CN1765985A - Flame-proof ABS factory formula and its production method - Google Patents
Flame-proof ABS factory formula and its production method Download PDFInfo
- Publication number
- CN1765985A CN1765985A CN 200510125571 CN200510125571A CN1765985A CN 1765985 A CN1765985 A CN 1765985A CN 200510125571 CN200510125571 CN 200510125571 CN 200510125571 A CN200510125571 A CN 200510125571A CN 1765985 A CN1765985 A CN 1765985A
- Authority
- CN
- China
- Prior art keywords
- speed mixer
- flame
- abs
- preparation
- proof abs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to product formula and preparation method of a flame-proof ABS. Wherein, the formula comprises mainly: ABS resin, antimony trioxide, decabromodiphenyl oxide, coupling-treated aluminum hydroxide, anti-oxidant 168, tricresyl phosphate, chlorinated polyethylene (CPE), polyvinyl chloride (PVC), EBS, magnesium stearate, SBS, nano-SiO2, and zinc borate. The preparation method comprises: mixing the ABS resin and tricresyl phosphate in high-speed mixer, adding other materials; putting into double screw extruder; cooling, granulating, screening, drying, and packaging. This product has well properties with low cost.
Description
Affiliated technical field
The invention belongs to chemical technology field, relate to a kind of flame-proof ABS factory formula and preparation method thereof.
Background technology
At present, the flame-proof ABS product on the market exists production cost and the equal problem of higher of product price, and in addition, it also exists, and melt flowability hangs down and the defective of poor toughness, and this situation has influenced the development and the use of flame-proof ABS product.
Summary of the invention:
The purpose of this invention is to provide production formula of the flame-proof ABS that a kind of flame retardant properties is good, melt flowability is good, toughness is high, production cost is low and preparation method thereof.
In order to achieve the above object, a kind of flame-proof ABS of the present invention is mainly by ABS resin, antimonous oxide, decabromodiphenyl oxide, aluminium hydroxide (through coupling processing), oxidation inhibitor 168, Tritolyl Phosphate, chlorinatedpolyethylene (CPE), polyvinyl chloride (PVC), ethylene bis stearic acid amide (EBS), Magnesium Stearate, thermoplastic elastomer (SBS), nano silicon (Nano-SiO
2) and zinc borate form, its proportioning (weight percent) is: ABS resin 65～80%, antimonous oxide 2～10%, decabromodiphenyl oxide 5～20%, aluminium hydroxide (through coupling processing) 1～5%, oxidation inhibitor 168 0.1～0.3%, Tritolyl Phosphate 0.2～2%, chlorinatedpolyethylene (CPE) 3～10%, polyvinyl chloride (PVC) 3～10%, ethylene bis stearic acid amide (EBS) 0.5～2%, Magnesium Stearate 0.5～2%, thermoplastic elastomer (SBS) 3～10%, Nano-SiO
20.2～3%, zinc borate 0.1～1%.
The specific embodiment of the present invention is:
ABS resin and Tritolyl Phosphate are added in the high-speed mixer, open high-speed mixer, behind the mixing 5min high-speed mixer is stopped, in mixing machine, add Nano-SiO then successively
2Zinc borate, antimonous oxide, decabromodiphenyl oxide, aluminium hydroxide (through coupling processing), oxidation inhibitor 168, chlorinatedpolyethylene (CPE), polyvinyl chloride (PVC), ethylene bis stearic acid amide (EBS), Magnesium Stearate, thermoplastic elastomer (SBS), cover tight high-speed mixer, open high-speed mixer then, will emit and send into behind mixing of materials 8～15min in the loading hopper of twin screw extruder, open twin screw extruder, controlling its rotating speed is 200～240r/min, control barrel front portion, the middle part, the temperature of rear portion and head is respectively: 180～185 ℃, 190～195 ℃, 200～205 ℃, 200～205 ℃, the material of extruding from forcing machine is through water-cooled, pelletizing, sieve, dry, be the flame-proof ABS product after the packing.
