CN1128843C - Flame-retardant ABS special material - Google Patents
Flame-retardant ABS special material Download PDFInfo
- Publication number
- CN1128843C CN1128843C CN 01136257 CN01136257A CN1128843C CN 1128843 C CN1128843 C CN 1128843C CN 01136257 CN01136257 CN 01136257 CN 01136257 A CN01136257 A CN 01136257A CN 1128843 C CN1128843 C CN 1128843C
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- CN
- China
- Prior art keywords
- flame
- parts
- abs
- retardant
- fire
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 41
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 239000000463 material Substances 0.000 title claims abstract description 16
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 20
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 9
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 9
- 239000000314 lubricant Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims description 7
- 238000005453 pelletization Methods 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 5
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 claims description 4
- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004135 Bone phosphate Substances 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- AQPHBYQUCKHJLT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4,5,6-pentabromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=C(Br)C(Br)=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br AQPHBYQUCKHJLT-UHFFFAOYSA-N 0.000 claims description 2
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 8
- 239000004709 Chlorinated polyethylene Substances 0.000 abstract description 4
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003607 modifier Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
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Abstract
A flame-retardant ABS special material for household appliances, automobile parts and the like is prepared by adding polyvinyl chloride, decabromodiphenyl ether, antimony trioxide, modifier chlorinated polyethylene, stabilizer, lubricant and the like into a high-speed mixer to obtain a flame-retardant master batch for standby, mixing ABS and the flame-retardant master batch and the like in the high-speed mixer at a high speed for 5-10 minutes at room temperature, taking out the mixture, transferring the mixture into a screw extruder, and extruding and granulating the mixture at 160-190 ℃. Therefore, the process is short, the product cost is low, and the comprehensive performance of the product is excellent.
Description
Affiliated field: the present invention is a kind of fire-resisting ABS special-purpose material that is used for aspects such as household electrical appliance and automobile component.
Background technology: the present invention is cooperated with the flame-retardant master batch of different ratios by universal ABS to form.Its technical process is as shown in Figure 1:
The flame-retardant master batch principal constituent is: components such as polyvinyl chloride, decabromodiphenyl oxide, tetrabromo-bisphenol, antimonous oxide, chlorinatedpolyethylene.
Stablizer in the flame-retardant master batch is general lead sulfate tribasic and dibasic lead phosphite
China Song of Nankai University such as works at the people, and to develop a kind of be main raw material by ABS and polyvinyl chloride resin, add the ABS/PVC injection alloy (CN-1120563A) that stablizer, properties-correcting agent, fire retardant, lubricant and pigment are made, this product excellent combination property, but the thermotolerance of this product is relatively poor, heat-drawn wire 75-80 ℃, be subjected to certain restriction in application facet.
U.S. scientific research personnel develops a kind of fire resistance thermoplastic constituent (CN-1034936) of shock-resistance.The flame retardant properties of this product reaches the requirement of UL-94V-0 level.But this product has increased certain degree of difficulty owing to need to add itrile group rubber to processing, has also increased cost simultaneously.
The fire-resisting ABS special-purpose material that the present invention developed, thermotolerance is better, heat-drawn wire 80-90 ℃, and heat resisting temperature can improve by the demand of product, and the technical process of this product is short, and product cost is lower, flame retardant properties reaches UL-94V-0 level index, and over-all properties is more excellent.
Summary of the invention
The purpose of this invention is to provide a kind of flame retardant resistance ABS PP Pipe Compound that is used for household appliances shell and auto-parts.The technical process of this product is short, and product price is cheap, and flame retardant properties reaches UL-94V-0 level index, and resistance toheat is better, excellent combination property.
Group of products of the present invention becomes: universal ABS 50-70 part, flame-retardant master batch 30-50 part (containing polyvinyl chloride 30-40 part, lubricant 0.3-1.0 part, heat resistance accessory 1.5-5 part, stablizer 0.5-2.5 part, pigment 0.25-1.5 part).
