CN108690343A - A kind of polyphenyl ether material and preparation method thereof - Google Patents
A kind of polyphenyl ether material and preparation method thereof Download PDFInfo
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- CN108690343A CN108690343A CN201710235278.0A CN201710235278A CN108690343A CN 108690343 A CN108690343 A CN 108690343A CN 201710235278 A CN201710235278 A CN 201710235278A CN 108690343 A CN108690343 A CN 108690343A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
- C08J2371/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08J2371/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08J2371/12—Polyphenylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
- C08J2471/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08J2471/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08J2471/12—Polyphenylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2477/06—Polyamides derived from polyamines and polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Abstract
The invention belongs to technical field of polymer materials, and in particular to a kind of polyphenyl ether material and preparation method thereof is prepared by weight by following components:42-82 parts of polyphenylene oxide, 1-5 parts of nylon66 fiber, 5-40 parts of glass fibre, 3-10 parts of toughener, synergistic colour 3-10 parts of reinforcing agent, 0.5-5 parts of color master-batch, 0.1-0.5 parts of antioxidant, 0.1-1.0 parts of lubricant.The present invention introduces the suitable polyphenylene oxide of melt index, nylon66 fiber by a large amount of experiment, solves that the melt encountered in process is easily rupturable, melt mixed is uneven, and filler auxiliary agent disperses non-uniform problem.The present invention is used using color master-batch, synergistic coloring reinforcing agent collaboration, and while material keeps mechanics stability, making material integrally has extraordinary colorability, good toner dispersibility.The advantages of invention is that product colour is bright-coloured, is evenly distributed, and property retention is good, has good color homogeneity.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of polyphenyl ether material and preparation method thereof.
Background technology
Polyphenylene oxide (PPO) is nontoxic, transparent, relative density is small, has excellent mechanical strength, proof stress relaxation, creep resistant
Property, heat resistance, water resistance, water vapor resistance, dimensional stability.
In order to promote material property and class, meet the needs of final component and client, generally passes through enhancing, filling, altogether
The methods of mixed its processability of improvement and modification, it is apparent with glass fiber-reinforcing effect, resin rigidity, heat resistance, drug resistance can be improved
Moral character, electric property and weatherability.
With continually developing for application, people's polyphenylene ether propose higher, more specifically require, for example, people for
The color of product has more pursuits, and this requires rapidoprints to have the advantages that easy dyeing.Since toner is in enhancing system
In be very easy to the problem for color divergence unevenness occur, and due to the addition of toner be easy to cause glass and polyphenylene oxide resin it
Between interfacial separation so that the performance of material declines apparent.Therefore, a kind of bright-coloured fiberglass reinforced polyphenyl ether material of exploitation is to polyphenyl
The evenly dispersed method of the modification technology and pigment of ether is to the resultant performance enhancements of Noryl, technological improvement and practical application
It is of great significance.
Invention content
The object of the present invention is to provide a kind of polyphenyl ether materials and preparation method thereof.
In order to achieve the object of the present invention, the present invention provides a kind of polyphenyl ether materials, are made by weight by following components
It is standby to form:
Further scheme, the polyphenylene oxide are that melt index is 8-10g/10min;Nylon66 fiber melt index is 12-15g/
10min;
The glass fibre is a diameter of non-twist coarse sand of 10 μm of alkali-free;The toughener is that maleic anhydride is grafted second
Alkene copolymer.
The synergistic coloring reinforcing agent is inorganic crystal whisker.
The inorganic crystal whisker is ZnOw, wollastonite whisker with 10:The scalemic thereof of 1 (mass ratio).
The color master-batch is made of by weight following components:
99 parts of polyphenylene oxide
0-25 parts of titanium dioxide
0-2 parts of blue or green blue
0-2 parts of dark green
0-5 parts of titanium yellow powder
0.01-1 parts of carbon black
0-2 parts of iron oxide red.
The carbon black is activating surface free flowing black.
