrates that resist printing color stabilizer has good resist printing effect.
Resist printing color stabilizer Piglet s colibacillosis II
One, test apparatus
Two, test method
1. respectively at respectively adding 100ml running water in A, B beaker (200ml);
2. (1) adds 4 grams of regular powders in A beaker, stirs with glass bar;
(2) in B beaker, add 4 grams of regular powders and 10 milliliters of resist printing color stabilizers, stir with another glass bar;
3. in A beaker, put into 1 white pure cotton cloth (A) and 2 painting cloths; In like manner in B beaker, put into 1 white pure cotton cloth (B) and 2 painting cloths, constantly stir with glass bar, cloth is immersed in the aqueous solution completely, timing simultaneously;
4. after approximately three to five minutes, outwell the aqueous solution, take out painting cloth, respectively add 100ml running water in A, B beaker, after fully stirring with glass bar, take out white pure cotton cloth A, B, extract water;
5. even up A, B cloth, contrast color.
Three, result of the test
A, B cloth detect by an unaided eye.As shown in Fig. 3 result, A cloth and B cloth have obvious aberration, and B cloth is without staining, illustrates that resist printing color stabilizer has extraordinary resist printing effect.
Resist printing color stabilizer and " Beckman doctor " anti-dyeing towel Piglet s colibacillosis I
One, test apparatus
Two, test method
1. respectively at respectively adding 100ml running water in A, B beaker (200ml);
2. (1) adds 4 grams of regular powders and the anti-dyeing towel of a slice " Beckman doctor " in A beaker, stirs with glass bar;
(2) in B beaker, add 4 grams of regular powders and 10 milliliters of resist printing color stabilizers, stir with another glass bar;
3. in A beaker, put into 1 white pure cotton cloth (A) and 2 painting cloths; In like manner in B beaker, put into 1 white pure cotton cloth (B) and 2 painting cloths, constantly stir with glass bar, cloth is immersed in the aqueous solution completely, timing simultaneously;
4. after approximately three to five minutes, outwell the aqueous solution, take out painting cloth, respectively add 100ml running water in A, B beaker, after fully stirring with glass bar, take out white pure cotton cloth A, B, extract water;
5. even up A, B cloth, contrast color.
Three, result of the test
A, B cloth detect by an unaided eye.A cloth and B cloth have obvious aberration, and B cloth is almost without staining, illustrates that resist printing color stabilizer has good resist printing effect.
Resist printing color stabilizer and " Beckman doctor " anti-dyeing towel Piglet s colibacillosis II
Test by mode that " resist printing color stabilizer with " Beckman doctor " anti-dyeing towel Piglet s colibacillosis I " is identical with above, just the product of embodiment 6-9 is used as to resist printing color stabilizer, result of the test shows that A cloth and B cloth have obvious aberration, and B cloth, without staining, illustrates that resist printing color stabilizer has extraordinary resist printing effect.
A, B cloth detect by an unaided eye.A cloth and B cloth have obvious aberration, and B cloth is almost without staining, illustrates that resist printing color stabilizer has good resist printing effect.
Although disclose for illustrative purposes preferred embodiment of the present invention, it will be understood by those skilled in the art that and do not departing under scope and spirit of the present invention as disclosed in appended claim, it is all possible carrying out various modifications, interpolation and replacement.
Claims (10)
1. a clothing resist printing color stabilizer, is characterized in that comprising the component (by weight) with following content:
。
2. the clothing resist printing color stabilizer of claim 1, is characterized in that comprising the component (by weight) with following content:
。
3. the clothing resist printing color stabilizer of claim 2, is characterized in that comprising the component (by weight) with following content:
。
4. the clothing resist printing color stabilizer of claim 3, is characterized in that comprising the component (by weight) with following content:
。
5. the clothing resist printing color stabilizer of claim 1, it is characterized in that described polyethylene glycol is Liquid Macrogol, PEG400, polyethylene glycol 500, Macrogol 600, polyethylene glycol 700, polyethylene glycol 800 or two or more mixture in them, preferably PEG400.
6. the clothing resist printing color stabilizer of claim 1, it is characterized in that described high molecular weight water soluble polymer is cellulose, cellulose ether, for example methylcellulose, hydroxyethylmethyl-cellulose, hydroxypropyl methylcellulose, hydroxy butyl methyl cellulose, hydroxyethylcellulose, hydroxypropyl cellulose, hydroxybutyl cellulose, sodium carboxymethylcellulose, polysaccharide is as amylopectin or pullulan, polyvinyl alcohol, polyvinylpyrrolidone, alginic acid or its salt, sodium chondroitin sulfate, chondroitin heparin or two or more mixture in them.
