CN105086283A - High-fluidity and flame-retardant PVC/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof - Google Patents
High-fluidity and flame-retardant PVC/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to the technical field of alloy materials, and discloses a high-fluidity and flame-retardant PVC/ABS (acrylonitrile butadiene styrene) alloy material and a preparation method thereof. The material is formed through mixing the following components: ABS resin, PVC resin, a fire retardant, an antioxidant, a lubricating agent, a stabilizer and a processing agent. The preparation method comprises the following steps: mixing all the components; carrying out fusion and extrusion pelletization to obtain the finished product. The high-fluidity and flame-retardant PVC/ABS alloy material prepared through the preparation method is good in flame retardation, strong in fluidity, good in surface perception and easy to process into shapes, the product technology is easy to operate, and the alloy material is low in cost, stable in quality, and widely applicable to the fields, such as machinery, electronic instruments, household appliances and construction.
Description
Technical field
The invention belongs to Material Field, be specifically related to a kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof.
Background technology
ABS resin is formed by acrylonitrile-butadiene-styrene (ABS) three kinds of monomer copolymerizations, both gloss and the processing fluidity of polystyrene had been maintained, there is again the shock-resistance of rubber, and the rigidity of vinyl cyanide, having good heat resistance, good stability of the dimension, be easy to the advantages such as forming process, is a kind of excellent property, broad-spectrum engineering plastics.Defect is that weathering resistance is poor, inflammable, and price is also higher.PVC take polyvinyl chloride resin as base-material, mix with the multiple auxiliary agent such as stablizer, softening agent, filler, tinting material and properties-correcting agent, through plasticizing, forming process.The excellent properties such as PVC plastic has good rigidly, intensity is high, fire-retardant, corrosion-resistant, electric insulating quality is good and soft or hard is adjustable, and raw material sources are abundant, and cheap, be the universal material of sexual valence comparative superiority, defect is that melt viscosity is large.PVC/ABS alloy is relative merits for PVC and ABS and a kind of polyblend that the performance prepared is learnt from other's strong points to offset one's weaknesses mutually.But the defect of PVC/ABS alloy itself, as poor in mobility etc. limits its development and application.
Summary of the invention
The defect that the object of the invention is to exist for prior art provides a kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A kind of high flowing flame-proof PVC/ABS alloy material, this material is mixed by ABS resin, polyvinyl chloride resin, fire retardant, oxidation inhibitor, lubricant, stablizer and processing aid, and the mass ratio of each component is followed successively by 20 ~ 25:63 ~ 70:5 ~ 8:0.4 ~ 1:0.1 ~ 0.3:1 ~ 2:0.5 ~ 1.
In some preferred technical schemes, described ABS resin is ABS709 and ABS757 mixture, and the mass ratio of the two is 55 ~ 67:33 ~ 45.
In some preferred technical schemes, described fire retardant is chlorine-based flame retardant; Be preferably in clorafin, tetrachlorophthalic tetrachlorophthalic anhydrid and chlorinatedpolyethylene any one; Most preferably be chlorinatedpolyethylene.
In some preferred technical schemes, described oxidation inhibitor is the mixture of antioxidant 1010 and irgasfos 168, and the two mass ratio is 1:2.
In some preferred technical schemes, described lubricant is the mixture of interior lubrication prescription and outer lubrication prescription, and interior lubrication prescription and outer lubrication prescription mass ratio are 2:1.Described interior lubrication prescription is one or more in Solsperse 2000, stearic amide, stearic acid butyl ester, glyceryl monostearate and fatty acid pentaerythritol ester, and outer lubrication prescription is one or more in EB-FF, PE wax, methylene bis stearylamide and ethylene bis stearic acid amide.
In some preferred technical schemes, described stablizer is organic tin stablizer, is preferably one or more in Methyl stannum mercaptide, butanethiol tin, two butyl tindichloride, dibutyl tin laurate, lauric acid dibutyitin maleate and dibutyitin maleate.
In some preferred technical schemes, described processing aid is one or more in fatty acid amide, silicone oil, white mineral oil, silicone mixture and ethylene bis stearic acid amide.
