CN102413684B - 含有农药、防腐剂和未支化1,2-链烷二醇的组合物 - Google Patents
含有农药、防腐剂和未支化1,2-链烷二醇的组合物 Download PDFInfo
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- CN102413684B CN102413684B CN201080018511.6A CN201080018511A CN102413684B CN 102413684 B CN102413684 B CN 102413684B CN 201080018511 A CN201080018511 A CN 201080018511A CN 102413684 B CN102413684 B CN 102413684B
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- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- MCVUKOYZUCWLQQ-UHFFFAOYSA-N tridecylbenzene Chemical compound CCCCCCCCCCCCCC1=CC=CC=C1 MCVUKOYZUCWLQQ-UHFFFAOYSA-N 0.000 description 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- Pest Control & Pesticides (AREA)
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明涉及一种包含农药、防腐剂和具有5-10个碳原子的未支化1,2-链烷二醇的农业化学组合物。本发明进一步涉及一种通过混合农药、防腐剂和具有5-10个碳原子的未支化1,2-链烷二醇而制备该组合物的方法。此外,本发明涉及该组合物在防治植物病原性真菌和/或不希望的植物生长和/或不希望的昆虫或螨虫侵袭和/或调节植物生长中的用途以及该组合物在植物上控制不希望的昆虫或螨虫侵袭和/或防治植物病原性真菌和/或防止不希望的植物生长的用途,其中用该组合物处理有用植物的种子,本发明最后涉及用该组合物处理的种子。
Description
本发明涉及一种包含农药、防腐剂和具有5-10个碳原子的未支化1,2-链烷二醇的农业化学组合物。本发明进一步涉及一种通过混合农药、防腐剂和具有5-10个碳原子的未支化1,2-链烷二醇而制备该组合物的方法。此外,本发明涉及该组合物在防治植物病原性真菌和/或不希望的植物生长和/或不希望的昆虫或螨虫侵袭和/或调节植物生长中的用途以及该组合物在植物上控制不希望的昆虫或螨虫侵袭和/或防治植物病原性真菌和/或防止不希望的植物生长的用途,其中用该组合物处理有用植物的种子,本发明最后涉及用该组合物处理的种子。优选特征与其他优选特征的组合也由本发明包括。
EP 1 201 125 A1公开了一种包含3-甲氧基丁醇和1,2-戊二醇的经皮软膏组合物。此外还公开了这些产品的联合使用导致优异的防腐效果。
EP 1 426 029 A1公开了一种乳液组合物,其中1,2-链烷二醇、表面活性剂、油状物质和水作为必要组分存在。
WO 2003/069994公开了两种、三种或更多种未支化1,2-链烷二醇的混合物作为抗微生物活性物质的用途。作为该混合物中的其他组分,可以以协同增效地提高链烷二醇混合物的抗微生物活性的量使用抗微生物活性物质。
