CN102471785B - 从丁醇、水和有机萃取剂的混合物中回收丁醇 - Google Patents
从丁醇、水和有机萃取剂的混合物中回收丁醇 Download PDFInfo
- Publication number
- CN102471785B CN102471785B CN201080032088.5A CN201080032088A CN102471785B CN 102471785 B CN102471785 B CN 102471785B CN 201080032088 A CN201080032088 A CN 201080032088A CN 102471785 B CN102471785 B CN 102471785B
- Authority
- CN
- China
- Prior art keywords
- butanol
- butanols
- water
- tower
- stream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/16—Butanols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/001—Processes specially adapted for distillation or rectification of fermented solutions
- B01D3/002—Processes specially adapted for distillation or rectification of fermented solutions by continuous methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
- C07C29/84—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by extractive distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/86—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by liquid-liquid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/94—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/12—Monohydroxylic acyclic alcohols containing four carbon atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Biotechnology (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22565909P | 2009-07-15 | 2009-07-15 | |
| US61/225659 | 2009-07-15 | ||
| PCT/US2010/042092 WO2011008924A2 (en) | 2009-07-15 | 2010-07-15 | Recovery of butanol from a mixture of butanol, water, and an organic extractant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102471785A CN102471785A (zh) | 2012-05-23 |
| CN102471785B true CN102471785B (zh) | 2015-04-22 |
Family
ID=43450191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080032088.5A Expired - Fee Related CN102471785B (zh) | 2009-07-15 | 2010-07-15 | 从丁醇、水和有机萃取剂的混合物中回收丁醇 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8968522B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2454375A2 (cg-RX-API-DMAC7.html) |
| JP (1) | JP2012533555A (cg-RX-API-DMAC7.html) |
| KR (1) | KR20120051695A (cg-RX-API-DMAC7.html) |
| CN (1) | CN102471785B (cg-RX-API-DMAC7.html) |
| AU (1) | AU2010273348A1 (cg-RX-API-DMAC7.html) |
| BR (1) | BR112012000822A2 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2766498C (cg-RX-API-DMAC7.html) |
| IN (1) | IN2012DN00440A (cg-RX-API-DMAC7.html) |
| MX (1) | MX2012000608A (cg-RX-API-DMAC7.html) |
| NZ (1) | NZ597205A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2011008924A2 (cg-RX-API-DMAC7.html) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8373008B2 (en) * | 2009-11-23 | 2013-02-12 | Butamax (Tm) Advanced Biofuels Llc | Recovery of butanol from a mixture of butanol, water, and an organic extractant |
| US8557540B2 (en) | 2010-06-18 | 2013-10-15 | Butamax (Tm) Advanced Biofuels Llc | Methods and systems for removing undissolved solids prior to extractive fermentation in the production of butanol |
| WO2012129555A2 (en) * | 2011-03-24 | 2012-09-27 | Butamax (Tm) Advanced Biofuels Llc | Host cells and methods for production of isobutanol |
| US9962623B2 (en) | 2011-12-09 | 2018-05-08 | Butamax Advanced Biofuels Llc | Process to remove product alcohols from fermentation broth |
| CA2861613A1 (en) | 2011-12-30 | 2013-07-04 | Butamax Advanced Biofuels Llc | Fermentative production of alcohols |
| AU2013256038A1 (en) | 2012-05-04 | 2014-10-16 | Butamax Advanced Biofuels Llc | Processes and systems for alcohol production and recovery |
| US9605281B2 (en) | 2012-09-12 | 2017-03-28 | Butamax Advanced Biofuels Llc | Processes and systems for the fermentative production of alcohols |
| CA2878966A1 (en) | 2012-07-26 | 2014-01-30 | Butamax Advanced Biofuels Llc | Butanol purification |
