CN102875920B - A kind of high light scratch-resistant ABS/PVC Alloy And Preparation Method - Google Patents
A kind of high light scratch-resistant ABS/PVC Alloy And Preparation Method Download PDFInfo
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Abstract
The invention discloses the ABS/PVC Alloy And Preparation Method of a kind of high smooth scratch-resistant, this alloy is made up of ABS, PVC, PMMA, toughener, auxiliary agent, stabilizer, lubricant and antioxidant. The mechanical property of the ABS/PVC alloy of the present invention is balanced, excellent fireproof performance have that easy processing, cost be low, the feature of easy coloring, scratch-resistant, high surface hardness, it is adaptable to the products such as high gloss, the electronic apparatus of scratch-resistant, automobile, machinery.
Description
Technical field
The invention belongs to macromolecule modified field, particularly to a kind of ABS/PVC Alloy And Preparation Method.
Background technology
Acrylonitrile-butadiene-styrene terpolymer (ABS) and polrvinyl chloride (PVC) are current most widely used general-purpose plastics in the world, and wherein PVC consumption comes the second in the world, and ABS is number five. PVC has good physical property and chemical property, has the chemical stability of excellence, anti-flammability and electrical insulating property, but its processing characteristics is poor; ABS then has combination property and the toughness of excellence, easy coloring, easily processes, but fire resistance is poor. By ABS and PVC compound, both can comprehensive both combination property, compensate for again both weakness.
ABS/PVC alloy is due to its outstanding combination property and fire resistance, electrical insulating property, and it is less costly, it is widely used in the industries such as household electrical appliances, electronic apparatus, automobile, machinery at present, has been used for substituting flame-proof ABS, flame-retarding HIPS (high impact polystyrene), fire retardation PC (Merlon), PC/ABS alloy, PPO/PS(polyphenyl ether/styrene) engineering plastics of the contour performance of alloy. But the surface gloss of ABS/PVC alloy is relatively low, the product that surface requirements is higher still cannot substitute flame-proof ABS or the PC/ABS alloy of high glaze. Therefore, the ABS/PVC alloy developing a kind of high glaze has critically important meaning for expanding its application, improving the scope of application. Patent CN101475727 disclose a kind of by PMMA blending and modifying ABS to prepare the production method of high-light ABS; Patent CN102311590 also discloses that the method for the blended preparation highlight antiflaming ABS of a kind of PMMA, all discloses and ABS/PVC alloy is modified improving the report of its glossiness and scraping and wiping resistance performance.
Summary of the invention
It is an object of the invention to provide a kind of Gao Guang, scratch-resistant, ABS/PVC alloy that cost is low, the product of the high gloss such as its alternative flame-proof ABS, flame-retarding HIPS, PC/ABS; The preparation method that it is a further object of the present invention to provide this ABS/PVC alloy.
In order to achieve the above object, the present invention is realized by following technical proposal:
A kind of high light scratch-resistant ABS/PVC alloy material, is made up of by its parts by weight following components:
ABS:200-400 part,
PVC:400-650 part,
PMMA:50-200 part,
Toughener: 0-50 part,
Antioxidant: 2-5 part,
Auxiliary agent: its ratio of weight and number with PVC is 2-5:100,
Heat stabilizer: its ratio of weight and number with PVC is 4-7:100,
Lubricant: its ratio of weight and number with PVC is 0.5-1:100.
The preferred version of such scheme is made up of by its parts by weight following components:
ABS:250-350 part,
PVC:500-600 part,
PMMA:100-150 part,
Toughener: 0-50 part,
Antioxidant: 2-5 part,
Auxiliary agent: its ratio of weight and number with PVC is 2-5:100,
Heat stabilizer: its ratio of weight and number with PVC is 4-7:100,
Lubricant: its ratio of weight and number with PVC is 0.5-1:100.
Wherein said ABS is the acrylonitrile-butadiene-styrene copolymer that emulsion method produces, and wherein acrylonitrile content is 25-35%, and butadiene content is 25-35%.
Described PVC is the degree of polymerization be 650-850 suspension method produce polrvinyl chloride.
Described PMMA is molecular weight is the polymethyl methacrylate of 5-30 ten thousand.
