CN107312357A - A kind of dark azoic dye disperse dye composition - Google Patents
A kind of dark azoic dye disperse dye composition Download PDFInfo
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- CN107312357A CN107312357A CN201710485693.1A CN201710485693A CN107312357A CN 107312357 A CN107312357 A CN 107312357A CN 201710485693 A CN201710485693 A CN 201710485693A CN 107312357 A CN107312357 A CN 107312357A
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- 239000000203 mixture Substances 0.000 title claims abstract description 85
- 239000000986 disperse dye Substances 0.000 title claims abstract description 35
- 239000000975 dye Substances 0.000 title claims description 39
- 150000001875 compounds Chemical class 0.000 claims abstract description 83
- 239000012752 auxiliary agent Substances 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims 2
- 238000005406 washing Methods 0.000 abstract description 14
- 230000002209 hydrophobic effect Effects 0.000 abstract description 6
- 239000002657 fibrous material Substances 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 239000002270 dispersing agent Substances 0.000 description 19
- 239000000047 product Substances 0.000 description 18
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 15
- 238000000227 grinding Methods 0.000 description 14
- 238000003756 stirring Methods 0.000 description 13
- 238000001035 drying Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 238000004043 dyeing Methods 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 0 CC([C@](C=C1*)N=Nc(c([N+]([O-])=O)cc(N)c2)c2C#N)C=C1N(*)C(C)=C Chemical compound CC([C@](C=C1*)N=Nc(c([N+]([O-])=O)cc(N)c2)c2C#N)C=C1N(*)C(C)=C 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 241001062009 Indigofera Species 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010017 direct printing Methods 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- CBCZQJLYYRPMRI-UHFFFAOYSA-N 2-benzylnaphthalene-1-sulfonic acid Chemical class C1=CC2=CC=CC=C2C(S(=O)(=O)O)=C1CC1=CC=CC=C1 CBCZQJLYYRPMRI-UHFFFAOYSA-N 0.000 description 1
- NMDKWAQVRNUKQH-UHFFFAOYSA-N 2-benzylnaphthalene-1-sulfonic acid formaldehyde Chemical compound C=O.C(C1=CC=CC=C1)C1=C(C2=CC=CC=C2C=C1)S(=O)(=O)O NMDKWAQVRNUKQH-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PLILWZJQAUTHSW-UHFFFAOYSA-N O=C(C(c1ccccc1)=C1C=C2OC3=O)OC1=CC2=C3c(cc1)ccc1OCC1OCCC1 Chemical compound O=C(C(c1ccccc1)=C1C=C2OC3=O)OC1=CC2=C3c(cc1)ccc1OCC1OCCC1 PLILWZJQAUTHSW-UHFFFAOYSA-N 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- -1 alkyl naphthalene sulfonic acid formaldehyde Chemical compound 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000009980 pad dyeing Methods 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8214—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing ester and amide groups
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The present invention relates to component A, the component B of 15~90 mass parts, the component C of 0.1~40 mass parts of a kind of Dark azo type disperse dye composition, including 5~80 mass parts；The component A is selected from formula (I) compound, the component B is selected from least one of formula (II 1)~(II 5) compound, and the component C is selected from least one of formula (III 1)~(III 7) compound.Dark azo type disperse dye composition of the present invention, when being dyed applied to hydrophobic fiber material, every dyeability and color fastness particularly washing fastness are protruded.
Description
Technical field
The invention belongs to dye field, it is related to a kind of Dark azo type disperse dye composition, especially one kind and is suitable for
The blue disperse dye composition to black high washing fastness of printing hydrophobic synthetic material.
Background technology
With high-grade dacron or requirement more and more higher of the ammonia elastic fabric to washing fastness is washed, point of high washing fastness
Scattered dyestuff demand is increasing, and especially blue-black series is used as the maximum kind of usage amount, many producers in deep color dispersion dyes
Exploitation dynamics is increased to it.The scattered blue-black dyestuff of 3.5-4 grades of requirements of AATCC standards can be particularly reached to washing fastness to be needed
Ask increasing.With 2,4- dinitro -6- bromines (or-chlorine) aniline as diazo component, and 2- methoxyl group -5- acetylaminohydroxyphenylarsonic acid N,
The blue kind of the obtained navy of N- oxalic acid methyl esters coupling, market be commonly called as it is purplish blue, due to its good washing fastness and lifting
Property and economy, are widely applied as the important blue color component of blue-black color system.But its washing fastness is also owed not
Foot, and coloured light compares feux rouges, therefore the dark blue and black that colorant match is obtained is often not ideal enough, still needing has the green of good fastness to washing
Light is blue and other bluenesss are compounded with it or individually compounded, so that the varieties and characteristicses of dark series are improved.
