CN103725041B - Acid dye and gravure ink as well as preparation method and application of gravure ink - Google Patents
Acid dye and gravure ink as well as preparation method and application of gravure ink Download PDFInfo
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- CN103725041B CN103725041B CN201310754906.8A CN201310754906A CN103725041B CN 103725041 B CN103725041 B CN 103725041B CN 201310754906 A CN201310754906 A CN 201310754906A CN 103725041 B CN103725041 B CN 103725041B
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Abstract
The invention relates to the dyeing industry, and in particular relates to an acid dye with an improved dye structure and excellent color fastness to washing. The invention relates to composition and a preparation method of acid dye gravure ink containing an acid agent, and relates to composition and a preparation method of the acid agent necessary for the temporary use of the acid dye gravure ink. The invention also relates to a gravure printing process capable of directly executing gravure printing, drying and color fixation through steam for protein fiber fabric and nylon fabric without rolling the acid agent. According to the invention, the dye ink printing process flow can be greatly shortened, a great amount of transfer printing paper which is coated with a special isolation agent can be saved, and the dye ink printing production cost can be greatly reduced; meanwhile, the color layer of the printing patterns is variable and rich, the dye color fixing rate is high, less flooding exists in the water washing process, the emission of the waste water is reduced, and the tarnishing of the dye without being color fixed on the printed fabric can be reduced.
Description
Technical field
The present invention relates to dyeing, the invention belongs to using acid dye intaglio printing ink to protein fibre fabric, chinlon
Fabric carries out the field of direct intaglio printing stamp.Specifically related to use a kind of dye structure water-fastness obtained by improvement
The excellent acid stain of fastness；It is related to a kind of composition of acid dye intaglio printing ink containing sour agent and preparation method thereof；It is related to
A kind of acid dye intaglio printing ink faces composition of sour agent that the used time must add and preparation method thereof；Further relate to protein fibre to knit
Thing, nylon fabric do not need to carry out rolling sour agent process just energy directly intaglio printing stamp, dry, the intaglio process of vapour steaming colour fixing is stenciled
Flower process.
Background technology
The method that dyestuff carries out stamp to yarn fabric is broadly divided into three major types at present in dyeing, and a class is up to ten
The dye paste PLATE SCREAM PRINTING of several chromatographys or ROTARY SCREAM PRINTING；Another kind of is dye ink transfer printing（Including thermal transfer printing and
Cold-transfer printing）；A class is also had to be that dye ink is ink-jet printed.
Dye paste PLATE SCREAM PRINTING or ROTARY SCREAM PRINTING are a kind of traditional printing methods, and it is shorter to have a technological process, produce
The advantages of processing cost is relatively low, but there is also the change of decalcomania color hierarchy and do not enrich, and some dye fixing rates are not high, water
During washing, loose colour is more, they washing when enter in a large number in rinsing solution, cause discharge of wastewater exceeded, simultaneously these not by
The dyestuff that fixation is fallen even also can stain printed textile in vain, cause printed textile product to there are quality problems etc. and lack
Point.
Dye ink transfer printing is a kind of novel printing method, mainly include at present disperse dyes to dacron,
The thermal transfer printing of the nylon fabric and reactive dye cold-transfer printing to bafta, they have decalcomania color hierarchy and become
Change abundant, less energy consumption during dye fixing, dye fixing rate is higher, and in water-washing process, loose colour is less, it is possible to reduce discharge of wastewater, with
When these dyestuffs of not fallen by fixation the white ground contamination of printed textile is greatly reduced, thus reducing printed textile
Product quality problem the advantages of, but it is longer to there is also technological process, needs to buy more printer（As intaglio press）, transfer
The equipment such as device, liter dacron, nylon fabric thermal transfer printing after higher to the technical requirements of dyestuff and its auxiliary aid
Magnificent fastness and ironing fastness are poor, and the production and processing cost of cotton fabric cold transfer printing is also higher, also can produce a large amount of turning simultaneously
Print waste paper, thus the shortcomings of cause a large amount of paper resources to be consumed.
Dye ink is ink-jet printed to be also a kind of novel printing method, can be directed to all yarn fabrics theoretically, it
There is the change of decalcomania color hierarchy abundant, less energy consumption during dye fixing, dye fixing rate is higher, loose colour in water-washing process
Less, it is possible to reduce discharge of wastewater, these are not fallen by fixation simultaneously dyestuff is to the white ground contamination of printed textile also significantly
Reduce, thus the advantages of reduce the product quality problem of printed textile, but there is also stamp speed relatively slowly it is impossible to carry out
Produce in enormous quantities, the personalized production of small lot can only be done, yield is relatively low, need to buy more relatively expensive ink-jet printed of price and beat
The equipment such as print machine, higher to the technical requirements of dyestuff and its auxiliary aid, the price of ink-jet printed dye ink is also more expensive,
The shortcomings of ink-jet printed production and processing of dye ink is relatively costly.
