CN102477206A - Flame retardant and antistatic ABS/PVC alloy material, and preparation method thereof - Google Patents
Flame retardant and antistatic ABS/PVC alloy material, and preparation method thereof Download PDFInfo
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- CN102477206A CN102477206A CN2010105636725A CN201010563672A CN102477206A CN 102477206 A CN102477206 A CN 102477206A CN 2010105636725 A CN2010105636725 A CN 2010105636725A CN 201010563672 A CN201010563672 A CN 201010563672A CN 102477206 A CN102477206 A CN 102477206A
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Abstract
The invention discloses a flame retardant and antistatic ABS/PVC alloy material. The material comprises the following components, by weight, 30-90 parts of ABS, 10-70 parts of PVC, 0.5-5 parts of a heat stabilizer, 1-10 parts of a toughening agent, 3-10 parts of a compatibilizer, 1-25 parts of a flame retardant agent, 0.1-5 parts of an antistatic agent, 0.1-5 parts of a processing assistant agent, and 0.1-1 parts of an antioxidant. The flame retardant and antistatic ABS/PVC alloy material of the present invention has the following advantages that: the preparation process is simple; the operation process is short; the mechanical properties of the material are maintained, the ABS is endowed with properties of environmental protection and flame retardation, and the antistatic performance of the product is increased; the cost is low; the material can be used in fields of household appliances, modern office supplies, machine parts and the like so as to enlarge the use range of the product.
Description
Technical field
The present invention relates to a kind of ABS/PVC alloy material, relate in particular to a kind of flame-retardant and antistatic ABS/PVC alloy material and preparation method thereof.
Background technology
ABS resin is the terpolymer of vinyl cyanide (A), divinyl (B) and vinylbenzene (S); Have the chemical resistant properties of vinyl cyanide, toughness and shock resistance and the cinnamic rigidity and the workability of divinyl concurrently, be widely used in vast fields such as household electrical appliance, mechanical fitting, office appliance, electron device, automotive industry.
But the flame retardant properties of ABS resin own is relatively poor, and its oxygen index is merely 18.3-20, belongs to inflammable material, needs it is carried out flame-retardant modifiedly just being used for fields such as household electrical appliance, electronic apparatus.In addition, easy accumulate static charge in ABS resin and other material surface contact process is given production and life is made troubles and potential safety hazard.
Do not see at present the report about fire-retardant and anlistatig ABS/PVC alloy material as yet, therefore developing flame-retardant and antistatic ABS/PVC alloy material has wide development and application prospect.
Summary of the invention
The present invention provides flame-retardant and antistatic ABS/PVC alloy material of a kind of environment friendly non-halogen and preparation method thereof for the deficiency that remedies above-mentioned prior art existence.
The object of the invention is realized through following technical scheme:
A kind of flame-retardant and antistatic ABS/PVC alloy material comprises following component and parts by weight:
ABS ?30-90，
PVC 10-70，
Thermo-stabilizer 0.5-5,
Toughner 1-10,
Compatilizer 3-10,
Fire retardant 1-25,
Static inhibitor 0.1-5,
Processing aid 0.1-5,
Oxidation inhibitor 0.1-1.
Said ABS is the acrylonitrile-butadiene-styrene resin of high rubber content, and rubber content is 60-65%.
Said PVC is that mean polymerisation degree is the loose type PVC RESINS of 700-800.
Said thermo-stabilizer is one or more in alkali type thermal stabilizing agent, metal soap thermal stabilizers, organic tin thermo-stabilizer, composite type heat stablizer or the organic cpds thermo-stabilizer.
Said toughner is chlorinatedpolyethylene; Said compatilizer is styrene-acrylonitrile resin SAN.
Said fire retardant is the mixture of decabromodiphynly oxide and Antimony Trioxide: 99.5Min, and blending ratio is a decabromodiphynly oxide: Antimony Trioxide: 99.5Min is 3-9:1-2.
Said static inhibitor is one or more in non-ionic antistatic agent, the anionic antistatic agent.
Said processing aid is one or more in stearate, ethylene bis stearic amide, the polyethylene wax.
Said oxidation inhibitor is one or more in antioxidant 1010, oxidation inhibitor 168, the antioxidant 1076.