The antioxidant is Si [β-(3,5- di-tert-butyl-hydroxy phenyl) Bing Suan ]Pentaerythritol ester and three (2,4-
Di-tert-butyl-phenyl) phosphite ester mixture;The lubricant is silicone powder.
Another goal of the invention of the present invention is to provide a kind of preparation method of polyphenyl ether material comprising following steps:
Weigh dried following components:42-82 parts of polyphenylene oxide, 1-5 parts of nylon66 fiber, 25-30 parts of glass fibre, toughening
3-10 parts of agent, synergistic colour 3-10 parts of reinforcing agent, 0.5-5 parts of color master-batch, 0.1-0.5 parts of antioxidant, lubricant 0.1-1.0
Part;Then the polyphenylene oxide weighed up, nylon66 fiber, toughener, synergistic coloring reinforcing agent, color master-batch, antioxidant, lubricant are passed through
2~10min is mixed with 600r/min in high-speed mixer;The raw material mixed is added in double screw extruder, glass fibers
Dimension is added from glass fiber opening, is granulated through melting extrusion, and polyphenyl ether material is made;One area's temperature of the double screw extruder is 260-
270 DEG C, two area's temperature are 270-280 DEG C, and three area's temperature are 280-290 DEG C, and four area's temperature are 290 DEG C, and five area's temperature are 290-
300 DEG C, six area's temperature are 290 DEG C;Twin-screw engine speed is 250-500rpm.
The preparation method of further scheme, the color master-batch includes the following steps:
By 99 parts of polyphenylene oxide, 0-25 parts of titanium dioxide, 0-2 parts of blue or green blue, 0-2 parts of dark green, 0-5 parts of titanium yellow powder, carbon black
0.01-1 parts, 0-2 parts of iron oxide red is added high-speed mixer and is uniformly mixed, and then extruding pelletization obtains in double screw extruder
Masterbatch;The processing conditions of wherein double screw extruder is:One area's temperature is 260-270 DEG C, and two area's temperature are 270-280 DEG C,
Three area's temperature are 280-290 DEG C, and four area's temperature are 290 DEG C, and five area's temperature are 290-300 DEG C, and six area's temperature are 290 DEG C;Double spiral shells
Bar engine speed is 250-500rpm.
Beneficial effects of the present invention:
The present invention introduces the suitable polyphenylene oxide of melt index, nylon66 fiber, solves in process by a large amount of experiment
In the melt that encounters is easily rupturable, melt mixed is uneven, filler auxiliary agent disperses non-uniform problem.
The present invention is used using color master-batch, synergistic coloring reinforcing agent collaboration, and material keeps the same of mechanics stability
When, making material integrally has extraordinary colorability, good toner dispersibility.The advantages of invention is that product colour is bright-coloured,
It is evenly distributed, property retention is good, has good color homogeneity.
Specific implementation mode
The following describes the present invention further through the description of specific embodiments, but this is not the limit to the present invention
System, those skilled in the art's basic thought according to the present invention can make various modifications or improvements, but without departing from this
The basic thought of invention, is all within the scope of the present invention.
Polyphenylene oxide is that melt index is 8-10g/10min;
Nylon66 fiber melt index is 12-15g/10min;
Glass fibre is a diameter of non-twist coarse sand of 10 μm of alkali-free;
Synergistic coloring reinforcing agent is ZnOw, wollastonite whisker with 10:The scalemic thereof of 1 (mass ratio).
Testing standard:
| Physical property | Test method |
| Tensile strength | ASTM D638 |
| Izod notch impact strengths (izodtest) | ASTM D256 |
| Bending strength | ASTM D790 |
| Bending modulus | ASTM D790 |
| Toner disperses (tinting strength, tinting power) grade | UL94 is estimated |
Embodiment 1
(1) preparation of color master-batch:By 99 parts of polyphenylene oxide, 1 part of carbon black is added high-speed mixer and is uniformly mixed, then exists
Extruding pelletization obtains color master-batch in double screw extruder;The processing conditions of wherein double screw extruder is:One area's temperature is 260
DEG C, two area's temperature are 270 DEG C, and three area's temperature are 280 DEG C, and four area's temperature are 290 DEG C, and five area's temperature are 290 DEG C, and six area's temperature are
290℃;Twin-screw engine speed is 300rpm.
