CN102731926A - Environment-friendly low-cost composite material capable of substituting flame retardant ABS - Google Patents
Environment-friendly low-cost composite material capable of substituting flame retardant ABS Download PDFInfo
- Publication number
- CN102731926A CN102731926A CN2012101880739A CN201210188073A CN102731926A CN 102731926 A CN102731926 A CN 102731926A CN 2012101880739 A CN2012101880739 A CN 2012101880739A CN 201210188073 A CN201210188073 A CN 201210188073A CN 102731926 A CN102731926 A CN 102731926A
- Authority
- CN
- China
- Prior art keywords
- matrix material
- low cost
- environment protection
- cost matrix
- proof abs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an environment-friendly low-cost composite material capable of substituting flame retardant ABS. The composite material is composed of the following raw materials, by weight: 40-55 parts of PVC, 25-45 parts of ABS, 2-4 parts of compatilizer, 0.5-2 parts of flame retardant synergist, 6-10 parts of flow modifier, 1-3 parts of plasticizer, and 0.1-0.5 parts of antioxidant. The composite material of the present invention is low-cost and easy for molding, and has good performance.
Description
Technical field
The present invention relates to a kind of environment protection, low cost matrix material of alternative flame-proof ABS.
Background technology
There are two big technical barriers in PVC and ABS blend: 1) processing stability of PVC is poor; Reason owing to environmental protection; Can not use stabilising effect good but the lead salt and the organic tin stablizer that are restricted; And both differ greatly at processing temperature, under the fused condition, process the thermal destruction that very easily causes PVC, therefore need to solve the stable problem of PVC; 2) PVC and ABS consistency are poor.Owing to except matrix resin, also have stablizer, lubricant etc. in the system, increase both uncompatibilities, therefore need to solve the mutual appearance problem of matrix resin.
Summary of the invention
The environment protection, low cost matrix material that the purpose of this invention is to provide a kind of alternative flame-proof ABS.
The technical scheme that the present invention taked is:
A kind of environment protection, low cost matrix material of alternative flame-proof ABS, its raw material by following mass parts is formed: the fire retarding synergist of the ABS of the PVC of 40-55 part, 25-45 part, the compatilizer of 2-4 part, 0.5-2 part, the flow ability modifying agent of 6-10 part, the softening agent of 1-3 part, the oxidation inhibitor of 0.1-0.5 part.
Described compatilizer comprises a kind of among MBS, CPE, the ACR.
Described fire retarding synergist comprises Antimony Trioxide: 99.5Min, zinc borate, Ammonium Heptamolybdate, zinc oxide.
Described flow ability modifying agent comprises EMI-200, calcium stearate, Magnesium Stearate, N, N-ethylene bis stearamide, PE wax, chlorinatedpolyethylene wax, oleylamide.
Described softening agent is non-phthalic ester plasticizer.
Described non-phthalic ester plasticizer is Dinch.
Described oxidation inhibitor comprises 1010,168,1076,626,1135,215,245.
Described organic stabilizer thiomethyl amphyl, Orgnic rare earth thiolate mixture, metal salt of organic carboxylic acid containing sulfur mixture.
The invention has the beneficial effects as follows: the cost of matrix material of the present invention is lower, is easy to moulding, and resulting matrix material has preferable performance.