Described auxiliary agent is hud typed acrylate copolymer (ACR).
Described toughener is MBS (MBS).
Described heat stabilizer is the mixture that organic tin stabilizer forms with brucite, zinc stearate, calcium stearate, epoxy soybean oil, contains organotin 1.5-3 part, brucite 0.5-1 part, zinc stearate 0.3-0.7 part, calcium stearate 0.6-1.2 part, epoxy soybean oil 0.8-1.3 part in every 100 parts of PVC respectively.
Described lubricant is Tissuemat E or OPE.
Described antioxidant is selected from β-(3,5-di-t-butyl hydroxy phenyl) acrylic acid ten caprylate (antioxidant 1076), three-(2,4-tert-butyl-phenyl) phosphite ester (irgasfos 168), four [β-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester (antioxidant 1010), one or more in the double; two lauryl alcohol ester (antioxidant DLTDP) of thio-2 acid.
A kind of method preparing high light scratch-resistant ABS/PVC alloy material, PVC, processing aid, stabilizer, antioxidant and lubricant are added in high mixer and mixes, after mixing 5-10min at 70-90 DEG C, in high mixer, continuously add ABS, PMMA, toughener, remix 5-10min; Then the material of mix homogeneously is sent into extruding pelletization in conical double screw extruder by pay-off, material screw rod shearing, mixing and conveying under fuse fully, making product after eventually passing extrusion, tie rod, cooling, each zone temperatures of extruder is set as 140-185 DEG C.
High-light ABS provided by the present invention/PVC alloy has the advantage that
1, owing to PVC has the chemical stability of excellence, anti-flammability in the present invention, and ABS has excellent toughness, and easy coloring is processed, thus the ABS/PVC alloy of the present invention have the mechanical property of equilibrium easily process, painted, and excellent fireproof performance, and with low cost.
2, ABS/PVC alloy is modified improving its glossiness and scraping and wiping resistance performance by the present invention so that it is the finished surface of processing is bright, hardness is high and scratch-resistant, and surface gloss is higher than flame-proof ABS, flame-retarding HIPS.
3, the suitable ABS/PVC alloy of the present invention is suitable in the product casing in the fields such as the household electrical appliances requiring that highlight antiflaming, surface gloss are good, having scratch-resistant to require, automobile, machinery.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and it is only for purpose of being best understood from the object of the invention, but not limits the scope of the invention. In the embodiment of the present invention, all substances are all known commercially available prod, and its unit is weight portion.
Embodiment 1
ABS(Zhenjiang is very beautiful, PA757): 350 parts
PVC(Qilu Petrochemical, S700, degree of polymerization 650-750): 600 parts
PMMA(Zhenjiang is very beautiful, CM211): 50 parts
ACR:25 part
Organotin: 15 parts
Brucite: 5.4 parts
Zinc stearate: 3 parts
Calcium stearate: 7.2 parts
Epoxy soybean oil: 7.2 parts
OPE: 3 parts
Antioxidant 1076: 1 part
Irgasfos 168: 2 parts
By load weighted PVC, ACR, organotin, brucite, zinc stearate, calcium stearate, epoxy soybean oil, antioxidant, OPE and antioxidant 1076, add together with 168 high mixer mixes 5-10min at 80 DEG C, then proceed to add ABS and PMMA and remix 5-10min, finally by the pay-off of delicate metering, the material of mix homogeneously being sent into extruding pelletization in conical double screw extruder, each zone temperatures of extruder is set as 140-185 DEG C.Material screw rod shearing, mixing and conveying under fuse fully, make product after eventually passing extrusion, tie rod, cooling.
Embodiment 2
ABS(platform, AG12A1): 370 parts
PVC(Qilu Petrochemical, S700, degree of polymerization 650-750): 500 parts
PMMA(Zhenjiang is very beautiful, CM211): 100 parts
MBS:30 part
ACR:15 part
Organotin: 11 parts
Brucite: 4 parts
Zinc stearate: 2.5 parts
Calcium stearate: 5 parts
Epoxy soybean oil: 5 parts
Tissuemat E: 3.7 parts
Antioxidant 1076: 2 parts
Irgasfos 168: 3 parts
Load weighted PVC, ACR, heat stabilizer, antioxidant and lubricant are added high mixer mixes 5-10min at 80 DEG C, then proceed to add ABS, PMMA and MBS and remix 5-10min, then by the pay-off of delicate metering, the material of mix homogeneously being sent into extruding pelletization in conical double screw extruder, each zone temperatures of extruder is set as 140-185 DEG C. Material screw rod shearing, mixing and conveying under fuse fully, make product after eventually passing extrusion, tie rod, cooling.