(2) dried following components is weighed by mass parts:62 parts of polyphenylene oxide, 1 part of nylon66 fiber, 25 parts of glass fibre increase
Tough dose 5 parts, synergistic colours 5 parts of reinforcing agent, 1 part of color master-batch, 0.5 part of antioxidant, 0.5 part of lubricant;The polyphenyl that will be weighed up again
Ether, nylon66 fiber, toughener, synergistic coloring reinforcing agent, color master-batch, antioxidant and lubricant are mixed equal by high-speed mixer
It is even, speed of agitator 600r/min, 2~10min of incorporation time;Then the raw material mixed is added to double screw extruder
In, then by glass fibre from glass fiber opening be added, be granulated through melting extrusion, be made polyphenyl ether material.The processing of double screw extruder
Condition is:One area's temperature is 260 DEG C, and two area's temperature are 270 DEG C, and three area's temperature are 280 DEG C, and four area's temperature are 290 DEG C, five area's temperature
Degree is 290 DEG C, and six area's temperature are 290 DEG C;Twin-screw engine speed is 300rpm.
Embodiment 2
(1) preparation of color master-batch:By 99 parts of polyphenylene oxide, 25 parts of titanium dioxide, 2 parts of blue or green blue, 2 parts of dark green, titanium yellow powder 5
Part, 0.01 part of carbon black, 2 parts of iron oxide red is added high-speed mixer and is uniformly mixed, and then extruding pelletization obtains in double screw extruder
Color master-batch.The processing conditions of double screw extruder is:One area's temperature is 260 DEG C, and two area's temperature are 270 DEG C, and three area's temperature are
280 DEG C, four area's temperature are 290 DEG C, and five area's temperature are 290 DEG C, and six area's temperature are 290 DEG C;Twin-screw engine speed is 300rpm.
(2) preparation of polyphenyl ether material:Dried following components is weighed by mass parts:62 parts of polyphenylene oxide, nylon66 fiber 5
Part, 25 parts of glass fibre, 5 parts of toughener, synergistic 5 parts of reinforcing agent of coloring, 3 parts of color master-batch, 0.1 part of antioxidant, lubricant 0.5
Part;The polyphenylene oxide weighed up, nylon66 fiber, toughener, synergistic coloring reinforcing agent, color master-batch, antioxidant, lubricant are passed through into high speed
Mixing machine is uniformly mixed, speed of agitator 600r/min, 2~10min of incorporation time;The raw material mixed is added to twin-screw
In extruder, glass fibre is added from glass fiber opening, is granulated through melting extrusion, and bright-coloured fiberglass reinforced polyphenyl ether material is made.Double spiral shells
The processing conditions of bar extruder is:One area's temperature is 260 DEG C, and two area's temperature are 270 DEG C, and three area's temperature are 280 DEG C, four area's temperature
It it is 290 DEG C, five area's temperature are 290 DEG C, and six area's temperature are 290 DEG C;Twin-screw engine speed is 300rpm..
Embodiment 3
(1) preparation of color master-batch:By 99 parts of polyphenylene oxide, 10 parts of titanium dioxide, 0.5 part of dark green, 1.0 parts of iron oxide red, carbon black
0.01 part of addition high-speed mixer is uniformly mixed, and then extruding pelletization obtains color master-batch in double screw extruder.Twin-screw
The processing conditions of extruder is:One area's temperature is 260 DEG C, and two area's temperature are 270 DEG C, and three area's temperature are 280 DEG C, and four area's temperature are
290 DEG C, five area's temperature are 290 DEG C, and six area's temperature are 290 DEG C;Twin-screw engine speed is 300rpm.