Production craft step is:
At first prepare flame-retardant master batch: polyvinyl chloride (70～90), decabromodiphenyl oxide (2～8) or tetrabromo-bisphenol (2～8), antimonous oxide (2～5), properties-correcting agent chlorinatedpolyethylene (3～9), stablizer (2～5), lubricant (1～3) etc. are joined in the high-speed mixer, carried out high-speed mixing 5～10 minutes, change in the screw extrusion press, extrude under 155～175 ℃ of temperature and granulation, it is stand-by to obtain flame-retardant master batch.Then with ABS (50～70) and flame-retardant master batch (30～50) etc. in high-speed mixer, high-speed mixing is 5～10 minutes under the room temperature, changes over to after the taking-up in the screw extrusion press, extruding pelletization under 160～190 ℃ of temperature can obtain the fire-retardant PP Pipe Compound of ABS.
The product that the present invention developed why thermotolerance and flame retardant resistance is more excellent, is because added heat resistance accessory and the more stable flame-retardant master batch of performance in blend composition.Only need high-speed mixer and screw extrusion press in the technical process of the present invention, need not add miscellaneous equipment.So technical process is short, product cost is low, but The comprehensive performance is more excellent.
The outstanding characteristics of the present invention are: technical process is short, and the good heat resistance of product can improve the thermotolerance of products according to the different purposes of product, and flame retardant properties can reach UL-94V-0 level index.
Description of drawings
Fig. 1, Fig. 2 are process flow sheet of the present invention.
Concrete enforcement
According to the proportioning shown in the table 1 fire retardant, stablizer are joined in the high-speed mixer, at room temperature mixed 10 minutes, extruding pelletization is made flame-retardant master batch then.An amount of then flame-retardant master batch and universal ABS carry out blend, and extruding pelletization makes fire-resisting ABS special-purpose material.
Table 1 embodiment 1 fire-resisting ABS special-purpose material products material proportioning
The fire-resisting ABS special-purpose material main performance index that present embodiment obtains is as follows: tensile strength (MPA) 42.1-47.6 (GB1040-79) melting index (220 ℃, 10KG) (g/10min) 8.1-11.948 (GB3682-83) notched Izod impact strength (23 ℃) (J/m) 190-273 (GB1043-79) heat-drawn wire (℃) 86-96 (GB1634-79) flame retardant properties UL-94 V-O level
| Fire-resisting ABS special-purpose material I II III IV | |
| Universal ABS 100 100 100 100 | |
| Flame-retardant master batch | PVC 40 30 50 40 |
| Decabromodiphenyl oxide 55 | |
| Tetrabromo-bisphenol 54 | |
| Antimonous oxide 2221 | |
| Chlorinatedpolyethylene 558 10 | |
| Tribasic sulfuric acid 2232 | |
| Dibasic lead phosphite 1121 | |
| Stearic acid 1111 | |
Embodiment 2: the fire-resisting ABS special-purpose material that makes is applied in the housing of TV set, its prescription is as follows: universal ABS100 part (weight part), the prescription of flame-retardant master batch is: 40 parts of polyvinyl chloride, 5 parts of decabromodiphenyl oxides, 2 parts of antimonous oxides, 2 parts of chlorinatedpolyethylenees, 2 parts of lead sulfate tribasics, 1 part of dibasic lead phosphite, 1 part of stearic acid.At first, carry out extruding pelletization then, make flame-retardant master batch carrying out the room temperature high-speed mixing in fire retardant in the above-mentioned flame-retardant master batch and the stablizer input high-speed mixer.Carry out blend with universal ABS and an amount of flame-retardant master batch, carry out extruding pelletization again, obtain flame retardant type ABS PP Pipe Compound, the salient features of this PP Pipe Compound is as follows: flame retardant resistance UL-94 V-O level heat-drawn wire (℃) (J/m) (220 ℃ of 267 melting index of 90 notched Izod impact strength (23 ℃), 10KG) (g/10min) 10.56 proportions 1.17 are used to make housing of TV set with above-mentioned fire-resisting ABS special-purpose material, and its performance index meet the requirements fully.