Content of the invention
In order to solve problem above, the present invention provides and can greatly shorten dye ink printing technology flow process, and again can
To save the transfer printing paper of substantial amounts of coated special separating agent, thus greatly reducing dye ink stamp production and processing
This, to continue to maintain the decalcomania color hierarchy change that dye ink transfer printing has abundant simultaneously again, dye ink
The dye fixing rate that transfer printing has is high, and in water-washing process, loose colour is less, reduces discharge of wastewater, and reduction is not fallen by fixation
The white ground contamination to printed textile for the dyestuff, reduces the dye ink transfer printing works such as the product quality problem of printed textile
Skill and its relevant inks and dyestuff.
First, the invention provides a kind of structure is through the excellent acid stain of the obtained washing fastness of improvement.
Acid stain, yellow acid dye compound, formula shown in general formula (I)（II）Shown carmoisine
Compound, formula（III）Shown Vickery blue compound and formula（IV）In shown black acid dye compound one
Plant or several composition；
In logical formula (I)：R1、R2、R3、R4、R5、R6、R7For-H or-SO3M1, wherein M1For hydrogen or alkali metal；X represent Cl or
F；Y is-CH=CH2Or-C2H4OSO3M2, wherein M2Define same M1；
In logical formula (II)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein M3
Define same M1And M2；
In logical formula (III)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein
M3Define same M1And M2；
In logical formula (IV)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein M3
Define same M1And M2.
Wherein, described yellow acid dye compound is formula（I-1）To formula（I-4）Described arbitrary compound：
Described carmoisine compound is formula（II-1）To formula（II-2）Described arbitrary compound
Described Vickery blue compound is formula（III-1）To formula（III-2）Described arbitrary compound：
Described black acid dye compound is formula（IV-1）To formula（IV-2）Described arbitrary compound：
In addition, a kind of present invention also offers acid dye intaglio printing ink and preparation method thereof.
Acid dye intaglio printing ink, including acid stain, cosolvent, surfactant, pH stable agent, viscosity modifier
With water composition, wherein acid stain yellow acid dye compound, formula shown in general formula (I)（II）Shown red acid
Dye composition, formula（III）Shown Vickery blue compound and formula（IV）In shown black acid dye compound
One or more composition
In logical formula (I)：R1、R2、R3、R4、R5、R6、R7For-H or-SO3M1, wherein M1For hydrogen or alkali metal；X represent Cl or
F；Y is-CH=CH2Or-C2H4OSO3M2, wherein M2Define same M1；
Formula（I）Priority structure：
In logical formula (II)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein M3
Define same M1And M2；
Formula（II）Priority structure：
In logical formula (III)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein
M3Define same M1And M2；
Formula（III）Priority structure：
In logical formula (IV)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein M3
Define same M1And M2.
Formula（IV）Priority structure：
Further, the percentage by weight of each component is：
Further, described cosolvent is carbamide, thiourea, ethanol, isopropanol, diethylene glycol, the imappropriate, dimethylformamide of card
DMF, caprolactam, ethylene glycol, polyethylene glycol 200, PEG400, Macrogol 600, glycerol and glycerol polyoxy second
One or more of alkene ether.
Further, described cosolvent includes carbamide and Ka Bie is appropriate, additionally includes ethylene glycol, polyethylene glycol 200 and third
Triol one or two.
Further, described surfactant be turkey red oil, pull open powder, dodecylbenzene sodium sulfonate, SAS,
Penetrating agent JFC, isomery fatty alcohol-polyoxyethylene ether series, emulsifying agent AEO series, Emulsifier O series, emulsifying agent LAE are serial, newborn
Agent EL series.
Further, described pH stable agent is biphosphate sodium salt or potassium salt or ammonium salt；Perlate salt or potassium
Salt or the compound of ammonium salt and dihydric phosphate and phosphoric acid hydrogen disalt.
Further, described viscosity modifier be modified starch, modified cellulose fibre, modified seed plant glue, synthesis
Thickening agent.
The preparation method of acid dye intaglio printing ink, comprises the following steps：
（1）Under agitation, viscosity modifier is slowly added in water, is modulated into the former paste that solid content is 1-15%, treats
With；
（2）Under agitation, pH stable agent, cosolvent, surfactant are added to the water, stir, make them molten
In Xie Yushui；
（3）Weigh acid stain be dividedly in some parts above-mentioned（2）In solution, stir so as to be dissolved or dispersed in water；
（4）Add above-mentioned（1）Former paste, stirs, and adds water to gravure ink total amount, stirs rear suction ball milling
Grind in machine, make ink fineness be less than 1 micron, obtain final product acid dye intaglio printing ink.
