CN103849053A - Functional white master batch for polyethylene and preparation method thereof - Google Patents
Functional white master batch for polyethylene and preparation method thereof Download PDFInfo
- Publication number
- CN103849053A CN103849053A CN201210594598.2A CN201210594598A CN103849053A CN 103849053 A CN103849053 A CN 103849053A CN 201210594598 A CN201210594598 A CN 201210594598A CN 103849053 A CN103849053 A CN 103849053A
- Authority
- CN
- China
- Prior art keywords
- master batch
- polyethylene
- white master
- functional
- coupling agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Abstract
The invention discloses a functional white master batch for polyethylene and a preparation method thereof. The functional white master batch for polyethylene disclosed by the invention comprises the following components by weight percent: 10-20% of polyethylene resin, 30-70% of white pigment, 10-50% of inorganic powder, 3-5% of dispersant, 0.5-3% of coupling agent, and 0.1-1% of antioxidant. Compared with the prior art, the functional white master batch has the beneficial effects that the functional white master batch disclosed by the invention is applied to coloring of a polyethylene product, not only has the same whitening function as a common white master batch, but also has reinforcing and toughening functions, is good in dispersibility, less in additive amount, low in cost and good in appearance quality. The functional white master batch for polyethylene provided by the invention is simple and practical in preparation method, and good in application prospect.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically a kind of functional white master batch and preparation method thereof for polyethylene.
Background technology
In recent years, along with the develop rapidly of plastic cement industry and improving constantly of plastic cement performance, polyethylene products has obtained application more widely, and some need to carry out painted processing.Conventionally, the method for polyethylene color is had: toner is painted, painted three kinds of the painted and Masterbatch of grain is drawn in dyeing.Toner is painted very simple, easily produces color dot, aberration is wayward, environmental pollution is larger shortcoming but exist.It is that pigment is mixed in plastic material that dyeing draws grain painted, and each plastic rubber material is all painted, so it is even to form goods colour stable, but damaged to a certain extent the mechanical property of goods, and cost is high, also needs to store a large amount of coloured raw materials.Masterbatch is painted is that pigment super quantity is attached in resin equably, thereby has greatly improved dispersing property and the coloration efficiency of pigment, has the advantages such as simple to operate, with low cost, environmentally safe.
Summary of the invention
The object of the present invention is to provide a kind of good dispersity, addition is few, cost is low, easy to use functional white master batch and preparation method thereof for polyethylene.
The technical solution adopted for the present invention to solve the technical problems is: the functional white master batch of polyethylene, its component by mass percent proportioning is: polyvinyl resin 10%～20%, white pigment 30%～70%, inorganic powder 10%～50%, dispersion agent 3%～5%, coupling agent 0.5%～3%, oxidation inhibitor 0.1%～1%.
Described white pigment is the one in titanium dioxide (titanium dioxide), zinc oxide (zinc white) and the zinc sulfide white (lithopone) of particle diameter between 0.1～0.5 μ m.
Described inorganic powder is one or more the mixture in calcium carbonate, kaolin, wollastonite powder, talcum powder, mica powder and the polynite powder of particle diameter between 5～15 μ m.
Described dispersion agent is the one in low molecular weight polyethylene wax, OP wax, Magnesium Stearate, calcium stearate.
Described coupling agent is the one in silane coupling agent, titanate coupling agent, phosphate coupling agent, boric acid ester coupler and aluminate coupling agent.
Described oxidation inhibitor is the compound of polyphenol antioxidant 1010 and phosphite antioxidant 168.
Above-mentioned polyethylene by the preparation method of functional white master batch is: each component is prepared burden by weight proportion, then in high-speed mixer, mix 5～25 minutes, adopt again that twin screw extruder is extruded, after granulation, drying, pack and obtain the functional white master batch of polyethylene of the present invention.
The invention has the beneficial effects as follows, compared with prior art, it is painted that functional white color master batch of the present invention is applied to polyethylene products, not only there is brighten function same with ordinary white master batch, but also there is strengthening and toughening function, its good dispersity, addition is few, and cost is low, and visual appearance is good.Polyethylene provided by the invention is simple and practical by the preparation method of functional white master batch, and application prospect is good.