The invention has the beneficial effects as follows that this flame-proof ABS product has that flame retardant properties is good, melt flow rate (MFR) is high and the characteristics of good toughness.In addition, this production cost of products is relatively low, has the good market competitiveness.Because the melt flowability height of this material, so this material can be used for producing thin-wall product, thereby can reduce the consumption of material, reduce production costs.
Embodiment 1, with ABS resin (70%, weight percent, below identical) and Tritolyl Phosphate (0.2%) add in the high-speed mixer, open high-speed mixer, high-speed mixer is stopped after mixing 5min, in mixing machine, add Nano-SiO then successively
2(1%), zinc borate (0.1%), antimonous oxide (3%), decabromodiphenyl oxide (8%), aluminium hydroxide is (through coupling processing, 3%), oxidation inhibitor 168 (0.2%), chlorinatedpolyethylene (3%), polyvinyl chloride (7%), ethylene bis stearic acid amide (0.5%), Magnesium Stearate (0.5%), thermoplastic elastomer (SBS, 3.5%), cover tight high-speed mixer, and then start high-speed mixer, will emit and send into behind the mixing of materials 10min in the loading hopper of twin screw extruder, open twin screw extruder, the control rotating speed is 230r/min, control barrel front portion, the middle part, the temperature of rear portion and head is respectively: 180 ℃, 190 ℃, 200 ℃, 205 ℃, the material of extruding from forcing machine is through water-cooled, pelletizing, sieve, dry, be the flame-proof ABS product after the packing.
Embodiment 2, with ABS resin (65%, weight percent, below identical) and Tritolyl Phosphate (0.5%) add in the high-speed mixer, open high-speed mixer, high-speed mixer is stopped after mixing 5min, in mixing machine, add Nano-SiO then successively
2(2%), zinc borate (0.4%), antimonous oxide (5%), decabromodiphenyl oxide (10%), aluminium hydroxide is (through coupling processing, 1%), oxidation inhibitor 168 (0.1%), chlorinatedpolyethylene (5%), polyvinyl chloride (5%), ethylene bis stearic acid amide (0.5%), Magnesium Stearate (0.5%), thermoplastic elastomer (SBS, 5%), cover tight high-speed mixer, and then start high-speed mixer, will emit and send into behind the mixing of materials 10min in the loading hopper of twin screw extruder, open twin screw extruder, controlling its rotating speed is 220r/min, control barrel front portion, the middle part, the temperature of rear portion and head is respectively: 185 ℃, 195 ℃, 205 ℃, 205 ℃, the material of extruding from forcing machine is through water-cooled, pelletizing, sieve, dry, be the flame-proof ABS product after the packing.
Claims (2)
1, a kind of flame-proof ABS factory formula and preparation method thereof, the proportioning (weight percent) that it is characterized in that this prescription is: ABS resin 65～80%, antimonous oxide 2～10%, decabromodiphenyl oxide 5～20%, aluminium hydroxide (through coupling processing) 1～5%, oxidation inhibitor 168 0.1～0.3%, Tritolyl Phosphate 0.2～2%, chlorinatedpolyethylene (CPE) 3～10%, polyvinyl chloride (PVC) 3～10%, ethylene bis stearic acid amide (EBS) 0.5～2%, Magnesium Stearate 0.5～2%, thermoplastic elastomer (SBS) 3～10%, Nano-SiO
20.2～3%, zinc borate 0.1～1%.