Embodiment 3
ABS(Zhenjiang is very beautiful, PA757): 250 parts
PVC(Qilu Petrochemical, S700, degree of polymerization 650-750): 650 parts
PMMA(Zhenjiang is very beautiful, CM211): 50 parts
MBS:50 part
ACR:30 part
Organotin: 19.5 parts
Brucite: 6.5 parts
Zinc stearate: 3.2 parts
Calcium stearate: 7.8 parts
Epoxy soybean oil: 8.5 parts
OPE: 3.9 parts
Antioxidant 1010: 1 part
Irgasfos 168: 2 parts
Load weighted PVC, ACR, heat stabilizer, antioxidant and lubricant are added high mixer mixes 5-10min at 80 DEG C, then proceed to add ABS, PMMA and MBS and remix 5-10min, then by the pay-off of delicate metering, the material of mix homogeneously being sent into extruding pelletization in conical double screw extruder, each zone temperatures of extruder is set as 145-175 DEG C. Material screw rod shearing, mixing and conveying under fuse fully, make product after eventually passing extrusion, tie rod, cooling.
Embodiment 4
ABS(Zhenjiang is very beautiful, PA757): 200 parts
PVC(Qilu Petrochemical, S700, degree of polymerization 650-750): 550 parts
PMMA(Zhenjiang is very beautiful, CM211): 200 parts
MBS:50 part
ACR:22 part
Organotin: 13.2 parts
Brucite: 4.4 parts
Zinc stearate: 2.2 parts
Calcium stearate: 6.6 parts
Epoxy soybean oil: 6.6 parts
Tissuemat E: 5.5 parts
Antioxidant 1010: 1 part
Antioxidant DLTDP:1.5 part
Load weighted PVC, ACR, heat stabilizer, antioxidant and lubricant are added high mixer mixes 5-10min at 70 DEG C, then proceed to add ABS, PMMA and MBS and remix 5-10min, then by the pay-off of delicate metering, the material of mix homogeneously being sent into extruding pelletization in conical double screw extruder, each zone temperatures of extruder is set as 140-185 DEG C. Material screw rod shearing, mixing and conveying under fuse fully, make product after eventually passing extrusion, tie rod, cooling.
Embodiment 5
ABS(Jin Hu, 750N): 320 parts
PVC(Qilu Petrochemical, S700, degree of polymerization 650-750): 500 parts
PMMA(Zhenjiang is very beautiful, CM211): 150 parts
MBS:30 part
ACR:18 part
Organotin: 11 parts
Brucite: 3.5 parts
Zinc stearate: 1.5 parts
Calcium stearate: 5 parts
Epoxy soybean oil: 5 parts
OPE: 3 parts
Antioxidant 1010: 1 part
Antioxidant DLTDP:3 part
Load weighted PVC, ACR, heat stabilizer, antioxidant and lubricant are added high mixer mixes 5-10min at 90 DEG C, then proceed to add ABS, PMMA and MBS and remix 5-10min, then by the pay-off of delicate metering, the material of mix homogeneously being sent into extruding pelletization in conical double screw extruder, each zone temperatures of extruder is set as 140-185 DEG C.Material screw rod shearing, mixing and conveying under fuse fully, make product after eventually passing extrusion, tie rod, cooling.