Further, following steps are specifically included：
（1）Under agitation, by modified starch or modified cellulose fibre or modified seed plant glue or their mixture
It is slowly added in water, then this thickener or mixture are risen to uniform temperature, be modulated into the former paste that solid content is 1-15%；Or
Directly synthetic thickening agent is slowly added in water, is modulated into the former paste that solid content is 1-15%（Viscosity modifier）, stand-by；
（2）Under agitation, by 0.1～1%pH value stabilization agent, 15～35% cosolvents, 1～7% surfactant add 34～
In 73.4% water（Percentage ratio is the mass percent that each component accounts for ink gross weight）, mixing speed be 60～80 revs/min, stir 10
～20 minutes, make their uniform dissolution in water；
（3）Weigh acid stain 10～20% described in claim 1 be dividedly in some parts above-mentioned（2）In solution, mixing speed is
100～1200 revs/min, stirring 30～60 minutes is so as to uniform dissolution or be dispersed in water；
（4）Will be above-mentioned for the mass percent 0.5～3% accounting for ink gross weight（1）Any one of former paste add above-mentioned（3）Step
Suddenly in the solution obtaining, mixing speed is 100～1200 revs/min, stirs 30～60 minutes, adds water to gravure ink total amount, fill
Divide suction grinding in ball grinder after stirring, make ink fineness be less than 1 micron, obtain final product acid dye intaglio printing ink.
Wherein, the percentage by weight of each component of acid dye intaglio printing ink is：
Wherein, described cosolvent is carbamide, thiourea, ethanol, isopropanol, diethylene glycol, imappropriate, the dimethylformamide DMF of card, oneself
In lactams, ethylene glycol, polyethylene glycol 200, PEG400, Macrogol 600, glycerol and glycerol polyoxyethylene ether
One or more；
Described surfactant is turkey red oil, pull open powder, dodecylbenzene sodium sulfonate, SAS, penetrating agent
JFC, isomery fatty alcohol-polyoxyethylene ether series, emulsifying agent AEO series, Emulsifier O series, emulsifying agent LAE series, emulsifier EL
Series；
Described pH stable agent is biphosphate sodium salt or potassium salt or ammonium salt；Perlate salt or potassium salt or ammonium salt
And the compound of dihydric phosphate and phosphoric acid hydrogen disalt.
In addition, the present invention has been provided with the intaglio printing printing technology using acid dye intaglio printing ink.
A kind of intaglio printing printing technology, its printing technology flow process comprises the following steps：
（1）Press acid dye intaglio printing ink and sour agent solution mass ratio 9-4 in advance:Sour agent solution is added to by 1 ratio
In acid dye intaglio printing ink, stir, obtain final product the acid dye intaglio printing ink after adjusting through sour agent；
（2）By adjusting through printing thickness, door width lengthens, and dries and strengthens, to spending synchronous intaglio press, with
10-40 m/min of speed will be above-mentioned（1）Gravure ink prints to protein fibre fabric or chinlon PRINTED FABRIC, and dries；
（3）Protein fibre fabric or chinlon PRINTED FABRIC enter decatizing apparatus vapour steaming colour fixing, steam temperature 115-125
DEG C, decatize humidity 85-100%, steaming time 20-30 minute；
（4）After fixation protein fibre or chinlon PRINTED FABRIC washed by open washing car cold water → open washing car soaps → open washing car
Hot water wash → open washing car cold water washes → dries → protein fibre, chinlon PRINTED FABRIC finished product.
Wherein, described acid dye intaglio printing ink, including acid stain, cosolvent, surfactant, pH stable agent,
Viscosity modifier and water composition, wherein acid stain yellow acid dye compound, formula shown in general formula (I)（II）Institute
Show carmoisine compound, formula（III）Shown Vickery blue compound and formula（IV）Shown black acidic dye
One or more of material compound composition
In logical formula (I)：R1、R2、R3、R4、R5、R6、R7For-H or-SO3M1, wherein M1For hydrogen or alkali metal；X represent Cl or
F；Y is-CH=CH2Or-C2H4OSO3M2, wherein M2Define same M1；
Formula（I）Priority structure：
In logical formula (II)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein M3
Define same M1And M2；
Formula（II）Priority structure：
In logical formula (III)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein
M3Define same M1And M2；
Formula（III）Priority structure：
In logical formula (IV)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein M3
Define same M1And M2.
Formula（IV）Priority structure：
Further, the percentage by weight of each component of acid dye intaglio printing ink is：
Further, described step（1）Mixing speed be 100～1200 revs/min, mixing time be 30～60 minutes.
Further, described step（2）Drying temperature between 80-100 DEG C.
Further, described step（4）Washed by open washing car cold water for protein fibre after fixation, chinlon PRINTED FABRIC →
Open washing car is soaped, 2g/L neutrality soap flakes, 85 DEG C of temperature of soaping, time 10 minutes → open washing car hot water wash of soaping, washing temperature 60
DEG C → open washing car cold water washes → dries, 90 DEG C → protein fibre of drying temperature, chinlon PRINTED FABRIC finished product.
Further, for acid dye intaglio printing ink dyeing and printing process sour agent solution, including water and ammonium sulfate, chlorination
Ammonium, ammonium dihydrogen phosphate, acetic acid, ammonium acetate, lactic acid, DL-Lactic acid ammonium salt., citric acid, ammonium citrate, tartaric acid, ammonium tartrate, polyhydric alcohol
Formic acid esters, polyol acid ester, oxalic acid monoesters or dibasic acid esters, malonic acid monoester or dibasic acid esters, succinate monoester or dibasic acid esters, lactate,
Lemon acid monoester or dibasic acid esters or three esters, winestone acid monoester or dibasic acid esters, maleic mono-ester or dibasic acid esters, propanoic acid polyoxyethylene ether and butanoic acid
The mixing of one or more of polyoxyethylene ether.