2, a kind of flame-proof ABS factory formula according to claim 1 and preparation method thereof adds ABS resin and Tritolyl Phosphate in the high-speed mixer earlier when it is characterized in that preparing, and after mixing, adds Nano-SiO more successively in high-speed mixer
2Zinc borate, antimonous oxide, decabromodiphenyl oxide, aluminium hydroxide (through coupling processing), oxidation inhibitor 168, chlorinatedpolyethylene (CPE), polyvinyl chloride (PVC), ethylene bis stearic acid amide (EBS), Magnesium Stearate, thermoplastic elastomer (SBS), cover tight high-speed mixer, and then the unlatching high-speed mixer, will emit and send into behind mixing of materials 8～15min in the loading hopper of twin screw extruder, open twin screw extruder, controlling its rotating speed is 200～240r/min, control barrel front portion, the middle part, the temperature of rear portion and head is respectively: 180～185 ℃, 190～195 ℃, 200～205 ℃, 200～205 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101255719A CN100393801C (en) | 2005-11-18 | 2005-11-18 | Flame-proof ABS factory formula and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101255719A CN100393801C (en) | 2005-11-18 | 2005-11-18 | Flame-proof ABS factory formula and its production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1765985A true CN1765985A (en) | 2006-05-03 |
| CN100393801C CN100393801C (en) | 2008-06-11 |
Family
ID=36742109
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101255719A Expired - Fee Related CN100393801C (en) | 2005-11-18 | 2005-11-18 | Flame-proof ABS factory formula and its production method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100393801C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101698738B (en) * | 2009-11-01 | 2011-10-12 | 王崇高 | High-toughness heat-resisting ABS resin |
| CN102234407A (en) * | 2011-05-06 | 2011-11-09 | 深圳市兴迪塑胶有限公司 | Flame-retardant acrylonitrile-butadiene-styrene resin composition and preparation method thereof |
| CN102311610A (en) * | 2011-07-06 | 2012-01-11 | 惠州市昌亿科技股份有限公司 | Acrylonitrile-butadiene-styrene (ABS) composite material used for housing of intelligent water meter and preparation method thereof |
| CN102477206A (en) * | 2010-11-29 | 2012-05-30 | 合肥杰事杰新材料股份有限公司 | Flame retardant and antistatic ABS/PVC alloy material, and preparation method thereof |
| CN102675812A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of flame retardant ABS (Acrylonitrile Butadiene Styrene) |
| CN106189049A (en) * | 2016-08-04 | 2016-12-07 | 浙江畅通科技有限公司 | A kind of lead-acid accumulator flame-retardant plastic-housing material |
| CN109294155A (en) * | 2018-09-20 | 2019-02-01 | 安徽江淮汽车集团股份有限公司 | A kind of low VOC flame-proof abrasion-resistant ABS composite material and preparation method thereof |
| CN112011146A (en) * | 2019-05-29 | 2020-12-01 | 浙江钦堂钙业股份有限公司 | High-performance flame-retardant ABS/CPE composite material and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1107487A (en) * | 1994-10-31 | 1995-08-30 | 南开大学 | Sanitary and flame-retardant ABS/PVC injection moulding alloy |
| CN1128843C (en) * | 2001-10-12 | 2003-11-26 | 中国石油天然气股份有限公司 | Fire-resisting ABS special-purpose material |
-
2005
- 2005-11-18 CN CNB2005101255719A patent/CN100393801C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101698738B (en) * | 2009-11-01 | 2011-10-12 | 王崇高 | High-toughness heat-resisting ABS resin |
| CN102477206A (en) * | 2010-11-29 | 2012-05-30 | 合肥杰事杰新材料股份有限公司 | Flame retardant and antistatic ABS/PVC alloy material, and preparation method thereof |
| CN102477206B (en) * | 2010-11-29 | 2015-05-13 | 合肥杰事杰新材料股份有限公司 | Flame retardant and antistatic ABS/PVC alloy material, and preparation method thereof |
| CN102234407A (en) * | 2011-05-06 | 2011-11-09 | 深圳市兴迪塑胶有限公司 | Flame-retardant acrylonitrile-butadiene-styrene resin composition and preparation method thereof |
| CN102234407B (en) * | 2011-05-06 | 2013-03-20 | 深圳市兴盛迪新材料有限公司 | Flame-retardant acrylonitrile-butadiene-styrene resin composition and preparation method thereof |
| CN102311610A (en) * | 2011-07-06 | 2012-01-11 | 惠州市昌亿科技股份有限公司 | Acrylonitrile-butadiene-styrene (ABS) composite material used for housing of intelligent water meter and preparation method thereof |
| CN102311610B (en) * | 2011-07-06 | 2012-09-05 | 惠州市昌亿科技股份有限公司 | Acrylonitrile-butadiene-styrene (ABS) composite material used for housing of intelligent water meter and preparation method thereof |