(2) preparation of polyphenyl ether material:Dried following components is weighed by mass parts:42 parts of polyphenylene oxide, nylon66 fiber 3
Part, 30 parts of glass fibre, 3 parts of toughener, synergistic 10 parts of reinforcing agent of coloring, 5 parts of color master-batch, 0.5 part of antioxidant, lubricant
1.0 part;The polyphenylene oxide weighed up, nylon66 fiber, toughener, synergistic coloring reinforcing agent, color master-batch, antioxidant, lubricant are passed through
High-speed mixer is uniformly mixed, speed of agitator 600r/min, 2~10min of incorporation time;The raw material mixed is added to double
In screw extruder, glass fibre is added from glass fiber opening, is granulated through melting extrusion, and bright-coloured fiberglass reinforced polyphenyl ether material is made.
The processing conditions of double screw extruder is:One area's temperature is 260 DEG C, and two area's temperature are 270 DEG C, and three area's temperature are 280 DEG C, 4th area
Temperature is 290 DEG C, and five area's temperature are 290 DEG C, and six area's temperature are 290 DEG C;Twin-screw engine speed is 300rpm.
Embodiment 4
(1) preparation of color master-batch:By 99 parts of polyphenylene oxide, 10 parts of titanium dioxide, 2.5 parts of titanium yellow powder, 0.5 part of iron oxide red, carbon black
0.01 part of addition high-speed mixer is uniformly mixed, and then extruding pelletization obtains color master-batch in double screw extruder.Twin-screw
The processing conditions of extruder is:One area's temperature is 260 DEG C, and two area's temperature are 270 DEG C, and three area's temperature are 280 DEG C, and four area's temperature are
290 DEG C, five area's temperature are 290 DEG C, and six area's temperature are 290 DEG C;Twin-screw engine speed is 300rpm.
(2) preparation of polyphenyl ether material:Dried following components is weighed by mass parts:82 parts of polyphenylene oxide, nylon66 fiber 5
Part, 30 parts of glass fibre, 10 parts of toughener, synergistic 3 parts of reinforcing agent of coloring, 0.5 part of color master-batch, 0.3 part of antioxidant, lubricant
0.1 part;The polyphenylene oxide weighed up, nylon66 fiber, toughener, synergistic coloring reinforcing agent, color master-batch, antioxidant, lubricant are passed through
High-speed mixer is uniformly mixed, speed of agitator 600r/min, 2~10min of incorporation time;The raw material mixed is added to double
In screw extruder, glass fibre is added from glass fiber opening, is granulated through melting extrusion, and bright-coloured fiberglass reinforced polyphenyl ether material is made.
The processing conditions of double screw extruder is:One area's temperature is 260 DEG C, and two area's temperature are 270 DEG C, and three area's temperature are 280 DEG C, 4th area
Temperature is 290 DEG C, and five area's temperature are 290 DEG C, and six area's temperature are 290 DEG C;Twin-screw engine speed is 300rpm.
Comparative example 1
With embodiment 1, difference lies in toner auxiliary agents not to make color master-batch
Dried following components is weighed by mass parts:62.99 parts of polyphenylene oxide, 1 part of nylon66 fiber, 25 parts of glass fibre increase
Tough dose 5 parts, synergistic colours 5 parts of reinforcing agent, 0.01 part of carbon black, 0.5 part of antioxidant, 0.5 part of lubricant;By the polyphenylene oxide weighed up,
Nylon66 fiber, toughener, synergistic coloring reinforcing agent, carbon black, antioxidant, lubricant are uniformly mixed by high-speed mixer, and stirring turns
Speed is 600r/min, 2~10min of incorporation time;The raw material mixed is added in double screw extruder, glass fibre is from glass
Fine mouth is added, is granulated through melting extrusion, and bright-coloured fiberglass reinforced polyphenyl ether material is made.The processing conditions of double screw extruder is:
One area's temperature is 260 DEG C, and two area's temperature are 270 DEG C, and three area's temperature are 280 DEG C, and four area's temperature are 290 DEG C, and five area's temperature are 290
DEG C, six area's temperature are 290 DEG C;Twin-screw engine speed is 300rpm.