Further, described acid agent solution is ammonium sulfate, ammonium acetate, citric acid or tartaric aqueous solution.
For the preparation method of the sour agent of acid dye intaglio printing ink dyeing and printing process, comprise the following steps：Weigh 100g water,
Low whipping speed is under 60～80 revs/min of stirrings, and 0.1-1g acid agent is slowly added in water, stirring 10～20 minutes to uniform,
So that sour agent is dissolved in the water, obtain final product sour agent solution.
A kind of patent for textile dye many chromatographys roller intaglio printing stamp that the present invention is invented based on our company
Production method, this patent production method is exactly can to adjust using through printed article thickness, and door width lengthens, and dries and strengthens, to flower
The intaglio press such as synchronous carries out direct intaglio printing stamp to yarn fabric, dries, the one-step method production process of vapour steaming colour fixing, should
It is textile dye ink direct printing that patent production method changes textile dye ink transfer stamp, this substantially reduces
Dye ink printing technology flow process, and the transfer printing paper of substantial amounts of coated special separating agent can be saved again, thus greatly
Reduce greatly dye ink stamp production and processing cost, continue to maintain the stamp that dye ink transfer printing has simultaneously again
Pattern color layer variability enriches, and the dye fixing rate that dye ink transfer printing has is high, and in water-washing process, loose colour is less,
Reduce discharge of wastewater, reduce the white ground contamination to printed textile for the dyestuff not fallen by fixation, reduce the product of printed textile
The dye ink transfer printing such as quality problem is had the advantage that.
For supporting textile dye many chromatographys roller gravure printing production method, our company have developed and matches
Serial gravure ink, acid dye intaglio printing ink is exactly one of them.
A kind of acid dye intaglio printing ink for direct intaglio printing stamp of this patent and preparation method thereof, specifically
Ground is said, the present invention relates to the excellent acid stain of the washing fastness obtained by improvement using a kind of dye structure；This
Bright be related to a kind of composition of acid dye intaglio printing ink and preparation method thereof, wherein comprise acid stain, cosolvent, surface activity
Agent, pH stable agent, viscosity modifier and water；The present invention relates to a kind of acid dye intaglio printing ink faces the acid that the used time must add
Composition of agent and preparation method thereof；The present invention relates to protein fibre fabric, nylon fabric do not need to carry out just rolling sour agent process
Energy directly intaglio printing stamp, dries, the intaglio printing printing technology of vapour steaming colour fixing.
A kind of acid dye intaglio printing ink described in this patent, is primarily adapted for use in protein fibre fabric, nylon fabric acid
Property dyestuff direct intaglio printing stamp production technology.
Due to passing through the acid stain of improvement using a kind of dye structure, through the fabric obtained by stamp production technology especially
The washing fastness being is excellent, and therefore the acid stain of solving over cannot carry out direct intaglio printing stamp life to nylon fabric
The technical barrier producing.
Because using a kind of acid dye intaglio printing ink, therefore, protein fibre fabric, nylon fabric do not need to be rolled
Sour agent is processed, and protein fibre fabric, nylon fabric, through acid stain direct intaglio printing stamp, are dried, after vapour steaming colour fixing, acid
Property dyestuff just can be bonded to protein fibre fabric, nylon fabric well.
With regard to such a kind of acid dye intaglio printing ink for direct intaglio printing stamp and preparation method thereof so far
There is not yet disclosed document or patent report.
Specific embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than restriction the scope of the present invention.In addition, it is to be understood that after having read the content of present invention instruction, people in the art
Member can make various changes or modifications to the present invention, and these equivalent form of values equally fall within the application appended claims and limited
Scope.
In the following example, method therefor if no special instructions, is conventional method.Required material in following examples
Material or reagent, are market if no special instructions and buy.
Formula（I）-（IV）Compound is buied for market.
Embodiment 1
Acid dye intaglio printing ink preparation and its intaglio printing stamp technological process of production 1
Production material：Nylon fabric deoils semi-products
Dye chemical medicine product：Formula（I-1）Shown acid yellow dye, cosolvent, surfactant, pH stable agent, viscosity adjustment
Agent, sour agent, soda liquid（2g/L soda）.
Production equipment：Intaglio press, steaming box, open washing car.
1. acid dye intaglio printing ink preparation
1.1 acid dye intaglio printing ink preparation prescriptions
1.2 acid dye intaglio printing ink preparation process
Weigh most of water, under agitation, pH stable agent, cosolvent, surfactant are added to the water, stir
（For example, mixing speed is 60 revs/min, stirs 20 minutes）, so that them is dissolved in the water；
Weigh formula（I-1）Acid yellow dye is dividedly in some parts in this above-mentioned solution, stirs（For example, mixing speed is 100
Rev/min, stir 60 minutes）So as to be dissolved or dispersed in water；
Add viscosity modifier, stir（For example, mixing speed is 100 revs/min, stirs 60 minutes）.Add water to recessed
Printing ink total amount, stirs rear suction grinding in ball grinder, makes ink fineness be less than 1 micron, obtains final product acid stain recessed
Printing ink is yellow.