Embodiment
Below in conjunction with specific embodiment the present invention is done further explanation:
Embodiment 1:
A kind of environment protection, low cost matrix material of alternative flame-proof ABS, its prescription is formed like following table 1:
Table 1: the prescription of the environment protection, low cost matrix material of alternative flame-proof ABS is formed
| Raw material | Mass parts |
| PVC | 48 |
| ABS (model: 121H-0013) | 36 |
| Toughness reinforcing compatilizer MBS | 2 |
| Modifier ACR K120 | 1 |
| Sb 2O 3 | 0.8 |
| Flow ability modifying agent EMI-200 | 5 |
| Antioxidant 1010 | 0.1 |
| Oxidation inhibitor 168 | 0.1 |
| Calcium stearate | 0.8 |
| Internal lubricant YG-16 | 0.8 |
| Environment-friendly plasticizer DINCH | 1.5 |
| Organic stabilizer 1 | 1.2 |
| Organic stabilizer 2 | 1 |
| Polyethylene wax AC-6A | 1 |
| Polyethylene wax AC-316A | 0.2 |
Embodiment 2:
A kind of environment protection, low cost matrix material of alternative flame-proof ABS, its prescription is formed like following table 2:
Table 2: the prescription of the environment protection, low cost matrix material of alternative flame-proof ABS is formed
| Raw material | Mass parts |
| PVC | 55 |
| ABS 8391 | 30 |
| Toughness reinforcing compatilizer MBS | 2 |
| Chlorinatedpolyethylene | 0.5 |
| Sb 2O 3 | 1 |
| Flow ability modifying agent EMI-200 | 5.5 |
| Antioxidant 1010 | 0.15 |
| Oxidation inhibitor 168 | 0.15 |
| Calcium stearate | 1.2 |
| Internal lubricant YG-16 | 0.5 |
| Environment-friendly plasticizer DINCH | 2.3 |
| Organic stabilizer 1 | 2.5 |
| Organic stabilizer 3 | 0.4 |
| Polyethylene wax AC-6A | 0.9 |
| Polyethylene wax AC-316A | 0.5 |
Embodiment 3:
A kind of environment protection, low cost matrix material of alternative flame-proof ABS, its prescription is formed like following table 3:
Table 3: the prescription of the environment protection, low cost matrix material of alternative flame-proof ABS is formed
| Raw material | Mass parts |
| PVC | 45 |
| ABS (model: 121H-0013) | 40 |
| Modifier ACR K120 | 2.8 |
| Chlorinatedpolyethylene | 0.6 |
| Sb 2O 3 | 1.2 |
| Flow ability modifying agent EMI-200 | 6.2 |
| Antioxidant 1010 | 0.1 |
| Oxidation inhibitor 168 | 0.2 |
| Calcium stearate | 1.5 |
| Internal lubricant YG-16 | 1.2 |
| Environment-friendly plasticizer DINCH | 2.5 |
| Organic stabilizer 2 | 2.3 |
| Organic stabilizer 3 | 0.3 |
| Polyethylene wax AC-6A | 0.8 |
| Polyethylene wax AC-316A | 0.4 |
Embodiment 4:
A kind of environment protection, low cost matrix material of alternative flame-proof ABS, its prescription is formed like following table 4:
Table 4: the prescription of the environment protection, low cost matrix material of alternative flame-proof ABS is formed
| Raw material | Mass parts |
| PVC | 43 |
| ABS747S | 45 |
| Modifier ACR K120 | 2.5 |
| Chlorinatedpolyethylene | 1 |
| Sb 2O 3 | 1.2 |
| Flow ability modifying agent EMI-200 | 6.5 |
| Antioxidant 1010 | 0.15 |
| Oxidation inhibitor 168 | 0.2 |
| Calcium stearate | 1.5 |
| Internal lubricant YG-16 | 1.2 |
| Environment-friendly plasticizer DINCH | 2.5 |
| Organic stabilizer 2 | 1.1 |
| Organic stabilizer 3 | 1.8 |
| Polyethylene wax AC-6A | 0.8 |
| Polyethylene wax AC-316A | 0.4 |
Embodiment 5:
A kind of environment protection, low cost matrix material of alternative flame-proof ABS, its prescription is formed like following table 5:
Table 5: the prescription of the environment protection, low cost matrix material of alternative flame-proof ABS is formed
| Raw material | Mass parts |
| PVC | 52 |
| ABS747S | 35 |
| Toughness reinforcing compatilizer MBS | 1.8 |
| Modifier ACR K120 | 1.7 |
| Sb 2O 3 | 1.2 |
| Flow ability modifying agent EMI-200 | 6.0 |
| Antioxidant 1010 | 0.15 |
| Oxidation inhibitor 168 | 0.2 |
| Calcium stearate | 1.5 |
| Internal lubricant YG-16 | 1.2 |
| Environment-friendly plasticizer DINCH | 2.5 |
| Organic stabilizer 1 | 1.3 |
| Organic stabilizer 2 | 1.2 |
| Polyethylene wax AC-6A | 0.8 |
| Polyethylene wax AC-316A | 0.4 |
Matrix material of the present invention can prepare through melt extruding, and is the example explanation with embodiment 1: various raw materials mix are even, and place twin screw extruder to melt extrude and get final product.The prescription of other embodiment all can adopt the method preparation that melt extrudes.