Comparative example 2
With embodiment 1, difference lies in synergistic is not added to colour reinforcing agent:
(1) preparation of color master-batch:By 99 parts of polyphenylene oxide, 1 part of carbon black is added high-speed mixer and is uniformly mixed, then exists
Extruding pelletization obtains color master-batch in double screw extruder.The processing conditions of double screw extruder is:One area's temperature is 260 DEG C,
Two area's temperature are 270 DEG C, and three area's temperature are 280 DEG C, and four area's temperature are 290 DEG C, and five area's temperature are 290 DEG C, and six area's temperature are 290
℃;Twin-screw engine speed is 300rpm.
(2) preparation of polyphenyl ether material:Dried following components is weighed by mass parts:62 parts of polyphenylene oxide, nylon66 fiber 1
Part, 25 parts of glass fibre, 5 parts of toughener, 1 part of color master-batch, 0.5 part of antioxidant, 0.5 part of lubricant are mixed by high-speed mixer
Close uniform, speed of agitator 600r/min, 2~10min of incorporation time;The raw material mixed is added to double screw extruder
In, glass fibre is added from glass fiber opening, is granulated through melting extrusion, and bright-coloured fiberglass reinforced polyphenyl ether material is made.Twin-screw extrusion
The processing conditions of machine is:One area's temperature is 260 DEG C, and two area's temperature are 270 DEG C, and three area's temperature are 280 DEG C, and four area's temperature are 290
DEG C, five area's temperature are 290 DEG C, and six area's temperature are 290 DEG C;Twin-screw engine speed is 300rpm.
Comparative example 3
With embodiment 1, difference lies in toner auxiliary agents not to make color master-batch, synergistic is not added to colour reinforcing agent:
Dried following components is weighed by mass parts:62.99 parts of polyphenylene oxide, 1 part of nylon66 fiber, 25 parts of glass fibre increase
Tough dose 5 parts, 0.01 part of carbon black, 0.5 part of antioxidant, 0.5 part of lubricant;By the polyphenylene oxide weighed up, nylon66 fiber, toughener, carbon black,
Antioxidant, lubricant are uniformly mixed by high-speed mixer, speed of agitator 600r/min, 2~10min of incorporation time;It will mix
The raw material got togather is added in double screw extruder, and glass fibre is added from glass fiber opening, is granulated through melting extrusion, and bright-coloured glass is made
Fibre enhancing polyphenyl ether material.The processing conditions of double screw extruder is:One area's temperature be 260 DEG C, two area's temperature be 270 DEG C, three
Area's temperature is 280 DEG C, and four area's temperature are 290 DEG C, and five area's temperature are 290 DEG C, and six area's temperature are 290 DEG C;Twin-screw engine speed
For 300rpm.
Fiberglass reinforced polyphenyl ether material prepared by above-described embodiment 1-4 and comparative example 1-3 is respectively according to GB testing standards
It is molded into corresponding batten, is tested after then being placed 24 hours in the environment of 23 ± 2 DEG C, 50 ± 5% relative humidity, performance
Test is as follows:
1 performance data of table
It can be seen that the present invention is by improving toner auxiliary agent from the performance comparison of upper table 1 embodiment 1-4 and comparative example 1-3
For color master-batch form, while the addition of synergistic coloring reinforcing agent, in the mechanical property for effectively keeping fiberglass reinforced polyphenyl ether product
Can while, be conducive to the coloring of color master-batch, make that product colour is bright-coloured, is evenly distributed.
Claims (10)
1. a kind of polyphenyl ether material, which is characterized in that be prepared by weight by following components:
42-82 parts of polyphenylene oxide,
1-5 parts of nylon66 fiber,
25-30 parts of glass fibre,
3-10 parts of toughener,
Synergistic colours 3-10 parts of reinforcing agent,
0.5-5 parts of color master-batch,
0.1-0.5 parts of antioxidant,
0.1-1.0 parts of lubricant.