1.3 sour agent preparation process
Weigh 100g water, low whipping speed is under 60 revs/min of stirrings, 0.2g acid agent ammonium acetate is slowly added to 100g water
In, stirring makes sour agent be dissolved in the water, obtains final product sour agent ammonium acetate solution to uniform for 20 minutes.
The 1.4 acid dye intaglio printing ink preparation process after sour agent regulation
Face the used time, in advance by ammonium acetate solution according to ammonium acetate solution and acid dye intaglio printing ink Huang 1：9 mass ratio,
It is added in acid dye intaglio printing ink Huang, stir（For example, mixing speed is 100 revs/min, stirs 60 minutes）, obtain final product
Acid dye intaglio printing ink after adjusting through sour agent is yellow.
2. printing technology
Printing technology flow process and condition
Polyamide fabric → intaglio press stamp → drying（90 DEG C of drying temperature）→ steaming box vapour steaming colour fixing（Steam temperature
120 DEG C, decatize humidity 100%, steaming time 20 minutes）→ stamp polyamide fabric
3. aftertreatment technology
Aftertreatment technology flow process and condition
After fixation stamp polyamide fabric → open washing car cold water wash → open washing car soda liquid washes（2g/L soda, alkali cleaning temperature 45 C,
10 minutes alkali cleaning time）→ open washing car cold water is washed → is dried（90 DEG C of drying temperature）→ stamp polyamide fabric finished product
Embodiment 2-8
By the formula in embodiment 1（I-1）Acid yellow dye replaces with formula successively（I-2）Acid yellow dye, formula（I-3）Acid
Yellow dye,（I-4）Acid yellow dye, formula（I-1）With formula（I-2）Mixing acid yellow dye, formula（I-2）With formula（I-3）Mixed
Close acid yellow dye, formula（I-2）With formula（I-4）Mixing acid yellow dye, formula（I-1）With formula（I-2）, formula（I-3）Three's
Mixing acid yellow dye, remaining is same as Example 1.
Embodiment 9
Acid dye intaglio printing ink preparation and its intaglio printing stamp technological process of production 2
Production material：Nylon fabric deoils semi-products
Dye chemical medicine product：Formula (II-1) acid red dye, cosolvent, surfactant, pH stable agent, viscosity modifier,
Soda liquid（2g/L soda）.
Production equipment：Intaglio press, steaming box, open washing car.
1. acid dye intaglio printing ink preparation
1.1 acid dye intaglio printing ink preparation prescriptions
1.2 acid dye intaglio printing ink preparation process
Weigh most of water, under agitation, pH stable agent, cosolvent, surfactant are added to the water, stir
（For example, mixing speed is 80 revs/min, stirs 10 minutes）, so that them is dissolved in the water；
Weigh formula (II-1) acid red dye to be dividedly in some parts in this above-mentioned solution, stir（For example, mixing speed is
1200 revs/min, stir 30 minutes）So as to be dissolved or dispersed in water；
Add viscosity modifier, stir（For example, mixing speed is 1200 revs/min, stirs 30 minutes）.Add water to recessed
Printing ink total amount, stirs rear suction grinding in ball grinder, makes ink fineness be less than 1 micron, obtains final product acid stain recessed
Printing ink is red.
1.3 sour agent preparation process
Weigh 100g water, low whipping speed is under 80 revs/min of stirrings, 0.5 sour agent ammonium sulfate be slowly added in 100g water,
Stirring makes sour agent be dissolved in the water, obtains final product sour agent ammonium sulfate to uniform for 10 minutes.
The 1.4 acid dye intaglio printing ink preparation process after sour agent regulation
Face the used time, in advance by ammonium sulfate according to 2：8 mass ratio, be added to acid dye intaglio printing ink red in, stir
Mix uniformly（For example, mixing speed is 1200 revs/min, stirs 30 minutes）, obtain final product the acid stain gravure oil after adjusting through sour agent
Mo Hong.
2. printing technology
Printing technology flow process and condition
Polyamide fabric → intaglio press stamp → drying（90 DEG C of drying temperature）→ steaming box vapour steaming colour fixing（Steam temperature
120 DEG C, decatize humidity 100%, steaming time 20 minutes）→ stamp polyamide fabric
3. aftertreatment technology
Aftertreatment technology flow process and condition
After fixation stamp polyamide fabric → open washing car cold water wash → open washing car soda liquid washes（2g/L soda, alkali cleaning temperature 45 C,
10 minutes alkali cleaning time）→ open washing car cold water is washed → is dried（90 DEG C of drying temperature）→ stamp polyamide fabric finished product
Embodiment 10-11
Formula (II-1) acid red dye in embodiment 9 is replaced with and formula (II-2) acid red dye, formula (II- successively
1) and the acid red dye that mixes of formula (II-2), remaining is same as Example 9.
