CN102461500A - Bactericidal composition containing mandipropamid - Google Patents
Bactericidal composition containing mandipropamid Download PDFInfo
- Publication number
- CN102461500A CN102461500A CN2010105351468A CN201010535146A CN102461500A CN 102461500 A CN102461500 A CN 102461500A CN 2010105351468 A CN2010105351468 A CN 2010105351468A CN 201010535146 A CN201010535146 A CN 201010535146A CN 102461500 A CN102461500 A CN 102461500A
- Authority
- CN
- China
- Prior art keywords
- metalaxyl
- mandipropamid amine
- mandipropamid
- bactericidal composition
- amine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to a bactericidal composition containing mandipropamid with a synergistic effect, which has an effective active component containing (A) mandipropamid and (B) one of metalaxyl or metalaxyl-M, wherein the weight ratio of the A to the B is (1-60) : (60-1). The effective active component is added with auxiliaries and polybutene so as to be prepared into wettable powder, water dispersible granules and microemulsion, and is mainly used for preventing and controlling oomycetes diseases.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of bactericidal composition that contains mandipropamid amine and metalaxyl or Metalaxyl-M.
Technical background
Mandipropamid amine (cyazofamid), molecular formula: C
23H
22CINO
4, chemical name: 2-(4-chloro-phenyl)-N-[2-(3-methoxyl group-4-(2-third alkynyloxy group)-phenyl-ethyl group]-2-(2-third alkynyloxy group)-acetamide.
Mandipropamid amine is acid amide fungicides.Its mechanism of action is for suppressing the biosynthesis of phosphatide, and leaf portion and fruit disease that exhausted big number is caused by oomycetes all have good preventive effect.The spore that is in the sprouting stage is had higher activity, and can suppress mycelia and grow up and sporulation.Can be absorbed rapidly through blade, and rested in the leaf table wax coat, blade is shielded.
Metalaxyl (metalaxyl), molecular formula are C
15H
21NO
4, chemical name: D, L-N-(2, the 6-3,5-dimethylphenyl)-N-(2 '-methoxyl group acetyl) methyl lactamine.
The systemic fungicide of protection of metalaxyl tool and therapeutic action; Can be absorbed by the root of plant, stem, leaf, and transfer to each organ of plant, can do the cauline leaf processing with moisture content in the plant corpus; Seed treatment and soil treatment are effective to downy mildew, phytophthora, the caused disease of pythium spp.But the germ pesticide resistance is brought out in the only spraying of this prescription easily, except that soil treatment can singly be used, generally all uses complex preparation.
Metalaxyl-M (metalaxyl-M) is the R isomer of common metalaxyl, is that first commercially has a photoactive bactericide of three-dimensional racemization in the world.Chemical name: N-(2, the 6-xylyl)-N-(methoxyl group acetyl group)-D-alanine methyl esters.Crop pests such as the vegetables due to Pseudoperonospora cubensis, phytophthora root rot bacterium, the rotten mildew fungus, fruit tree, tobacco, oil plant, cotton, grain are had efficiently.Higher 2～10 times than the drug effect of racemic metalaxyl, fast 2 times in degraded in soil, help to reduce dose and spraying times, increase spraying cycle, and increased to user's safety and with the compatibility of environment.
No matter be mandipropamid amine, metalaxyl or Metalaxyl-M, long-term use separately makes disease develop immunity to drugs easily, causes the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, and is unfavorable for environment sustainable development.And a kind ofly do not have the novel pesticide of cross resistance to prevent and treat pathogen if want newly developed, and then need screen 10,000～1.5 ten thousand compounds, expensive 1～1.5 hundred million dollar, the construction cycle is 6～10 years.And that the active ingredient of different effects mechanism is carried out is composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is more significantly filled a prescription, and can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency.
Mandipropamid amine is different with the metalaxyl or the Metalaxyl-M mechanism of action, and each other composite have good synergistic effect within the specific limits.And composite about mandipropamid amine and metalaxyl or Metalaxyl-M do not see relevant report at present at home and abroad as yet.
Summary of the invention
The objective of the invention is to propose a kind of generation or delaying drug resistance speed that can prevent disease drug resistance, the bactericidal composition that use cost is low, preventive effect is good.