The preparation method of a kind of flame-retardant and antistatic ABS/PVC alloy material may further comprise the steps:
(1) PVC, fire retardant, thermo-stabilizer, processing aid are added in the high-speed mixer, carried out mixed at high speed 5-10 minute, change over to then in the screw extrusion press, under 155-175 ℃, extrude and granulation, it is for use to obtain flame-retardant master batch;
(2) then ABS resin, static inhibitor, compatilizer, toughner, oxidation inhibitor and the above-mentioned flame-retardant master batch that makes are added in the high-speed mixer; Under the room temperature mixed at high speed 5-10 minute; Change in the twin screw extruder after the taking-up; In melt temperature is that 150-220 ℃, screw speed are 200-600 rev/min of following extruding pelletization, obtains flame-retardant and antistatic ABS/PVC alloy material.
Compared with prior art, the present invention has following beneficial effect:
A kind of flame-retardant and antistatic ABS provided by the invention/PVC alloy material and preparation method thereof; Technology is simple, operating process is short; When keeping material mechanical performance, give the flame retardant properties of ABS environment friendly non-halogen and improve the antistatic property of product; And with low cost, can be used for fields such as household electrical appliance, modern handle official bussiness articles for use, mechanical fitting, enlarged the use range of product.
Embodiment
Describe the present invention in detail below in conjunction with each embodiment.
Each component of the flame-retardant and antistatic ABS of embodiment 1, embodiment 2, embodiment 3/PVC alloy material and proportioning (parts by weight) are seen table 1.
The preparation method:
(1) PVC, fire retardant, thermo-stabilizer, processing aid are added in the high-speed mixer, carried out mixed at high speed 5-10 minute, change over to then in the screw extrusion press, under 155-175 ℃, extrude and granulation, it is for use to obtain flame-retardant master batch;
(2) then ABS resin, static inhibitor, compatilizer SAN, toughner, oxidation inhibitor and the above-mentioned flame-retardant master batch that makes are added in the high-speed mixer; Under the room temperature mixed at high speed 5-10 minute; Change in the twin screw extruder after the taking-up; In melt temperature is that 150-220 ℃, screw speed are 200-600 rev/min of following extruding pelletization, can obtain flame-retardant and antistatic ABS/PVC alloy material.
By China's national standard and U.S. UL standard testing, performance index and testing standard are seen table 2 to the physicals of embodiment 1, embodiment 2, embodiment 3 respectively.
The The performance test results of embodiment 1, embodiment 2, embodiment 3 is seen table 3.
Visible by the foregoing description 1-3, ABS/PVC alloy material of the present invention also has excellent flame and static resistance on the basis that keeps ABS good mechanical performance.
Embodiment 4
The preparation method of a kind of flame-retardant and antistatic ABS/PVC alloy material may further comprise the steps:
(1) be that 700 PVC, 15 weight part decabromodiphynly oxides, 10 weight part Antimony Trioxide: 99.5Mins, 0.5 weight part alkali type thermal stabilizing agent, 0.1 weight part processing aid stearate add in the high-speed mixer with 10 weight part mean polymerisation degree; Carried out mixed at high speed 5 minutes; Change in the screw extrusion press then; Under 155-175 ℃, extrude and granulation, it is for use to obtain flame-retardant master batch;
(2) be that 60% ABS resin, 0.1 weight part non-ionic antistatic agent, 3 weight part compatilizer SAN, 1 weight part toughner chlorinatedpolyethylene, 0.1 weight part antioxidant 1076 and the above-mentioned flame-retardant master batch that makes add in the high-speed mixer with 90 parts by weight of rubber content then; Mixed at high speed is 5 minutes under the room temperature; Change in the twin screw extruder after the taking-up; In melt temperature is that 150-220 ℃, screw speed are 200 rev/mins of following extruding pelletizations, can obtain flame-retardant and antistatic ABS/PVC alloy material.
Embodiment 5
The preparation method of a kind of flame-retardant and antistatic ABS/PVC alloy material may further comprise the steps:
(1) be that 800 PVC, 0.9 weight part decabromodiphynly oxide, 0.1 weight part Antimony Trioxide: 99.5Min, 5 weight part metal soap thermal stabilizerses, 5 weight part processing aid ethylene bis stearic amides add in the high-speed mixer with 70 weight part mean polymerisation degree; Carried out mixed at high speed 10 minutes; Change in the screw extrusion press then; Under 155-175 ℃, extrude and granulation, it is for use to obtain flame-retardant master batch;
(2) be that 65% ABS resin, 5 weight part anionic antistatic agent, 10 weight part compatilizer SAN, 10 weight part toughner chlorinatedpolyethylenees, 0.5 weight part oxidation inhibitor, 168,0.5 weight part antioxidant 1076 and the above-mentioned flame-retardant master batch that makes add in the high-speed mixer with 30 parts by weight of rubber content then; Mixed at high speed is 10 minutes under the room temperature; Change in the twin screw extruder after the taking-up; In melt temperature is that 150-220 ℃, screw speed are 600 rev/mins of following extruding pelletizations, can obtain flame-retardant and antistatic ABS/PVC alloy material.