Pillai等在 -Journal,2005,131(6),13-22(“1,2-戊二醇-用于个人护理应用的多功能成分”)中公开了1,2-戊二醇在化妆品配制剂中提高防腐剂苯氧基乙醇、对羟基苯甲酸甲酯、对羟基苯甲酸丁酯、对羟基苯甲酸丙酯和对羟基苯甲酸异丁酯的混合物的防腐活性。
防腐剂在农业化学制剂中的使用长时间以来是已知的。不加入或者不足量地加入防腐剂,主要由于微生物生长而出现各种问题:放出气体,因而含有农业化学组合物的塑料罐或金属桶可能爆炸;产生不舒服的臭味,这在杀虫或杀鼠组合物中可能导致对昆虫或啮齿动物的排斥效果;变色; pH变化,某些农药对该变化敏感;包含多糖的增稠剂降解引起粘度变化,从而可能在喷雾施用时出现问题;或乳液或悬浮液由于表面活性剂的微生物降解而出现相分离或沉降,这可能在配制桶混物并施用它们时产生问题。
上述问题尤其降低农业化学制剂的储存稳定性,因为后者通常不是储存在环境受控的空间,而是敞开储存。理论上讲,农业化学组合物可以通过加入高浓度的防腐剂而长时间稳定,从而鲜见上述问题。然而,各种防腐剂,如对羟基苯甲酸及其酯、甲醛释放剂、氯己定、苯扎氯铵、丙酸,苯氧基乙醇被怀疑是变应性的或有毒的。
因此,本发明的目的是发现一种包含农药和防腐剂的农业化学组合物,该组合物的特征在于防腐剂的浓度降低。另一目的是防腐剂在农业化学组合物中的抗微生物活性非常高,甚至在降低浓度下。此外,目的是待发现的农业化学组合物此外还可以无问题地配制,可以使用常规农业化学配制助剂,可以使用常规农业化学施用技术如喷雾或拌种和/或杀虫或杀鼠活性不受不希望的臭味或气味的不利影响。
该目的由一种包含农药、防腐剂和具有5-10个碳原子的未支化1,2-链烷二醇的农业化学组合物实现。
优选具有5-10个碳原子的未支化1,2-链烷二醇为1,2-戊二醇、1,2-己二醇、1,2-辛二醇和1,2-癸二醇。尤其优选1,2-戊二醇。1,2-戊二醇可以以各种纯度市购,例如至少70重量%到至少99.95重量%。本发明组合物通常包含0.01-10重量%,优选0.1-8重量%,尤其优选0.5-3重量%链烷二醇。
术语农药(下文也称为植物保护剂)指至少一种选自杀真菌剂、杀虫剂、杀线虫剂、除草剂、杀鼠剂、安全剂和/或生长调节剂的活性物质,优选杀虫剂、杀线虫剂、除草剂、杀鼠剂、安全剂和/或生长调节剂。对于农药,本领域熟练技术人员通常理解为用于农业化学组合物中的那些活性物质。
在优选实施方案中,植物保护剂为用于下列目的的物质:a)保护植物或活的植物部分和植物产品以防有害生物体;b)保护植物或活的植物部分和植物产品以防动物、植物或不为有害生物体的微生物;c)参与植物的生物过程而不用于其营养(如生长调节剂);以及d)破坏植物或抑制或防止植物生长。
本领域熟练技术人员通常知道植物保护剂被清楚地以法律术语定义和管理,例如在涉及植物保护剂的许可、限制在食品或饮用水中的残留、保护蜜蜂、正确使用、禁止危险的植物保护剂如DDT或林丹(lindane)的法律中。因此,本领域熟练技术人员清楚地区分植物保护剂(如杀真菌剂)和药物(如杀真菌药、抗生素或消毒剂)或用于化妆品中的物质。
