CN106349605A - Fluorescence wood plastic decorative board and preparation method - Google Patents
Fluorescence wood plastic decorative board and preparation method Download PDFInfo
- Publication number
- CN106349605A CN106349605A CN201610748539.4A CN201610748539A CN106349605A CN 106349605 A CN106349605 A CN 106349605A CN 201610748539 A CN201610748539 A CN 201610748539A CN 106349605 A CN106349605 A CN 106349605A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
This invention discloses a kind of fluorescence wood plastic decorative board and preparing method thereof, the key technical point is adopting organic modification treated fluorescence material as luminous pigment, and adding it to wood plastic compound material, then plasticize and mix and fix pattern by mold, then the fluorescence wood plastic decorative board is got. This preparing method can solve the compatibility of inorganic luminous pigment and wood plastic, and the blackening problem of luminous pigment during wood plasticized material process, the prepared fluorescence wood plastic decorative board has even tint, good mechanical performance and luminous performance, and can be widely applied to building indoor and outdoor decoration for weak light indication and beautification.
Description
Technical field
The present invention relates to a kind of wood-plastic decorative board and preparation method thereof is and in particular to a kind of fluorescent wood-plastic decorative panel and its system
Preparation Method, belongs to wood plastic composite technical field.
Background technology
Due to it, fluorescent material has the characteristics that "dead", energy-saving and environmental protection application in people's life is more and more, mesh
The major domain of its industrial applications front is plastics and paint field, is also rarely reported in wood plastic composite field.China is specially
Sharp (cn 201410309580) is lighted with after light accumulation type luminous pigment, pa6, oxidant, ultraviolet (UV) resistant agent blending pelletize
Master batch, luminous master batch can be separately added into top layer or the bottom of Wood-plastic material, and light accumulation type luminous Wood-plastic material is finally obtained.But should
In method preparation process, can there is inconsistent problem when being blended in the luminous pigment as inorganic material and organic system, prepared
Plastic products luminous can mechanical property drastically declines with increasing of luminescent powder addition.Meanwhile, plastified in mixing
In journey, luminous pigment contact with process equipment interior metal device and friction can lead to luminous pigment blackening, and then have a strong impact on
The luminescent properties of wood plastic product and glossiness.
Content of the invention
It is an object of the invention to fluorescent material according to present in prior art and organic system poor compatibility, luminous material
In the material course of processing, the shortcoming of easily blackening, invents a kind of fluorescent wood-plastic decorative panel and preparation method thereof, the method can be prepared
Uniform color, and there is the fluorescent wood-plastic decorative panel of good luminous performance and mechanical property, play low light level instruction and decoration
Effect.
The technical scheme is that
A kind of fluorescent wood-plastic decorative panel it is characterised in that: will also have luminous face in the composite raw material of wood-plastic decorative board
Material, described luminous pigment is the fluorescent material using organically-modified process.
Described luminous pigment is more than aluminates system, silicate systems, phosphate system, oxysulfide system or rare earth length
One or more of brightness fluorescent material.
Described organically-modified processing method refers to using various modified additives, using method pair physically and/or chemically
The thing that is modified is processed, and described physical method includes but is not limited to: using modified additive, the thing that is modified is made by hydrogen bond
With or electrostatic interaction implement physics cladding, thus changing the be modified surface of thing and interface physico-chemical property；Described chemical method
Including but not limited to: can occur the modified additive of the functional group of chemical reaction that the thing that is modified is passed through with the thing that is modified using carrying
The mode of chemical bonding implements chemical modification, thus changing surface and the interface physico-chemical property of the thing that is modified.
A kind of preparation method of fluorescent wood-plastic decorative panel, using organically-modified process fluorescent material as luminous pigment,
Add in the composite raw material of wood-plastic decorative board, after mixing, process through fusion plastification equipment, oral mould sizing, obtain final product.
Described luminous pigment is more than aluminates system, silicate systems, phosphate system, oxysulfide system or rare earth length
One or more of brightness fluorescent material.