Embodiment 6
The preparation method of a kind of flame-retardant and antistatic ABS/PVC alloy material may further comprise the steps:
(1) be that 760 PVC, 10 weight part decabromodiphynly oxides, 2 weight part Antimony Trioxide: 99.5Mins, 2.5 weight part organic tin thermo-stabilizers, 3.5 weight part processing aid polyethylene waxs add in the high-speed mixer with 50 weight part mean polymerisation degree; Carried out mixed at high speed 8 minutes; Change in the screw extrusion press then; Under 155-175 ℃, extrude and granulation, it is for use to obtain flame-retardant master batch;
(2) be that 62% ABS resin, 2 weight part anionic antistatic agent, 1 weight part non-ionic antistatic agent, 7 weight part compatilizer SAN, 5 weight part toughner chlorinatedpolyethylenees, 0.6 weight part antioxidant 1010 and the above-mentioned flame-retardant master batch that makes add in the high-speed mixer with 50 parts by weight of rubber content then; Mixed at high speed is 7 minutes under the room temperature; Change in the twin screw extruder after the taking-up; In melt temperature is that 150-220 ℃, screw speed are 500 rev/mins of following extruding pelletizations, can obtain flame-retardant and antistatic ABS/PVC alloy material.
More than the disclosed several specific embodiments that are merely the application, but the application is not limited thereto, any those skilled in the art can think variation, all should drop in the application's the protection domain.
Table 1
Table 2
Table 3
Claims (10)
1. flame-retardant and antistatic ABS/PVC alloy material is characterized in that, comprises following component and parts by weight:
ABS ?30-90，
PVC 10-70，
Thermo-stabilizer 0.5-5,
Toughner 1-10,
Compatilizer 3-10,
Fire retardant 1-25,
Static inhibitor 0.1-5,
Processing aid 0.1-5,
Oxidation inhibitor 0.1-1.
2. a kind of flame-retardant and antistatic ABS as claimed in claim 1/PVC alloy material is characterized in that said ABS is the acrylonitrile-butadiene-styrene resin of high rubber content, and rubber content is 60-65%.
3. a kind of flame-retardant and antistatic ABS as claimed in claim 1/PVC alloy material is characterized in that, said PVC is that mean polymerisation degree is the loose type PVC RESINS of 700-800.
4. a kind of flame-retardant and antistatic ABS as claimed in claim 1/PVC alloy material; It is characterized in that said thermo-stabilizer is one or more in alkali type thermal stabilizing agent, metal soap thermal stabilizers, organic tin thermo-stabilizer, composite type heat stablizer or the organic cpds thermo-stabilizer.
5. a kind of flame-retardant and antistatic ABS as claimed in claim 1/PVC alloy material is characterized in that said toughner is chlorinatedpolyethylene; Said compatilizer is styrene-acrylonitrile resin SAN.
6. a kind of flame-retardant and antistatic ABS as claimed in claim 1/PVC alloy material is characterized in that said fire retardant is the mixture of decabromodiphynly oxide and Antimony Trioxide: 99.5Min, and blending ratio is a decabromodiphynly oxide: Antimony Trioxide: 99.5Min is 3-9:1-2.
7. a kind of flame-retardant and antistatic ABS as claimed in claim 1/PVC alloy material is characterized in that said static inhibitor is one or more in non-ionic antistatic agent, the anionic antistatic agent.
8. a kind of flame-retardant and antistatic ABS as claimed in claim 1/PVC alloy material is characterized in that said processing aid is one or more in stearate, ethylene bis stearic amide, the polyethylene wax.
9. a kind of flame-retardant and antistatic ABS as claimed in claim 1/PVC alloy material is characterized in that, said oxidation inhibitor is one or more in antioxidant 1010, oxidation inhibitor 168, the antioxidant 1076.