Embodiment 12
Acid dye intaglio printing ink preparation and its intaglio printing stamp technological process of production 3
Production material：Nylon fabric deoils semi-products
Dye chemical medicine product：Formula（III-2）Acid stain is blue, cosolvent, surfactant, pH stable agent, viscosity modifier,
Soda liquid（2g/L soda）.
Production equipment：Intaglio press, steaming box, open washing car.
1. acid dye intaglio printing ink preparation
1.1 acid dye intaglio printing ink preparation prescriptions
1.2 reactive dye intaglio printing ink preparation process
Weigh most of water, under agitation, pH stable agent, cosolvent, surfactant are added to the water, stir
（For example, mixing speed is 70 revs/min, stirs 15 minutes）, so that them is dissolved in the water；
Weigh formula（III-2）Acid blue dye is dividedly in some parts in this above-mentioned solution, stirs（For example, mixing speed is
500 revs/min, stir 50 minutes）So as to be dissolved or dispersed in water；
Add viscosity modifier（5% modified seed plant glue concocting method is：Weigh 100g water, under agitation, by modification
Seed plant glue is slowly added in water, then this thickener or mixture are risen to uniform temperature, and being modulated into solid content is 5%
Former paste）, stir（For example, mixing speed is 500 revs/min, stirs 50 minutes）.Add water to gravure ink total amount, fully stir
Mix suction grinding in ball grinder after uniformly, make ink fineness be less than 1 micron, obtain final product acid dye intaglio printing ink blue.
The 1.3 acid dye intaglio printing ink preparation process after sour agent regulation
Face the used time, in advance by citric acid solution according to 1.7：8.3 mass ratio, is added to acid dye intaglio printing ink blue
In, stir（For example, mixing speed is 500 revs/min, stirs 50 minutes）, obtain final product through sour agent adjust after acid stain recessed
Stamp-pad ink blue black.
2. printing technology
Printing technology flow process and condition
Polyamide fabric → intaglio press stamp → drying（90 DEG C of drying temperature）→ steaming box vapour steaming colour fixing（Steam temperature
120 DEG C, decatize humidity 100%, steaming time 20 minutes）→ stamp polyamide fabric
3. aftertreatment technology
Aftertreatment technology flow process and condition
After fixation stamp polyamide fabric → open washing car cold water wash → open washing car soda liquid washes（2g/L soda, alkali cleaning temperature 45 C,
10 minutes alkali cleaning time）→ open washing car cold water is washed → is dried（90 DEG C of drying temperature）→ stamp polyamide fabric finished product
Embodiment 13-14
Formula (III-2) acid blue dye in embodiment 12 is replaced with formula (III-1) acid blue dye, formula successively
(III-1) and the acid blue dye that mixes of formula (III-2), remaining is identical with embodiment 12.
Embodiment 15
Acid dye intaglio printing ink preparation and its intaglio printing stamp technological process of production 4
Production material：Nylon fabric deoils semi-products
Dye chemical medicine product：Formula（IV-2）Acid black dye（Zhejiang Yide Chemical Co., Ltd. produces）, cosolvent, surface activity
Agent, pH stable agent, viscosity modifier, soda liquid（2g/L soda）.
Production equipment：Intaglio press, steaming box, open washing car.
1. acid dye intaglio printing ink preparation
1.1 acid dye intaglio printing ink preparation prescriptions
1.2 reactive dye intaglio printing ink preparation process
Weigh most of water, under agitation, pH stable agent, cosolvent, surfactant are added to the water, stir
（For example, mixing speed is 75 revs/min, stirs 12 minutes）, so that them is dissolved in the water；
Weigh formula（IV-2）Acid black dye is dividedly in some parts in this above-mentioned solution, stirs（For example, mixing speed is
1000 revs/min, stir 40 minutes）So as to be dissolved or dispersed in water；
Add viscosity modifier, stir（For example, mixing speed is 1000 revs/min, stirs 40 minutes）.Add water to recessed
Printing ink total amount, stirs rear suction grinding in ball grinder, makes ink fineness be less than 1 micron, obtains final product acid stain recessed
Stamp-pad ink is pitch-dark.
The 1.3 acid dye intaglio printing ink preparation process after sour agent regulation
Face the used time, in advance by tartaric acid solution according to 1.6：8.4 mass ratio, is added to acid dye intaglio printing ink black
In, stir（For example, mixing speed is 1000 revs/min, stirs 40 minutes）, obtain final product through sour agent adjust after acid stain recessed
Stamp-pad ink is pitch-dark.
