CN106280125A - A kind of outdoor fluorescent wood-plastic floor and preparation method thereof - Google Patents
A kind of outdoor fluorescent wood-plastic floor and preparation method thereof Download PDFInfo
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- CN106280125A CN106280125A CN201610748458.4A CN201610748458A CN106280125A CN 106280125 A CN106280125 A CN 106280125A CN 201610748458 A CN201610748458 A CN 201610748458A CN 106280125 A CN106280125 A CN 106280125A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/02177—Floor elements for use at a specific location
- E04F15/02183—Floor elements for use at a specific location for outdoor use, e.g. in decks, patios, terraces, verandas or the like
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
- E04F15/102—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials of fibrous or chipped materials, e.g. bonded with synthetic resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Mechanical Engineering (AREA)
- Floor Finish (AREA)
Abstract
The present invention relates to a kind of outdoor fluorescent wood-plastic floor, add luminous pigment in Wood-plastic floor raw material, described luminous pigment is the fluorescent material using organically-modified process, after mixing, after fusion plastification equipment, shape through mouth die, obtain the fluorescent wood-plastic floor of Integral luminous；Or use the fluorescent material of organically-modified process as luminous pigment, mix with Wood-plastic floor co-extrusion material, add the side extruder hopper of co-extrusion extruder, it is fixed to top layer co-extrusion Wood-plastic floor with after the raw material co-extrusion of main extruder Wood-plastic floor through die extrusion, obtains the fluorescent wood-plastic floor that top layer is luminous.The invention also discloses preparation method.Method disclosed by the invention can prepare uniform color, good endurance, and has the fluorescent wood-plastic goods of good luminous performance, plays low light level instruction and the effect of decoration.
Description
Technical field
The present invention relates to a kind of Wood-plastic floor and preparation method thereof, be specifically related to a kind of outdoor fluorescent wood-plastic floor and system thereof
Preparation Method, belongs to wood plastic composite technical field.
Background technology
Fluorescent material gets more and more owing to it has feature application in people live "dead", energy-saving and environmental protection, mesh
The major domain of its industrial applications front is plastics and paint field, is also rarely reported in wood plastic composite field.China is specially
Profit (CN 201410309580) has obtained luminescence after pelletize being blended with light accumulation type luminous pigment, PA6, oxidant, ultraviolet (UV) resistant agent
Master batch, luminous master batch can be separately added into top layer or the bottom of Wood-plastic material, final prepared light accumulation type luminescence Wood-plastic material.But should
In method preparation process, can there is inconsistent problem when being blended in luminous pigment and organic system as inorganic material, prepared
Along with increasing of luminescent powder addition, mechanical property drastically declines in plastic products luminous meeting.Meanwhile, plastified in mixing
In journey luminous pigment and process equipment interior metal device contact and friction can cause luminous pigment blackening, and then have a strong impact on
The luminescent properties of wood plastic product and glossiness.
Summary of the invention
It is an object of the invention to according to fluorescent material present in prior art and organic system poor compatibility, luminous material
The shortcoming of easily blackening in the material course of processing, a kind of fluorescent wood-plastic floor of invention and preparation method thereof, the method can prepare color
Pool is uniform, and has the fluorescent wood-plastic floor of good luminous performance and mechanical property, plays low light level instruction and the effect of decoration
Really.
The technical scheme is that
A kind of outdoor fluorescent wood-plastic floor, it is characterised in that: Wood-plastic floor raw material adds luminous pigment, described luminescence
Pigment is the outdoor fluorescent material using organically-modified process, after mixing, after fusion plastification equipment, shapes through mouth die, obtains
The outdoor fluorescent wood-plastic floor of Integral luminous；Or use the outdoor fluorescent material of organically-modified process as luminous pigment, with wood
Mould floor co-extrusion material mixing, add the side extruder hopper of co-extrusion extruder, after the raw material co-extrusion of main extruder Wood-plastic floor
It is top layer co-extrusion Wood-plastic floor through mouth die extrusioning shaping, obtains the fluorescent wood-plastic floor that top layer is luminous.