A preparation method for above-mentioned height flowing flame-proof PVC/ABS alloy material, the method is carried out as follows:
(1) take ABS resin, polyvinyl chloride resin, fire retardant, oxidation inhibitor, lubricant, stablizer and processing aid by mass parts ratio in high-speed mixer, stir fully mixing;
(2) send in twin screw extruder by above-mentioned blend through metering, through mixing fusing, extruding pelletization, after dry, packaging becomes finished product.
In some preferred technical schemes, described twin screw extruder length-to-diameter ratio is 36 ~ 40, and extruder temperature controls at 130 ~ 180 DEG C, and screw speed controls at 150 ~ 300 revs/min.
The preparation method of aforesaid height flowing flame-proof PVC/ABS alloy material, raw materials used mass ratio is as follows:
The mass ratio of ABS resin, polyvinyl chloride resin, fire retardant, oxidation inhibitor, lubricant, stablizer and processing aid is followed successively by 20 ~ 25:63 ~ 70:5 ~ 8:0.4 ~ 1:0.1 ~ 0.3:1 ~ 2:0.5 ~ 1.
In some preferred technical schemes, described ABS resin is ABS709 and ABS757 mixture, and the mass ratio of the two is 55 ~ 67:33 ~ 45.Described fire retardant is chlorine-based flame retardant; Be preferably clorafin, tetrachlorophthalic tetrachlorophthalic anhydrid, any one in chlorinatedpolyethylene; Most preferably be chlorinatedpolyethylene.Described oxidation inhibitor is the mixture of antioxidant 1010 and irgasfos 168, and the two mass ratio is 1:2.Described lubricant is the mixture of interior lubrication prescription and outer lubrication prescription, and interior lubrication prescription and outer lubrication prescription mass ratio are 2:1; Described interior lubrication prescription is one or more in Solsperse 2000, stearic amide, stearic acid butyl ester, glyceryl monostearate, fatty acid pentaerythritol ester, and outer lubrication prescription is one or more in EB-FF, PE wax, methylene bis stearylamide or ethylene bis stearic acid amide.Described stablizer is organic tin stablizer, is preferably Methyl stannum mercaptide, butanethiol tin, two butyl tindichloride, dibutyl tin laurate, lauric acid dibutyitin maleate, one or more in dibutyitin maleate.Described processing aid is the mixture of one or several in fatty acid amide, silicone oil, white mineral oil, silicone mixture, ethylene bis stearic acid amide.
Beneficial effect of the present invention:
The present invention, by ABS resin, polyvinyl chloride resin, fire retardant, oxidation inhibitor, lubricant, synergy between stablizer and processing aid, not only increases alloy material mechanical property, also substantially increases the mobility of alloy material.And described alloy material has excellent flame retardant properties, all reaches UL94 standard V-0 level.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but protection scope of the present invention is not limited thereto:
Various raw material in embodiment 1 ~ 3 and comparative example 1 ~ 2 and auxiliary agent are commercially available general commodity.
Embodiment 1 ~ 3
Table 1 embodiment 1 ~ 3 and comparative example 1 ~ 2 raw material used and each amounts of components
Implement the preparation method of 1-3 and comparative example 1 ~ 2:
(1) take ABS resin, polyvinyl chloride resin, fire retardant, oxidation inhibitor, lubricant, stablizer and processing aid by mass parts ratio in table 1 in high-speed mixer, stir fully mixing;
(2) send in twin screw extruder by above-mentioned blend through metering, through mixing fusing, extruding pelletization, after dry, packaging becomes finished product.
Wherein, described twin screw extruder length-to-diameter ratio is 40, and with accurate temperature controller device and vacuum extractor, wherein extruder temperature controls at 150 ~ 180 DEG C, and screw speed controls at 180 ~ 220 revs/min.
Performance Detection:
The testing method of the alloy material that embodiment 1 ~ 3 and comparative example 1 ~ 2 prepare is: density measures by GB/T1033-2008, melt flow rate (MFR) is pressed GB/T3682-2000 and is measured, heat-drawn wire is pressed GB/T1634-2004 and is measured, bending property is pressed GB/T9341-2000 and is measured, and combustionproperty presses UL94 standard test.Concrete measurement result is as shown in table 2.