It is hard that existing literature CN102352125A, CN104987751A, CN105838109A etc. provide a kind of every dyeing
The excellent black-and-blue Azo type disperse dye composition of fastness, but still have the space further lifted.Exploitation has higher washing
The dark kind of fastness turns into the trend and emphasis of Recent study.
The content of the invention
In order to solve problems of the prior art, the invention provides a kind of combination of Dark azo type disperse dye
Thing, during applied to printing hydrophobic synthetic material, every dyeability and color fastness particularly washing fastness are protruded.
The technical scheme is that：
A kind of Dark azo type disperse dye composition, mainly the component A including 5~80 mass parts, 15~90 mass parts
Component B, the component C of 0.1~40 mass parts；The component A be selected from formula (I) compound, the component B be selected from formula (II-1)~
(II-5) at least one of compound, the component B is selected from least one of formula (III-1)~(III-7) compound:
It is preferred that, based on described component A, component B, component C summation, component A mass percent is 5~80%；
Component B mass percent is 15~90%；The percentage of component C mass parts is 0.1~40%.
It is preferred that, the composition is made up of component A, component B and component C, and component A mass percent is 5~80%；
Component B mass percent is 15~90%；The percentage 0.1~40% of component C mass parts.
It is preferred that, the also component D including 1-30 mass parts in the composition, the component D be selected from formula (IV-1)~
(IV-2) at least one of compound shown in：
It is preferred that, the composition is made up of component A, component B, component C and component D, and component A mass percent is 5
~80%, component B mass percent are 15~90%, and the percentage of component C mass parts is 0.1~40%, component D matter
It is 1~30% to measure percentage.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：Formula (II-1) compound；
Component C：At least one of formula (III-1)~(III-7) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：Formula (II-2) and/or formula (II-3) compound；
Component C：At least one of formula (III-1)~(III-7) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：(II-1), formula (II-2) and/or (II-3) compound；
Component C：At least one of formula (III-1)~(III-7) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：Formula (II-1), formula (II-4) and/or formula (II-5) compound；
Component C：At least one of formula (III-1)~(III-7) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：Formula (II-2) or/and formula (II-3), formula (II-4) or/and compound shown in formula (II-5)；
Component C：At least one of formula (III-1)~(III-7) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：Compound shown in formula (II-1), formula (II-2) or/and formula (II-3), formula (II-4) or/and formula (II-5)；
Component C：At least one of formula (III-1)~(III-7) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：Formula (II-1) compound；
Component C：At least one of formula (III-1)~(III-7) compound；
Component D：Formula (IV-2) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：Formula (II-2) or/and formula (II-3) compound；
Component C：At least one of formula (III-1)~(III-7) compound；
Component D：Formula (IV-2) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：(II-1), formula (II-2) or/and (II-3) compound；
Component C：At least one of formula (III-1)~(III-7) compound；
Component D：Formula (IV-2) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：Formula (II-1), formula (II-4) or/and formula (II-5) compound；
Component C：At least one of formula (III-1)~(III-7) compound；
Component D：Formula (IV-1) or/and formula (IV-2) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：Formula (II-2) or/and formula (II-3), formula (II-4) or/and compound shown in formula (II-5)；
Component C：At least one of formula (III-1)~(III-7) compound；
Component D：Formula (IV-1) or/and formula (IV-2) compound.
In addition, disperse dye composition of the present invention, particularly preferably composition are as follows：
Component A：Formula (I) compound；
Component B：Compound shown in formula (II-1), formula (II-2) or/and formula (II-3), formula (II-4) or/and formula (II-5)；
Component C：At least one of formula (III-1)~(III-7) compound；
Component D：Formula (IV-1) or/and formula (IV-2) compound.
Disperse dye composition of the present invention, when selling or apply as product, it usually needs carry out conventional business
Product Final finishing is processed, and is existed in the form of dye formulations, and described dye formulations include dye composite and auxiliary agent two parts.