Embodiment
Enter～walk explanation technical scheme of the present invention below in conjunction with specific embodiment.
Embodiment 1:
The functional white master batch of a kind of polyethylene, its component by mass percent proportioning is: the compound 0.5% of polyvinyl resin 15%, titanium dioxide (titanium dioxide) 50%, calcium carbonate 30%, low molecular weight polyethylene wax 3%, silane coupling agent 1.5%, polyphenol antioxidant 1010 and phosphite antioxidant 168, wherein, the particle diameter of titanium dioxide (titanium dioxide) is between 0.1～0.5 μ m, and the particle diameter of calcium carbonate is between 5～15 μ m.
Preparation method: each component is prepared burden by weight proportion, then mix in high-speed mixer 5～25 minutes, then adopt that twin screw extruder is extruded, after granulation, drying, pack and obtain the functional white master batch of polyethylene of the present invention.
Embodiment 2:
The functional white master batch of a kind of polyethylene, its component by mass percent proportioning is: the compound 1% of polyvinyl resin 10%, titanium dioxide (titanium dioxide) 70%, kaolin 12%, OP wax 5%, titanate coupling agent 2%, polyphenol antioxidant 1010 and phosphite antioxidant 168, wherein, the particle diameter of titanium dioxide (titanium dioxide) is between 0.1～0.5 μ m, and kaolinic particle diameter is between 5～15 μ m.
Preparation method: each component is prepared burden by weight proportion, then mix in high-speed mixer 5～25 minutes, then adopt that twin screw extruder is extruded, after granulation, drying, pack and obtain the functional white master batch of polyethylene of the present invention.
Embodiment 3:
The functional white master batch of a kind of polyethylene, its component by mass percent proportioning is: the compound 1% of polyvinyl resin 15%, zinc sulfide white (lithopone) 30%, talcum powder 50%, calcium stearate 3%, aluminate coupling agent 1%, polyphenol antioxidant 1010 and phosphite antioxidant 168, wherein, the particle diameter of zinc sulfide white (lithopone) is between 0.1～0.5 μ m, and talcous particle diameter is between 5～15 μ m.
Preparation method: each component is prepared burden by weight proportion, then mix in high-speed mixer 5～25 minutes, then adopt that twin screw extruder is extruded, after granulation, drying, pack and obtain the functional white master batch of polyethylene of the present invention.
Claims (7)
1. the functional white master batch of polyethylene, it is characterized in that, its component by mass percent proportioning is: polyvinyl resin 10%～20%, white pigment 30%～70%, inorganic powder 10%～50%, dispersion agent 3%～5%, coupling agent 0.5%～3%, oxidation inhibitor 0.1%～1%.
2. the functional white master batch of polyethylene according to claim 1, it is characterized in that, described white pigment is the one in titanium dioxide (titanium dioxide), zinc oxide (zinc white) and the zinc sulfide white (lithopone) of particle diameter between 0.1～0.5 μ m.
3. the functional white master batch of polyethylene according to claim 1, it is characterized in that, described inorganic powder is one or more the mixture in calcium carbonate, kaolin, wollastonite powder, talcum powder, mica powder and the polynite powder of particle diameter between 5～15 μ m.
4. the functional white master batch of polyethylene according to claim 1, is characterized in that, described dispersion agent is the one in low molecular weight polyethylene wax, OP wax, Magnesium Stearate, calcium stearate.
5. the functional white master batch of polyethylene according to claim 1, is characterized in that, described coupling agent is the one in silane coupling agent, titanate coupling agent, phosphate coupling agent, boric acid ester coupler and aluminate coupling agent.
6. the functional white master batch of polyethylene according to claim 1, is characterized in that, described oxidation inhibitor is the compound of polyphenol antioxidant 1010 and phosphite antioxidant 168.
7. the preparation method of functional white master batch for polyethylene according to claim 1, it is characterized in that, comprise the following steps: each component is prepared burden by weight proportion, then in high-speed mixer, mix 5～25 minutes, adopt again that twin screw extruder is extruded, after granulation, drying, pack and obtain the functional white master batch of polyethylene of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210594598.2A CN103849053A (en) | 2012-12-04 | 2012-12-04 | Functional white master batch for polyethylene and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210594598.2A CN103849053A (en) | 2012-12-04 | 2012-12-04 | Functional white master batch for polyethylene and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103849053A true CN103849053A (en) | 2014-06-11 |
Family
ID=50857194
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210594598.2A Pending CN103849053A (en) | 2012-12-04 | 2012-12-04 | Functional white master batch for polyethylene and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103849053A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105001494A (en) * | 2015-08-04 | 2015-10-28 | 苏州博云塑业有限公司 | Light-resistant color master batch |
| CN105061853A (en) * | 2015-07-30 | 2015-11-18 | 广东致顺化工环保设备有限公司 | Regenerated modified material specially used for solid wall tubes, and preparation method and application thereof |
| CN105754182A (en) * | 2016-04-01 | 2016-07-13 | 重庆澳彩新材料股份有限公司 | Color master batch for cast film and preparation method thereof |
| CN106397922A (en) * | 2016-09-12 | 2017-02-15 | 苏州清丰兴业塑胶有限公司 | White whitening master batch and preparation method thereof |
| CN106753056A (en) * | 2016-12-29 | 2017-05-31 | 苏州度辰新材料有限公司 | White polyolefin packaging adhesive film for solar cell module and preparation method thereof |
| CN107663327A (en) * | 2017-09-18 | 2018-02-06 | 苏州武江新材料科技有限公司 | A kind of polyethylene color master batch and preparation method thereof |
| CN109331327A (en) * | 2018-09-05 | 2019-02-15 | 贵州千叶药品包装股份有限公司 | A kind of pre- filling vaginal administration device of bilayer and preparation method thereof |
| CN110591204A (en) * | 2019-09-28 | 2019-12-20 | 武汉鑫恒顺科技有限公司 | Antistatic weather-resistant anti-adhesion color master batch for PE (polyethylene) film |
| CN110903524A (en) * | 2019-10-22 | 2020-03-24 | 稀美师新材料科技(常州)有限公司 | White polyethylene color master batch with high-reflectivity effect and preparation method thereof |
| CN112011108A (en) * | 2019-05-31 | 2020-12-01 | 苏州清丰兴业塑胶有限公司 | Preparation method of white whitening master batch |
| CN115260794A (en) * | 2022-07-26 | 2022-11-01 | 江苏镇钛化工有限公司 | Titanium dioxide special for high-bulk-density color master batch and processing technology thereof |
| CN115418008A (en) * | 2022-09-14 | 2022-12-02 | 长兴科隆新材料科技有限公司 | Industrial production method of color master batch |
| CN115975282A (en) * | 2023-01-05 | 2023-04-18 | 惠州市艳丽彩塑胶科技有限公司 | Highlight modified white master batch and preparation method thereof |
-
2012
- 2012-12-04 CN CN201210594598.2A patent/CN103849053A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105061853A (en) * | 2015-07-30 | 2015-11-18 | 广东致顺化工环保设备有限公司 | Regenerated modified material specially used for solid wall tubes, and preparation method and application thereof |
| CN105001494A (en) * | 2015-08-04 | 2015-10-28 | 苏州博云塑业有限公司 | Light-resistant color master batch |
| CN105754182A (en) * | 2016-04-01 | 2016-07-13 | 重庆澳彩新材料股份有限公司 | Color master batch for cast film and preparation method thereof |
| CN106397922A (en) * | 2016-09-12 | 2017-02-15 | 苏州清丰兴业塑胶有限公司 | White whitening master batch and preparation method thereof |
| CN106753056B (en) * | 2016-12-29 | 2018-08-31 | 苏州度辰新材料有限公司 | White polyolefin packaging adhesive film and preparation method thereof for solar cell module |
| CN106753056A (en) * | 2016-12-29 | 2017-05-31 | 苏州度辰新材料有限公司 | White polyolefin packaging adhesive film for solar cell module and preparation method thereof |
| CN107663327A (en) * | 2017-09-18 | 2018-02-06 | 苏州武江新材料科技有限公司 | A kind of polyethylene color master batch and preparation method thereof |
| CN109331327A (en) * | 2018-09-05 | 2019-02-15 | 贵州千叶药品包装股份有限公司 | A kind of pre- filling vaginal administration device of bilayer and preparation method thereof |
| CN112011108A (en) * | 2019-05-31 | 2020-12-01 | 苏州清丰兴业塑胶有限公司 | Preparation method of white whitening master batch |
| CN110591204A (en) * | 2019-09-28 | 2019-12-20 | 武汉鑫恒顺科技有限公司 | Antistatic weather-resistant anti-adhesion color master batch for PE (polyethylene) film |
| CN110903524A (en) * | 2019-10-22 | 2020-03-24 | 稀美师新材料科技(常州)有限公司 | White polyethylene color master batch with high-reflectivity effect and preparation method thereof |
| CN115260794A (en) * | 2022-07-26 | 2022-11-01 | 江苏镇钛化工有限公司 | Titanium dioxide special for high-bulk-density color master batch and processing technology thereof |
| CN115418008A (en) * | 2022-09-14 | 2022-12-02 | 长兴科隆新材料科技有限公司 | Industrial production method of color master batch |
| CN115975282A (en) * | 2023-01-05 | 2023-04-18 | 惠州市艳丽彩塑胶科技有限公司 | Highlight modified white master batch and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103849053A (en) | Functional white master batch for polyethylene and preparation method thereof | |
| CN103709475A (en) | Functional white master batch for plastic cement and preparation method thereof | |
| CN103709489A (en) | General white master batch and preparation method thereof | |
| CN104327378B (en) | A kind of antistatic antibiotic color masterbatch and preparation method thereof | |
| CN103849058A (en) | Coloring master batches for polyethylene and preparation method thereof | |
| CN101392077B (en) | Polypropylene color master-batch with pearlescent interference effect and preparation method thereof | |
| CN104861479A (en) | Antibacterial color master batch used for polyethylene glycol terephthalate | |
| CN103709668A (en) | Color master batch for polyester and preparation method thereof | |
| CN102558680A (en) | Antibacterial masterbatch | |
| CN102040764A (en) | Black master batch and preparation method thereof | |
| CN103709676A (en) | Functional white master batch for PBT and preparation method thereof | |
| CN103665816B (en) | Titanium dioxide PC matrix material of a kind of good fluidity and preparation method thereof | |
| CN105542292A (en) | Functional white masterbatch and preparation method thereof | |
| CN104059273A (en) | Special polyethylene coloring masterbatch for white thin film and preparation method of masterbatch | |
| CN104479229A (en) | Spray-free baking varnish metal-like polypropylene material and preparation method thereof | |
| CN103709667A (en) | PBT high density color master batch and preparation method thereof | |
| CN103937088A (en) | High-concentration polyolefin calcium carbonate filled white master batch and preparation method thereof | |
| CN104861543A (en) | PTT polyester plastic color master batch | |
| CN101367970A (en) | Novel material special for transparent plastic and method of preparing the same | |
| CN103709611A (en) | Polyester black master batch and preparation method thereof | |
| CN102675847A (en) | Zero-shrinkage internal-colorable BMC (bulk molding compounds) material, and preparation method and applications thereof | |
| CN103709662A (en) | High-concentration white master batch for polyester, and preparation method thereof | |
| CN108410140A (en) | A kind of high molecular polymer white master material and preparation method thereof based on nano-aluminum hydroxide | |
| CN103709488A (en) | Plastic color master batch and preparation method thereof | |
| CN104530569A (en) | Environment-friendly high-glossiness colorful polypropylene material and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140611 |