10. the preparation method of flame-retardant and antistatic ABS as claimed in claim 1/PVC alloy material is characterized in that, may further comprise the steps:
(1) PVC, fire retardant, thermo-stabilizer, processing aid are added in the high-speed mixer, carried out mixed at high speed 5-10 minute, change over to then in the screw extrusion press, under 155-175 ℃, extrude and granulation, it is for use to obtain flame-retardant master batch;
(2) then ABS resin, static inhibitor, compatilizer, toughner, oxidation inhibitor and the above-mentioned flame-retardant master batch that makes are added in the high-speed mixer; Under the room temperature mixed at high speed 5-10 minute; Change in the twin screw extruder after the taking-up; In melt temperature is that 150-220 ℃, screw speed are 200-600 rev/min of following extruding pelletization, obtains flame-retardant and antistatic ABS/PVC alloy material.
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102731926A (en) * | 2012-06-08 | 2012-10-17 | 佛山市顺德区圆融新材料有限公司 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
| CN102757617A (en) * | 2012-07-02 | 2012-10-31 | 洛阳市河之阳高分子材料有限公司 | High-toughness ABS (Acrylonitrile Butadiene Styrene) flame retardant material and preparation method thereof |
| CN102875920A (en) * | 2012-10-08 | 2013-01-16 | 合肥杰事杰新材料股份有限公司 | High-gloss scratch-resistant ABS/PVC (acrylonitrile-butadiene-styrene/polyvinyl chloride) alloy and preparation method thereof |
| CN103059497A (en) * | 2012-11-23 | 2013-04-24 | 高凡 | Novel environment-friendly flame-retardant antistatic ABS (acrylonitrile-butadiene-styrene) master batch |
| CN103073833A (en) * | 2012-11-23 | 2013-05-01 | 高凡 | Preparation method of novel environmental protection flame retardant anti-static ABS master batch |
| CN103172946A (en) * | 2013-02-07 | 2013-06-26 | 钭礼俊 | Environment-friendly ABS (Acrylonitrile-Butadiene-Styrene) flame retardant material and preparation method thereof |
| CN103232649A (en) * | 2013-04-03 | 2013-08-07 | 广东工业大学 | High-impact high-surface hardness polymer alloy and preparation method thereof |
| CN103396646A (en) * | 2013-08-06 | 2013-11-20 | 上海瀚氏模具成型有限公司 | Antistatic plastic automobile radiator grille and its preparation method |
| CN104098857A (en) * | 2014-08-04 | 2014-10-15 | 山东瀚氏汽车零部件有限公司 | Yellowing-resistant antistatic PVC (Polyvinyl Chloride)/CPE (Chlorinated Polyethylene) alloy for automotive interior part and preparation method |
| CN105237913A (en) * | 2015-10-30 | 2016-01-13 | 无锡嘉弘塑料科技有限公司 | PVC/ABS alloy injection molded bulk molding compound |
| CN105504658A (en) * | 2016-01-07 | 2016-04-20 | 苏州法斯特信息科技有限公司 | Solvent-resistant ABS composite material and preparing method thereof |
| CN108690278A (en) * | 2017-04-11 | 2018-10-23 | 合肥杰事杰新材料股份有限公司 | A kind of dedicated PVC/ABS alloy materials of pit gear and preparation method thereof |
| CN110305440A (en) * | 2019-06-17 | 2019-10-08 | 金发科技股份有限公司 | A kind of environment-friendly flame-resistant ABS composite material and preparation method |
| CN110387097A (en) * | 2019-08-21 | 2019-10-29 | 苏州铂普乐新材料科技有限公司 | A kind of hybrid alloys formula of ABS, PVC |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1191232A (en) * | 1997-02-17 | 1998-08-26 | 上海氯碱化工股份有限公司 | PVC/ABS alloy material having low content of ABS |
| CN1765985A (en) * | 2005-11-18 | 2006-05-03 | 王崇高 | Flame-proof ABS factory formula and its production method |
| CN101693778A (en) * | 2009-10-13 | 2010-04-14 | 广东联塑科技实业有限公司 | PVC/ABS blend and pipe thereof |
-
2010
- 2010-11-29 CN CN201010563672.5A patent/CN102477206B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1191232A (en) * | 1997-02-17 | 1998-08-26 | 上海氯碱化工股份有限公司 | PVC/ABS alloy material having low content of ABS |