Described organically-modified processing method refers to using various modified additives, using method physically or chemically to being changed
Property thing processed, described physical method includes but is not limited to: using modified additive to be modified thing pass through hydrogen bond action or
Electrostatic interaction implements physics cladding, thus changing surface and the interface physico-chemical property of the thing that is modified；Described chemical method includes
But it is not limited to: using with the modified additive that with the thing that is modified, the functional group of chemical reaction can occur, chemistry is passed through to the thing that is modified
The mode of bonding implements chemical modification, thus changing surface and the interface physico-chemical property of the thing that is modified.
Preferably, described organically-modified processing method is: take alcohols solvent to add in reactor, fluorescent material is added,
Stirring, adds chemical bonding or chelating class coupling agent, is progressively heated up to 70～90 DEG C, takes, after stirring, the fluorescent material handled well
Go out, be dried and remove solvent, grind, obtain final product the fluorescent material of organically-modified process.
Preferably, described coupling agent is: silane coupler and/or titanate coupling agent and/or zirconium class coupling agent,
And/or stannum class coupling agent.
Preferably, described fusion plastification equipment includes but is not limited to mill, banbury, twin screw, Single screw extrusion
Machine；The temperature of described fusion plastification is 170 210 DEG C.
Described raw material is: pvc resin, calcium powder, wood powder, stabilizer, compatilizer, foaming agent, lubricant；Or pe resin,
Pulvis Talci, wood powder, compatilizer, lubricant, UV absorbent；Or pp resin, Pulvis Talci, wood powder, compatilizer, lubricant, purple
Ultraviolet absorbers；Or pe resin, Pulvis Talci, wood powder, compatilizer, lubricant, UV absorbent；Or pvc resin, Pulvis Talci,
Wood powder, compatilizer, lubricant.
Beneficial effects of the present invention:
It is processed with organic system poor compatibility, luminescent material that the present invention solves fluorescent material present in prior art
The shortcoming of easy blackening in journey, invents a kind of fluorescent wood-plastic decorative panel and preparation method thereof, the method can prepare uniform color,
And there is the fluorescent wood-plastic decorative panel of good luminous performance and mechanical property, play low light level instruction and the effect of decoration.
Organically-modified luminous pigment used in the present invention has good surface hydrophobicity effect, not only increases inorganic
The compatibility between light powder body and Wood-plastic material, makes material maintain preferable mechanical property；And can be processed in Wood-plastic material
Intercept the direct friction between luminescent powder and metal in journey, and then be prevented effectively from the problem of luminescent powder blackening.
The preparation method process is simple of luminous wood-plastic decorative board of the present invention, fundamentally solves luminous pigment and wood
The problem of incompatible problem and luminescent powder blackening between moulding material, has expanded category and the application neck of fluorescent material
Domain, has broad application prospects.
Through the luminous pigment after organically-modified process, itself and wood can be improved while keeping luminescent material luminescent properties
Mould the compatibility of matrix material so that Wood-plastic material mechanical property will not decline to a great extent because of the addition of luminescent material, simultaneously
In mixing plasticizing process, luminous pigment through organically-modified process is due to the presence of organic treating agents modified layer, it is to avoid send out
The contact with process equipment interior metal device of delustering pigment body and friction and lead to luminous pigment blackening the drawbacks of.
Specific embodiment
The present invention can be expressly understood further by the specific embodiment of invention now given below, but following enforcement
Example is not limitation of the invention.Following examples are merely to illustrate technical scheme and unrestricted, this area
It will be appreciated by the skilled person that technical scheme can be modified or equivalent, without deviating from skill of the present invention
The objective of art scheme and scope, it all should be covered in the middle of scope of the presently claimed invention.