2. a kind of polyphenyl ether material according to claim 1, which is characterized in that the color master-batch is by following components by weight
Measure part composition:
100 parts of polyphenylene oxide,
0-25 parts of titanium dioxide,
0-2 parts of blue or green blue,
0-2 parts of dark green,
0-5 parts of titanium yellow powder,
0.01-1 parts of carbon black,
0-2 parts of iron oxide red.
3. a kind of polyphenyl ether material according to claim 1, it is characterised in that:The melt index of the polyphenylene oxide is 8-
10g/10min。
4. a kind of polyphenyl ether material according to claim 1, it is characterised in that:The melt index of the nylon66 fiber is 12-
15g/10min。
5. a kind of polyphenyl ether material according to claim 1, it is characterised in that:The glass fibre is a diameter of 10 μm
The non-twist coarse sand of alkali-free;The toughener is maleic anhydride grafted ethene copolymer;The synergistic coloring reinforcing agent is inorganic crystal whisker.
6. a kind of polyphenyl ether material according to claim 5, it is characterised in that:The inorganic crystal whisker be ZnOw,
Wollastonite whisker is with 10:1(Mass ratio)The mixture that mixes of ratio.
7. a kind of polyphenyl ether material according to claim 2, it is characterised in that:The carbon black is the dustless charcoal of activating surface
It is black.
8. a kind of polyphenyl ether material according to claim 1, it is characterised in that:The antioxidant is Si [β-(3,5- bis- uncles
Butyl -4- hydroxy phenyls)Bing Suan ]The mixture of pentaerythritol ester and three (2,4- di-tert-butyl-phenyl) phosphite esters;Described
Lubricant is silicone powder.
9. the method for preparing claim 1 ~ 8 any one of them polyphenyl ether material, which is characterized in that include the following steps:
Weigh dried following components:42-82 parts of polyphenylene oxide, 1-5 parts of nylon66 fiber, 25-30 parts of glass fibre, toughener 3-
10 parts, synergistic colours 3-10 parts of reinforcing agent, 0.5-5 parts of color master-batch, 0.1-0.5 parts of antioxidant, 0.1-1.0 parts of lubricant;So
The polyphenylene oxide weighed up, nylon66 fiber, toughener, synergistic coloring reinforcing agent, color master-batch, antioxidant and lubricant are passed through into high speed afterwards
2~10min is mixed with 600r/min in mixing machine;The raw material mixed is added in double screw extruder, glass fibre from
Glass fiber opening is added, is granulated through melting extrusion, and polyphenyl ether material is made;One area's temperature of the double screw extruder is 260-270 DEG C,
Two area's temperature are 270-280 DEG C, and three area's temperature are 280-290 DEG C, and four area's temperature are 290 DEG C, and five area's temperature are 290-300 DEG C,
Six area's temperature are 290 DEG C;Twin-screw engine speed is 250-500rpm.
10. a kind of preparation method of polyphenyl ether material according to claim 9, which is characterized in that the color master-batch
Preparation method includes the following steps:
By 99 parts of polyphenylene oxide, 0-25 parts of titanium dioxide, 0-2 parts of blue or green blue, 0-2 parts of dark green, 0-5 parts of titanium yellow powder, carbon black 0.01-1
Part, 0-2 parts of iron oxide red is added high-speed mixer and is uniformly mixed, and then extruding pelletization obtains color master-batch in double screw extruder;
The processing conditions of wherein double screw extruder is:One area's temperature is 260-270 DEG C, and two area's temperature are 270-280 DEG C, three area's temperature
It it is 280-290 DEG C, four area's temperature are 290 DEG C, and five area's temperature are 290-300 DEG C, and six area's temperature are 290 DEG C;Twin-screw host turns
Speed is 250-500rpm.