Present invention additionally comprises a kind of Dark azo type disperse dye, by described dye composite (A+B+C or A+B+C+D)
With auxiliary agent composition, the mass ratio of auxiliary agent and dye composite is 0.3-5:1.
When disperse dye composition of the present invention is processed into dye formulations, it can carry out in known manner, for example,
After dye component is mixed for A~D filter cake by above-mentioned proportioning, with sand milling in the presence of auxiliary agent, water or other wetting agents
The pulverizer such as machine or grinder carries out corpusculed, and can be further dried；Also dye component A~D can respectively helped in addition
Carried out in the presence of agent, water or other wetting agents with pulverizers such as sand mill or grinders after corpusculed processing with above-mentioned ratio
Example is mixed, and is further dried.
Described auxiliary agent dispersant, diffusant and surfactant conventional when being disperse dyes commercialization etc., preferably under
One of row or its any several mixture：Naphthalene sulfonic acid-formaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic acids first
The anionic dispersing agents such as aldehyde condensate, lignosulfonates.Specifically, naphthalene sulfonic acid-formaldehyde condensation product such as dispersing agent NNO, alkylnaphthalene
Sulfonic formaldehyde condensation compound such as Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), benzyl naphthalene sulfonic acid-formaldehyde condensation product such as diffusant
CNF etc., lignosulfonates such as sodium lignin sulfonate (such as commercial dispersants Reax83A, Reax85A).
Due to the particularity of dye industry, it is difficult to also It is not necessary to which sterling is made, it will usually with some preparation process
Impurity, also allow when finished product is made in dye composite of the present invention containing a small amount of moisture and micro physical impurity.
Disperse dye composition of the present invention, used component A~D can easily press those skilled in the art
Well known mode is synthesized, and is such as prepared according to conventional diazotising, couling process, wherein B component refer to CN1208057A,
JPS58152056A, component C refers to GB1326124A preparations, can also use commercially available prod.
According to the disperse dyes preparation of the present invention being made, it can be dyed, also may be used using common dip method, pad-dyeing method
For direct printing.Wherein, common dip method is such as pre-processed polyester textile, is put into dye vat and is contaminated, and dye finishes, cold
Water is cleaned to neutrality, is squeezed out, then carries out reduction cleaning, drying；Direct printing such as carries out fabric to contaminate preceding pretreatment, dries, fixed
Shape, prints disperse dyes mill base on printing machine, then is evaporated, and the dye fixing on fabric, last water are made using decatize mode
Wash, stentering forming.
Disperse dye composition of the present invention, after commercial treatment, the dye formulations of gained can be with micro- material for making clothes
Rear liquid, emulsifiable paste state or powdery after being dried with spray drying process etc., graininess supply dyeing, with foregoing specific
Mixed proportion prepare, can obtain black or blue color.The disperse dye composition is particularly suitable for use in hydrophobic textile material
Printing and dyeing, including it is semi-synthetic or synthesis hydrophobic fibre blending textile material dyeing and stamp, this kind of textile material can
Hope that any form is dyed, including fiber, yarn or adhesive-bonded fabric or yarn fabric or knitting fabric.
Compared with prior art, the beneficial effects are mainly as follows：The Dark azo type disperse dye of the present invention
Composition, when especially washing ammonia textile dyeing applied to hydrophobic fiber material, every dyeability and color fastness particularly water
Wash fastness protrusion.
Embodiment
In order that the purpose of the present invention, technical scheme and beneficial effect are clearer, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.
Embodiment 1
By the component A of 63 grams of formulas (I), the component B of 36 grams of formulas (II-1), 1 gram of formula (III -1) component C, 170 grams scattered
Agent MF, 30 grams of sodium lignin sulfonate (Reax85A), are added water 750 grams and stir, and grinding distribution and drying are produced into
Product, the dyestuff can be supplied to the excellent blueness of the every fastness ability of fabric.
Embodiment 2
By the component A of 25 grams of formulas (I), the component B of 74.9 grams of formulas (II-2), 0.1 gram of formula (III -4) component C, 170 grams
Dispersant MF, 30 grams of sodium lignin sulfonate (Reax85A), add water 750 grams and stir, grinding distribution and drying, i.e.,
Finished product is obtained, the dyestuff can be supplied to the excellent navy blue of the every fastness ability of fabric.