优选的农药是杀真菌剂、杀虫剂、杀鼠剂和除草剂,特别优选杀虫剂、杀鼠剂和除草剂。还可以使用两种或更多种上述类别的农药的混合物。熟练技术人员熟知该类农药,例如它们可以在Pesticide Manual,第14版(2006),The British Crop Protection Council,London中找到。合适的杀虫剂是选自如下类别的杀虫剂:氨基甲酸酯类、有机磷酸酯类、有机氯杀虫剂、苯基吡唑类、合成除虫菊酯类、新类烟碱类、斯皮诺素类(spinosins)、阿维菌素类(avermectins)、米尔霉素类(milbemycins)、保幼激素类似物、烷基卤、有机锡化合物、沙蚕毒素类似物、苯甲酰脲类、二酰基肼类、METI杀螨剂以及杀虫剂如氯化苦(chloropicrin)、拒嗪酮(pymetrozine)、氟啶虫酰胺(flonicamid)、四螨嗪(clofentezine)、噻螨酮(hexythiazox)、特苯 唑(etoxazole)、杀螨硫隆(diafenthiuron)、克螨特(propargite)、三氯杀螨砜(tetradifon)、氟唑虫清(chlorfenapyr)、二硝酚(DNOC)、噻嗪酮(buprofezin)、灭蝇胺(cyromazine)、双甲脒(amitraz)、灭蚁腙(hydramethylnon)、灭螨醌(acequinocyl)、fluacrypyrim、鱼藤酮(rotenon)或其衍生物。合适的杀真菌剂是如下类别的杀真菌剂:二硝基苯胺类、烯丙基胺类、苯胺基嘧啶类、抗生素类、芳族烃类、苯磺酰胺类、苯并咪唑类、苯并异噻唑类、二苯甲酮类、苯并噻二唑类、苯并三嗪类、苄基氨基甲酸酯类、氨基甲酸酯类、羧酰胺类、羧酸酰胺类、氯代腈类、氰基乙酰胺肟类、氰基咪唑类、环丙烷羧酰胺类、二羧酰亚胺类、二氢二 嗪类、二硝基苯基巴豆酸酯类、二硫代氨基甲酸酯类、二硫戊环类、乙基膦酸酯类、乙基氨基噻唑羧酰胺类、胍类、羟基-(2-氨基-)嘧啶类、羟基酰替苯胺类、咪唑类、咪唑啉酮类、无机物质、异苯并呋喃酮类、甲氧基丙烯酸酯类、甲氧基氨基甲酸酯类、吗啉类、N-苯基氨基甲酸酯类、 唑烷二酮类、肟基乙酸酯类、肟基乙酰胺类、肽基嘧啶核苷、苯基乙酰胺类、苯基酰胺类、苯基吡咯类、苯基脲类、 膦酸酯类、硫代磷酸酯类、邻氨甲酰苯甲酸类、苯邻二甲酰亚胺类、哌嗪类、哌啶类、丙酰胺类、哒嗪酮类、吡啶类、吡啶基甲基苯甲酰胺类、嘧啶胺类、嘧啶类、嘧啶酮腙类、吡咯并喹啉酮类、喹唑啉酮类、喹啉类、醌类、磺酰胺类、氨磺酰三唑类、噻唑羧酰胺类、硫代氨基甲酸酯类、托布津类(thiophanates)、噻吩羧酰胺类、甲苯甲酰胺类、三苯基锡化合物、三嗪类、三唑类。合适的除草剂是如下类别的除草剂:乙酰胺类、酰胺类、芳氧基苯氧基丙酸酯类、苯甲酰胺类、苯并呋喃、苯甲酸类、苯并噻二嗪酮类、联吡啶 氨基甲酸酯类、氯代乙酰胺类、氯代羧酸、环己烷二酮类、二硝基苯胺类、二硝基苯酚类、二苯基醚类、甘氨酸类、咪唑啉酮类、异 唑类、异 唑烷酮类、腈类、N-苯基苯邻二甲酰亚胺类、 二唑类、 唑烷二酮类、羟乙酰胺类、苯氧基羧酸类、苯基氨基甲酸酯类、苯基吡唑类、苯基吡唑啉类、苯基哒嗪类、次膦酸类、氨基磷酸酯类、二硫代磷酸酯类、邻氨甲酰苯甲酸酯类、吡唑类、哒嗪酮类、吡啶类、吡啶羧酸类、吡啶羧酰胺类、嘧啶二酮类、嘧啶基(硫代)苯甲酸酯类、喹啉羧酸类、缩氨基脲类、磺酰氨基羰基三唑啉酮类、磺酰脲类、四唑啉酮类、噻二唑类、硫代氨基甲酸酯类、三嗪类、三嗪酮类、三唑类、三唑啉酮类、三唑并羧酰胺类、三唑并嘧啶类、三酮类、尿嘧啶类、脲类。合适类别的杀鼠剂包括抗凝血剂,无机杀鼠剂,有机氯杀鼠剂,有机磷杀鼠剂,嘧啶胺类杀鼠剂,硫脲杀鼠剂,脲杀鼠剂。
在一个实施方案中,农药包含杀虫剂;优选农药由至少一种杀虫剂构成。在另一实施方案中,农药包含杀真菌剂;优选农药由至少一种杀真菌剂构成。优选的杀真菌剂是唑菌胺酯(pyraclostrobin)、环戊唑菌(metconazole)和氧唑菌(epoxiconazole)。在另一实施方案中,农药包含除草剂;优选农药由至少一种除草剂构成。在另一实施方案中,农药包含杀鼠剂,优选抗凝血剂,尤其是香豆素衍生物,尤其优选氟鼠酮(flocoumafen)和敌拿鼠(difenacoum)。此外还优选抗凝血剂与麦角骨化醇或维生素D3的混合物。