A kind of embodiment 1: fluorescent wood-plastic decorative panel
Raw materials used and weight is:
Pvc resin 100kg
Calcium powder 50kg
Wood powder 20kg
Stabilizer 4kg
Compatilizer 8kg
Foaming agent 3kg
Lubricant 3kg
Organically-modified type strontium aluminate fluorescent material 2kg；
After the raw materials such as wood powder, pvc resin-oatmeal are tentatively mixed with organically-modified strontium aluminate fluorescent material, twin screw is added to squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, oral mould extrusioning shaping is wood-plastic decorative board afterwards.Obtain body colour
Homogeneous, be in yellowish green fluorescent wood-plastic decorative panel, its tensile strength is good, smooth surface, and illumination effect is good.
A kind of embodiment 2: fluorescent wood-plastic decorative panel
Raw materials used and weight is:
Pe resin 100kg
Pulvis Talci 20kg
Wood powder 80kg
Compatilizer 7kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type strontium carbonate fluorescent material 2kg；
After the raw materials such as wood powder, pe resin-oatmeal are tentatively mixed with organically-modified strontium carbonate fluorescent material, twin screw is added to squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, oral mould extrusioning shaping is wood-plastic decorative board afterwards.Obtain body colour
Homogeneous, greeny fluorescent wood-plastic decorative panel, its tensile strength is good, smooth surface, and illumination effect is good.
A kind of embodiment 3: fluorescent wood-plastic decorative panel
Raw materials used and weight is:
Pp resin 100kg
Pulvis Talci 10kg
Wood powder 60kg
Compatilizer 8kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type zinc silicate fluorescent material 1.5kg；
After the raw materials such as wood powder, pp resin-oatmeal are tentatively mixed with organically-modified silicic acid zinc fluorescent material, twin screw is added to squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, oral mould extrusioning shaping is wood-plastic decorative board afterwards.Obtain body colour
Homogeneous, be in yellowish green fluorescent wood-plastic decorative panel, its tensile strength is good, smooth surface, and illumination effect is good.
A kind of embodiment 4: fluorescent wood-plastic decorative panel
Raw materials used and weight is:
Pvc resin 100kg
Pulvis Talci 10kg
Wood powder 50kg
Compatilizer 8kg
Lubricant 3kg
Organically-modified type zinc-cadmium sulfide fluorescent material 1.5kg；
After the raw materials such as wood powder, pvc resin-oatmeal are tentatively mixed with organically-modified zinc-cadmium sulfide fluorescent material, add twin screw
In extruder hopper, control screw rod to head temperature at 190 DEG C, oral mould extrusioning shaping is wood-plastic decorative board afterwards.Obtain body
Color is homogeneous, be in yellowish green fluorescent wood-plastic decorative panel, and its tensile strength is good, smooth surface, and illumination effect is good.
A kind of embodiment 5: fluorescent wood-plastic decorative panel
Raw materials used and weight is:
Pe resin 100kg
Pulvis Talci 10kg
Wood powder 50kg
Compatilizer 8kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type calcium halophosphate activated by antimony andmanganese fluorescent material 1.5kg；
After the raw materials such as wood powder, pvc resin-oatmeal are tentatively mixed with organically-modified calcium halophosphate activated by antimony andmanganese fluorescent material, add comminutor
Pelletize, pellet is added single screw extrusion machine hopper, controls screw rod to head temperature at 185 DEG C, afterwards oral mould extrusioning shaping
For wood-plastic decorative board.Obtain that body colour is homogeneous, be in saffron fluorescent wood-plastic decorative panel, its tensile strength is good, and smooth surface is sent out
Light effect is good.
A kind of embodiment 6: fluorescent wood-plastic decorative panel
Raw materials used and weight is:
Pvc resin 100kg
Calcium powder 50kg
Wood powder 20kg
Stabilizer 4kg
Compatilizer 8kg
Foaming agent 3kg
Lubricant 3kg
Organically-modified type strontium aluminate fluorescent material 2kg；
Organically-modified process is: takes anhydrous ethanol solvent to add in reactor, strontium aluminate fluorescent material is added, stirring
0.5h, add chemical bonding coupling agent, be progressively heated up to 70～90 DEG C, stir 2h, after by the fluorescent material handled well take out, do
Dry removing solvent, grinds, obtains final product the fluorescent material of organically-modified process；
After the raw materials such as wood powder, pvc resin-oatmeal are tentatively mixed with organically-modified strontium aluminate fluorescent material, twin screw is added to squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, oral mould extrusioning shaping is wood-plastic decorative board afterwards.Obtain body colour
Homogeneous, be in yellowish green fluorescent wood-plastic decorative panel, its tensile strength is good, smooth surface, and illumination effect is good.