Embodiment 6
ABS(Zhenjiang is very beautiful, PA757): 350 parts
Peak, PVC(upper chlorine Shen, WS800, degree of polymerization 750-850): 450 parts
PMMA(Zhenjiang is very beautiful, CM211): 150 parts
MBS:50 part
ACR:13.5 part
Organotin: 9 parts
Brucite: 2.7 parts
Zinc stearate: 1.4 parts
Calcium stearate: 2.6 parts
Epoxy soybean oil: 3.6 parts
Tissuemat E: 4 parts
Antioxidant 1010: 1.5 parts
Antioxidant DLTDP:2.5 part
Load weighted PVC, ACR, heat stabilizer, antioxidant and lubricant are added high mixer mixes 5-10min at 80 DEG C, then proceed to add ABS, PMMA and MBS and remix 5-10min, then by the pay-off of delicate metering, the material of mix homogeneously being sent into extruding pelletization in conical double screw extruder, each zone temperatures of extruder is set as 140-185 DEG C. Material screw rod shearing, mixing and conveying under fuse fully, make product after eventually passing extrusion, tie rod, cooling.
Embodiment 7
ABS(platform, AG12A1): 400 parts
Peak, PVC(upper chlorine Shen, WS800, degree of polymerization 750-850): 400 parts
PMMA(Zhenjiang is very beautiful, CM211): 170 parts
MBS:30 part
ACR:8 part
Organotin: 6 parts
Brucite: 2 parts
Zinc stearate: 1.2 parts
Calcium stearate: 2.8 parts
Epoxy soybean oil: 4 parts
Tissuemat E: 3 parts
Antioxidant 1010: 2 parts
Antioxidant DLTDP:3 part
Load weighted PVC, ACR, heat stabilizer, antioxidant and lubricant are added high mixer mixes 5-10min at 90 DEG C, then proceed to add ABS, PMMA and MBS and remix 5-10min, then by the pay-off of delicate metering, the material of mix homogeneously being sent into extruding pelletization in conical double screw extruder, each zone temperatures of extruder is set as 140-185 DEG C. Material screw rod shearing, mixing and conveying under fuse fully, make product after eventually passing extrusion, tie rod, cooling.
Embodiment 8
ABS(Jin Hu, 750N): 300 parts
Peak, PVC(upper chlorine Shen, WS800, degree of polymerization 750-850): 600 parts
PMMA(Zhenjiang is very beautiful, CM211): 80 parts
MBS:20 part
ACR:30 part
Organotin: 15 parts
Brucite: 4.8 parts
Zinc stearate: 4.2 parts
Calcium stearate: 7.2 parts
Epoxy soybean oil: 7.2 parts
Tissuemat E: 6 parts
Antioxidant 1076: 1 part
Irgasfos 168: 1.5 parts
Load weighted PVC, ACR, heat stabilizer, antioxidant and lubricant are added high mixer mixes 5-10min at 70 DEG C, then proceed to add ABS and MBS and remix 5-10min, then by the pay-off of delicate metering, the material of mix homogeneously being sent into extruding pelletization in conical double screw extruder, each zone temperatures of extruder is set as 140-185 DEG C. Material screw rod shearing, mixing and conveying under fuse fully, make product after eventually passing extrusion, tie rod, cooling.
Prior art formula composition according to ABS/PVC alloy and preparation method thereof prepares three ABS/PVC alloy contrast product, its composition component is mainly made up of ABS and PVC, other components are prepared with reference to the component provided in the present invention, its preparation method also with the preparation method of the present invention, blended, pelletize, extrusion, one-tenth product. Concrete component and content thereof are as follows:
Comparative example 1:
ABS(platform, AG12A1): 550 parts
PVC(Qilu Petrochemical, S700, degree of polymerization 650-750): 450 parts,
ACR:15 part
Organotin: 10 parts
Brucite: 3 parts
Zinc stearate: 1.5 parts
Calcium stearate: 2.5 parts
Epoxy soybean oil: 4.5 parts
Tissuemat E: 4.5 parts
Antioxidant 1076: 1 part
Irgasfos 168: 3 parts.
Comparative example 2
ABS(Jin Hu, 750N): 370 parts
PVC(Qilu Petrochemical, S700, degree of polymerization 650-750): 600 parts
MBS:30 part
ACR:20 part
Organotin: 15 parts
Brucite: 5 parts
Zinc stearate: 3 parts
Calcium stearate: 7 parts
Epoxy soybean oil: 6 parts
OPE: 3 parts
Antioxidant 1076: 1 part
Irgasfos 168: 2 parts.