Embodiment 3
By the component A of 37 grams of formulas (I), the component B of 50 grams of formulas (II-1) and 12.5 grams of formulas (II-3), 0.5 gram of formula (III -2)
Component C, 170 grams of Dispersant MF, 30 grams of sodium lignin sulfonate (Reax85A) add water 750 grams and stirred, grind
Mill is scattered and dries, and gets product, and the dyestuff can be supplied to the excellent navy blue of the every fastness ability of fabric.
Embodiment 4
By the component A of 40 grams of formulas (I), 22 grams of formulas (II-1), 15 grams of formulas (II-2) and the component B of 15 grams of formulas (II-3), 3 grams
The component C of formula (III -3), the component D of 5 grams of formulas (IV-2), 170 grams of Dispersant MF, 30 grams of sodium lignin sulfonate
(Reax85A), add water 750 grams and stir, grinding distribution and drying are got product, and the dyestuff can be supplied to fabric each
The excellent navy blue of item fastness ability.
Embodiment 5~14:
According to the method described in embodiment l, the difference is that using component A, component B, component C, component D weight in table l, plus
Enter 180 grams of auxiliary agent (Dispersant MF is 170 grams, and sodium lignin sulfonate Reax85A is 30 grams), add water after 750 grams of blendings, fully stir
Mix uniform, slurries are made, grinding distribution is dried, finished product, the dyestuff can be supplied to the excellent indigo plant of the every fastness ability of fabric
Color or navy blue tone.
Table 1
Embodiment 15
By the component A of 60 grams of formulas (I), 28 grams of formulas (II-1), the component B of 5 grams of formulas (II-4), 7 grams of formulas (III -1) component
C, 170 grams of Dispersant MF, 30 grams of sodium lignin sulfonate (Reax85A), adds water 750 grams and stirs, grinding distribution
And dry, get product, the dyestuff can be supplied to the excellent navy blue of the every fastness ability of fabric.
Embodiment 16
By the component A of 60 grams of formulas (I), the component B of 28 grams of formulas (II-1), 5 grams of formulas (III -2), 2 grams of formulas (III -4) component
C, the component D of 5 grams of formulas (IV-1), 170 grams of Dispersant MF, 30 grams of sodium lignin sulfonate (Reax85A) add water 750 grams and filled
Point stir, grinding distribution and drying are got product, the dyestuff can be supplied to excellent dark blue of the every fastness ability of fabric
Color.
Embodiment 17
By the component A of 60 grams of formulas (I), 28 grams of formulas (II-1), the component B of 4 grams of formulas (II-5), 6 grams of formulas (III -3), 2 grams of formulas
The component C of (III -5), 170 grams of Dispersant MF, 30 grams of sodium lignin sulfonate (Reax85A) add water 750 grams and are sufficiently stirred for
Even, grinding distribution and drying are got product, and the dyestuff can be supplied to the excellent navy blue of the every fastness ability of fabric.
Embodiment 18~24:
According to the method described in embodiment l, the difference is that using component A, component B, component C, component D weight in table 2, plus
Enter 200 grams of auxiliary agent (Dispersant MF is 170 grams, and sodium lignin sulfonate Reax85A is 30 grams), add water after 750 grams of blendings, fully stir
Mix uniform, slurries are made, grinding distribution is dried, finished product, the dyestuff can be supplied to the excellent depth of the every fastness ability of fabric
Blue color.
Table 2
Embodiment 25
By the component A of 27.5 grams of formulas (I), 11 grams of formulas (II-1), 12.5 grams of formulas (II-2), 12.5 grams of formulas (II-3), 13 grams
The component B of formula (II-4), 7 grams of formulas (III -1), 7 grams of formulas (III -2), the component C of 9.5 grams of formulas (III -4), 130 grams of Dispersant MF,
20 grams of sodium lignin sulfonate (Reax85A), is added water 750 grams and stirs, and grinding distribution and drying are got product, should
Dyestuff can be supplied to the excellent black of the every fastness ability of fabric.
Embodiment 26
By the component A of 12.5 grams of formulas (I), 61 grams of formulas (II-2), the component B of 7 grams of formulas (II-5), 7.2 grams of formulas (III -1),
7.2 grams of formulas (III -2), the component C of 5.1 grams of formulas (III -7), 130 grams of Dispersant MF, 20 grams of sodium lignin sulfonate
(Reax85A), add water 750 grams and stir, grinding distribution and drying are got product, and the dyestuff can be supplied to fabric each
The excellent black of item fastness ability.