Described luminous pigment is more than aluminates system, silicate systems, phosphate system, oxysulfide system or rare earth length
One or more in brightness fluorescent material.
Described organically-modified processing method refers to utilize various modified additive, uses method physically or chemically to being changed
Property thing carry out processing described physical method and include but not limited to: use modified additive to the thing that is modified by hydrogen bond action or quiet
Electro ultrafiltration implements physics cladding, thus changes surface and the interface physico-chemical property of the thing that is modified；Described chemical method include but
It is not limited to: use with the modified additive of the functional group of the thing generation chemical reaction that is modified, the thing that is modified being passed through chemical bond
The mode closed implements chemical modification, thus changes surface and the interface physico-chemical property of the thing that is modified.
The preparation method on a kind of outdoor fluorescent wood-plastic floor, uses the fluorescent material of organically-modified process as luminous face
Material, adds in wood plastic composite raw material, after mixing, after fusion plastification equipment, shapes through mouth die, obtains the glimmering of Integral luminous
Light Wood-plastic floor；Or use the fluorescent material of organically-modified process as luminous pigment, mix with Wood-plastic floor co-extrusion material, add
It is fixed to top layer altogether through die extrusion after the side extruder hopper of co-extrusion extruder, with the raw material co-extrusion of main extruder Wood-plastic floor
Squeeze Wood-plastic floor, obtain the fluorescent wood-plastic floor that top layer is luminous.
Preferably, described luminous pigment be aluminates system, silicate systems, phosphate system, oxysulfide system or
One or more in long afterglow fluorescent material.
Described organically-modified processing method refers to utilize various modified additive, uses method physically or chemically to being changed
Property thing process, described physical method includes but not limited to: use modified additive to the thing that is modified by hydrogen bond action or
Electrostatic interaction implements physics cladding, thus changes surface and the interface physico-chemical property of the thing that is modified；Described chemical method includes
But it is not limited to: use with the modified additive of the functional group of the thing generation chemical reaction that is modified, the thing that is modified being passed through chemistry
The mode of bonding implements chemical modification, thus changes surface and the interface physico-chemical property of the thing that is modified.
Preferably, described organically-modified processing method is: takes alcohols solvent and adds in reactor, is added by fluorescent material,
Stirring, adds chemical bonding or chelating class coupling agent, is progressively heated up to 70～90 DEG C, glimmering by handle well after stirring certain time
Luminescent material is taken out, and is dried and removes solvent, grinds, obtains the fluorescent material of organically-modified process.
Preferably, described coupling agent is: silane coupler and/or titanate coupling agent and/or zirconium class coupling agent,
And/or stannum class coupling agent.
Preferably, described fusion plastification equipment includes but not limited to mill, banbury, twin screw, Single screw extrusion
Machine；The temperature of described fusion plastification is 170 210 DEG C.
Preferably, described raw material is: polyvinyl chloride resin, calcium powder, wood powder, stabilizer, compatilizer, foaming agent, lubricant；Or
PE resin, Pulvis Talci, wood powder, compatilizer, lubricant, UV absorbent；Or PP resin, Pulvis Talci, wood powder, compatilizer, profit
Lubrication prescription, UV absorbent；Or PE resin, Pulvis Talci, wood powder, compatilizer, lubricant, UV absorbent；Or polyvinyl chloride resin,
Pulvis Talci, wood powder, compatilizer, lubricant.
Beneficial effects of the present invention:
It is processed that the present invention solves fluorescent material and organic system poor compatibility present in prior art, luminescent material
The shortcoming of easy blackening in journey, a kind of fluorescent wood-plastic floor of invention and preparation method thereof, the method can prepare uniform color, and
There is the fluorescent wood-plastic floor of good luminous performance and mechanical property, play low light level instruction and the effect of decoration
Organically-modified luminous pigment used in the present invention has good surface hydrophobicity effect, not only increases inorganic
The compatibility between light powder body and Wood-plastic material, makes material maintain preferable mechanical property；And can be processed at Wood-plastic material
Journey intercepts the direct friction between luminescent powder and metal, and then the problem being prevented effectively from luminescent powder blackening.