A kind of embodiment 7: fluorescent wood-plastic decorative panel
Raw materials used and weight is:
Pe resin 100kg
Pulvis Talci 20kg
Wood powder 80kg
Compatilizer 7kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type strontium carbonate fluorescent material 2kg；
Organically-modified process is: takes absolute methanol solvent to add in reactor, strontium carbonate fluorescent material is added, stirring
0.5h, adds chelating class coupling agent, is progressively heated up to 70～90 DEG C, takes out, after stirring 1h, the fluorescent material handled well, is dried
Remove solvent, grind, obtain final product the fluorescent material of organically-modified process；
After the raw materials such as wood powder, pe resin-oatmeal are tentatively mixed with organically-modified strontium carbonate fluorescent material, twin screw is added to squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, oral mould extrusioning shaping is wood-plastic decorative board afterwards.Obtain body colour
Homogeneous, greeny fluorescent wood-plastic decorative panel, its tensile strength is good, smooth surface, and illumination effect is good.
A kind of embodiment 8: fluorescent wood-plastic decorative panel
Raw materials used and weight is:
Pp resin 100kg
Pulvis Talci 10kg
Wood powder 60kg
Compatilizer 8kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type zinc silicate fluorescent material 1.5kg；
Organically-modified process is: takes anhydrous propyl alcohol solvent to add in reactor, zinc silicate fluorescent material is added, stirring
0.5h, adds silane coupler, is progressively heated up to 70～90 DEG C, takes out, after stirring 3h, the fluorescent material handled well, drying removes
Remove solvent, grind, obtain final product the fluorescent material of organically-modified process；
After the raw materials such as wood powder, pp resin-oatmeal are tentatively mixed with organically-modified silicic acid zinc fluorescent material, twin screw is added to squeeze
Go out in machine hopper, control screw rod to head temperature at 190 DEG C, oral mould extrusioning shaping is wood-plastic decorative board afterwards.Obtain body colour
Homogeneous, be in yellowish green fluorescent wood-plastic decorative panel, its tensile strength is good, smooth surface, and illumination effect is good.
A kind of embodiment 9: fluorescent wood-plastic decorative panel
Raw materials used and weight is:
Pvc resin 100kg
Pulvis Talci 10kg
Wood powder 50kg
Compatilizer 8kg
Lubricant 3kg
Organically-modified type zinc-cadmium sulfide fluorescent material 1.5kg；
Organically-modified process is: takes anhydrous isopropyl alcohol solvent to add in reactor, zinc-cadmium sulfide fluorescent material is added, stirring
0.5h, adds titanate coupling agent, is progressively heated up to 70～90 DEG C, takes out, after stirring 3h, the fluorescent material handled well, is dried
Remove solvent, grind, obtain final product the fluorescent material of organically-modified process；
After the raw materials such as wood powder, pvc resin-oatmeal are tentatively mixed with organically-modified zinc-cadmium sulfide fluorescent material, add twin screw
In extruder hopper, control screw rod to head temperature at 190 DEG C, oral mould extrusioning shaping is wood-plastic decorative board afterwards.Obtain body
Color is homogeneous, be in yellowish green fluorescent wood-plastic decorative panel, and its tensile strength is good, smooth surface, and illumination effect is good.