本发明组合物基于该组合物通常包含0.1-70重量%,优选1-50重量%,尤其是3-30重量%农药。
防腐剂通常为加入农业化学组合物中以在微生物(如细菌和真菌)、昆虫和其他小的生物体影响方面延长后者的储存期限的那些化合物。优选的防腐剂具有杀菌和杀真菌活性,尤其是杀菌活性。
防腐剂的实例是苯甲酸、其酯和盐,对羟基苯甲酸(对羟基苯甲酸酯)、其酯和盐,丙酸及其盐,水杨酸及其盐,2,4-己二烯酸(山梨酸)及其盐,甲醛和低聚甲醛,2-羟基联苯醚及其盐,2-锌硫基吡啶N-氧化物,无机亚硫酸盐和亚硫酸氢盐,碘酸钠,氯丁醇,脱氢乙酸,甲酸,1,6-二(4-脒基-2-溴苯氧基)-正己烷及其盐,10-十一碳烯酸及其盐,5-氨基-1,3-二(2-乙基己基)-5-甲基六氢嘧啶,5-溴-5-硝基-1,3-二 烷,2-溴-2-硝基丙烷-1,3-二醇,2,4-二氯苄醇,N-(4-氯苯基)-N′-(3,4-二氯苯基)脲,4-氯间甲酚,2,4,4′-三氯-2′-羟基二苯基醚,4-氯-3,5-二甲基苯酚,1,1′-亚甲基二(3-(1-羟基甲基-2,4-二氧代咪唑烷-5-基)脲),聚(六亚甲基缩二胍)盐酸盐,2-苯氧基乙醇,六亚甲基四胺,1-(3-氯烯丙基)-3,5,7-三氮杂-1-氮 金刚烷氯化物,1(4-氯苯氧基)-1-(1H-咪唑-1-基)-3,3-二甲基-2-丁酮,1,3-二(羟基甲基)-5,5-二甲基-2,4-咪唑烷二酮,苄醇,吡啶酮乙醇胺盐(octopirox),1,2-二溴-2,4-二氰基丁烷,2,2′-亚甲基二(6-溴-4-氯苯酚),溴氯苯,二氯芬,2-苄基-4-氯苯酚,2-氯乙酰胺,氯己定,氯己定乙酸盐,氯己定葡糖酸盐,氯己定盐酸盐,1-苯氧基丙-2-醇,N-烷基(C12-C22)三甲基铵溴化物和氯化物,4,4-二甲基-1,3- 唑烷,N-羟甲基-N-(1,3-二(羟甲基)-2,5-二氧代咪唑烷-4-基)-N′-羟甲基脲,1,6-二(4-脒基苯氧基)-正己烷及其盐,戊二醛,5-乙基-1-氮杂-3,7-二氧杂双环(3.3.0)辛烷,3-(4-氯苯氧基)丙烷-1,2-二醇,季铵盐(Hyamine),烷基(C8-C18)二甲基苄基氯化铵,烷基(C8-C18)二甲基苄基溴化铵,烷基(C8-C18)二甲基苄基铵糖精酸盐,苄基半缩甲醛,丁基氨基甲酸3-碘-2-丙炔基酯,羟甲基氨基乙酸钠,十六烷基三甲基溴化铵,十六烷基氯化吡啶 2H-异噻唑-3-酮的衍生物(所谓的异噻唑啉酮衍生物)如烷基异噻唑啉酮类(例如2-甲基-2H-异噻唑-3-酮,MIT;氯-2-甲基-2H-异噻唑-3-酮,CIT),苯并异噻唑啉酮类(例如1,2-苯并异噻唑-3(2H)-酮,BIT,以 类型由ICI市购)或2-甲基-4,5-三亚甲基-2H-异噻唑-3-酮(MTIT),以及它们的混合物。
优选的防腐剂是丙酸及其盐,山梨酸及其盐,苯甲酸、其酯和盐,对 羟基苯甲酸及其盐,对羟基苯甲酸C1-C4烷基酯(对羟基苯甲酸烷基酯)以及异噻唑啉酮衍生物及其混合物,2-苯氧基乙醇,十六烷基三甲基溴化铵,十六烷基氯化吡啶 苄基半缩甲醛和二氯芬。尤其优选对羟基苯甲酸C1-C4烷基酯(对羟基苯甲酸烷基酯),异噻唑啉酮衍生物及其混合物以及2-苯氧基乙醇。
非常尤其优选的防腐剂是异噻唑啉酮衍生物及其混合物,如烷基异噻唑啉酮(例如MIT,CIT),苯并异噻唑啉酮类(例如BIT),MTIT,MIT和CIT的混合物或MIT和BIT的混合物。非常尤其优选异噻唑啉酮衍生物的混合物,如MIT和CIT的混合物或MIT和BIT的混合物,尤其是MIT和BIT的混合物。该类混合物通常以10∶1-1∶10,优选5∶1-1∶5,具体为3∶1-1∶3的重量比存在。