The present invention realizes through following technical scheme:
A kind of bactericidal composition that contains mandipropamid amine, wherein mandipropamid amine and metalaxyl or Metalaxyl-M weight ratio are 1～60: 60～1.
The described bactericidal composition that contains mandipropamid amine, wherein the weight ratio of mandipropamid amine and metalaxyl is 5～40: 60～5.
The described bactericidal composition that contains mandipropamid amine, wherein the weight ratio of mandipropamid amine and Metalaxyl-M is 1～30: 30～1.
The described bactericidal composition that contains mandipropamid amine couplet, wherein the effective active component content accounts for 1～80% of gross weight, is preferably 10～60%.
The described bactericidal composition that contains mandipropamid amine adds corresponding additive and filler according to method known in those skilled in the art, can process wetting powder, water dispersible granules or microemulsion.
Described auxiliary agent has dispersant, wetting agent, disintegrant, binding agent, emulsifier, antifoaming agent, antifreeze, thickener and solvent.
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, ester polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described binding agent is selected from: one or more in diatomite, starch, PVA, carboxymethyl (ethyl) cellulose.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described antifoaming agent is selected from: silicone oil, silicone compound, C
10-20Saturated fat acid compounds, C
8-10In the aliphatic alcohols compound one or more.
Described thickener is selected from: one or more in xanthan gum, polyvinyl alcohol, the polyethylene glycol.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, aluminium-magnesium silicate, the glucose.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate); OP series phosphate (NPE phosphate); 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate); Styrene polyoxyethylene ether ammonium sulfate salt; Alkyl biphenyl ether disulfonic acid magnesium salts; Triethanolamine salt; Farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether); Farming newborn 600# (phenyl phenol polyoxy ethyl ether); Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether); Farming newborn 36# (phenethyl fluosite polyoxy ethyl ether); Farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether); Ethylene oxide-propylene oxide block copolymer; OP series (NPE); By series (castor oil polyoxyethylene ether); Farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether); Farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether); Sapn series (sorbitan monostearate); Tween series (sorbitan fatty acid ester APEO); In the AEO series (the pure APEO of fat) one or more.
Described solvent is selected from: N, dinethylformamide, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, toluene, propyl alcohol, carrene, cyclohexanone, acetone, methyl alcohol, ethanol, butanols, EGME, butyl ether, ethyl acetate, n-octyl alcohol, vegetable oil, acetonitrile one or more.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention is mainly used in control oomycetes order disease such as downy mildew, eqpidemic disease etc.
Beneficial effect of the present invention: (1) present composition effective active composition mandipropamid amine and metalaxyl or Metalaxyl-M belong to the bactericide of two kinds of different effects mechanism, and both are mixed each other and can produce conflict; (2) present composition shows good synergistic effect in given scope, and preventive effect is apparently higher than single agent, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition is used to prevent the oomycetes disease, like downy mildew, eqpidemic disease, white blister, root rot, stem rot, pythium rot, fruit rot etc., downy mildew, the eqpidemic disease of vegetables and fruit tree is had special efficacy.
Embodiment
Below in conjunction with embodiment the present invention is further explained, but the present invention is not limited thereto.Percentage in following examples all is weight percentage.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Practice example one: mandipropamid amine and metalaxyl (or Metalaxyl-M) are composite to the cucumber downy mildew Toxicity Determination
After the effective inhibition concentration scope of each medicament was confirmed in prerun, each medicament was established 7 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament cucumber downy mildew.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is following:
Wherein: a, b are respectively mandipropamid amine and metalaxyl (or Metalaxyl-M) shared ratio in combination
A is a mandipropamid amine
B is metalaxyl (or Metalaxyl-M)
Result of the test is as shown in the table:
Table 1 mandipropamid amine, metalaxyl and composite toxicity test analysis of results table thereof to cucumber downy mildew
Can know that by table 1 mandipropamid amine, metalaxyl are to the EC of cucumber downy mildew
50Be respectively 0.392mg/L and 12.388mg/L.The virulence of mandipropamid amine is higher than the virulence of metalaxyl.6: 1,3: 1,1: 1,1: 3,1: 6,1: 9,1: 12 synergy ratio of mandipropamid amine and metalaxyl proportioning is respectively 1.537,1.718,2.021,2.548,1.968,1.849,1.558; Explaining that mandipropamid amine and metalaxyl were mixed in the scope at 6: 1～1: 12 all shows obvious synergistic effect; Wherein synergy ratio SR is maximum when mandipropamid amine and Metalaxyl-M weight ratio are 1: 3, and synergistic effect is the most obvious.