Claims (10)
1. one kind high flowing flame-proof PVC/ABS alloy material, it is characterized in that this material is mixed by ABS resin, polyvinyl chloride resin, fire retardant, oxidation inhibitor, lubricant, stablizer and processing aid, the mass ratio of each component is followed successively by 20 ~ 25:63 ~ 70:5 ~ 8:0.4 ~ 1:0.1 ~ 0.3:1 ~ 2:0.5 ~ 1.
2. height flowing flame-proof PVC/ABS alloy material according to claim 1, it is characterized in that: described ABS resin is ABS709 and ABS757 mixture, the mass ratio of the two is 55 ~ 67:33 ~ 45.
3. height flowing flame-proof PVC/ABS alloy material according to claim 1, is characterized in that: described fire retardant is chlorine-based flame retardant; Be preferably in clorafin, tetrachlorophthalic tetrachlorophthalic anhydrid and chlorinatedpolyethylene any one; Most preferably be chlorinatedpolyethylene.
4. height flowing flame-proof PVC/ABS alloy material according to claim 1, it is characterized in that wherein said oxidation inhibitor is the mixture of antioxidant 1010 and irgasfos 168, the two mass ratio is 1:2.
5. height flowing flame-proof PVC/ABS alloy material according to claim 1, it is characterized in that wherein said lubricant is the mixture of interior lubrication prescription and outer lubrication prescription, interior lubrication prescription and outer lubrication prescription mass ratio are 2:1.
6. height flowing flame-proof PVC/ABS alloy material according to claim 5, it is characterized in that wherein said interior lubrication prescription is one or more in Solsperse 2000, stearic amide, stearic acid butyl ester, glyceryl monostearate and fatty acid pentaerythritol ester, outer lubrication prescription is one or more in EB-FF, PE wax, methylene bis stearylamide and ethylene bis stearic acid amide.
7. height flowing flame-proof PVC/ABS alloy material according to claim 1, it is characterized in that wherein said stablizer is organic tin stablizer, be preferably one or more in Methyl stannum mercaptide, butanethiol tin, two butyl tindichloride, dibutyl tin laurate, lauric acid dibutyitin maleate and dibutyitin maleate.
8. height flowing flame-proof PVC/ABS alloy material according to claim 1, is characterized in that wherein said processing aid is one or more in fatty acid amide, silicone oil, white mineral oil, silicone mixture and ethylene bis stearic acid amide.
9. a preparation method for the height flowing flame-proof PVC/ABS alloy material according to any one of claim 1 ~ 8, is characterized in that carrying out as follows:
(1) take ABS resin, polyvinyl chloride resin, fire retardant, oxidation inhibitor, lubricant, stablizer and processing aid by mass parts ratio in high-speed mixer, stir fully mixing;
(2) send in twin screw extruder by above-mentioned blend through metering, through mixing fusing, extruding pelletization, after dry, packaging becomes finished product.