Need to prove: organic stabilizer 1 of the present invention is 2,6-di-t-butyl-4-((dodecyl sulfenyl) methyl) phenol, and its compound method is existingly among the embodiment 17 of 200510121357.6 patent application document to set forth explanation at application number;
Organic stabilizer 2 of the present invention is three (isooctyl mercaptoacetate) lanthanum-epoxy soybean oil-phosphorous acid ester one package stabilizer, and its preparation method is existingly among the embodiment 10 of 200610132485.5 patent application document to set forth explanation at application number;
Organic stabilizer 3 of the present invention is a composite stabilizer of metal salt of organic carboxylic acid containing sulfur, and its preparation method is existingly among the embodiment 5 of 200610132464.3 patent application document to set forth explanation at application number.
Performance of composites such as following table 6 by embodiment 1-5 preparation:
Table 6: the performance of composites of the present invention's preparation
| Test event | Testing standard | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Tensile strength (MPa) | ASTM D638 | 45 | 48 | 43 | 46 | 48 |
| Elongation (%) | ASTM D638 | 20 | 16 | 22 | 25 | 15 |
| Flexural strength (MPa) | ASTM D790 | 65 | 68 | 62 | 66 | 68 |
| Modulus in flexure (MPa) | ASTM D790 | 2200 | 2350 | 2100 | 2250 | 2350 |
| Notched Izod impact strength (KJ/m2) | ASTM D256 | 30 | 26 | 33 | 34 | 26 |
Prescription to embodiment carries out dynamic thermally-stabilised test: the mixing tank of HAAKE torque rheometer is warming up to 180 ℃; Rotor speed is 30r/min; According to the proportioning of embodiment add total mass be the mixture of 70g to mixing tank, after mixture plastified fully, the timing definition of balancing torque increase 3Nm was dynamic heat-stable time; Through test, the dynamic heat-stable time of the prescription of embodiments of the invention is between 18-20min.
Claims (8)
1. the environment protection, low cost matrix material of an alternative flame-proof ABS, it is characterized in that: its raw material by following mass parts is formed: the fire retarding synergist of the ABS of the PVC of 40-55 part, 25-45 part, the compatilizer of 2-4 part, 0.5-2 part, the flow ability modifying agent of 6-10 part, the softening agent of 1-3 part, the oxidation inhibitor of 0.1-0.5 part.
2. the environment protection, low cost matrix material of a kind of alternative flame-proof ABS according to claim 1 is characterized in that: described compatilizer comprises a kind of among MBS, CPE, the ACR.
3. the environment protection, low cost matrix material of a kind of alternative flame-proof ABS according to claim 1, it is characterized in that: described fire retarding synergist comprises Antimony Trioxide: 99.5Min, zinc borate, Ammonium Heptamolybdate, zinc oxide.
4. the environment protection, low cost matrix material of a kind of alternative flame-proof ABS according to claim 1; It is characterized in that: described flow ability modifying agent comprises EMI-200, calcium stearate, Magnesium Stearate, N, N-ethylene bis stearamide, PE wax, chlorinatedpolyethylene wax, oleylamide.
5. the environment protection, low cost matrix material of a kind of alternative flame-proof ABS according to claim 1, it is characterized in that: described softening agent is non-phthalic ester plasticizer.
6. the environment protection, low cost matrix material of a kind of alternative flame-proof ABS according to claim 5, it is characterized in that: described non-phthalic ester plasticizer is Dinch.
7. the environment protection, low cost matrix material of a kind of alternative flame-proof ABS according to claim 1, it is characterized in that: described oxidation inhibitor comprises 1010,168,1076,626,1135,215,245.