| CN102675812A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of flame retardant ABS (Acrylonitrile Butadiene Styrene) |
| CN106189049A (en) * | 2016-08-04 | 2016-12-07 | 浙江畅通科技有限公司 | A kind of lead-acid accumulator flame-retardant plastic-housing material |
| CN109294155A (en) * | 2018-09-20 | 2019-02-01 | 安徽江淮汽车集团股份有限公司 | A kind of low VOC flame-proof abrasion-resistant ABS composite material and preparation method thereof |
| CN112011146A (en) * | 2019-05-29 | 2020-12-01 | 浙江钦堂钙业股份有限公司 | High-performance flame-retardant ABS/CPE composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100393801C (en) | 2008-06-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1765985A (en) | Flame-proof ABS factory formula and its production method | |
| CN101698738B (en) | High-toughness heat-resisting ABS resin | |
| CN100341813C (en) | Non-halogen flame-resistant sandwich materials with polyethylene for fire-proof aluminium plastic plate and production thereof | |
| CN101775179B (en) | Degradable polyvinyl chloride film and preparation method thereof | |
| CN105860424B (en) | A kind of granular phenolaldehyde moulding compound of rule and preparation method thereof | |
| CN108250566A (en) | A kind of low warpage halogen-free expanded flame-retardant Long Glass Fiber Reinforced PP Composite and preparation method thereof | |
| CN111040277A (en) | Filling master batch for inner wall of high-strength polyethylene double-wall corrugated pipe and manufacturing method thereof | |
| CN102212243B (en) | Environment friendly thermoplastic elastomer used as fire-retardant sealing strip and preparation method thereof | |
| CN101003634A (en) | Method for manufacturing agglomerate of decabromodiphenyl ethane and antimony trioxide | |
| CN105419064A (en) | Laminated composite metal hydroxide and multifunctional master batch preparation method thereof | |
| CN103819865B (en) | Environmentally friendly flame-retardant modified HIPS casing of liquid crystal television set and preparation method thereof | |
| CN102604228A (en) | Multi-functional plastic masterbatch and preparation method thereof | |
| CN105419046A (en) | Whitening masterbatch of reclaimed materials for plastic woven bags and preparation method thereof | |
| CN101445642A (en) | Reinforcing and toughening auxiliary agent composite for flexible freight bag and preparation method thereof | |
| CN113930030B (en) | Warm frame section bar for shutter and manufacturing method thereof | |
| CN102532744A (en) | Polyvinyl chloride (PVC)/6000-mesh ground limestone antistatic cable hook special material and preparing technology thereof | |
| CN108250678A (en) | A kind of environment-friendly PVC section bar organic tin stabilizer | |
| CN109096777A (en) | A kind of Masterbatch and production method | |
| CN106280125A (en) | A kind of outdoor fluorescent wood-plastic floor and preparation method thereof | |
| CN100592979C (en) | Polyolefin complete transparent master batch and preparation thereof | |
| CN105440621B (en) | PLA noctilucence master batch and preparation method thereof | |
| CN104403342A (en) | High-strength wood-plastic composite with swelling resistance, moisture resistance and ageing resistance and preparation method of wood-plastic composite | |
| CN103102609A (en) | Mining high-impact flame-retardant special material for polyvinyl chloride (PVC)/6000-mesh superfine coarse whiting ore | |
| CN109400799A (en) | It is a kind of can reinforced plastics intensity and weatherability modifying plastics technique | |
| CN109265822A (en) | Without white point thermoplastic flame-proof process for producing composite material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: TAIZHOU SPRING BRIGHT PLASTICS TECHNOLOGY CO., LTD. Assignor: Wang Chonggao Contract fulfillment period: 2009.9.18 to 2014.9.17 contract change Contract record no.: 2009320001694 Denomination of invention: Flame-proof ABS factory formula and its production method Granted publication date: 20080611 License type: Exclusive license Record date: 20091022 |
|
| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.9.18 TO 2014.9.17; CHANGE OF CONTRACT Name of requester: TAIZHOU YANYANGTIAN PLASTICS TECHNOLOGY CO., LTD. Effective date: 20091022 |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080611 Termination date: 20101118 |