2. printing technology
Printing technology flow process and condition
Polyamide fabric → intaglio press stamp → drying（90 DEG C of drying temperature）→ steaming box vapour steaming colour fixing（Steam temperature
120 DEG C, decatize humidity 100%, steaming time 20 minutes）→ stamp polyamide fabric
3. aftertreatment technology
Aftertreatment technology flow process and condition
After fixation stamp polyamide fabric → open washing car cold water wash → open washing car soda liquid washes（2g/L soda, alkali cleaning temperature 45 C,
10 minutes alkali cleaning time）→ open washing car cold water is washed → is dried（90 DEG C of drying temperature）→ stamp polyamide fabric finished product
Embodiment 16-17
Formula (IV-2) acid black dye in embodiment 15 is replaced with formula (IV-1) acid black dye, formula (IV-1) successively
The acid black dye mixing with formula (IV-2), remaining is identical with embodiment 15.
Table 1 the performance test results
Note：
It is yellow that sequence number 1-8 refers to acid dye intaglio printing ink；
It is red that sequence number 9-11 refers to acid dye intaglio printing ink；
It is blue that sequence number 12-14 refers to acid dye intaglio printing ink；
It is black that sequence number 15-17 refers to acid dye intaglio printing ink.
Claims (8)
1. acid dye intaglio printing ink, by acid stain, cosolvent, surfactant, pH stable agent, viscosity modifier and water
Composition, wherein acid stain yellow acid dye compound, carmoisine shown in logical formula (II) shown in general formula (I)
In compound, Vickery blue compound and black acid dye compound shown in logical formula (IV) shown in logical formula (III) one
Plant or several composition
In logical formula (I)：R1、R2、R3、R4、R5、R6、R7For-H or-SO3M1, wherein M1For hydrogen or alkali metal；X represents Cl or F；Y be-
CH=CH2Or-C2H4OSO3M2, wherein M2Define same M1；
In logical formula (II)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein M3Fixed
The same M of justice1And M2；
In logical formula (III)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein M3Fixed
The same M of justice1And M2；
In logical formula (IV)：M1、M2For hydrogen or alkali metal；X represents Cl or F；Y is-CH=CH2Or-C2H4OSO3M3, wherein M3Fixed
The same M of justice1And M2；
The percentage by weight of each component of acid dye intaglio printing ink is：
2. acid dye intaglio printing ink according to claim 1 it is characterised in that：Described yellow acid dye compound is
At least one compound described in formula (I-4) for the formula (I-1)：
Described carmoisine compound is at least one compound described in formula (II-2) for the formula (II-1)
Described Vickery blue compound is at least one compound described in formula (III-2) for the formula (III-1)：
Described black acid dye compound is at least one compound described in formula (IV-2) for the formula (IV-1)：
3. the preparation method of the acid dye intaglio printing ink described in claim 1, comprises the following steps：
(1) under agitation, viscosity modifier is slowly added in water, is modulated into the former paste that solid content is 1-15%, stand-by；
(2) under agitation, pH stable agent, cosolvent, surfactant are added to the water, stir, so that them is dissolved in
In water；
(3) weigh acid stain to be dividedly in some parts in above-mentioned (2) solution, stir so as to be dissolved or dispersed in water；
(4) add above-mentioned (1) former paste, stir, add water to gravure ink total amount, stir in rear suction ball mill
Grind, make ink fineness be less than 1 micron, obtain final product acid dye intaglio printing ink.
4. the preparation method of acid dye intaglio printing ink according to claim 3, specifically includes following steps：
(1) under agitation, will be slow to modified starch or modified cellulose fibre or modified seed plant glue or their mixture
It is added to the water, then this thickener or mixture are risen to uniform temperature, be modulated into the former paste that solid content is 1-15%；Or directly
Synthetic thickening agent is slowly added in water, is modulated into the former paste that solid content is 1-15%, stand-by；
(2) under agitation, pH stable agent, cosolvent, surfactant are added to the water, mixing speed is 60～80 revs/min,
Stirring 10～20 minutes, makes their uniform dissolution in water；
(3) weigh acid stain described in claim 1 to be dividedly in some parts in above-mentioned (2) solution, mixing speed is 100～1200
Rev/min, stirring 30～60 minutes is so as to uniform dissolution or be dispersed in water；
(4) former to any one of above-mentioned (1) paste is added in the solution that above-mentioned (3) step obtains, mixing speed is 100～1200
Rev/min, stir 30～60 minutes, add water to gravure ink total amount, stir rear suction grinding in ball grinder, make ink
Fineness is less than 1 micron, obtains final product acid dye intaglio printing ink.
5. the acid dye intaglio printing ink according to claim 3 or 4 preparation method it is characterised in that：Described cosolvent
For carbamide, thiourea, ethanol, isopropanol, diethylene glycol, card imappropriate, dimethylformamide DMF, caprolactam, ethylene glycol, Polyethylene Glycol
200th, one or more of PEG400, Macrogol 600, glycerol and glycerol polyoxyethylene ether；Live in described surface
Property agent be turkey red oil, pull open powder, dodecylbenzene sodium sulfonate, SAS, penetrating agent JFC, isomery fatty alcohol polyoxy second
Alkene ether series, emulsifying agent AEO series, Emulsifier O series, emulsifying agent LAE series, emulsifier EL series；Described pH stable agent
For biphosphate sodium salt, biphosphate potassium salt, biphosphate ammonium salt, perlate salt, dipotassium hydrogen phosphate salt, diammonium phosphate
Salt, or the compound of dihydric phosphate and phosphoric acid hydrogen disalt；Described viscosity modifier is modified starch, modified cellulose is fine
Dimension, modified seed plant glue, synthetic thickening agent.
6. a kind of intaglio printing printing technology, its printing technology flow process comprises the following steps：
(1) acid dye intaglio printing ink as claimed in claim 1 and sour agent solution mass ratio 9～4 are pressed in advance：1 ratio is by acid
Agent solution is added in acid dye intaglio printing ink, stirs, and obtains final product the acid dye intaglio printing ink after adjusting through sour agent；
(2) pass through can adjust through printing thickness, door width lengthens, and dries and strengthens, to spending synchronous intaglio press, with 10-
40 ms/min of speed prints above-mentioned (1) gravure ink to protein fibre fabric or chinlon PRINTED FABRIC, and dries；
(3) protein fibre fabric or chinlon PRINTED FABRIC enter decatizing apparatus vapour steaming colour fixing, 115-125 DEG C of steam temperature, vapour
Steam humidity 85-100%, steaming time 20-30 minute；
(4) after fixation protein fibre or chinlon PRINTED FABRIC washed by open washing car cold water → open washing car soaps → open washing car hot water
Wash → open washing car cold water washes → dries → protein fibre, chinlon PRINTED FABRIC finished product.
7. intaglio printing printing technology according to claim 6 it is characterised in that：The mixing speed of described step (1) is
100～1200 revs/min, mixing time is 30～60 minutes；The drying temperature of described step (2) is between 80-100 DEG C；Described
Step (4) be after fixation protein fibre, chinlon PRINTED FABRIC washed by open washing car cold water → open washing car soaps, 2g/L neutral soap
Piece, 85 DEG C of temperature of soaping, time 10 minutes → open washing car hot water wash of soaping, washing temperature 60 DEG C → open washing car cold water is washed → is dried
Dry, 90 DEG C → protein fibre of drying temperature, chinlon PRINTED FABRIC finished product.
8. intaglio printing printing technology according to claim 6 it is characterised in that：Described acid agent solution includes water and sulphuric acid
Ammonium, ammonium chloride, ammonium dihydrogen phosphate, acetic acid, ammonium acetate, lactic acid, DL-Lactic acid ammonium salt., citric acid, ammonium citrate, tartaric acid, ammonium tartrate,
Polyhydric alcohol formic acid esters, polyol acid ester, oxalic acid monoesters or dibasic acid esters, malonic acid monoester or dibasic acid esters, succinate monoester or dibasic acid esters, breast
Acid esters, lemon acid monoester or dibasic acid esters or three esters, winestone acid monoester or dibasic acid esters, maleic mono-ester or dibasic acid esters, propanoic acid polyoxyethylene ether
Mixing with one or more of butanoic acid polyoxyethylene ether.
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| CN104140714A (en) * | 2014-07-18 | 2014-11-12 | 浙江亿得化工有限公司 | Novel acid ink and preparation method and direct printing technology of novel acid ink |
| CN106009895A (en) * | 2016-07-05 | 2016-10-12 | 广东汇益纺织有限公司 | High-stability ink for printing machine and preparation method thereof |
| CN107829320A (en) * | 2017-10-20 | 2018-03-23 | 江苏新瑞贝科技股份有限公司 | A kind of dye penetrant and preparation method thereof |
| CN117024989A (en) * | 2022-05-09 | 2023-11-10 | 台湾永光化学工业股份有限公司 | Reactive dye composition and use thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101044211A (en) * | 2004-10-19 | 2007-09-26 | 亨斯迈先进材料（瑞士）有限公司 | Reactive dyers, their preparation and their use |
| CN102257074A (en) * | 2009-01-21 | 2011-11-23 | 亨斯迈先进材料（瑞士）有限公司 | Reactive dyes, their preparation and their use |
| CN102618073A (en) * | 2012-02-21 | 2012-08-01 | 浙江亿得化工有限公司 | Blue double-reactive-group dye compound, as well as preparation method and composition thereof |
| CN102850822A (en) * | 2012-09-28 | 2013-01-02 | 浙江亿得化工有限公司 | Composite type reactive dye composition and dyeing method by using composition |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101044211A (en) * | 2004-10-19 | 2007-09-26 | 亨斯迈先进材料（瑞士）有限公司 | Reactive dyers, their preparation and their use |
| CN102257074A (en) * | 2009-01-21 | 2011-11-23 | 亨斯迈先进材料（瑞士）有限公司 | Reactive dyes, their preparation and their use |
| CN102618073A (en) * | 2012-02-21 | 2012-08-01 | 浙江亿得化工有限公司 | Blue double-reactive-group dye compound, as well as preparation method and composition thereof |
| CN102850822A (en) * | 2012-09-28 | 2013-01-02 | 浙江亿得化工有限公司 | Composite type reactive dye composition and dyeing method by using composition |
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