10. the preparation method of height flowing flame-proof PVC/ABS alloy material according to claim 9, it is characterized in that described twin screw extruder length-to-diameter ratio is 36 ~ 40, extruder temperature controls at 130 ~ 180 DEG C, and screw speed controls at 150 ~ 300 revs/min.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105602161A (en) * | 2016-03-24 | 2016-05-25 | 叶青 | PVC (polyvinyl chloride) alloy |
| CN107118498A (en) * | 2017-05-05 | 2017-09-01 | 安徽彩晶光电有限公司 | A kind of modified ABS plastic alloy material for casing of liquid crystal television set |
| CN109796704A (en) * | 2019-02-20 | 2019-05-24 | 厦门源亚泰塑胶科技有限公司 | A kind of hard ABS/PVC alloy and preparation method thereof improving mobility |
| CN114516996A (en) * | 2022-03-28 | 2022-05-20 | 金发科技股份有限公司 | Boiling-resistant PVC alloy material and preparation method and application thereof |
| CN114524986A (en) * | 2022-04-07 | 2022-05-24 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | Environment-friendly flame-retardant PVC/PE composite material and preparation method thereof |
| CN115772303A (en) * | 2021-09-08 | 2023-03-10 | 中国石油化工股份有限公司 | High-fluidity flame-retardant polyvinyl chloride injection molding composition and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382388A (en) * | 2010-09-01 | 2012-03-21 | 中国石油化工股份有限公司 | PVC/ABS alloy material with high anti-impact strength and preparation method thereof |
| CN102731926A (en) * | 2012-06-08 | 2012-10-17 | 佛山市顺德区圆融新材料有限公司 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
| CN102964715A (en) * | 2011-09-01 | 2013-03-13 | 合肥杰事杰新材料股份有限公司 | Flame-retardant cold-resistant PVC/ABS alloy and preparation method thereof |
| CN104277355A (en) * | 2014-08-15 | 2015-01-14 | 辽宁工程技术大学 | Flame-retardant toughening HPVC (polyvinyl with high degree of polymerization)/ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
-
2015
- 2015-09-02 CN CN201510557616.3A patent/CN105086283B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382388A (en) * | 2010-09-01 | 2012-03-21 | 中国石油化工股份有限公司 | PVC/ABS alloy material with high anti-impact strength and preparation method thereof |
| CN102964715A (en) * | 2011-09-01 | 2013-03-13 | 合肥杰事杰新材料股份有限公司 | Flame-retardant cold-resistant PVC/ABS alloy and preparation method thereof |
| CN102731926A (en) * | 2012-06-08 | 2012-10-17 | 佛山市顺德区圆融新材料有限公司 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
| CN104277355A (en) * | 2014-08-15 | 2015-01-14 | 辽宁工程技术大学 | Flame-retardant toughening HPVC (polyvinyl with high degree of polymerization)/ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105602161A (en) * | 2016-03-24 | 2016-05-25 | 叶青 | PVC (polyvinyl chloride) alloy |
| CN107118498A (en) * | 2017-05-05 | 2017-09-01 | 安徽彩晶光电有限公司 | A kind of modified ABS plastic alloy material for casing of liquid crystal television set |
| CN109796704A (en) * | 2019-02-20 | 2019-05-24 | 厦门源亚泰塑胶科技有限公司 | A kind of hard ABS/PVC alloy and preparation method thereof improving mobility |
| CN115772303A (en) * | 2021-09-08 | 2023-03-10 | 中国石油化工股份有限公司 | High-fluidity flame-retardant polyvinyl chloride injection molding composition and preparation method thereof |
| CN115772303B (en) * | 2021-09-08 | 2024-04-09 | 中国石油化工股份有限公司 | High-fluidity flame-retardant polyvinyl chloride injection molding composition and preparation method thereof |
| CN114516996A (en) * | 2022-03-28 | 2022-05-20 | 金发科技股份有限公司 | Boiling-resistant PVC alloy material and preparation method and application thereof |
| CN114516996B (en) * | 2022-03-28 | 2023-08-22 | 金发科技股份有限公司 | Boiling-resistant PVC alloy material and preparation method and application thereof |
| CN114524986A (en) * | 2022-04-07 | 2022-05-24 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | Environment-friendly flame-retardant PVC/PE composite material and preparation method thereof |
| CN114524986B (en) * | 2022-04-07 | 2023-09-08 | 山东鲁泰控股集团有限公司石墨烯高分子复合材料研发中心 | Environment-friendly flame-retardant PVC/PE composite material and preparation method thereof |
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Effective date of registration: 20170809 Address after: 222000 Jiangsu Province, Lianyungang City Lianyun District Banqiao Industrial Park, Xianghe Road No. 8 Applicant after: Lianyungang Engineering Investment Group Li Hai Chemical Co., Ltd. Address before: Banqiao Industrial Park in Jiangsu Province, Lianyungang City Lianyun District 222046 longitudinal road four Southeast Applicant before: Lianyungang Sea Water Chemical Co., Ltd. |
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