Table 2 mandipropamid amine, Metalaxyl-M and composite toxicity test analysis of results table thereof to cucumber downy mildew
Can know that by table 1 mandipropamid amine, Metalaxyl-M are to the EC of cucumber downy mildew
50Be respectively 0.392mg/L and 1.264mg/L.The virulence of mandipropamid amine is higher than the virulence of Metalaxyl-M.9: 1,6: 1,3: 1,1: 1,1: 3,1: 6,1: 9 synergy ratio of mandipropamid amine and Metalaxyl-M proportioning is respectively 1.531,1.739,1.926,2.394,1.893,1.651,1.516; Explaining that mandipropamid amine and Metalaxyl-M were mixed in the scope at 9: 1～1: 9 all shows obvious synergistic effect; Wherein synergy ratio SR is maximum when mandipropamid amine and Metalaxyl-M weight ratio are 1: 1, and synergistic effect is the most obvious.
Practice example two and implement the prescription example
(1) mandipropamid amine Metalaxyl-M:
Embodiment 1 50% mandipropamid amine Metalaxyl-M wetting powder
Mandipropamid amine 45%, Metalaxyl-M 5%, lignosulfonates 5%, neopelex 3%, spaonin powder 2%, fine particle calcium carbonate 10%, attapulgite 30%, mixture carries out comminution by gas stream, makes 50% mandipropamid amine Metalaxyl-M wetting powder.
Embodiment 2 40% mandipropamid amine Metalaxyl-M wetting powders
Mandipropamid amine 20%, Metalaxyl-M 20%, polycarboxylate 5%, soapberry powder 3%, white carbon 27%, attapulgite 25%, mixture carries out comminution by gas stream, makes 40% mandipropamid amine Metalaxyl-M wetting powder.
Embodiment 3 15% mandipropamid amine Metalaxyl-M wetting powders
Mandipropamid amine 5%, Metalaxyl-M 10%, alkylphenol-polyethenoxy are phonetic 5%, silkworm excrement 3%, white carbon 15% attapulgite 62%, and mixture carries out comminution by gas stream, makes 15% mandipropamid amine Metalaxyl-M wetting powder.
Embodiment 4 70% mandipropamid amine Metalaxyl-M water dispersible granules
Mandipropamid amine 60%, Metalaxyl-M 10%, polycarboxylate 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, white carbon 20%, the mixed 70% mandipropamid amine Metalaxyl-M water dispersible granules that gets.
Embodiment 5 40% mandipropamid amine Metalaxyl-M water dispersible granules
Mandipropamid amine 10%, Metalaxyl-M 30%, alkylphenol-polyethenoxy are phonetic 5%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, aluminium-magnesium silicate 10%, attapulgite 35%, mixed 40% mandipropamid amine Metalaxyl-M water dispersible granules.
Embodiment 6 28% mandipropamid amine Metalaxyl-M water dispersible granules
Mandipropamid amine 4%, Metalaxyl-M 24%, alkylphenol-polyethenoxy are phonetic 5%, dodecyl benzene sulfonate 3%, starch 10%, white carbon 32%, attapulgite 12%, mixed 28% mandipropamid amine Metalaxyl-M water dispersible granules.
Embodiment 7 50% mandipropamid amine Metalaxyl-M microemulsions
Mandipropamid amine 40%, Metalaxyl-M 10%, normal octane 20%, acetone 15%, EGME 2%, farming breast 34
#5%, triethanolamine salt 5%, ethylene glycol 2%, silicone oil 0.4%, deionized water supplies 100%, the mixed 50% mandipropamid amine Metalaxyl-M microemulsion that gets.