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| CN201710235278.0A CN108690343A (en) | 2017-04-11 | 2017-04-11 | A kind of polyphenyl ether material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110354583A (en) * | 2019-07-15 | 2019-10-22 | 安徽东大滤材有限公司 | A kind of wear-resisting filter material material and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005226020A (en) * | 2004-02-16 | 2005-08-25 | Toray Ind Inc | Masterbatch resin composition for coloring polyoxymethylene resin and colored polyoxymethylene resin composition |
| CN102492293A (en) * | 2011-12-04 | 2012-06-13 | 上海金发科技发展有限公司 | Low temperature resistance stained glass fiber reinforcement nylon 6 and preparation method thereof |
| CN102585478A (en) * | 2011-01-14 | 2012-07-18 | 合肥杰事杰新材料股份有限公司 | Toughened polyphenyl ether and nylon alloy and preparation method for toughened polyphenyl ether and nylon alloy |
| CN103160108A (en) * | 2011-12-09 | 2013-06-19 | 上海杰事杰新材料(集团)股份有限公司 | Halogen-free flame-retardant polyphenylene oxide/polyamide 6 blend alloy as well as preparation and application for same |
| CN103160062A (en) * | 2011-12-16 | 2013-06-19 | 合肥杰事杰新材料股份有限公司 | Polyoxymethylene masterbatch and preparation method thereof |
| CN103709489A (en) * | 2012-09-29 | 2014-04-09 | 青岛欣展塑胶有限公司 | General white master batch and preparation method thereof |
| CN103937072A (en) * | 2014-04-29 | 2014-07-23 | 浙江普耐姆塑业股份有限公司 | Composite granule colored high-density polyethylene material and preparation method thereof |
| CN103980692A (en) * | 2014-05-22 | 2014-08-13 | 深圳市沃特新材料股份有限公司 | Polyphenyl ether resin alloy material for pillow inner framework of massage chair and preparation method thereof |
| CN105885324A (en) * | 2016-04-21 | 2016-08-24 | 上海宏盎实业发展有限公司 | Universal masterbatch and preparation method thereof |
-
2017
- 2017-04-11 CN CN201710235278.0A patent/CN108690343A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005226020A (en) * | 2004-02-16 | 2005-08-25 | Toray Ind Inc | Masterbatch resin composition for coloring polyoxymethylene resin and colored polyoxymethylene resin composition |
| CN102585478A (en) * | 2011-01-14 | 2012-07-18 | 合肥杰事杰新材料股份有限公司 | Toughened polyphenyl ether and nylon alloy and preparation method for toughened polyphenyl ether and nylon alloy |
| CN102492293A (en) * | 2011-12-04 | 2012-06-13 | 上海金发科技发展有限公司 | Low temperature resistance stained glass fiber reinforcement nylon 6 and preparation method thereof |
| CN103160108A (en) * | 2011-12-09 | 2013-06-19 | 上海杰事杰新材料(集团)股份有限公司 | Halogen-free flame-retardant polyphenylene oxide/polyamide 6 blend alloy as well as preparation and application for same |
| CN103160062A (en) * | 2011-12-16 | 2013-06-19 | 合肥杰事杰新材料股份有限公司 | Polyoxymethylene masterbatch and preparation method thereof |
| CN103709489A (en) * | 2012-09-29 | 2014-04-09 | 青岛欣展塑胶有限公司 | General white master batch and preparation method thereof |
| CN103937072A (en) * | 2014-04-29 | 2014-07-23 | 浙江普耐姆塑业股份有限公司 | Composite granule colored high-density polyethylene material and preparation method thereof |
| CN103980692A (en) * | 2014-05-22 | 2014-08-13 | 深圳市沃特新材料股份有限公司 | Polyphenyl ether resin alloy material for pillow inner framework of massage chair and preparation method thereof |
| CN105885324A (en) * | 2016-04-21 | 2016-08-24 | 上海宏盎实业发展有限公司 | Universal masterbatch and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 武鹏 等: "纳米硫酸钡对高浓度聚烯烃色母粒色彩性能的影响", 《塑料科技》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110354583A (en) * | 2019-07-15 | 2019-10-22 | 安徽东大滤材有限公司 | A kind of wear-resisting filter material material and preparation method thereof |
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