A kind of embodiment 10: fluorescent wood-plastic decorative panel
Raw materials used and weight is:
Pe resin 100kg
Pulvis Talci 10kg
Wood powder 50kg
Compatilizer 8kg
Lubricant 3kg
UV absorbent 2kg
Organically-modified type calcium halophosphate activated by antimony andmanganese fluorescent material 1.5kg；
Organically-modified process is: take anhydrous isopropyl alcohol solvent to add in reactor, halogen calcium phosphate fluoressent powder added, stirring
0.5h, adds titanate coupling agent, is progressively heated up to 70～90 DEG C, takes out, after stirring 3h, the fluorescent material handled well, is dried
Remove solvent, grind, obtain final product the fluorescent material of organically-modified process；
After the raw materials such as wood powder, pvc resin-oatmeal are tentatively mixed with organically-modified calcium halophosphate activated by antimony andmanganese fluorescent material, add comminutor
Pelletize, pellet is added single screw extrusion machine hopper, controls screw rod to head temperature at 185 DEG C, afterwards oral mould extrusioning shaping
For wood-plastic decorative board.Obtain that body colour is homogeneous, be in saffron fluorescent wood-plastic decorative panel, its tensile strength is good, and smooth surface is sent out
Light effect is good.
Claims (10)
1. a kind of fluorescent wood-plastic decorative panel it is characterised in that: will in the composite raw material of wood-plastic decorative board also have luminous pigment,
Described luminous pigment is the fluorescent material using organically-modified process.
2. fluorescent wood-plastic decorative panel according to claim 1 it is characterised in that: described luminous pigment be aluminates system,
One or more of silicate systems, phosphate system, oxysulfide system or long afterglow fluorescent material.
3. fluorescent wood-plastic decorative panel according to claim 1 it is characterised in that: described organically-modified processing method refers to
Using various modified additives, using method physically and/or chemically, the thing that is modified is processed, described physical method includes
But it is not limited to: hydrogen bond action is passed through to the thing that is modified using modified additive or electrostatic interaction implements physics cladding, thus changing quilt
The surface of modifier and interface physico-chemical property；Described chemical method includes but is not limited to: can be sent out with the thing that is modified using carrying
The modified additive of the functional group of biochemical reaction implements chemical modification to the thing that is modified by way of chemical bonding, thus changing
Be modified the surface of thing and interface physico-chemical property.
4. a kind of preparation method of fluorescent wood-plastic decorative panel it is characterised in that: using the fluorescent material conduct of organically-modified process
Luminous pigment, adds in the composite raw material of wood-plastic decorative board, after mixing, processes through fusion plastification equipment, oral mould sizing,
Obtain final product.
5. fluorescent wood-plastic decorative panel according to claim 4 preparation method it is characterised in that: described luminous pigment be aluminum
One of silicate system, silicate systems, phosphate system, oxysulfide system or long afterglow fluorescent material or several
Kind.
6. fluorescent wood-plastic decorative panel according to claim 4 preparation method it is characterised in that: described organically-modified place
Reason method refers to, using various modified additives, using method physically and/or chemically, the thing that is modified be processed, described thing
Reason method includes but is not limited to: hydrogen bond action passed through to the thing that is modified using modified additive or electrostatic interaction implements physics cladding,
Thus changing surface and the interface physico-chemical property of the thing that is modified；Described chemical method includes but is not limited to: using with can be with
The modified additive of the functional group of the thing that is modified generation chemical reaction is implemented chemistry by way of chemical bonding to the thing that is modified and is changed
Property, thus changing surface and the interface physico-chemical property of the thing that is modified.
7. the preparation method of fluorescent wood-plastic decorative panel according to claim 4 is it is characterised in that described organically-modified place
Reason method is: takes alcohols solvent to add in reactor, fluorescent material added, stirring, and add chemical bonding or chelating class coupling agent,
Progressively it is heated up to 70～90 DEG C, after stirring, the fluorescent material handled well is taken out, be dried and remove solvent, grind, obtain final product organic changing
Property process fluorescent material.
8. fluorescent wood-plastic decorative panel according to claim 7 preparation method it is characterised in that: described coupling agent is:
Silane coupler and/or titanate coupling agent and/or zirconium class coupling agent and/or stannum class coupling agent.
9. the preparation method of fluorescent wood-plastic decorative panel according to claim 4 is it is characterised in that described fusion plastification sets
Standby including but not limited to mill, banbury, twin screw, single screw extrusion machine；The temperature of described fusion plastification is 170 210
℃.
10. the preparation method of fluorescent wood-plastic decorative panel according to claim 4 is it is characterised in that described raw material is:
Pvc resin, calcium powder, wood powder, stabilizer, compatilizer, foaming agent, lubricant；Or pe resin, Pulvis Talci, wood powder, compatilizer, profit
Lubrication prescription, UV absorbent；Or pp resin, Pulvis Talci, wood powder, compatilizer, lubricant, UV absorbent；Or pe resin, cunning
Stone powder, wood powder, compatilizer, lubricant, UV absorbent；Or pvc resin, Pulvis Talci, wood powder, compatilizer, lubricant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610748539.4A CN106349605A (en) | 2016-08-29 | 2016-08-29 | Fluorescence wood plastic decorative board and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610748539.4A CN106349605A (en) | 2016-08-29 | 2016-08-29 | Fluorescence wood plastic decorative board and preparation method |
Publications (1)
| Publication Number | Publication Date |
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| CN106349605A true CN106349605A (en) | 2017-01-25 |
Family
ID=57855666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201610748539.4A Pending CN106349605A (en) | 2016-08-29 | 2016-08-29 | Fluorescence wood plastic decorative board and preparation method |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141600A (en) * | 2017-06-22 | 2017-09-08 | 合肥易美特建材有限公司 | A kind of manufacture craft of new waterproof Wood plastic wall board |
| CN108058468A (en) * | 2018-01-16 | 2018-05-22 | 四川大学 | A kind of heat discoloration shines the preparation method of Synthetic Leather |
| CN108559053A (en) * | 2018-04-24 | 2018-09-21 | 四川大学 | The preparation method of photochromic luminous polyurethane based on long after glow luminous material and spiro-pyrans |
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|---|---|---|---|---|
| CN101486846A (en) * | 2009-02-16 | 2009-07-22 | 南京林业大学 | Method for improving compatibility of noctilucent powder in organic resin system |
| CN102408700A (en) * | 2011-09-13 | 2012-04-11 | 暨南大学 | Preparation method of long-afterglow luminescent plastic |
| CN104164082A (en) * | 2014-06-30 | 2014-11-26 | 江苏旭华圣洛迪建材有限公司 | Preparing method of light-storage type luminescent wood-plastic composite |
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2016
- 2016-08-29 CN CN201610748539.4A patent/CN106349605A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486846A (en) * | 2009-02-16 | 2009-07-22 | 南京林业大学 | Method for improving compatibility of noctilucent powder in organic resin system |
| CN102408700A (en) * | 2011-09-13 | 2012-04-11 | 暨南大学 | Preparation method of long-afterglow luminescent plastic |
| CN104164082A (en) * | 2014-06-30 | 2014-11-26 | 江苏旭华圣洛迪建材有限公司 | Preparing method of light-storage type luminescent wood-plastic composite |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141600A (en) * | 2017-06-22 | 2017-09-08 | 合肥易美特建材有限公司 | A kind of manufacture craft of new waterproof Wood plastic wall board |
| CN108058468A (en) * | 2018-01-16 | 2018-05-22 | 四川大学 | A kind of heat discoloration shines the preparation method of Synthetic Leather |
| CN108058468B (en) * | 2018-01-16 | 2019-12-20 | 四川大学 | Preparation method of temperature-sensitive color-changing luminous polyurethane synthetic leather |
| CN108559053A (en) * | 2018-04-24 | 2018-09-21 | 四川大学 | The preparation method of photochromic luminous polyurethane based on long after glow luminous material and spiro-pyrans |
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Application publication date: 20170125 |