8. the environment protection, low cost matrix material of a kind of alternative flame-proof ABS according to claim 1 is characterized in that: described organic stabilizer thiomethyl amphyl, Orgnic rare earth thiolate mixture, metal salt of organic carboxylic acid containing sulfur mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210188073.9A CN102731926B (en) | 2012-06-08 | 2012-06-08 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210188073.9A CN102731926B (en) | 2012-06-08 | 2012-06-08 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102731926A true CN102731926A (en) | 2012-10-17 |
| CN102731926B CN102731926B (en) | 2014-07-09 |
Family
ID=46988274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210188073.9A Active CN102731926B (en) | 2012-06-08 | 2012-06-08 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102731926B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073813A (en) * | 2012-11-20 | 2013-05-01 | 无锡常安通用金属制品有限公司 | Polrvinyl chloride alloy material and preparation method |
| CN103980654A (en) * | 2014-06-03 | 2014-08-13 | 山东瀚氏汽车零部件有限公司 | Anti-aging and high temperature resistant alloy for automotive interior parts and preparation method thereof |
| CN105086283A (en) * | 2015-09-02 | 2015-11-25 | 连云港海水化工有限公司 | High-fluidity and flame-retardant PVC/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof |
| CN105754281A (en) * | 2016-03-09 | 2016-07-13 | 苏州莱特复合材料有限公司 | ABS (acrylonitrile butadiene styrene) and PVC (polyvinyl chloride) alloy and preparation method thereof |
| CN106221115A (en) * | 2016-08-11 | 2016-12-14 | 苏州柯创电子材料有限公司 | Blooming tubing |
| CN109401166A (en) * | 2018-09-25 | 2019-03-01 | 上海锦湖日丽塑料有限公司 | High-elongation high-impact ASA special material for tube composition and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747568A (en) * | 2008-12-16 | 2010-06-23 | 金发科技股份有限公司 | PVC/ABS alloy material and preparation method thereof |
| CN101875748A (en) * | 2010-03-31 | 2010-11-03 | 深圳市科聚新材料有限公司 | Heat-resistance ABS/PVC alloy and preparation method thereof |
| CN102040786A (en) * | 2010-12-30 | 2011-05-04 | 佛山市顺德区圆融新材料有限公司 | Antiflaming PVC (poly vinyl chloride)/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof |
| CN102477206A (en) * | 2010-11-29 | 2012-05-30 | 合肥杰事杰新材料股份有限公司 | Flame retardant and antistatic ABS/PVC alloy material, and preparation method thereof |
-
2012
- 2012-06-08 CN CN201210188073.9A patent/CN102731926B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747568A (en) * | 2008-12-16 | 2010-06-23 | 金发科技股份有限公司 | PVC/ABS alloy material and preparation method thereof |
| CN101875748A (en) * | 2010-03-31 | 2010-11-03 | 深圳市科聚新材料有限公司 | Heat-resistance ABS/PVC alloy and preparation method thereof |
| CN102477206A (en) * | 2010-11-29 | 2012-05-30 | 合肥杰事杰新材料股份有限公司 | Flame retardant and antistatic ABS/PVC alloy material, and preparation method thereof |
| CN102040786A (en) * | 2010-12-30 | 2011-05-04 | 佛山市顺德区圆融新材料有限公司 | Antiflaming PVC (poly vinyl chloride)/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073813A (en) * | 2012-11-20 | 2013-05-01 | 无锡常安通用金属制品有限公司 | Polrvinyl chloride alloy material and preparation method |
| CN103980654A (en) * | 2014-06-03 | 2014-08-13 | 山东瀚氏汽车零部件有限公司 | Anti-aging and high temperature resistant alloy for automotive interior parts and preparation method thereof |
| CN103980654B (en) * | 2014-06-03 | 2016-06-08 | 山东瀚氏汽车零部件有限公司 | Automotive upholstery aging resistance high-temperature alloy and preparation method |
| CN105086283A (en) * | 2015-09-02 | 2015-11-25 | 连云港海水化工有限公司 | High-fluidity and flame-retardant PVC/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof |
| CN105754281A (en) * | 2016-03-09 | 2016-07-13 | 苏州莱特复合材料有限公司 | ABS (acrylonitrile butadiene styrene) and PVC (polyvinyl chloride) alloy and preparation method thereof |
| CN106221115A (en) * | 2016-08-11 | 2016-12-14 | 苏州柯创电子材料有限公司 | Blooming tubing |
| CN109401166A (en) * | 2018-09-25 | 2019-03-01 | 上海锦湖日丽塑料有限公司 | High-elongation high-impact ASA special material for tube composition and preparation method thereof |