Embodiment 27
By the component A of 14 grams of formulas (I), 51 grams of formulas (II-2), the component B of 10 grams of formulas (II-5), 13 grams of formulas (III -3), 7 grams
The component C of formula (III -4), the component D of 5 grams of formulas (IV-2), 130 grams of Dispersant MF, 20 grams of sodium lignin sulfonate
(Reax85A), add water 750 grams and stir, grinding distribution and drying are got product, and the dyestuff can be supplied to fabric each
The excellent black of item fastness ability.
Embodiment 28
By the component A of 25 grams of formulas (I), 25 grams of formulas (II-1), the component B of 7 grams of formulas (II-4), 25 grams of formulas (III -1), 7 grams of formulas
The component C of (III -5), 6 grams of formulas (IV-1), the component D of 5 grams of formulas (IV-2), 130 grams of Dispersant MF, 20 grams of lignin sulfonic acid
Sodium (Reax85A), is added water 750 grams and stirs, and grinding distribution and drying are got product, and the dyestuff can be supplied to fabric
The excellent black of every fastness ability.
Embodiment 29
By the component A of 25 grams of formulas (I), 20 grams of formulas (II-1), 10 grams of formulas (II-2), the component B of 6 grams of formulas (II-4), 20 grams
Formula (III -1), the component C of 7 grams of formulas (III -4), 7 grams of formulas (IV-1), the component D of 5 grams of formulas (IV-2), 130 grams of Dispersant MF, 20
Gram sodium lignin sulfonate (Reax85A), add water 750 grams and stir, grinding distribution and drying are got product, the dye
Material can be supplied to the excellent black of the every fastness ability of fabric.
Embodiment 30~46:
According to the method described in embodiment 1, the difference is that using component A, component B, component C, component D weight in table 3, plus
Enter 150 grams of auxiliary agent (Dispersant MF is 130 grams, and sodium lignin sulfonate Reax85A is 20 grams), add water after 750 grams of blendings, fully stir
Mix uniform, slurries are made, grinding distribution is dried, finished product, the dyestuff can be supplied to excellent black of the every fastness ability of fabric
Color tone.
Table 3
Comparative example：
By the embodiment 1 in patent CN105838109A as a comparison case 1；
By the embodiment 1 in patent CN104987751A as a comparison case 2；
By the embodiment 1 in patent CN102352125A as a comparison case 3.
Dyeing Example：
Above-described embodiment 1~46, disperse dyes made from comparative example 1~3 are chosen respectively, using conventional high temperature high pressure dyeing
In method and thermal finalization processing polyester fibre/spandex intertexture, processing procedure, control dye level (o.w.f) 5.0%, bath raio 1：10, adjust
Value in Dyeing Process 4~4.5, room temperature enters dye, and 130 DEG C are warming up to l.5 DEG C/min, is incubated 45min, by well-established law reduce washing, washing,
Dry, 170 DEG C of thermal finalization 60 seconds, obtain blueness to the dyeing and weaving thing of black.Test resistance to respectively according to AATCC 8, AATCC 61-2A
Rub and washing color fastness, as a result table 4 below：
Table 4
From the indigo plant in upper table 4, the present invention to black disperse dye composition, dyed fabric is fixed through Final finishing high warm
After type, its water-fastness staining fastness is substantially better than comparative example l~3, disclosure satisfy that high fastness requires the printing and dyeing of fabric.
Although by referring to the preferred embodiments of the present invention, invention has been described, this area it is common
It will be appreciated by the skilled person that various changes can be made to it in the form and details, without departing from appended right
The spirit and scope of the present invention that claim is limited.
Claims (18)
1. a kind of Dark azo type disperse dye composition, it is characterised in that component A, 15~90 matter including 5~80 mass parts
Measure the component B, the component C of 0.1~40 mass parts of part；The component A is selected from formula (I) compound, and the component B is selected from formula (II-
1)~(II-5) at least one of compound, the component C is selected from least one of formula (III-1)~(III-7) compound:
2. composition as claimed in claim 1, it is characterised in that：Based on described component A, component B, component C, component A's
Mass percent is 5~80%；Component B mass percent is 15~90%；The percentage of component C mass parts be 0.1~
40%.