Comparative example 3
ABS(platform, AG12A1): 500 parts
PVC(Qilu Petrochemical, S700, degree of polymerization 650-750): 500 parts
ACR:15 part
Organotin: 12 parts
Brucite: 4 parts
Zinc stearate: 2 parts
Calcium stearate: 8 parts
Epoxy soybean oil: 5 parts
OPE: 2.5 parts
Antioxidant 1076: 2 parts
Irgasfos 168: 3 parts.
The sample prepared in above-described embodiment 1-8 and comparative example 1-3 is injection molded into the laggard row test of standard batten according to unified technique, characterizes according to GB and test, wherein:
Simply supported beam notch impact strength is undertaken by GB GB/T1043, characterizes the toughness of material;
Anti-flammability is undertaken by GB GB/T2408, characterizes the anti-flammability of material;
Pencil hardness is undertaken by GB/T13448-2006, characterizes the resistance to scratch performance of material, and its characterization result is recorded as 6B, 5B, 4B, 3B, 2B, 1B, F, HB, 1H, 2H, 3H, 4H, 5H, 6H, and record value resistance to scratch performance about rearward is more good;
Glossiness is undertaken by ASTMD523, characterizes the surface gloss of material, and the more high expression surface gloss of record value is more high.
And their test result is contrasted, its test data are as shown in table 1 below:
Table 1 embodiment the performance test results
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Simply supported beam notch impact strength | 15 | 36 | 30 | 28 | 25 | 58 | 48 | 28 | 30 | 48 | 40 |
| Anti-flammability | V0 | V1 | V0 | V0 | V0 | V1 | HB | V0 | HB | V0 | V1 |
| Pencil hardness | 2H | 3H | 2H | 4H | 3H | 3H | 3H | 2H | 1H | 1H | 1H |
| Glossiness | 90 | 88 | 88 | 98 | 95 | 92 | 90 | 90 | 75 | 78 | 72 |
Be typically in about 70-80 by the glossiness of the known existing ABS/PVC alloy material of the result of upper table 1, pencil hardness is 1H; And add after it is modified by appropriate PMMA in the present invention, with the increase of PMMA content, the glossiness of ABS/PVC alloy is consequently increased, and is up to 98, pencil hardness is up to 4H.
Compare comparative example 1 and embodiment 6, comparative example 2 and embodiment 1 and 8, comparative example 3 and embodiment 5 again, can be seen that, when ABS, PVC ratio is close, part ABS is replaced to PMMA, the pencil hardness of material then improves 1H-2H, glossiness has brought up to more than 90, and the fire resistance of the alloy material of the present invention does not significantly reduce, illustrate that glossiness and the resistance to scratch performance of ABS/PVC alloy after adding PMMA are significantly improved, and have not significant impact its key performance such as toughness, anti-flammability.
The above-mentioned description to embodiment is to be understood that for ease of those skilled in the art and apply the present invention. These embodiments obviously easily can be made various amendment by person skilled in the art, and General Principle described herein is applied in other embodiments without through performing creative labour. Therefore, the invention is not restricted to embodiment here, those skilled in the art's announcement according to the present invention, the improvement made without departing from scope and amendment all should within protection scope of the present invention.
Claims (10)
1. one kind high smooth scratch-resistant ABS/PVC alloy, it is characterised in that: it is made up of by its weight portion following component:
ABS:200-400 part,
PVC:400-650 part,
PMMA:50-200 part,
Toughener: 0-50 part,
Antioxidant: 2-5 part,
Hud typed acrylate copolymer: its ratio of weight and number with PVC is 2-5:100,
Heat stabilizer: its ratio of weight and number with PVC is 4-7:100,
Lubricant: its ratio of weight and number with PVC is 0.5-1:100.
2. the high light scratch-resistant ABS/PVC alloy of one according to claim 1, it is characterised in that: it is made up of by its parts by weight following components:
ABS:250-350 part,
PVC:500-600 part,
PMMA:100-150 part,
Toughener: 0-50 part,
Antioxidant: 2-5 part,
Hud typed acrylate copolymer: its ratio of weight and number with PVC is 2-5:100,
Heat stabilizer: its ratio of weight and number with PVC is 4-7:100,
Lubricant: its ratio of weight and number with PVC is 0.5-1:100.
