CN103709489A - General white master batch and preparation method thereof - Google Patents
General white master batch and preparation method thereof Download PDFInfo
- Publication number
- CN103709489A CN103709489A CN201210373207.4A CN201210373207A CN103709489A CN 103709489 A CN103709489 A CN 103709489A CN 201210373207 A CN201210373207 A CN 201210373207A CN 103709489 A CN103709489 A CN 103709489A
- Authority
- CN
- China
- Prior art keywords
- master batch
- white master
- coupling agent
- universal
- batch according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L35/06—Copolymers with vinyl aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses general white master batch and a preparation method thereof. The general white master batch provided by the invention contains the following components by weight: 10-20% of carrier, 30-60% of titanium dioxide, 10-40% of inorganic filling material, 5-10% of dispersant, 0.5-3% of coupling agent, 0.1-1% of anti-oxidant, and 0-1% of other auxiliary agents. The beneficial effects reside in that: when the general white master batch prepared by using a high-molecular elastomer as a carrier is used for coloring engineering plastics, the general white master batch has advantages of high dispersibility, impact resistance, good compatibility, and strong versatility in different engineering plastics, also has advantages of uniform coloring, stable color, high concentration, small usage amount, low cost, simple process and convenient usage, can avoid environment pollution, can be wide applied for coloring five kinds of engineering plastics: polycarbonate (PC), polyformaldehyde (POM), polyamide (PA), polybutylene telephthalate (PBT), and polyphenyl ether (PPO), and has a wide application prospect.
Description
Technical field
The present invention relates to a kind of Masterbatch, specifically a kind of universal white master batch and preparation method thereof.
Background technology
In recent years, along with the develop rapidly of plastic cement industry and improving constantly of plastic cement performance, plasthetics has obtained application more widely.Conventionally, plasthetics is wanted and color coordination, and its colorize method can be divided into: toner is painted, painted three kinds of the painted and Masterbatch of grain is drawn in dyeing.The shortcomings such as directly toner is painted very simple, but has color dot, aberration, and environmental pollution is larger.It is that pigment is mixed in plastic material that dyeing draws grain painted, and each plastic rubber material is all painted, so it is even to form goods colour stable, but damaged to a certain extent the mechanical property of goods, and cost is high, also needs to store a large amount of coloured raw materials.Masterbatch is painted is that pigment super quantity is attached in resin equably, thereby has greatly improved dispersing property and the coloration efficiency of pigment, has the advantages such as simple to operate, with low cost, environmentally safe.
Because the pigment that plastic cement is painted is various, and differing materials is not quite similar to the requirement of Masterbatch, the Masterbatch that this will cause same manufacturer is used is various in style, and the material of a plurality of parts when a product on all just need to be used a plurality of special color master batch during difference especially.So all too many levels such as the monitoring of quality product, warehousing management buying are had to higher requirement, thereby cause production cost increase, the fraction defective of manufacturer also greatly to raise.In this case, adopt general Masterbatch can make up the deficiency of above-mentioned use special color master batch.The feature of general Masterbatch is that same Masterbatch can be used in multiple plastics, and its addition few (being generally 1%), painted with low cost.But, along with plastic cement industry development, various engineering plastic applications scope also constantly expands, existing general Masterbatch and preparation technology thereof can not meet plastics in the demand of the aspects such as physical strength and dispersiveness, main because existing general Masterbatch bad dispersibility, concentration is low, and its carrier mostly is low-molecular polyethylene wax, EVE, K resin, metal soap, although these and polyethylene, polyacrylic consistency is good, but with polycarbonate (PC), polyoxymethylene (POM), polyamide (PA), polybutylene terephthalate (PBT), the consistency of the five large-engineering plastics such as polyphenylene oxide (PPO) is poor, and very easily cause peeling, layering, degradation phenomenon under impact property, particularly when goods whiteness, surface gloss requires high, as white domestic appliances etc., increase along with present general Masterbatch addition, above-mentioned phenomenon can be more serious, and directly have influence on the quality of the finished product.
Summary of the invention
The object of the present invention is to provide a kind of good dispersity, shock-resistance is strong, concentration is high, cost is low and easy to use universal white master batch and preparation method thereof, this Masterbatch can, for five large-engineering coloring plastics such as polycarbonate (PC), polyoxymethylene (POM), polyamide (PA), polybutylene terephthalate (PBT), polyphenylene oxide (PPO), can be avoided degradation shortcoming under peeling, layering, impact property.