7. the clothing resist printing color stabilizer described in claim 1-6 any one, is characterized in that described high molecular weight water soluble polymer is pullulan or sodium chondroitin sulfate.
8. the clothing resist printing color stabilizer of claim 7, is characterized in that described preservative agent is Sodium Benzoate, potassium sorbate, isothiazolinone, P-hydroxybenzoic acid sodium, dimethyl hydantoin, or two or more mixture in them.
9. the preparation method of the clothing resist printing color stabilizer described in claim 1-8 any one, is characterized in that the method comprises:
(1) accurate-metering deionized water is in reactor, and under agitation (600 revs/min) add gluconic acid sodium salt, polyethylene glycol, organic phosphoric acid (ATMP), potassium hydroxide, stir more 10 minutes,
(2) whether under rapid stirring, (1500 revs/min) add the high molecular weight water soluble polymer having measured fast, stir and within 30 minutes, stop stirring, and soak approximately 2 hours, open stirring, observe and dissolve completely.After dissolving completely, adding preservative agent also stirs and after 10 minutes, filters discharging packaging.
10. the clothing resist printing color stabilizer described in claim 1-8 any one prevents the purposes of clothing dyeing (altering look).
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410217181.3A CN103981714B (en) | 2014-05-21 | 2014-05-21 | Medicated clothing resist printing colour fixative and its preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410217181.3A CN103981714B (en) | 2014-05-21 | 2014-05-21 | Medicated clothing resist printing colour fixative and its preparation method and application |
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| CN103981714A true CN103981714A (en) | 2014-08-13 |
| CN103981714B CN103981714B (en) | 2016-06-08 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105064085A (en) * | 2015-09-08 | 2015-11-18 | 湖州南浔宏亮纺织有限公司 | Novel levelling agent for dyeing pure cotton and dyeing method thereof |
| CN105296191A (en) * | 2015-11-19 | 2016-02-03 | 黑龙江大学 | Efficient decontaminating and color-protecting laundry detergent and preparation method therefor |
| CN111519455A (en) * | 2020-04-17 | 2020-08-11 | 广州科丰达新材料科技有限公司 | Anti-ballistic and anti-dyeing powder and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3087909B2 (en) * | 1991-07-23 | 2000-09-18 | イーストマン ケミカル カンパニー | Method for producing lubricant-impregnated fiber |
| US20070161538A1 (en) * | 2004-02-13 | 2007-07-12 | Kao Corporation | Method of washing |
| CN102493234A (en) * | 2011-12-22 | 2012-06-13 | 东莞市广利行洗涤原料有限公司 | Reserving agent for washing jean garments and preparation method thereof |
| CN103276615A (en) * | 2011-12-22 | 2013-09-04 | 东莞市广利行洗涤原料有限公司 | Resist agent for jeans wear washing and preparation method of resist agent |
-
2014
- 2014-05-21 CN CN201410217181.3A patent/CN103981714B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3087909B2 (en) * | 1991-07-23 | 2000-09-18 | イーストマン ケミカル カンパニー | Method for producing lubricant-impregnated fiber |
| US20070161538A1 (en) * | 2004-02-13 | 2007-07-12 | Kao Corporation | Method of washing |
| CN102493234A (en) * | 2011-12-22 | 2012-06-13 | 东莞市广利行洗涤原料有限公司 | Reserving agent for washing jean garments and preparation method thereof |
| CN103276615A (en) * | 2011-12-22 | 2013-09-04 | 东莞市广利行洗涤原料有限公司 | Resist agent for jeans wear washing and preparation method of resist agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105064085A (en) * | 2015-09-08 | 2015-11-18 | 湖州南浔宏亮纺织有限公司 | Novel levelling agent for dyeing pure cotton and dyeing method thereof |
| CN105296191A (en) * | 2015-11-19 | 2016-02-03 | 黑龙江大学 | Efficient decontaminating and color-protecting laundry detergent and preparation method therefor |
| CN111519455A (en) * | 2020-04-17 | 2020-08-11 | 广州科丰达新材料科技有限公司 | Anti-ballistic and anti-dyeing powder and preparation method thereof |
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| CN103981714B (en) | 2016-06-08 |
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