Embodiment 8 35% mandipropamid amine Metalaxyl-M microemulsions
Mandipropamid amine 30%, Metalaxyl-M 5%, carrene 17%, ethyl acetate 13%, N-pyrrolidones 4%, tween 4%, farming breast 600
#3%, Nongru-700
#5%, propane diols 3%, silicone oil 0.4%, deionized water supplies 100%, the mixed 35% mandipropamid amine Metalaxyl-M microemulsion that gets.
Embodiment 9 30% mandipropamid amine Metalaxyl-M microemulsions
Mandipropamid amine 3%, Metalaxyl-M 27%, ethyl acetate 20%, vegetable oil 10%, sapn series 8%, styrene polyoxyethylene ether ammonium sulfate salt 7%, propane diols 3%, silicone oil 0.4%; Deionized water supplies 100%, the mixed 30% mandipropamid amine Metalaxyl-M microemulsion that gets.
(2) mandipropamid amine metalaxyl
Embodiment 10 80% mandipropamid amine metalaxyl wetting powders
Mandipropamid amine 20%, metalaxyl 60%, lignosulfonates 3%, neopelex 5%, bentonite 12%, mixture carries out comminution by gas stream, makes 80% mandipropamid amine metalaxyl wetting powder.
Embodiment 11 60% mandipropamid amine metalaxyl wetting powders
Mandipropamid amine 45%, metalaxyl 15%, polycarboxylate 5%, spaonin powder 3%, white carbon 5%, bentonite 27%, mixture carries out comminution by gas stream, makes 60% mandipropamid amine metalaxyl wetting powder.
Embodiment 12 35% mandipropamid amine metalaxyl wetting powders
Mandipropamid amine 30%, metalaxyl 5%, alkylphenol-polyethenoxy are phonetic 4%, soapberry powder 4%, white carbon 14%, bentonite 20%, and mixture carries out comminution by gas stream, makes 30% mandipropamid amine metalaxyl wetting powder.
Embodiment 13 65% mandipropamid amine metalaxyl water dispersible granules
Mandipropamid amine 5%, metalaxyl 60%, alkylphenol-polyethenoxy are phonetic 3%, polyoxyethylene carboxylate 3%, dodecyl sulphate calcium 4%, bentonite 25%, mixed 65% mandipropamid amine metalaxyl water dispersible granules.
Embodiment 14 60% mandipropamid amine metalaxyl water dispersible granules
Mandipropamid amine 15%, metalaxyl 45%, polycarboxylate 3%, lignosulfonates 5%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, kaolin 25%, the mixed 60% mandipropamid amine metalaxyl water dispersible granules that gets.
Embodiment 15 45% mandipropamid amine metalaxyl water dispersible granules
Mandipropamid amine 40%, metalaxyl 5%, alkylphenol-polyethenoxy are phonetic 6%, DBSA 4%, starch 15%, diatomite 30%, mixed 45% mandipropamid amine metalaxyl water dispersible granules.
Embodiment 16 45% mandipropamid amine metalaxyl microemulsions
Mandipropamid amine 5%, metalaxyl 40%, ethanol 20%, vegetable oil 10%, sapn series 8%, styrene polyoxyethylene ether ammonium sulfate salt 7%, propane diols 3%, silicone oil 0.4%; Deionized water supplies 100%, the mixed 45% mandipropamid amine metalaxyl microemulsion that gets.
Embodiment 17 40% mandipropamid amine metalaxyl microemulsions
Mandipropamid amine 10%, metalaxyl 30%, toluene 15%, acetone 15%, EGME 4%, ethyl acetate 8%, farming breast 34
#6%, triethanolamine salt 6%, ethylene glycol 2%, silicone oil 0.4%, deionized water supplies 100%, the mixed 40% mandipropamid amine metalaxyl microemulsion that gets.
Embodiment 18 35% mandipropamid amine metalaxyl microemulsions
Mandipropamid amine 5%, metalaxyl 30%, ethanol 17%, acetone 15%, EGME 4%, farming breast 500
#6%, triethanolamine salt 6%, glycerine 2%, silicone oil 0.4%, deionized water supplies 100%, and deionized water adds to 100%, the mixed 35% mandipropamid amine metalaxyl microemulsion that gets.