要使用的防腐剂浓度取决于在每种情况下使用的防腐剂。因此,合适的浓度在每种情况下由制造商提及或在现有技术中提及,例如:
-对于来自Thor GmbH的 MBS(2.5重量%BIT和2.5重量%MIT),推荐对农业化学配制剂加入25-250ppm活性物质(对应于0.0025-0.025重量%的BIT和MIT的总和)。
-对于来自Thor GmbH的 MBL(2.5重量%BIT,2.5重量%MIT和8重量%2-溴-2-硝基丙烷-1,3-二醇),推荐对农业化学配制剂加入0.05-0.5重量%(对应于0.0065-0.065重量%三种活性物质的总和)。
-对于来自Arch的 DL(9重量%BIT溶液),推荐对农业化学配制剂加入0.1-0.5重量%(对应于0.0001-0.0045重量%BIT)。
-对于来自Arch的 BD20(19.3重量%BIT悬浮液),推荐对农业化学配制剂加入0.1-0.5重量%(对应于0.0193-0.0965重量%BIT)。
因此,要在本发明组合物中使用的防腐剂浓度也取决于在每种情况下使用的防腐剂,但通常低于防腐剂制造商所推荐的量,或者在制造商推荐的较低范围。熟练技术人员可以通过简单的初步试验确定合适的防腐剂浓度:为此,测试不加入1,2-链烷二醇和加入链烷二醇并降低防腐剂浓度时组合物的的储存期限。然后选择与不加入链烷二醇的组合物具有同样长储存期限的降低的防腐剂浓度。
本发明组合物基于该组合物通常包含小于0.5重量%,优选小于0.1重量%,尤其优选小于0.05重量%,特别是小于0.02重量%的防腐剂。在防腐剂混合物的情况下,浓度数据涉及所有防腐剂的总和。在稀的含水防腐剂或已经以其他方式配制的防腐剂情况下,浓度数据涉及纯防腐剂。
在大多数情况下,本发明组合物包含配制助剂,助剂的选择通常取决于具体的使用形式或活性成分。合适助剂的实例是溶剂,固体载体,表面活性物质(如表面活性剂、加溶剂、保护性胶体、润湿剂和增粘剂),有机和无机增稠剂,防冻剂,消泡剂,任选的着色剂和粘合剂(例如用于种子处理)或诱饵材料和引诱剂(例如用于诱饵)。
合适的表面活性物质(助剂、润湿剂、增粘剂、分散剂或乳化剂)是芳族磺酸如木素磺酸( 类型,挪威Borregaard)、苯酚磺酸、萘磺酸( 类型,Akzo Nobel,USA)和二丁基萘磺酸( 类型,德国BASF)以及脂肪酸的碱金属、碱土金属和铵盐,烷基-和烷基芳基磺酸盐,烷基硫酸盐,月桂基醚硫酸盐和脂肪醇硫酸盐,以及硫酸化十六-、十七-和十八烷醇以及脂肪醇乙二醇醚的盐,磺化萘及其衍生物与甲醛的缩合物,萘或萘磺酸与苯酚和甲醛的缩合物,聚氧乙烯辛基酚醚,乙氧基化异辛基酚、辛基酚或壬基酚,烷基苯基聚乙二醇醚,三丁基苯基聚乙二醇醚,烷基芳基聚醚醇,异十三烷醇,脂肪醇/氧化乙烯缩合物,乙氧基化蓖麻油,聚氧乙烯烷基醚或聚氧丙烯烷基醚,月桂醇聚乙二醇醚乙酸酯,山梨醇酯,木素亚硫酸盐废液,以及蛋白质,变性蛋白,多糖(例如甲基纤维素),疏水改性淀粉,聚乙烯醇( 类型,瑞士Clariant),聚羧酸盐( 类型,德国BASF),聚烷氧基化物,聚乙烯胺( 类型,德国BASF),聚乙烯亚胺( 类型,德国BASF),聚乙烯吡咯烷酮及其共聚物。