The preparation method technique of luminous Wood-plastic floor of the present invention is simple, fundamentally solves luminous pigment and moulds with wood
Problem incompatible between material and the problem of luminescent powder blackening, expanded category and the application of fluorescent material,
Have broad application prospects.
Luminous pigment after organically-modified process, can improve itself and wood while keeping luminescent material luminescent properties
Mould the compatibility of matrix material so that Wood-plastic material mechanical property will not decline to a great extent because of the addition of luminescent material, simultaneously
In mixing plasticizing process through the luminous pigment of organically-modified process due to the existence of organic treating agents modified layer, it is to avoid send out
Contacting and friction and the drawback of luminous pigment blackening that causes of delustering pigment body and process equipment interior metal device.
Detailed description of the invention
The present invention can be expressly understood further by the specific embodiment of invention now given below, but following enforcement
Example is not limitation of the invention.Following example are merely to illustrate technical scheme and unrestricted, this area
It will be appreciated by the skilled person that technical scheme can be modified or equivalent, without deviating from skill of the present invention
The objective of art scheme and scope, it all should be contained in the middle of scope of the presently claimed invention.
Embodiment 1: the preparation on a kind of outdoor fluorescent wood-plastic floor
Raw materials used and weight is:
Polyvinyl chloride resin 100kg
Calcium powder 50kg
Wood powder 20kg
Stabilizer 4kg
Compatilizer 8kg
Foaming agent 3kg
Lubricant 3kg
Organically-modified type strontium aluminate fluorescent material 2kg；
After the raw material such as wood powder, PVC resin powder is tentatively mixed with organically-modified strontium aluminate fluorescent material, add twin screw and squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, afterwards through mouth die extrusioning shaping be Wood-plastic floor.Obtain body colour equal
One, in yellowish green fluorescent wood-plastic floor, its hot strength is good, and smooth surface, illumination effect is good.
Embodiment 2: the preparation on a kind of outdoor fluorescent wood-plastic floor
Raw materials used and percentage by weight is:
PE resin 100kg
Pulvis Talci 20kg
Wood powder 80kg
Compatilizer 7kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type strontium carbonate fluorescent material 2kg；
After the raw materials such as wood powder, PE resin-oatmeal are tentatively mixed with organically-modified strontium carbonate fluorescent material, add twin screw and squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, afterwards through mouth die extrusioning shaping be Wood-plastic floor.Obtain body colour equal
One, greeny fluorescent wood-plastic floor, its hot strength is good, and smooth surface, illumination effect is good.
Embodiment 3: a kind of outdoor fluorescent wood-plastic floor
PP resin 100kg
Pulvis Talci 10kg
Wood powder 60kg
Compatilizer 8kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type zinc silicate fluorescent material 1.5kg；
After the raw materials such as wood powder, PP resin-oatmeal are tentatively mixed with organically-modified silicic acid zinc fluorescent material, add twin screw and squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, afterwards through mouth die extrusioning shaping be Wood-plastic floor.Obtain body colour equal
One, in yellowish green fluorescent wood-plastic floor, its hot strength is good, and smooth surface, illumination effect is good.
Embodiment 4: the preparation on a kind of outdoor fluorescent wood-plastic floor
Polyvinyl chloride resin 100kg
Pulvis Talci 10kg
Wood powder 50kg
Compatilizer 8kg
Lubricant 3kg
Organically-modified type zinc-cadmium sulfide fluorescent material 1.5kg；
After tentatively being mixed with organically-modified zinc-cadmium sulfide fluorescent material by the raw material such as wood powder, PVC resin powder, add twin screw
In extruder hopper, control screw rod to head temperature at 190 DEG C, afterwards through mouth die extrusioning shaping be Wood-plastic floor.Obtain body colour
Homogeneous, in yellowish green fluorescent wood-plastic floor, its hot strength is good, and smooth surface, illumination effect is good.
Embodiment 5: a kind of outdoor fluorescent wood-plastic floor
PE resin 100kg
Pulvis Talci 10kg
Wood powder 50kg
Compatilizer 8kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type calcium halophosphate activated by antimony andmanganese fluorescent material 1.5kg；
After tentatively being mixed with organically-modified calcium halophosphate activated by antimony andmanganese fluorescent material by the raw material such as wood powder, PVC resin powder, add twin screw
In extruder hopper, control screw rod to head temperature at 190 DEG C, afterwards through mouth die extrusioning shaping be Wood-plastic floor.Obtain body colour
Homogeneous, in saffron fluorescent wood-plastic floor, its hot strength is good, and smooth surface, illumination effect is good.
Embodiment 6: the preparation on a kind of outdoor fluorescent wood-plastic floor
Raw materials used and percentage by weight is:
Polyvinyl chloride resin 100kg
Calcium powder 50kg
Wood powder 20kg
Stabilizer 4kg
Compatilizer 8kg
Foaming agent 3kg
Lubricant 3kg
Organically-modified type strontium aluminate fluorescent material 2kg；
Organically-modified process is: takes anhydrous ethanol solvent and adds in reactor, is added by strontium aluminate fluorescent material, stirring
0.5h, adds chemical bonding coupling agent, is progressively heated up to 70～90 DEG C, stirs 2h, after the fluorescent material that handle well is taken out, dry
Dry removing solvent, grinds, obtains the fluorescent material of organically-modified process；
After the raw material such as wood powder, PVC resin powder is tentatively mixed with organically-modified strontium aluminate fluorescent material, add twin screw and squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, afterwards through mouth die extrusioning shaping be Wood-plastic floor.Obtain body colour equal
One, in yellowish green fluorescent wood-plastic floor, its hot strength is good, and smooth surface, illumination effect is good.
Embodiment 7: the preparation on a kind of outdoor fluorescent wood-plastic floor:
PE resin 100kg
Pulvis Talci 20kg
Wood powder 80kg
Compatilizer 7kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type strontium carbonate fluorescent material 2kg；
Organically-modified process is: takes absolute methanol solvent and adds in reactor, is added by strontium carbonate fluorescent material, stirring
0.5h, adds chelating class coupling agent, is progressively heated up to 70～90 DEG C, is taken out by the fluorescent material handled well, be dried after stirring 1h
Remove solvent, grind, obtain the fluorescent material of organically-modified process；
After the raw materials such as wood powder, PE resin-oatmeal are tentatively mixed with organically-modified strontium carbonate fluorescent material, add twin screw and squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, afterwards through mouth die extrusioning shaping be Wood-plastic floor.Obtain body colour equal
One, greeny fluorescent wood-plastic floor, its hot strength is good, and smooth surface, illumination effect is good.
Embodiment 8: a kind of outdoor fluorescent wood-plastic floor
PP resin 100kg
Pulvis Talci 10kg
Wood powder 60kg
Compatilizer 8kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type zinc silicate fluorescent material 1.5kg；
Organically-modified process is: takes anhydrous propanol solvent and adds in reactor, is added by zinc silicate fluorescent material, stirring
0.5h, adds silane coupler, is progressively heated up to 70～90 DEG C, is taken out by the fluorescent material handled well, be dried and remove after stirring 3h
Remove solvent, grind, obtain the fluorescent material of organically-modified process；
After the raw materials such as wood powder, PP resin-oatmeal are tentatively mixed with organically-modified silicic acid zinc fluorescent material, add twin screw and squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, afterwards through mouth die extrusioning shaping be Wood-plastic floor.Obtain body colour equal
One, in yellowish green fluorescent wood-plastic floor, its hot strength is good, and smooth surface, illumination effect is good.
Embodiment 9: a kind of outdoor fluorescent wood-plastic floor
Polyvinyl chloride resin 100kg
Pulvis Talci 10kg
Wood powder 50kg
Compatilizer 8kg
Lubricant 3kg
Organically-modified type zinc-cadmium sulfide fluorescent material 1.5kg
Organically-modified process is: takes anhydrous isopropyl alcohol solvent and adds in reactor, is added by zinc-cadmium sulfide fluorescent material, stirring
0.5h, adds titanate coupling agent, is progressively heated up to 70～90 DEG C, is taken out by the fluorescent material handled well, be dried after stirring 3h
Remove solvent, grind, obtain the fluorescent material of organically-modified process；
After tentatively being mixed with organically-modified zinc-cadmium sulfide fluorescent material by the raw material such as wood powder, PVC resin powder, add twin screw
In extruder hopper, control screw rod to head temperature at 190 DEG C, afterwards through mouth die extrusioning shaping be Wood-plastic floor.Obtain body colour
Homogeneous, in yellowish green fluorescent wood-plastic floor, its hot strength is good, and smooth surface, illumination effect is good.
Embodiment 10: a kind of outdoor fluorescent wood-plastic floor
PE resin 100kg
Pulvis Talci 10kg
Wood powder 50kg
Compatilizer 8kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type calcium halophosphate activated by antimony andmanganese fluorescent material 1.5kg
Organically-modified process is: takes anhydrous isopropyl alcohol solvent and adds in reactor, is added by halogen calcium phosphate fluoressent powder, stirring
0.5h, adds titanate coupling agent, is progressively heated up to 70～90 DEG C, is taken out by the fluorescent material handled well, be dried after stirring 3h
Remove solvent, grind, obtain the fluorescent material of organically-modified process；
After tentatively being mixed with organically-modified calcium halophosphate activated by antimony andmanganese fluorescent material by the raw material such as wood powder, PVC resin powder, add twin screw
In extruder hopper, control screw rod to head temperature at 190 DEG C, afterwards through mouth die extrusioning shaping be Wood-plastic floor.Obtain body colour
Homogeneous, in saffron fluorescent wood-plastic floor, its hot strength is good, and smooth surface, illumination effect is good.
Embodiment 11:
A kind of preparation on fluorescent wood-plastic floor, raw materials used and weight is:
Polyvinyl chloride resin 100kg
Calcium powder 50kg
Wood powder 20kg
Stabilizer 4kg
Compatilizer 8kg
Foaming agent 3kg
Lubricant 3kg
Organically-modified type strontium aluminate fluorescent material 2kg
After tentatively being mixed with organically-modified strontium aluminate fluorescent material by the raw material such as wood powder, PVC resin powder, add co-extrusion extrusion
The side extruder hopper of machine, controls screw rod to head temperature at 190 DEG C, shapes through die extrusion after main extruder material co-extrusion
For top layer co-extrusion Wood-plastic floor.Obtain top layer uniformly, containing the Wood-plastic floor in yellow green luminescent material, its hot strength is good
Good, smooth surface, illumination effect is good.
Embodiment 12:
A kind of preparation on outdoor fluorescent wood-plastic floor, raw materials used and weight is:
PE resin 100kg
Pulvis Talci 20kg
Wood powder 80kg
Compatilizer 7kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type strontium carbonate fluorescent material 2kg
After tentatively being mixed with organically-modified strontium carbonate fluorescent material by the raw materials such as wood powder, PE resin-oatmeal, add co-extrusion extrusion
The side extruder hopper of machine, controls screw rod to head temperature at 190 DEG C, shapes through die extrusion after main extruder material co-extrusion
For top layer co-extrusion Wood-plastic floor.Obtain top layer uniformly, containing the Wood-plastic floor in green luminescent material, its hot strength is good,
Smooth surface, illumination effect is good.
Embodiment 13:
A kind of preparation on outdoor fluorescent wood-plastic floor, raw materials used and weight is:
PP resin 100kg
Pulvis Talci 10kg
Wood powder 60kg
Compatilizer 8kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type zinc silicate fluorescent material 1.5kg
Organically-modified process is: takes anhydrous propanol solvent and adds in reactor, is added by zinc silicate fluorescent material, stirring
0.5h, adds silane coupler, is progressively heated up to 70～90 DEG C, is taken out by the fluorescent material handled well, be dried and remove after stirring 3h
Remove solvent, grind, obtain the fluorescent material of organically-modified process；
After tentatively being mixed with organically-modified silicic acid zinc fluorescent material by the raw materials such as wood powder, PP resin-oatmeal, add co-extrusion extrusion
The side extruder hopper of machine, controls screw rod to head temperature at 190 DEG C, shapes through die extrusion after main extruder material co-extrusion
For top layer co-extrusion Wood-plastic floor.Obtain top layer uniformly, containing the Wood-plastic floor in yellow green luminescent material, its hot strength is good
Good, smooth surface, illumination effect is good.
Embodiment 14:
A kind of preparation on fluorescent wood-plastic floor, raw materials used and weight is:
Polyvinyl chloride resin 100kg
Pulvis Talci 10kg
Wood powder 50kg
Compatilizer 8kg
Lubricant 3kg
Organically-modified type zinc-cadmium sulfide fluorescent material 1.5kg
Organically-modified process is: takes anhydrous propanol solvent and adds in reactor, is added by zinc silicate fluorescent material, stirring
0.5h, adds silane coupler, is progressively heated up to 70～90 DEG C, is taken out by the fluorescent material handled well, be dried and remove after stirring 3h
Remove solvent, grind, obtain the fluorescent material of organically-modified process；
After the raw material such as wood powder, PVC resin powder is tentatively mixed with organically-modified zinc-cadmium sulfide fluorescent material, add co-extrusion and squeeze
Go out the side extruder hopper of machine, control screw rod to head temperature at 190 DEG C, determine through die extrusion after main extruder material co-extrusion
Type is top layer co-extrusion Wood-plastic floor.Obtain top layer uniformly, containing the Wood-plastic floor in yellow green luminescent material, its hot strength is good
Good, smooth surface, illumination effect is good.
Embodiment 15:
A kind of preparation on outdoor fluorescent wood-plastic floor, raw materials used and weight is:
PE resin 100kg
Pulvis Talci 10kg
Wood powder 50kg
Compatilizer 8kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type calcium halophosphate activated by antimony andmanganese fluorescent material 1.5kg
Organically-modified process is: takes anhydrous isopropyl alcohol solvent and adds in reactor, is added by halogen calcium phosphate fluoressent powder, stirring
0.5h, adds titanate coupling agent, is progressively heated up to 70～90 DEG C, is taken out by the fluorescent material handled well, be dried after stirring 3h
Remove solvent, grind, obtain the fluorescent material of organically-modified process；
After the raw material such as wood powder, PVC resin powder is tentatively mixed with organically-modified calcium halophosphate activated by antimony andmanganese fluorescent material, add co-extrusion and squeeze
Go out the side extruder hopper of machine, control screw rod to head temperature at 190 DEG C, determine through die extrusion after main extruder material co-extrusion
Type is top layer co-extrusion Wood-plastic floor.Obtain top layer uniformly, containing the Wood-plastic floor in crocus luminescent material, its hot strength is good
Good, smooth surface, illumination effect is good.
Claims (10)
1. an outdoor fluorescent wood-plastic floor, it is characterised in that: Wood-plastic floor raw material adds luminous pigment, described luminous face
Material is for using the fluorescent material of organically-modified process, after mixing, after fusion plastification equipment, shapes through mouth die, obtains overall sending out
The fluorescent wood-plastic floor of light；Or use the fluorescent material of organically-modified process as luminous pigment, mix with Wood-plastic floor co-extrusion material
Close, add the side extruder hopper of co-extrusion extruder, shape through die extrusion after the raw material co-extrusion of main extruder Wood-plastic floor
For top layer co-extrusion Wood-plastic floor, obtain the fluorescent wood-plastic floor that top layer is luminous.
Outdoor fluorescent wood-plastic floor the most according to claim 1, it is characterised in that: described luminous pigment is aluminate body
One or more in system, silicate systems, phosphate system, oxysulfide system or long afterglow fluorescent material.
Outdoor fluorescent wood-plastic floor the most according to claim 1, it is characterised in that: described organically-modified processing method is
Refer to utilize various modified additive, use method physically or chemically the thing that is modified is processed described physical method include but
It is not limited to: use modified additive that by hydrogen bond action or electrostatic interaction, the thing that is modified is implemented physics and be coated with, thus change and changed
The surface of property thing and interface physico-chemical property；Described chemical method includes but not limited to: use with occurring with the thing that is modified
The thing that is modified is implemented chemical modification by the way of chemical bonding by the modified additive of the functional group of chemical reaction, thus changes quilt
The surface of modifier and interface physico-chemical property.