Embodiment use three contain mandipropamid amine the bactericidal composition control capsicum epidemic disease test of pesticide effectiveness
This EE is in the Jize County, Hebei province; Test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 350g/L Metalaxyl-M emulsion (commercial), 25% metalaxyl wetting powder (commercial), 250g/L mandipropamid amine microemulsion (commercial).
The investigation capsicum epidemic disease state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigate the capsicum epidemic disease disease index respectively in 7 days, 14 days behind the last medicine and calculate preventive effect.Experimental result is as follows:
Table 3 contains the bactericidal composition control capsicum epidemic disease test of pesticide effectiveness of mandipropamid amine
Can be found out that by table 3 can effectively prevent and treat capsicum epidemic disease after mandipropamid amine and metalaxyl or Metalaxyl-M are composite, control efficiency all is superior to contrasting medicament, the lasting period is long.In the test scope of medication, the target crop is had no adverse effects, preventive effect reaches more than 90%.
Practice example four: the bactericidal composition control cucumber downy mildew test of pesticide effectiveness that contains mandipropamid amine
This EE is Changan District in the Xian City, Shanxi Province; Test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 350g/L Metalaxyl-M emulsion (commercial), 25% metalaxyl wetting powder (commercial), 250g/L mandipropamid amine microemulsion (commercial).
Investigation cucumber downy mildew state of an illness radix before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively in 7 days, 14 days behind the last medicine and calculates preventive effect.Experimental result is as follows:
Table 4 contains the bactericidal composition control cucumber downy mildew test of pesticide effectiveness of mandipropamid amine
Can be found out that by table 4 can effectively prevent and treat cucumber downy mildew after mandipropamid amine and metalaxyl or Metalaxyl-M are composite and take place, control efficiency all is superior to contrasting medicament, in this test scope of medication, the target crop is had no adverse effects, preventive effect reaches more than 90%.
Practice example five: the bactericidal composition that contains mandipropamid amine is prevented and treated the downy mildew of garpe test of pesticide effectiveness
This EE is in Lantian, Xian City, Shanxi Province district; Test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 350g/L Metalaxyl-M emulsion (commercial), 25% metalaxyl wetting powder (commercial), 250g/L mandipropamid amine microemulsion (commercial).
Investigation downy mildew of garpe state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 3 times, investigates disease index respectively in 7 days, 14 days behind the last medicine and calculates preventive effect.Experimental result is as follows:
Table 5 contains the bactericidal composition of mandipropamid amine and prevents and treats the downy mildew of garpe test of pesticide effectiveness
Can be found out that by table 5 can effectively prevent and treat downy mildew of garpe after mandipropamid amine and Metalaxyl-M are composite and take place, control efficiency all is superior to contrasting medicament, in this test scope of medication, the target crop is had no adverse effects, preventive effect reaches more than 90%.
Claims (6)
1. bactericidal composition that contains mandipropamid amine is characterized in that bactericidal composition effective active composition (A) the mandipropamid amine and (B) weight ratio of metalaxyl or Metalaxyl-M are 1～60: 60～1.
2. the bactericidal composition that contains mandipropamid amine according to claim 1 is characterized in that: wherein (A) mandipropamid amine is 5～30: 60～5 with (B) weight ratio of metalaxyl.
3. the bactericidal composition that contains mandipropamid amine according to claim 1 is characterized in that: wherein (A) mandipropamid amine is 1～30: 30～1 with (B) weight ratio of Metalaxyl-M.
4. the bactericidal composition that contains mandipropamid amine according to claim 1 is characterized in that: wherein the effective active component content accounts for 1～80% of gross weight.
5. the bactericidal composition that contains mandipropamid amine according to claim 4 is characterized in that: wherein the effective active component content accounts for 10～60% of gross weight.