特别合适的表面活性剂是阴离子、阳离子、非离子和两性表面活性剂,嵌段聚合物和聚电解质。合适的阴离子表面活性剂是磺酸、硫酸、磷酸或羧酸的碱金属、碱土金属或铵盐。磺酸盐的实例是烷基芳基磺酸盐、二苯基磺酸盐、α-烯烃磺酸盐、脂肪酸和油的磺酸盐、乙氧基化烷基酚的磺酸盐、缩合萘的磺酸盐、十二烷基-和十三烷基苯的磺酸盐、萘和烷基萘的磺酸盐、磺基琥珀酸盐或磺基琥珀酰胺酸盐。硫酸盐的实例是脂肪酸和油的 硫酸盐、乙氧基化烷基酚的硫酸盐、醇的硫酸盐、乙氧基化醇的硫酸盐或脂肪酸酯的硫酸盐。磷酸盐的实例是磷酸盐酯。羧酸盐的实例是烷基羧酸盐和羧化醇或烷基酚乙氧基化物。
合适的非离子表面活性剂是烷氧基化物,N-烷基化脂肪酸酰胺,胺氧化物,酯或基于糖的表面活性剂。烷氧基化物的实例是诸如已经被烷氧基化的醇、烷基酚、胺、酰胺、芳基酚、脂肪酸或脂肪酸酯的化合物。氧化乙烯和/或氧化丙烯可以用于烷氧基化,优选氧化乙烯。N-烷基化脂肪酸酰胺的实例是脂肪酸葡糖酰胺或脂肪酸链烷醇酰胺。酯的实例是脂肪酸酯、甘油酯或甘油单酯。基于糖的表面活性剂的实例是脱水山梨醇、乙氧基化脱水山梨醇、蔗糖和葡萄糖酯或烷基聚葡糖苷。合适的阳离子表面活性剂是季表面活性剂,例如具有一个或两个疏水基团的季铵化合物,或长链伯胺的盐。合适的两性表面活性剂是烷基内铵盐和咪唑啉类。合适的嵌段聚合物是包含聚氧化乙烯和聚氧化丙烯嵌段的A-B或A-B-A型嵌段聚合物或包含链烷醇、聚氧化乙烯和聚氧化丙烯的A-B-C型嵌段聚合物。合适的聚电解质是聚酸或聚碱。聚酸的实例是聚丙烯酸的碱金属盐。聚碱的实例是聚乙烯基胺或聚乙烯胺。
本发明组合物可以包含各种量的表面活性物质和表面活性剂。基于该组合物的总量,它可以包含0.1-40重量%,优选1-30重量%,尤其是2-20重量%的表面活性物质和表面活性剂的总量。
助剂的实例是有机改性的聚硅氧烷如BreakThruS 醇烷氧基化物如 1303, 和 ON;EO/PO嵌段聚合物,例如 RPE 2035和 B;醇乙氧基化物,例如 XP 80;以及磺基琥珀酸二辛酯钠,例如 RA。
增稠剂(即赋予组合物以改性的流动性能,即静止状态下的高粘度和运动状态下的低粘度的化合物)的实例是多糖以及有机和无机层状矿物如黄原胶( CP Kelco), 23(Rhodia)或 (R.T.Vanderbilt)或 (Engelhard Corp.)。
合适防冻剂的实例是乙二醇、丙二醇、尿素和甘油。
消泡剂实例是聚硅氧烷乳液(例如 SRE,德国Wacker或 法国Rhodia),长链醇,脂肪酸,脂肪酸盐,有机氟化合物及其混合物。
着色剂实例是微水溶性颜料和水溶性染料。可以提到的实例是以下列名称已知的染料和颜料:若丹明B、C.I.颜料红112和C.I.溶剂红1、颜料蓝15:4、颜料蓝15:3、颜料蓝15:2、颜料蓝15:1、颜料蓝80、颜料黄1、颜料黄13、颜料红48:2、颜料红48:1、颜料红57:1、颜料红53:1、颜料橙43、颜料橙34、颜料橙5、颜料绿36、颜料绿7、颜料白6、颜料棕25、碱性紫10、碱性紫49、酸性红51、酸性红52、酸性红14、酸性蓝9、酸性黄23、碱性红10、碱性红108。
增粘剂的实例是聚乙烯吡咯烷酮、聚乙酸乙烯酯、聚乙烯醇和纤维素醚( 日本Shin-Etsu)。
通常使用的诱饵材料是植物或动物食品和饲料。合适的实例是(例如燕麦、小麦、大麦、玉米、大豆、稻的)粗谷粉、谷粒、片状谷物或谷粉,椰片,磨碎的椰子,糖浆(例如通过水解淀粉而得到(葡萄糖浆),转化糖浆、甜菜糖浆、枫液),糖类(例如蔗糖、乳糖、果糖、葡萄糖),搓碎的坚果,磨碎的坚果(例如榛子、核桃、杏仁),植物脂肪/油(例如菜籽油、大豆脂、葵花油、可可脂、花生酱、玉米油),动物脂肪/油(黄油、猪脂、鱼油),蛋白质(例如脱脂奶粉、蛋粉、蛋白水解物)和矿物(例如食盐)。
引诱剂的实例是信息素、酵母、磨碎的贝类、粪便、浆果、巧克力、鱼粉、肉、黑胡椒和增味剂如谷氨酸盐,尤其是谷氨酸钠和谷氨酸二钠。
本发明组合物通常作为常用于农业化学应用的组合物存在:
1.在水中稀释的组合物
i)水溶性浓缩物(SL,LS):将10重量份活性物质溶于90重量份水或水溶性溶剂中。作为替换,加入润湿剂或其他助剂。活性物质在用水稀释时溶解。这得到活性物质含量为10重量%的组合物。
ii)分散性浓缩物(DC):将20重量份活性物质溶于70重量份环己酮中并加入10重量份分散剂如聚乙烯吡咯烷酮。用水稀释得到分散体。活性物质含量为20重量%。
iii)可乳化浓缩物(EC):将15重量份活性物质溶于75重量份二甲苯中并加入十二烷基苯磺酸钙和蓖麻油乙氧基化物(在每种情况下5重量份)。用水稀释得到乳液。该组合物的活性物质含量为15重量%。
iv)乳液(EW,EO,ES):将25重量份活性物质溶于35重量份二甲苯中并加入十二烷基苯磺酸钙和蓖麻油乙氧基化物(在每种情况下5重量份)。使用乳化机(例如Ultra-Turrax)将该混合物引入30重量份水中并制成均相乳液。用水稀释得到乳液。该组合物的活性物质含量为25重量%。
v)悬浮液(SC,OD,FS):在搅拌的球磨机中将20重量份活性物质在加入10重量份分散剂和润湿剂以及70重量份水或有机溶剂下粉碎,得到细碎活性物质悬浮液。用水稀释得到稳定的活性物质悬浮液。该组合物的活性物质含量为20重量%。
vi)水分散性颗粒和水溶性颗粒(WG,SG):将50重量份活性物质细碎研磨并加入50重量份分散剂和润湿剂,借助工业装置(例如挤出机、喷雾塔、流化床)将其制成水分散性或水溶性颗粒。用水稀释得到稳定的活性物质分散体或溶液。该组合物的活性物质含量为50重量%。
vii)水分散性粉末和水溶性粉末(WP,SP,SS,WS):将75重量份活性物质在加入25重量份分散剂、润湿剂和硅胶下在转子-定子磨机中研磨。用水稀释得到稳定的活性物质分散体或溶液。该组合物的活性物质含量为75重量%。
viii)凝胶(GF):在球磨机中研磨20重量份活性物质、10重量份分散剂、1重量份胶凝剂和70重量份水或有机溶剂而得到精细悬浮液。用水稀释得到活性物质含量为20重量%的稳定悬浮液。
2.不经稀释施用的组合物
ix)粉剂(DP,DS):将5重量份活性物质细碎研磨并与95重量份细碎高岭土充分混合。这得到活性物质含量为5重量%的粉剂。
x)颗粒(GR,FG,GG,MG):将0.5重量份活性物质细碎研磨并结合99.5重量份载体。该目的的常用方法是挤出、喷雾干燥或流化床方法。这得到活性物质含量为0.5重量%的不经稀释施用的颗粒。
xi)ULV溶液(UL):将10重量份活性物质溶于90重量份有机溶剂如二甲苯中。这得到活性物质含量为10重量%的不经稀释施用的组合物。
优选液体组合物,如包含至少10重量%,优选20重量%,尤其优选至少40重量%水的水溶性浓缩物、乳液或悬浮液。在另一优选实施方案中,优选固体组合物如包含至少1重量%,优选至少3重量%,尤其优选至少5重量%水的诱饵、颗粒或凝胶。
在大多数情况下,在施用之前稀释本发明组合物以制备所谓的桶混物。适合稀释的物质是中到高沸点的矿物油馏分,如煤油或柴油,此外还有煤焦油和植物或动物来源的油,脂族、环状和芳族烃类,例如甲苯、二甲苯、石蜡、四氢化萘、烷基化萘或其衍生物,甲醇,乙醇,丙醇,丁醇,环己醇,环己酮,异佛尔酮,强极性溶剂,如二甲亚砜、N-甲基吡咯烷酮或水。优选使用水。稀组合物通常通过喷雾或雾化而施用。可以在紧临施用之前将各种类型的油、润湿剂、助剂、除草剂、杀菌剂、杀真菌剂加入桶混物中(桶混合)。这些试剂以1∶100-100∶1,优选1∶10-10∶1的重量比混入本发明组合物中。桶混物中的农药浓度可以在相当大范围内变化。它们通常为0.0001-10%,优选0.01-1%。当用于植物保护时,施用率为0.01-2.0kg活性物质/ha,这取决于所需效果的性质。