4. the preparation method on an outdoor fluorescent wood-plastic floor, it is characterised in that: use the fluorescent material of organically-modified process to make
For luminous pigment, add in wood plastic composite raw material, after mixing, after fusion plastification equipment, shape through mouth die, obtain overall
Luminous Wood-plastic floor；Or use the fluorescent material of organically-modified process as luminous pigment, mix with Wood-plastic floor co-extrusion material,
Add the side extruder hopper of co-extrusion extruder, be fixed to table through die extrusion after the raw material co-extrusion of main extruder Wood-plastic floor
Layer co-extrusion Wood-plastic floor, obtains the Wood-plastic floor that top layer is luminous.
The preparation method on outdoor fluorescent wood-plastic floor the most according to claim 4, it is characterised in that: described luminous pigment is
One or several in aluminates system, silicate systems, phosphate system, oxysulfide system or long afterglow fluorescent material
Kind.
The preparation method on outdoor fluorescent wood-plastic floor the most according to claim 4, it is characterised in that: described is organically-modified
Processing method refers to utilize various modified additive, uses method physically or chemically to process the thing that is modified, described thing
Reason method includes but not limited to: uses modified additive that by hydrogen bond action or electrostatic interaction, the thing that is modified is implemented physics and is coated with,
Thus change surface and the interface physico-chemical property of the thing that is modified；Described chemical method includes but not limited to: use with can be with
The thing that is modified is implemented chemistry by the way of chemical bonding and is changed by the modified additive of functional group of thing generation chemical reaction of being modified
Property, thus change surface and the interface physico-chemical property of the thing that is modified.
The preparation method on outdoor fluorescent wood-plastic floor the most according to claim 4, it is characterised in that described is organically-modified
Processing method is: takes alcohols solvent and adds in reactor, is added by fluorescent material, stirring, adds chemical bonding or chelating class coupling
Agent, is progressively heated up to 70～90 DEG C, is taken out by the fluorescent material handled well, is dried and removes solvent, grind after stirring certain time,
Obtain the fluorescent material of organically-modified process.
The preparation method on outdoor fluorescent wood-plastic floor the most according to claim 7, it is characterised in that: described coupling agent
For: silane coupler and/or titanate coupling agent and/or zirconium class coupling agent and/or stannum class coupling agent.
The preparation method on outdoor fluorescent wood-plastic floor the most according to claim 4, it is characterised in that: described fusion plastification
Equipment includes but not limited to mill, banbury, twin screw, single screw extrusion machine；The temperature of described fusion plastification is 170
210℃。
The preparation method on outdoor fluorescent wood-plastic floor the most according to claim 4, it is characterised in that: described raw material is:
Polyvinyl chloride resin, calcium powder, wood powder, stabilizer, compatilizer, foaming agent, lubricant；Or PE resin, Pulvis Talci, wood powder, compatilizer, profit
Lubrication prescription, UV absorbent；Or PP resin, Pulvis Talci, wood powder, compatilizer, lubricant, UV absorbent；Or PE resin, cunning
Stone powder, wood powder, compatilizer, lubricant, UV absorbent；Or polyvinyl chloride resin, Pulvis Talci, wood powder, compatilizer, lubricant.
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| CN201610748458.4A CN106280125A (en) | 2016-08-29 | 2016-08-29 | A kind of outdoor fluorescent wood-plastic floor and preparation method thereof |
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| CN201610748458.4A CN106280125A (en) | 2016-08-29 | 2016-08-29 | A kind of outdoor fluorescent wood-plastic floor and preparation method thereof |
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| CN109720040A (en) * | 2018-11-28 | 2019-05-07 | 安徽红树林新材料科技有限公司 | A kind of wood-plastic board preparation method that can be absorbed ultraviolet light and issue fluorescence |
| CN109929194A (en) * | 2019-04-03 | 2019-06-25 | 北新弹性地板有限公司 | A kind of PVC floor and production technology |
| CN111516343A (en) * | 2020-04-24 | 2020-08-11 | 安徽红树林新材料科技有限公司 | Night self-luminous wood-plastic product and preparation method thereof |
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Application publication date: 20170104 |