6. the bactericidal composition that contains mandipropamid amine according to claim 1 is characterized in that: bactericidal composition is processed wetting powder, water dispersible granules or microemulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105351468A CN102461500A (en) | 2010-11-08 | 2010-11-08 | Bactericidal composition containing mandipropamid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105351468A CN102461500A (en) | 2010-11-08 | 2010-11-08 | Bactericidal composition containing mandipropamid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102461500A true CN102461500A (en) | 2012-05-23 |
Family
ID=46065851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105351468A Pending CN102461500A (en) | 2010-11-08 | 2010-11-08 | Bactericidal composition containing mandipropamid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102461500A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105028417A (en) * | 2015-06-08 | 2015-11-11 | 柳州市天姿园艺有限公司 | Composition for preventing and treating phytophthora root rot of cymbidium kanran |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005110080A2 (en) * | 2004-05-13 | 2005-11-24 | Basf Aktiengesellschaft | Fungicidal mixtures and novel triazolopyrimidines |
| WO2010118946A2 (en) * | 2009-04-15 | 2010-10-21 | Syngenta Participations Ag | Fungicidal mixtures |
-
2010
- 2010-11-08 CN CN2010105351468A patent/CN102461500A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005110080A2 (en) * | 2004-05-13 | 2005-11-24 | Basf Aktiengesellschaft | Fungicidal mixtures and novel triazolopyrimidines |
| WO2010118946A2 (en) * | 2009-04-15 | 2010-10-21 | Syngenta Participations Ag | Fungicidal mixtures |
Non-Patent Citations (3)
| Title |
|---|
| LOUISE R.COOKE等: "Evaluation of mandipropamid for the control of potato late blight in North Ireland", 《TWELFTH EUROBLIGHT WORKSHORP ARRAS(FRANCE)》 * |
| 赵卫松等: "辣椒疫霉菌对甲霜灵的敏感性和不同杀菌剂的交互抗性", 《农药》 * |
| 马辉杰等: "黄瓜霜霉病菌抗药性的发生及化学防治", 《河北农业科学》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105028417A (en) * | 2015-06-08 | 2015-11-11 | 柳州市天姿园艺有限公司 | Composition for preventing and treating phytophthora root rot of cymbidium kanran |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102302025A (en) | Bactericidal composition containing pyraclostrobin and thiocarbamate | |
| CN102047898A (en) | Bactericidal composition containing prochloraz and methoxy acrylic acid ester type compound | |
| CN102100234B (en) | Sterilization composition containing pyraclostrobin and carbamates | |
| CN102007912B (en) | Cyprodinil-containing germicide composition | |
| CN102308823B (en) | Bactericide composition containing pyraclostrobin | |
| CN102461501A (en) | Bactericidal composition containing mandipropamid and cyazofamid | |
| CN101990895B (en) | Germicidal composition of mandipropamid | |
| CN102308801A (en) | Germicide composition containing spiroxamine and antibiotics compound | |
| CN101999380B (en) | Difenoconazole- and propineb-containing pesticidal composition | |
| CN101999362B (en) | Fenoxanil and epoxiconazole-containing bactericidal composition | |
| CN102461500A (en) | Bactericidal composition containing mandipropamid | |
| CN102461526A (en) | Germicide composition containing mandipropamid | |
| CN102232382A (en) | Bactericidal composition containing trifloxystrobin and thiocarbamates | |
| CN101755823A (en) | Fungicidal composition containing flusilazole and pyrimethanil | |
| CN101755792B (en) | Fungicidal composition containing kresoxim methyl and thiophanate methyl | |
| CN101836639B (en) | Sterilization composition containing kresoxim and thiabendazole | |
| CN101731248B (en) | Penconazole-containing and thioneb-containing sterilizing composition | |
| CN101720774B (en) | Bactericide composition containing penconazole and propineb | |
| CN101715767B (en) | Bactericidal composition containing kresoxim-methyl and penconazole | |
| CN103918670B (en) | A kind of bactericidal composition containing pyrimorph and Boscalid | |
| CN101999390A (en) | Antibacterial composition containing prochloraz and thiocatbamate compounds | |
| CN101715772B (en) | Bactericidal composition containing carbendazim and ethirimol | |
| CN103719103A (en) | Flutriafol-containing sterilization composite | |
| CN101743973B (en) | Bactericidal composition containing penconazole and chlorothalonil | |
| CN101971813B (en) | Sterilization composition containing mandipropamid and azoxystrobin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 715500 middle section of North Ring Road, Pucheng County, Shaanxi Applicant after: Shanxi Thompson Biological Technology Co., Ltd. Address before: 710075, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Applicant before: Shanxi Thompson Biological Technology Co., Ltd. |
|
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120523 |