3. the high light scratch-resistant ABS/PVC alloy of one according to claim 1, it is characterised in that: described ABS is the acrylonitrile-butadiene-styrene copolymer that emulsion method produces, and wherein acrylonitrile content is 25-35%, butadiene content is 25-35%.
4. the high light scratch-resistant ABS/PVC alloy of one according to claim 1, it is characterised in that: described PVC is the degree of polymerization be 650-850 suspension method produce polrvinyl chloride.
5. the high light scratch-resistant ABS/PVC alloy of one according to claim 1, it is characterised in that: described PMMA is molecular weight is the polymethyl methacrylate of 5-30 ten thousand.
6. the high light scratch-resistant ABS/PVC alloy of one according to claim 1, it is characterised in that: described toughener is MBS.
7. the high light scratch-resistant ABS/PVC alloy of one according to claim 1, it is characterized in that: described heat stabilizer is the mixture that organic tin stabilizer forms with brucite, zinc stearate, calcium stearate, epoxy soybean oil, contains organotin 1.5-3 part, brucite 0.5-1 part, zinc stearate 0.3-0.7 part, calcium stearate 0.6-1.2 part, epoxy soybean oil 0.8-1.3 part in every 100 parts of PVC respectively.
8. the high light scratch-resistant ABS/PVC alloy of one according to claim 1, it is characterised in that: described lubricant is Tissuemat E or OPE.
9. the high light scratch-resistant ABS/PVC alloy of one according to claim 1, it is characterized in that: described antioxidant is selected from β-(3,5-di-t-butyl hydroxy phenyl) acrylic acid ten caprylate (antioxidant 1076), three-(2,4-tert-butyl-phenyl) phosphite ester (irgasfos 168), four [β-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester (antioxidant 1010), one or more in the double; two lauryl alcohol ester (antioxidant DLTDP) of thio-2 acid.
10. the method preparing a kind of high smooth scratch-resistant ABS/PVC alloy as claimed in claim 1, it is characterized in that: PVC, hud typed acrylate copolymer, heat stabilizer, antioxidant and lubricant are added in high mixer and mixes, after mixing 5-10min at 70-90 DEG C, in high mixer, continuously add ABS, PMMA, toughener, remix 5-10min; Then by pay-off, the material of mix homogeneously being sent into extruding pelletization in conical double screw extruder, each zone temperatures of extruder is set as 140-185 DEG C.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0101900B1 (en) * | 1982-08-04 | 1988-02-10 | Bayer Ag | Moulding compositions of polyvinyl chloride, abs polymerisation and polymeric lubricants with ageing stability |
| CN101475727A (en) * | 2008-11-28 | 2009-07-08 | 上海锦湖日丽塑料有限公司 | ABS/PMMA composite material |
| CN102101932A (en) * | 2010-12-01 | 2011-06-22 | 福建奥峰科技有限公司 | High-gloss, flame-retarding and heat-resistance ABS alloy and preparation method thereof |
| CN102477206A (en) * | 2010-11-29 | 2012-05-30 | 合肥杰事杰新材料股份有限公司 | Flame retardant and antistatic ABS/PVC alloy material, and preparation method thereof |
-
2012
- 2012-10-08 CN CN201210377047.0A patent/CN102875920B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0101900B1 (en) * | 1982-08-04 | 1988-02-10 | Bayer Ag | Moulding compositions of polyvinyl chloride, abs polymerisation and polymeric lubricants with ageing stability |
| CN101475727A (en) * | 2008-11-28 | 2009-07-08 | 上海锦湖日丽塑料有限公司 | ABS/PMMA composite material |
| CN102477206A (en) * | 2010-11-29 | 2012-05-30 | 合肥杰事杰新材料股份有限公司 | Flame retardant and antistatic ABS/PVC alloy material, and preparation method thereof |
| CN102101932A (en) * | 2010-12-01 | 2011-06-22 | 福建奥峰科技有限公司 | High-gloss, flame-retarding and heat-resistance ABS alloy and preparation method thereof |
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