| EP2888350A1 (en) | 2012-08-22 | 2015-07-01 | Butamax Advanced Biofuels LLC | Production of fermentation products |
| US9029615B2 (en) | 2012-09-05 | 2015-05-12 | Dynasep Inc. | Energy efficient method and apparatus for the extraction of lower alcohols from dilute aqueous solution |
| US9630894B2 (en) | 2012-09-05 | 2017-04-25 | Dynasep Inc. | Energy efficient method and apparatus for the extraction of biomolecules from dilute aqueous solution |
| US9109196B2 (en) | 2012-09-12 | 2015-08-18 | Butamax Advanced Biofuels Llc | Processes and systems for the production of fermentation products |
| US9249076B2 (en) | 2012-09-21 | 2016-02-02 | Butamax Advanced Biofuels Llc | Recyclable extractant compositions |
| WO2014105840A1 (en) | 2012-12-31 | 2014-07-03 | Butamax Advanced Biofuels Llc | Fermentative production of alcohols |
| WO2014159309A1 (en) | 2013-03-12 | 2014-10-02 | Butamax Advanced Biofuels Llc | Processes and systems for the production of alcohols |
| US9517985B2 (en) | 2013-03-15 | 2016-12-13 | Butamax Advanced Biofuels Llc | Method for producing butanol using extractive fermentation |
| WO2014144728A1 (en) | 2013-03-15 | 2014-09-18 | Butamax Advanced Biofuels Llc | Method for production of butanol using extractive fermentation |
| GB201315475D0 (en) | 2013-08-30 | 2013-10-16 | Green Biologics Ltd | Solvent production |
| RU2531993C1 (ru) * | 2013-08-15 | 2014-10-27 | Открытое акционерное общество "Каменскволокно" | Способ регенерации изобутилового спирта в производстве высокопрочных арамидных нитей |
| EP3129116A4 (en) | 2014-04-11 | 2018-02-14 | Butamax Advanced Biofuels LLC | Contamination mitigation |
| EP3180440A4 (en) | 2014-08-11 | 2018-01-10 | Butamax Advanced Biofuels LLC | Yeast preparations and methods of making the same |
| RU2606118C1 (ru) * | 2015-12-22 | 2017-01-10 | Акционерное общество "Каменскволокно" | Способ выведения воды из технологического контура в химическом производстве |
| CN114681942B (zh) * | 2020-12-28 | 2023-07-07 | 天津市华瑞奕博化工科技有限公司 | 一种叔丁醇回收完全变压耦合精馏装置及精馏方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4428798A (en) * | 1982-07-26 | 1984-01-31 | Allied Corporation | Extraction and/or extractive distillation of low molecular weight alcohols from aqueous solutions |
| WO2008143704A2 (en) * | 2006-12-01 | 2008-11-27 | Gevo, Inc. | Engineered microorganisms for producing n-butanol and related methods |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3143734A1 (de) * | 1981-11-04 | 1983-05-11 | Hoechst Ag, 6230 Frankfurt | Verfahren zur kontinuierlichen rektifikation eines alkohole enthaltenden fluessigkeitsgemisches" |
| JPS59216591A (ja) * | 1983-05-23 | 1984-12-06 | Chiyoda Chem Eng & Constr Co Ltd | ブタノ−ルの製造法 |
| JPS60172290A (ja) * | 1984-02-17 | 1985-09-05 | Kao Corp | ブタノ−ルの製造方法 |
| US4636284A (en) * | 1984-05-18 | 1987-01-13 | English John C | Process for the separation of water from a water-containing mixture or azeotrope with an extractant, and for the separation of water from said extractant |
| US4865973A (en) | 1985-09-13 | 1989-09-12 | Queen's University At Kingston | Process for extractive fermentation |
| DE3618265A1 (de) * | 1986-05-30 | 1987-12-03 | Basf Ag | Neue heterocyclenhaltige trisazofarbstoffe |
| JPS63102687A (ja) * | 1986-10-20 | 1988-05-07 | Res Assoc Petroleum Alternat Dev<Rapad> | ブタノ−ルの製造方法 |
| JPH0763561B2 (ja) * | 1986-10-29 | 1995-07-12 | ケイエフエンジニアリング株式会社 | アセトン，ブタノ−ル及びエタノ−ル発酵液の蒸留法 |
| US4978430A (en) * | 1986-12-06 | 1990-12-18 | Ube Industries, Ltd. | Method for dehydration and concentration of aqueous solution containing organic compound |