The technical solution adopted for the present invention to solve the technical problems is: a kind of universal white master batch, its component by mass percent proportioning is: carrier 10%～20%, titanium dioxide 30%～60%, mineral filler 10%～40%, dispersion agent 5%～10%, coupling agent 0.5%～3%, oxidation inhibitor 0.1%～1%, other auxiliary agents 0～1%.
Described carrier is macromolecular elastomer, can select a kind of in ethylene-octene copolymer (POE), terpolymer EP rubber (EPDM), styrene-butadiene-styrene block copolymer (SBS), methyl methacrylate-glycidyl methacrylate-propylene ethyl ester ter-polymers (MGE), styrene maleic anhydride copolymer (SMA).
Described titanium dioxide is a kind of in anatase thpe white powder and Rutile type Titanium Dioxide or both mixtures, and its particle diameter is 0.2～0.4 μ m.
Described mineral filler is one or more the mixture in calcium carbonate, magnesiumcarbonate, barium sulfate, aluminium hydroxide, mica powder, kaolin, wollastonite, talcum and the polynite of particle diameter between 5～15 μ m.
Described dispersion agent is a kind of in low molecular weight polyethylene wax, OP wax, Magnesium Stearate, calcium stearate.
Described coupling agent is a kind of in silane coupling agent, titanate coupling agent, phosphate coupling agent and aluminate coupling agent.
Described oxidation inhibitor is the compound of polyphenol antioxidant 1010 and phosphite antioxidant 168.
Other described auxiliary agents are whitening agent, and described whitening agent is ultramarine rongalite or white dyes.
The preparation method of above-mentioned a kind of universal white master batch is: each component is prepared burden by weight proportion, then in the high-speed mixer of 1500～3000 revs/min, mix 5～20 minutes, adopt again twin screw extruder melt blending to extrude, temperature is controlled at 190 ℃～220 ℃, rotating speed is 80～400 revs/min, by the shearing of screw rod, the mixing titanium white powder pigment that makes, in carrier, be uniformly dispersed, then carry out granulation, be drying to obtain a kind of universal white master batch of the present invention.
The invention has the beneficial effects as follows, it is that the prepared universal white master batch of carrier is applied to engineering plastics when painted that the present invention adopts macromolecular elastomer, it has high dispersive, shock-resistant, consistency good and in different engineering plastics the advantage such as highly versatile, and uniform coloring, colour stable, concentration is high, consumption is few, with low cost, operation is simple, easy to use, avoid again environmental pollution, can be widely used in polycarbonate (PC), polyoxymethylene (POM), polyamide (PA), polybutylene terephthalate (PBT), the five large-engineering coloring plastics such as polyphenylene oxide (PPO), avoid occurring material peeling, degradation phenomenon under layering and impact property, it has a extensive future.
Embodiment
Below in conjunction with specific embodiment, further illustrate technical scheme of the present invention.
Embodiment 1:
A kind of universal white master batch, its component by mass percent proportioning is: the compound 0.5% of ethylene-octene copolymer (POE) 15%, anatase thpe white powder 45%, calcium carbonate 30%, low molecular weight polyethylene wax 8%, silane coupling agent 1.5%, polyphenol antioxidant 1010 and phosphite antioxidant 168, wherein, the particle diameter of anatase thpe white powder is 0.2～0.4 μ m, and the particle diameter of mineral filler is between 5～15 μ m.
Preparation method: each component is prepared burden by weight proportion, then in the high-speed mixer of 1500～3000 revs/min, mix 5～20 minutes, adopt again twin screw extruder melt blending to extrude, temperature is controlled at 190 ℃～220 ℃, rotating speed is 80～400 revs/min, by the shearing of screw rod, the mixing anatase thpe white powder that makes, in ethylene-octene copolymer (POE), be uniformly dispersed, then carry out granulation, be drying to obtain a kind of universal white master batch of the present invention.
Embodiment 2:
A kind of universal white master batch, its component by mass percent proportioning is: compound 0.5%, the ultramarine rongalite 0.5% of terpolymer EP rubber (EPDM) 10%, Rutile type Titanium Dioxide 60%, barium sulfate 16%, OP wax 10%, titanate coupling agent 3%, polyphenol antioxidant 1010 and phosphite antioxidant 168, wherein, the particle diameter of Rutile type Titanium Dioxide is 0.2～0.4 μ m, and the particle diameter of barium sulfate is between 5～15 μ m.