Implement reference example:
Flame retardant extruded level ABS PP Pipe Compound, its prescription is: universal ABS100 part, 46 parts of flame-retardant master batchs, 9 parts of lubricants, through drying treatment, extruding pelletization after the blend can make flame retardant extruded level ABS PP Pipe Compound, and this material can be made the goods that household appliances shell, automotive interior spare etc. have fire-retardant requirement.
Claims (3)
1. fire-resisting ABS special-purpose material, it is to be cooperated with flame-retardant master batch by general ABS raw material to form, it is characterized in that: flame-retardant master batch is joined in the high-speed mixer by 70～90 parts of polyvinyl chloride, 2～8 parts of decabromodiphenyl oxides or tetrabromo-bisphenol, 2～5 parts of antimonous oxides, 3～9 parts of properties-correcting agent chlorinatedpolyethylenees, 2～5 parts of stablizers, 1～3 part of lubricant, carried out high-speed mixing 5～10 minutes, change in the screw extrusion press, extrude under 155～175 ℃ of temperature and granulation, it is stand-by to obtain flame-retardant master batch.Then 50～70 parts of general ABS raw materials and above-mentioned 30～50 parts of flame-retardant master batchs that make are joined in the high-speed mixer, high-speed mixing is 5～10 minutes under the room temperature, change over to after the taking-up in the screw extrusion press, extruding pelletization under 160～190 ℃ of temperature promptly obtains the fire-retardant PP Pipe Compound of ABS.
2. fire-resisting ABS special-purpose material according to claim 1 is characterized in that: the stablizer that is adopted is lead sulfate tribasic and/or dibasic lead phosphite.
3. fire-resisting ABS special-purpose material according to claim 1, it is characterized in that: the lubricant that is adopted is a stearic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01136257 CN1128843C (en) | 2001-10-12 | 2001-10-12 | Flame-retardant ABS special material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01136257 CN1128843C (en) | 2001-10-12 | 2001-10-12 | Flame-retardant ABS special material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1412238A CN1412238A (en) | 2003-04-23 |
| CN1128843C true CN1128843C (en) | 2003-11-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01136257 Expired - Fee Related CN1128843C (en) | 2001-10-12 | 2001-10-12 | Flame-retardant ABS special material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1128843C (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100393801C (en) * | 2005-11-18 | 2008-06-11 | 王崇高 | Flame-proof ABS factory formula and its production method |
| KR100787772B1 (en) * | 2005-12-19 | 2007-12-24 | 주식회사 엘지화학 | Flame-retardant resin composition having good on |
| CN100467530C (en) * | 2007-04-20 | 2009-03-11 | 浙江工业大学 | Special-purpose material for environmental protection flame-proof ABS and preparing method thereof |
| CN101220194B (en) * | 2007-10-15 | 2011-03-02 | 张发饶 | Production method for environment-protection flame-proof ABS system master batch |
| KR101100453B1 (en) * | 2008-09-18 | 2011-12-29 | 주식회사 엘지화학 | Thermoplastic Resin Composition Having Superior Flame Retardany, Coloring Property And Scratch-resistance |
| CN101891952B (en) * | 2010-06-03 | 2012-07-11 | 佛山市顺德区高怡新塑料有限公司 | Precipitate-free flame retardant masterbatch |
| CN101948605A (en) * | 2010-09-29 | 2011-01-19 | 深圳市科聚新材料有限公司 | Flame retardant ABS master batch and preparation method thereof |
| CN101982496A (en) * | 2010-10-20 | 2011-03-02 | 深圳市科聚新材料有限公司 | Flame retardant masterbatch modified ABS resin and ABS flame retardant masterbatch and preparation methods thereof |
| CN105820497A (en) * | 2016-05-20 | 2016-08-03 | 海宁市鲲鹏塑业有限公司 | Production method of mixed material for ABS modified plastic cover plate with high pressure resistance |
| CN106752054A (en) * | 2016-12-26 | 2017-05-31 | 凤阳嘉禾农业科技有限公司 | A kind of manufacture method of flame retardant plastic products |
-
2001
- 2001-10-12 CN CN 01136257 patent/CN1128843C/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN1412238A (en) | 2003-04-23 |
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Granted publication date: 20031126 Termination date: 20201012 |