3. composition as claimed in claim 1, it is characterised in that the composition is made up of component A, component B, component C, group
The mass percent for dividing A is 5~80%；Component B mass percent is 15~90%；The percentage of component C mass parts is
0.1~40%.
4. composition as claimed in claim 1, it is characterised in that also include the component D of 1~30 mass parts in the composition,
The component D is selected from formula (IV-1)~at least one of compound shown in (IV-2)：
。
5. composition as claimed in claim 4, it is characterised in that the composition is by component A, component B, component C and component D
Composition, component A mass percent is 5~80%, and component B mass percent is 15~90%, the hundred of component C mass parts
Divide than being 0.1~40%, component D mass percent is 1~30%.
6. composition as claimed in claim 3, it is characterised in that component B is chemical combination shown in formula (II-1) in the composition
Thing；Component C is formula (III-1)~at least one of compound shown in (III-7).
7. composition as claimed in claim 3, it is characterised in that component B is formula (II-2) and/or formula in the composition
(II-3) compound shown in；Component C is formula (III-1)~at least one of compound shown in (III-7).
8. composition as claimed in claim 3, it is characterised in that component B is formula (II-1), formula (II-2) in the composition
And/or compound shown in (II-3)；Component C is formula (III-1)~at least one of compound shown in (III-7).
9. composition as claimed in claim 3, it is characterised in that component B is formula (II-1), formula (II-4) in the composition
And/or compound shown in formula (II-5)；Component C is formula (III-1)~at least one of compound shown in (III-7).
10. composition as claimed in claim 3, it is characterised in that component B is formula (II-2) and/or formula in the composition
(II-3), compound shown in formula (II-4) and/or formula (II-5)；Component C is in formula (III-1)~compound shown in (III-7)
It is at least one.
11. composition as claimed in claim 3, it is characterised in that component B is formula (II-1), formula (II-2) in the composition
And/or formula (II-3), formula (II-4) and/or compound shown in formula (II-5)；Component C is formula (III-1)~(III-7) shownization
At least one of compound.
12. composition as claimed in claim 5, it is characterised in that component B is chemical combination shown in formula (II-1) in the composition
Thing；Component C is formula (III-1)~at least one of compound shown in (III-7)；Component D is compound shown in formula (IV-2).
13. composition as claimed in claim 5, it is characterised in that component B is formula (II-2) and/or formula in the composition
(II-3) compound shown in；Component C is formula (III-1)~at least one of compound shown in (III-7)；Component D is formula (IV-
2) compound shown in.
14. composition as claimed in claim 5, it is characterised in that component B is formula (II-1), formula (II-2) in the composition
And/or compound shown in (II-3)；Component C is formula (III-1)~at least one of compound shown in (III-7)；Component D is formula
(IV-2) compound shown in.
15. composition as claimed in claim 5, it is characterised in that component B is formula (II-1), formula (II-4) in the composition
And/or compound shown in formula (II-5)；Component C is formula (III-1)~at least one of compound shown in (III-7)；Component D is
Compound shown in formula (IV-1) and/or formula (IV-2).
16. composition as claimed in claim 5, it is characterised in that component B is formula (II-2) and/or formula in the composition
(II-3), compound shown in formula (II-4) and/or formula (II-5)；Component C is in formula (III-1)~compound shown in (III-7)
It is at least one；Component D is compound shown in formula (IV-1) and/or formula (IV-2).
17. composition as claimed in claim 5, it is characterised in that component B is formula (II-1), formula (II-2) in the composition
And/or formula (II-3), formula (II-4) and/or compound shown in formula (II-5)；Component C is formula (III-1)~(III-7) shownization
At least one of compound；Component D is compound shown in formula (IV-1) and/or formula (IV-2).
18. a kind of Dark azo type disperse dye composition, as the dye composite any one of claim 1-17 and
Auxiliary agent is constituted, and the mass ratio of auxiliary agent and described dye composite is 0.3~5：1.
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| CN107312357B (en) | 2018-08-17 |
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Denomination of invention: A dark azo dye dispersed dye composition Effective date of registration: 20231117 Granted publication date: 20180817 Pledgee: Agricultural Bank of China Limited Leping sub branch Pledgor: LEPING SAFELY PHARMACEUTICAL Co.,Ltd. Registration number: Y2023980066395 |