Preparation method: each component is prepared burden by weight proportion, then in the high-speed mixer of 1500～3000 revs/min, mix 5～20 minutes, adopt again twin screw extruder melt blending to extrude, temperature is controlled at 190 ℃～220 ℃, rotating speed is 80～400 revs/min, by the shearing of screw rod, the mixing Rutile type Titanium Dioxide that makes, in terpolymer EP rubber (EPDM), be uniformly dispersed, then carry out granulation, be drying to obtain a kind of universal white master batch of the present invention.
Embodiment 3:
A kind of universal white master batch, its component by mass percent proportioning is: compound 1%, the white dyes 0.5% of styrene-butadiene-styrene block copolymer (SBS) 20%, Rutile type Titanium Dioxide 30%, polynite 40%, OP wax 6%, aluminate coupling agent 2.5%, polyphenol antioxidant 1010 and phosphite antioxidant 168, wherein, the particle diameter of Rutile type Titanium Dioxide is 0.2～0.4 μ m, and the particle diameter of polynite is between 5～15 μ m.
Preparation method: each component is prepared burden by weight proportion, then in the high-speed mixer of 1500～3000 revs/min, mix 5～20 minutes, adopt again twin screw extruder melt blending to extrude, temperature is controlled at 190 ℃～220 ℃, rotating speed is 80～400 revs/min, by the shearing of screw rod, the mixing Rutile type Titanium Dioxide that makes, in styrene-butadiene-styrene block copolymer (SBS), be uniformly dispersed, then carry out granulation, be drying to obtain a kind of universal white master batch of the present invention.
Claims (9)
1. a universal white master batch, it is characterized in that, its component by mass percent proportioning is: carrier 10%～20%, titanium dioxide 30%～60%, mineral filler 10%～40%, dispersion agent 5%～10%, coupling agent 0.5%～3%, oxidation inhibitor 0.1%～1%, other auxiliary agents 0～1%.
2. a kind of universal white master batch according to claim 1, it is characterized in that, described carrier is macromolecular elastomer, can select a kind of in ethylene-octene copolymer (POE), terpolymer EP rubber (EPDM), styrene-butadiene-styrene block copolymer (SBS), methyl methacrylate-glycidyl methacrylate-propylene ethyl ester ter-polymers (MGE), styrene maleic anhydride copolymer (SMA).
3. a kind of universal white master batch according to claim 1, is characterized in that, described titanium dioxide is a kind of in anatase thpe white powder and Rutile type Titanium Dioxide or both mixtures, and its particle diameter is 0.2～0.4 μ m.
4. a kind of universal white master batch according to claim 1, it is characterized in that, described mineral filler is one or more the mixture in calcium carbonate, magnesiumcarbonate, barium sulfate, aluminium hydroxide, mica powder, kaolin, wollastonite, talcum and the polynite of particle diameter between 5～15 μ m.
5. a kind of universal white master batch according to claim 1, is characterized in that, described dispersion agent is a kind of in low molecular weight polyethylene wax, OP wax, Magnesium Stearate, calcium stearate.
6. a kind of universal white master batch according to claim 1, is characterized in that, described coupling agent is a kind of in silane coupling agent, titanate coupling agent, phosphate coupling agent and aluminate coupling agent.
7. a kind of universal white master batch according to claim 1, is characterized in that, described oxidation inhibitor is the compound of polyphenol antioxidant 1010 and phosphite antioxidant 168.
8. a kind of universal white master batch according to claim 1, is characterized in that, other described auxiliary agents are whitening agent, and described whitening agent is ultramarine rongalite or white dyes.