| US5985100A (en) * | 1995-08-30 | 1999-11-16 | Basf Aktiengesellschaft | Process for separating butanol and dibutyl ether by means of dual-pressure distillation |
| US7311813B2 (en) | 2003-03-20 | 2007-12-25 | Ineos Usa Llc | Distillation sequence for the purification and recovery of hydrocarbons |
| DE10312918A1 (de) * | 2003-03-22 | 2004-09-30 | Oxeno Olefinchemie Gmbh | Verfahren zur Abtrennung von 2-Butanol aus tert.-Butanol/Wasser-Gemischen |
| NZ566406A (en) | 2005-10-26 | 2012-04-27 | Butamax Advanced Biofuels Llc | Fermentive production of four carbon alcohols |
| US20080132741A1 (en) * | 2006-06-16 | 2008-06-05 | D Amore Michael B | Process for making butenes from dry isobutanol |
| US20090030537A1 (en) | 2007-03-19 | 2009-01-29 | Allen Hartle | Interactive radio system and method |
| US20100205857A1 (en) | 2007-07-23 | 2010-08-19 | Einte-Karst Dijk | Butanol production in a eukaryotic cell |
| EP2238098A4 (en) * | 2007-12-27 | 2016-06-01 | Gevo Inc | RECOVERING HIGHER ALCOHOLS IN DILUTED AQUEOUS SOLUTIONS |
| EP2283141B1 (en) * | 2008-06-04 | 2014-04-23 | Butamax (TM) Advanced Biofuels LLC | A method for producing butanol using extraction and gas stripping |
| US8828695B2 (en) | 2008-06-04 | 2014-09-09 | Butamax Advanced Biofuels Llc | Method for producing butanol using two-phase extractive fermentation |
| EP2419517A2 (en) | 2009-04-13 | 2012-02-22 | Butamax(TM) Advanced Biofuels LLC | Method for producing butanol using extractive fermentation |
-
2010
- 2010-07-13 US US12/834,915 patent/US8968522B2/en active Active
- 2010-07-15 IN IN440DEN2012 patent/IN2012DN00440A/en unknown
- 2010-07-15 KR KR1020127003849A patent/KR20120051695A/ko not_active Withdrawn
- 2010-07-15 JP JP2012520771A patent/JP2012533555A/ja active Pending
- 2010-07-15 NZ NZ597205A patent/NZ597205A/xx not_active IP Right Cessation
- 2010-07-15 BR BR112012000822A patent/BR112012000822A2/pt not_active IP Right Cessation
- 2010-07-15 AU AU2010273348A patent/AU2010273348A1/en not_active Abandoned
- 2010-07-15 CN CN201080032088.5A patent/CN102471785B/zh not_active Expired - Fee Related
- 2010-07-15 CA CA2766498A patent/CA2766498C/en not_active Expired - Fee Related
- 2010-07-15 EP EP10734421A patent/EP2454375A2/en not_active Withdrawn
- 2010-07-15 WO PCT/US2010/042092 patent/WO2011008924A2/en not_active Ceased
- 2010-07-15 MX MX2012000608A patent/MX2012000608A/es not_active Application Discontinuation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4428798A (en) * | 1982-07-26 | 1984-01-31 | Allied Corporation | Extraction and/or extractive distillation of low molecular weight alcohols from aqueous solutions |
| WO2008143704A2 (en) * | 2006-12-01 | 2008-11-27 | Gevo, Inc. | Engineered microorganisms for producing n-butanol and related methods |
Non-Patent Citations (1)
| Title |
|---|
| Extractive fermentation of acetone and butanol:Process design and economic evaluation;Roffler et al;《Biotechnology progress》;19871231;第3卷(第3期);第132页第1栏第2段,第134页第1栏最后一段 * |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2012000608A (es) | 2012-01-27 |
| EP2454375A2 (en) | 2012-05-23 |
| CN102471785A (zh) | 2012-05-23 |
| JP2012533555A (ja) | 2012-12-27 |
| KR20120051695A (ko) | 2012-05-22 |
| BR112012000822A2 (pt) | 2017-06-13 |
| WO2011008924A2 (en) | 2011-01-20 |
| IN2012DN00440A (cg-RX-API-DMAC7.html) | 2015-05-15 |
| CA2766498C (en) | 2017-08-22 |
| US20110162953A1 (en) | 2011-07-07 |
| AU2010273348A1 (en) | 2012-01-19 |
| WO2011008924A3 (en) | 2011-04-07 |
| US8968522B2 (en) | 2015-03-03 |
| AU2010273348A2 (en) | 2012-02-02 |
| CA2766498A1 (en) | 2011-01-20 |
| NZ597205A (en) | 2013-05-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150422 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |