CN102458653A - 用于电化学应用的催化剂 - Google Patents

用于电化学应用的催化剂 Download PDF

Info

Publication number
CN102458653A
CN102458653A CN2010800341805A CN201080034180A CN102458653A CN 102458653 A CN102458653 A CN 102458653A CN 2010800341805 A CN2010800341805 A CN 2010800341805A CN 201080034180 A CN201080034180 A CN 201080034180A CN 102458653 A CN102458653 A CN 102458653A
Authority
CN
China
Prior art keywords
catalyst
transition metal
platinum
nickel
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010800341805A
Other languages
English (en)
Chinese (zh)
Inventor
E·施瓦布
S·布罗伊宁格
A·潘琴科
C·奎尔纳
O·因萨尔
M·沃格特
Q·何
N·拉马斯瓦米
S·穆克尔耶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN102458653A publication Critical patent/CN102458653A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913Cobalt and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892Nickel and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/898Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with vanadium, tantalum, niobium or polonium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8986Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • H01M4/921Alloys or mixtures with metallic elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • H01M4/925Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/08Fuel cells with aqueous electrolytes
    • H01M8/086Phosphoric acid fuel cells [PAFC]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Inert Electrodes (AREA)
CN2010800341805A 2009-06-02 2010-05-27 用于电化学应用的催化剂 Pending CN102458653A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US18325109P 2009-06-02 2009-06-02
US61/183,251 2009-06-02
PCT/EP2010/057313 WO2010139596A2 (en) 2009-06-02 2010-05-27 Catalyst for electrochemical applications

Publications (1)

Publication Number Publication Date
CN102458653A true CN102458653A (zh) 2012-05-16

Family

ID=43037069

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010800341805A Pending CN102458653A (zh) 2009-06-02 2010-05-27 用于电化学应用的催化剂

Country Status (6)

Country Link
US (1) US20120094199A1 (enExample)
EP (1) EP2437883A2 (enExample)
JP (1) JP2012529135A (enExample)
KR (1) KR20120024889A (enExample)
CN (1) CN102458653A (enExample)
WO (1) WO2010139596A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112536042A (zh) * 2020-11-19 2021-03-23 福州大学 一种甲醇催化氧化光电催化剂的制备方法

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010033829A1 (en) 2008-09-18 2010-03-25 Northeastern University Platinum alloy electrocatalyst with enhanced resistance to anion poisoning for low and medium temperature fuel cells
WO2011139693A2 (en) * 2010-04-26 2011-11-10 3M Innovative Properties Company Platinum nickel catalyst alloy
US9095845B2 (en) 2010-10-21 2015-08-04 Basf Se Catalyst support material comprising polyazole salt, electrochemical catalyst, and the preparation of a gas diffusion electrode and a membrane-electrode assembly therefrom
JP6008272B2 (ja) * 2012-04-24 2016-10-19 国立大学法人名古屋大学 金属ナノクスラスター担持カーボン多孔体の製造方法
JP6232505B2 (ja) * 2014-10-24 2017-11-15 株式会社キャタラー 燃料電池用電極触媒及びその製造方法
TWI618290B (zh) * 2015-08-27 2018-03-11 Univ Osaka 金屬奈米粒子的製造方法、載置金屬奈米粒子的載體的製造方法、及載置金屬奈米粒子的載體
JP6581455B2 (ja) * 2015-09-30 2019-09-25 ダイハツ工業株式会社 酸素還元触媒における過酸化水素の発生率推定方法
CN105655600A (zh) * 2016-03-22 2016-06-08 陈波 一种Pt-Mn-石墨烯燃料电池催化剂的制备方法
KR20180013629A (ko) * 2016-07-29 2018-02-07 에스케이하이닉스 주식회사 다층 자성 박막 스택 및 이를 포함하는 데이터 저장 장치
CN110799266B (zh) * 2018-05-30 2020-12-18 南方科技大学 金硫化镍核壳结构纳米电催化剂及其制备方法
KR102478160B1 (ko) * 2019-10-30 2022-12-15 부산대학교 산학협력단 연료전지용 이종금속나노입자-탄소 혼성 촉매, 이의 제조방법 및 이를 포함하는 연료전지
KR20220091754A (ko) * 2020-12-24 2022-07-01 현대자동차주식회사 인터메탈릭 촉매 및 이의 제조 방법
EP4074415A1 (en) * 2021-04-16 2022-10-19 Basf Corporation Novel nanoparticle alloys and catalytic compositions comprising the same for emission controls

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2697118A1 (en) * 2007-08-24 2009-03-05 Basf Se Catalyst and process for producing it and its use
WO2009060019A1 (de) * 2007-11-09 2009-05-14 Basf Se Verfahren zur herstellung eines katalysators sowie verwendung als elektrokatalysator
CN102164668A (zh) * 2008-08-26 2011-08-24 巴斯夫欧洲公司 连续生产催化剂的方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1140168A (ja) * 1997-07-15 1999-02-12 Jatco Corp ガス拡散電極及び該ガス拡散電極を用いた燃料電池
US7208437B2 (en) * 2004-01-16 2007-04-24 T/J Technologies, Inc. Catalyst and method for its manufacture

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2697118A1 (en) * 2007-08-24 2009-03-05 Basf Se Catalyst and process for producing it and its use
WO2009060019A1 (de) * 2007-11-09 2009-05-14 Basf Se Verfahren zur herstellung eines katalysators sowie verwendung als elektrokatalysator
CN102164668A (zh) * 2008-08-26 2011-08-24 巴斯夫欧洲公司 连续生产催化剂的方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112536042A (zh) * 2020-11-19 2021-03-23 福州大学 一种甲醇催化氧化光电催化剂的制备方法

Also Published As

Publication number Publication date
JP2012529135A (ja) 2012-11-15
EP2437883A2 (en) 2012-04-11
WO2010139596A2 (en) 2010-12-09
KR20120024889A (ko) 2012-03-14
US20120094199A1 (en) 2012-04-19
WO2010139596A3 (en) 2011-02-24

Similar Documents

Publication Publication Date Title
CN102458653A (zh) 用于电化学应用的催化剂
Calderón et al. Electrochemical oxidation of CO and methanol on Pt–Ru catalysts supported on carbon nanofibers: The influence of synthesis method
US8912114B2 (en) Platinum alloy electrocatalyst with enhanced resistance to anion poisoning for low and medium temperature fuel cells
US10844501B2 (en) Carbon supported single atom carbon dioxide reduction electro catalysts
Kim et al. Effect of surface oxygen functionalization of carbon support on the activity and durability of Pt/C catalysts for the oxygen reduction reaction
Xu et al. Nanoporous PdNi alloys as highly active and methanol-tolerant electrocatalysts towards oxygen reduction reaction
Amin et al. Electrocatalytic activity of nanostructured Ni and Pd–Ni on Vulcan XC-72R carbon black for methanol oxidation in alkaline medium
JP4401059B2 (ja) 燃料電池用のアノード触媒を調製するプロセスおよびそのプロセスを用いて調製されたアノード触媒
US9054355B2 (en) Catalyst with metal oxide doping for fuel cells
Bhunia et al. Trimetallic PtAuNi alloy nanoparticles as an efficient electrocatalyst for the methanol electrooxidation reaction
CN102164668B (zh) 连续生产催化剂的方法
Li et al. Architecture of PtFe/C catalyst with high activity and durability for oxygen reduction reaction
Wang et al. Microfluidic synthesis and characterization of FePtSn/C catalysts with enhanced electro-catalytic performance for direct methanol fuel cells
Sharma et al. Graphene–cobaltite–Pd hybrid materials for use as efficient bifunctional electrocatalysts in alkaline direct methanol fuel cells
Lee et al. Octahedral Pt-Pd alloy catalysts with enhanced oxygen reduction activity and stability in proton exchange membrane fuel cells
Chen et al. A non-intermetallic PtPb/C catalyst of hollow structure with high activity and stability for electrooxidation of formic acid
Hernández-Ramírez et al. Evaluation of the nickel titanate-modified Pt nanostructured catalyst for the ORR in alkaline media
WO2020065005A1 (en) Process for producing alloy nanoparticles
Cheng et al. Enhanced activity and stability of core–shell structured PtRuNix electrocatalysts for direct methanol fuel cells
Liu et al. Development of ruthenium-based bimetallic electrocatalysts for oxygen reduction reaction
Crabb et al. Effect of Ru surface composition on the CO tolerance of Ru modified carbon supported Pt catalysts
JP5313891B2 (ja) カーボンに担持された白金・タングステン電極触媒およびその製造方法
Li et al. Multi-skeletal PtPdNi nanodendrites as efficient electrocatalyst with high activity and durability towards oxygen reduction reaction
Rao et al. Pt–Co electrocatalyst with varying atomic percentage of transition metal
Obradović et al. Core-shell structured tungsten–tungsten carbide as a Pt catalyst support and its activity for methanol electrooxidation

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C05 Deemed withdrawal (patent law before 1993)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20120516