9. the preparation method of a kind of universal white master batch according to claim 1, it is characterized in that, comprise the following steps: each component is prepared burden by weight proportion, then in the high-speed mixer of 1500～3000 revs/min, mix 5～20 minutes, adopt again twin screw extruder melt blending to extrude, temperature is controlled at 190 ℃～220 ℃, rotating speed is 80～400 revs/min, by the shearing of screw rod, the mixing titanium white powder pigment that makes, in carrier, be uniformly dispersed, then carry out granulation, be drying to obtain a kind of universal white master batch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210373207.4A CN103709489A (en) | 2012-09-29 | 2012-09-29 | General white master batch and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210373207.4A CN103709489A (en) | 2012-09-29 | 2012-09-29 | General white master batch and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103709489A true CN103709489A (en) | 2014-04-09 |
Family
ID=50402866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210373207.4A Pending CN103709489A (en) | 2012-09-29 | 2012-09-29 | General white master batch and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103709489A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761861A (en) * | 2015-04-15 | 2015-07-08 | 常州市改性塑料厂有限公司 | High-dispersion ABS color masterbatch |
| CN105419046A (en) * | 2015-11-27 | 2016-03-23 | 康平县塑编产业集群综合服务中心 | Whitening masterbatch of reclaimed materials for plastic woven bags and preparation method thereof |
| CN105694242A (en) * | 2016-04-21 | 2016-06-22 | 宁波硫华聚合物有限公司 | Colored or white rubber brightener titanium dioxide pre-dispersion masterbatch particles and preparation method thereof |
| CN105713281A (en) * | 2016-04-21 | 2016-06-29 | 上海宏盎实业发展有限公司 | Universal white master batch and preparation method thereof |
| CN106432925A (en) * | 2016-09-29 | 2017-02-22 | 东莞市彩隆塑胶科技有限公司 | Color masterbatch formula and preparing process thereof |
| CN106467615A (en) * | 2016-08-18 | 2017-03-01 | 徐英豪 | The application in plastic pipe of barium sulfate and titanium white compound powder |
| WO2017066973A1 (en) * | 2015-10-23 | 2017-04-27 | 揭东巴黎万株纱华纺织有限公司 | Colour masterbatch formula |
| CN107286593A (en) * | 2017-06-13 | 2017-10-24 | 浙江金彩新材料有限公司 | It is a kind of for graphene heat discoloration Masterbatch of polyester fiber and preparation method thereof |
| CN108690343A (en) * | 2017-04-11 | 2018-10-23 | 合肥杰事杰新材料股份有限公司 | A kind of polyphenyl ether material and preparation method thereof |
| CN109096777A (en) * | 2018-09-04 | 2018-12-28 | 北京撕得物流技术有限公司 | A kind of Masterbatch and production method |
| CN110229408A (en) * | 2019-07-02 | 2019-09-13 | 多华塑胶色料(深圳)有限公司 | A kind of universal white master batch and preparation method thereof |
| CN111574854A (en) * | 2020-06-16 | 2020-08-25 | 佛山市鑫新新材料有限公司 | Preparation method of calcium carbonate filler for producing high-gloss toughened synthetic resin tile |
| CN112876802A (en) * | 2020-12-25 | 2021-06-01 | 金发科技股份有限公司 | Engineering plastic formula and injection molding color matching method thereof |
| CN115819946A (en) * | 2022-12-01 | 2023-03-21 | 龙岩市润峰科技有限公司 | Polycarbonate black carving white functional master batch and preparation method thereof |
| CN118085561A (en) * | 2024-04-29 | 2024-05-28 | 安特普工程塑料（苏州）有限公司 | High-thermal-conductivity nylon composite material and preparation method thereof |
-
2012
- 2012-09-29 CN CN201210373207.4A patent/CN103709489A/en active Pending
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761861B (en) * | 2015-04-15 | 2017-11-14 | 常州市改性塑料厂有限公司 | Polymolecularity ABS color masterbatches |
| CN104761861A (en) * | 2015-04-15 | 2015-07-08 | 常州市改性塑料厂有限公司 | High-dispersion ABS color masterbatch |
| WO2017066973A1 (en) * | 2015-10-23 | 2017-04-27 | 揭东巴黎万株纱华纺织有限公司 | Colour masterbatch formula |
| CN105419046A (en) * | 2015-11-27 | 2016-03-23 | 康平县塑编产业集群综合服务中心 | Whitening masterbatch of reclaimed materials for plastic woven bags and preparation method thereof |
| CN105694242A (en) * | 2016-04-21 | 2016-06-22 | 宁波硫华聚合物有限公司 | Colored or white rubber brightener titanium dioxide pre-dispersion masterbatch particles and preparation method thereof |
| CN105713281A (en) * | 2016-04-21 | 2016-06-29 | 上海宏盎实业发展有限公司 | Universal white master batch and preparation method thereof |