| CN109401166B (en) * | 2018-09-25 | 2021-05-04 | 上海锦湖日丽塑料有限公司 | Special ASA pipe material composition with high elongation and high impact resistance and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102731926B (en) | 2014-07-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102731926B (en) | Environment-friendly low-cost composite material capable of substituting flame retardant ABS | |
| CN101967280B (en) | Preparation method of anti-cracking polyphenyl thioether composite material | |
| CN101914251B (en) | Method for preparing high-flow high-heat-resistance transparent polyvinyl chloride alloy capable of injection molding | |
| CN104086970B (en) | A kind of efficient fire-retardant weather polycarbonate composite material of bromine silicon and preparation method thereof | |
| CN107082949B (en) | High-performance polypropylene plastic packaging barrel and preparation method thereof | |
| CN102690476B (en) | Heat-resisting material and preparing method thereof as well as base station antenna outer cover | |
| JP2018024871A (en) | Composition containing polyamide selected from group consisting of polyamide 66 and polyamide 610, polyamide 1010 and polyamide 1012 | |
| CN104004296A (en) | Antimony-free flame-retardant polyvinyl chloride cable material and preparation method thereof | |
| CN101113236A (en) | Non-halogen non-phosphate flame-proof polycarbonate resin and method for preparing same | |
| CN102786761A (en) | Modified high-impact polystyrene plastic | |
| CN102964750A (en) | Halogen-free flame-retardant PVC (Polyvinyl Chloride) elastic composite material and preparation method thereof | |
| CN103073809B (en) | High-impact high-weather-resistance environmental-friendly brominated flame-retardant ASA material and preparation method and application thereof | |
| CN105647001B (en) | A kind of low-luster modified polypropylene material and preparation method thereof | |
| CN103709681B (en) | A kind of high tenacity, high-heat-resisting glass-fiber strengthen PBT composite and preparation method thereof | |
| CN103396643A (en) | Modifier-containing polyacrylate grafted vinyl chloride composite resin composition | |
| CN103073808B (en) | Low-cost high-flow weather-proof environment-friendly brominated flame retardant ASA material as well as preparation method and application thereof | |
| EP2828322B1 (en) | Thermoplastic moulding compositions | |
| CN107760022A (en) | A kind of plasticising type toughened Nylon 6 material and preparation method thereof | |
| CN104744781A (en) | High impact reinforced modified polyethylene powder | |
| CN104877296A (en) | ABS/recovery PET composite material and product thereof | |
| CN105400051A (en) | Environment-friendly migration-resistant refrigerator door sealing strip | |
| CN103102633B (en) | Highly weather-proof environment-friendly high-molecular weight bromine flame-retardant ASA material and preparation method and application thereof | |
| CN104693725A (en) | Reinforced low-temperature-resistant PC/PET alloy and preparation method thereof | |
| CN103554662A (en) | High-performance conductive PP (Propene Polymer) polymer as well as preparation method and application thereof | |
| CN104650557A (en) | Elastomer coated inorganic powder filled modified PC/PBT composite material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 528322 Guangdong City, Shunde District Leliu street even Du Tian Ren Ren Industrial Park (self) plant No. 10 Patentee after: Guangdong harmony new materials Co. Ltd. Address before: 528315 Industrial Road, Penglai Road, Beijiao neighborhood, Beijiao Town, Shunde District, Guangdong, Foshan Patentee before: Foshan City Shunde District Yuanrong New Materials Co., Ltd. |
|
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: 528311 Longchuang Road, Malong Village Committee, Beijiao Town, Shunde District, Foshan City, Guangdong Province Patentee after: GUANGDONG ALDEX NEW MATERIAL Co.,Ltd. Address before: 528322 Guangdong City, Shunde District Leliu street even Du Tian Ren Ren Industrial Park (self) plant No. 10 Patentee before: GUANGDONG ALDEX NEW MATERIAL Co.,Ltd. |