| CN1765985A (en) * | 2005-11-18 | 2006-05-03 | 王崇高 | Flame-proof ABS factory formula and its production method |
| CN101693778A (en) * | 2009-10-13 | 2010-04-14 | 广东联塑科技实业有限公司 | PVC/ABS blend and pipe thereof |
Non-Patent Citations (1)
| Title |
|---|
| 秦凯等: ""对生产ABS高胶粉质量控制的探讨"", 《炼油与化工》, vol. 15, no. 4, 31 December 2004 (2004-12-31), pages 16 - 18 * |
Cited By (20)
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| CN102731926A (en) * | 2012-06-08 | 2012-10-17 | 佛山市顺德区圆融新材料有限公司 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
| CN102731926B (en) * | 2012-06-08 | 2014-07-09 | 佛山市顺德区圆融新材料有限公司 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
| CN102757617A (en) * | 2012-07-02 | 2012-10-31 | 洛阳市河之阳高分子材料有限公司 | High-toughness ABS (Acrylonitrile Butadiene Styrene) flame retardant material and preparation method thereof |
| CN102875920A (en) * | 2012-10-08 | 2013-01-16 | 合肥杰事杰新材料股份有限公司 | High-gloss scratch-resistant ABS/PVC (acrylonitrile-butadiene-styrene/polyvinyl chloride) alloy and preparation method thereof |
| CN102875920B (en) * | 2012-10-08 | 2016-06-15 | 合肥杰事杰新材料股份有限公司 | A kind of high light scratch-resistant ABS/PVC Alloy And Preparation Method |
| CN103059497A (en) * | 2012-11-23 | 2013-04-24 | 高凡 | Novel environment-friendly flame-retardant antistatic ABS (acrylonitrile-butadiene-styrene) master batch |
| CN103073833A (en) * | 2012-11-23 | 2013-05-01 | 高凡 | Preparation method of novel environmental protection flame retardant anti-static ABS master batch |
| CN103172946A (en) * | 2013-02-07 | 2013-06-26 | 钭礼俊 | Environment-friendly ABS (Acrylonitrile-Butadiene-Styrene) flame retardant material and preparation method thereof |
| CN103232649A (en) * | 2013-04-03 | 2013-08-07 | 广东工业大学 | High-impact high-surface hardness polymer alloy and preparation method thereof |
| CN103396646B (en) * | 2013-08-06 | 2015-08-19 | 上海瀚氏模具成型有限公司 | A kind of Antistatic plastic automobile radiator grille and preparation method thereof |
| CN103396646A (en) * | 2013-08-06 | 2013-11-20 | 上海瀚氏模具成型有限公司 | Antistatic plastic automobile radiator grille and its preparation method |
| CN104098857A (en) * | 2014-08-04 | 2014-10-15 | 山东瀚氏汽车零部件有限公司 | Yellowing-resistant antistatic PVC (Polyvinyl Chloride)/CPE (Chlorinated Polyethylene) alloy for automotive interior part and preparation method |
| CN105237913A (en) * | 2015-10-30 | 2016-01-13 | 无锡嘉弘塑料科技有限公司 | PVC/ABS alloy injection molded bulk molding compound |
| CN105504658A (en) * | 2016-01-07 | 2016-04-20 | 苏州法斯特信息科技有限公司 | Solvent-resistant ABS composite material and preparing method thereof |
| CN105504658B (en) * | 2016-01-07 | 2017-11-14 | 罗仙花 | A kind of solvent resistance ABS composite material and preparation method thereof |
| CN108690278A (en) * | 2017-04-11 | 2018-10-23 | 合肥杰事杰新材料股份有限公司 | A kind of dedicated PVC/ABS alloy materials of pit gear and preparation method thereof |
| CN110305440A (en) * | 2019-06-17 | 2019-10-08 | 金发科技股份有限公司 | A kind of environment-friendly flame-resistant ABS composite material and preparation method |
| WO2020253483A1 (en) * | 2019-06-17 | 2020-12-24 | 金发科技股份有限公司 | Environment-friendly flame-retardant abs composite material and preparation method therefor |
| CN110305440B (en) * | 2019-06-17 | 2021-07-13 | 金发科技股份有限公司 | Environment-friendly flame-retardant ABS (acrylonitrile-butadiene-styrene) composite material and preparation method thereof |
| CN110387097A (en) * | 2019-08-21 | 2019-10-29 | 苏州铂普乐新材料科技有限公司 | A kind of hybrid alloys formula of ABS, PVC |
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