| CN105694242B (en) * | 2016-04-21 | 2018-07-20 | 宁波艾克姆新材料有限公司 | Colored or pre-dispersed masterbatch particles of white rubber brightening agent titanium dioxide and preparation method thereof |
| CN106467615A (en) * | 2016-08-18 | 2017-03-01 | 徐英豪 | The application in plastic pipe of barium sulfate and titanium white compound powder |
| CN106432925A (en) * | 2016-09-29 | 2017-02-22 | 东莞市彩隆塑胶科技有限公司 | Color masterbatch formula and preparing process thereof |
| CN108690343A (en) * | 2017-04-11 | 2018-10-23 | 合肥杰事杰新材料股份有限公司 | A kind of polyphenyl ether material and preparation method thereof |
| CN107286593A (en) * | 2017-06-13 | 2017-10-24 | 浙江金彩新材料有限公司 | It is a kind of for graphene heat discoloration Masterbatch of polyester fiber and preparation method thereof |
| CN109096777A (en) * | 2018-09-04 | 2018-12-28 | 北京撕得物流技术有限公司 | A kind of Masterbatch and production method |
| CN110229408A (en) * | 2019-07-02 | 2019-09-13 | 多华塑胶色料(深圳)有限公司 | A kind of universal white master batch and preparation method thereof |
| CN111574854A (en) * | 2020-06-16 | 2020-08-25 | 佛山市鑫新新材料有限公司 | Preparation method of calcium carbonate filler for producing high-gloss toughened synthetic resin tile |
| CN112876802A (en) * | 2020-12-25 | 2021-06-01 | 金发科技股份有限公司 | Engineering plastic formula and injection molding color matching method thereof |
| CN115819946A (en) * | 2022-12-01 | 2023-03-21 | 龙岩市润峰科技有限公司 | Polycarbonate black carving white functional master batch and preparation method thereof |
| CN115819946B (en) * | 2022-12-01 | 2024-06-25 | 龙岩市润峰科技有限公司 | Polycarbonate black carving white functional master batch and preparation method thereof |
| CN118085561A (en) * | 2024-04-29 | 2024-05-28 | 安特普工程塑料（苏州）有限公司 | High-thermal-conductivity nylon composite material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103709489A (en) | General white master batch and preparation method thereof | |
| CN103849053A (en) | Functional white master batch for polyethylene and preparation method thereof | |
| CN101392077B (en) | Polypropylene color master-batch with pearlescent interference effect and preparation method thereof | |
| CN101392078A (en) | Universal white master batch and preparation method thereof | |
| CN103709475A (en) | Functional white master batch for plastic cement and preparation method thereof | |
| CN104327378B (en) | A kind of antistatic antibiotic color masterbatch and preparation method thereof | |
| CN103709668A (en) | Color master batch for polyester and preparation method thereof | |
| CN102367320A (en) | General white master batch and its preparation method | |
| CN103849058A (en) | Coloring master batches for polyethylene and preparation method thereof | |
| CN104059273A (en) | Special polyethylene coloring masterbatch for white thin film and preparation method of masterbatch | |
| CN104861543A (en) | PTT polyester plastic color master batch | |
| CN104861479A (en) | Antibacterial color master batch used for polyethylene glycol terephthalate | |
| CN101838398A (en) | Composition and processing technique for plastic colored sand | |
| CN109929264A (en) | A kind of modified Masterbatch and preparation method thereof | |
| CN103254546A (en) | ABS color master batch and preparation process thereof | |
| CN104479229A (en) | Spray-free baking varnish metal-like polypropylene material and preparation method thereof | |
| CN103709676A (en) | Functional white master batch for PBT and preparation method thereof | |
| CN103937088A (en) | High-concentration polyolefin calcium carbonate filled white master batch and preparation method thereof | |
| CN102675847A (en) | Zero-shrinkage internal-colorable BMC (bulk molding compounds) material, and preparation method and applications thereof | |
| CN101367970A (en) | Novel material special for transparent plastic and method of preparing the same | |
| CN103709667A (en) | PBT high density color master batch and preparation method thereof | |
| CN103709662A (en) | High-concentration white master batch for polyester, and preparation method thereof | |
| CN104530569A (en) | Environment-friendly high-glossiness colorful polypropylene material and manufacturing method thereof | |
| CN101372533B (en) | Color crystal and method for coloring plastic using the same | |
| CN103709488A (en) | Plastic color master batch and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140409 |