本发明还涉及本发明组合物在防治植物病原性真菌和/或不希望的植物生长和/或不希望的昆虫或螨虫侵袭和/或调节植物生长中的用途,其中使该组合物作用于相应害虫、其环境或要防止相应害虫的植物、土壤和/或不希望的植物和/或有用植物和/或其环境。本发明此外还涉及本发明组合物在植物上控制不希望的昆虫或螨虫侵袭和/或防治植物病原性真菌和/或防止不希望的植物生长的用途,其中用该组合物处理有用植物的种子。
此外,本发明涉及已经用本发明组合物处理,优选拌种的种子。对于种子处理,本领域熟练技术人员理解拌种,其中该组合物保留在种子上。尤其优选种子包含本发明组合物。该组合物可以以未稀释形式或优选以稀释形式施用于种子上。此时所述组合物可以稀释2-10倍,从而在要用于拌种的组合物中存在0.01-60重量%,优选0.1-40重量%农药。施用可以在播种之前进行。植物繁殖材料的处理,尤其是种子的处理对熟练技术人员 而言是已知的且通过撒粉、包衣、造粒、浸渍或浸泡植物繁殖材料而进行,其中优选通过造粒、包衣和撒粉进行处理,从而例如防止种子的早期萌发。在种子处理中,通常使用1-1000g/100kg,优选5-100g/100kg繁殖材料或种子的农药量。
此外,本发明涉及一种制备本发明组合物的方法,其中混合农药、防腐剂和具有5-10个碳原子的未支化1,2-链烷二醇。优选的农药、防腐剂和1,2-链烷二醇如上所述。各组分通过熟练技术人员已知且常用于制备所需组合物的方法混合。
此外,本发明涉及具有5-10个碳原子的未支化1,2-链烷二醇在用于包含农药和防腐剂的组合物中的用途。该链烷二醇优选用于提高防腐剂的杀菌活性。优选该组合物额外包含配制助剂。该农药优选为除草剂、杀虫剂或杀鼠剂,尤其优选除草剂或杀鼠剂。该链烷二醇在该组合物中优选用于提高防腐剂的防腐活性。该链烷二醇在该组合物中尤其优选用于提高异噻唑啉酮衍生物及其混合物,如烷基异噻唑啉酮(例如MIT,CIT),苯并异噻唑啉酮(例如BIT),MTIT,MIT和CIT的混合物或MIT和BIT的混合物的防腐活性。非常尤其优选的是异噻唑啉酮衍生物的混合物,如MIT和CIT的混合物或MIT和BIT的混合物,尤其是MIT和BIT的混合物。
本发明的优点是该农业化学组合物的特征在于防腐剂浓度降低;防腐剂在农业化学组合物中的抗微生物活性本身非常高,同时浓度降低;此外还可以没有问题地配制该农业化学组合物;可以使用常规农业化学配制助剂;可以使用常规农业化学施用技术如喷雾或拌种;以及杀虫或杀鼠活性不受不希望的臭味或气味的不利影响。
实施例
防腐剂:2.35-2.65重量%2-甲基-4-异噻唑啉-3-酮(MIT)和2.35-2.65重量%1,2-苯并异噻唑啉-3-酮(BIT)的含水配制剂,由Thor以名称 MBS市购。制造商推荐在含水产品中使用0.2-0.4重量%的浓度。
实施例1-制备农业化学配制剂
首先在每种情况下制备2.0L下列含水悬浮浓缩物:
A)悬浮浓缩物A(“SC A”)
400g/l二甲嘧菌胺(pyrimethanil)(杀真菌剂)
50g/l含磺酸盐的分散剂
2g/l增稠剂(黄原胶)
1.0g/l含聚硅氧烷的消泡剂
用水配成1000ml
B)悬浮浓缩物B(“SC B”)
50g/l喹唑菌酮(fluquinconazole)(杀真菌剂)
150g/l二甲嘧菌胺
50g/l含磺酸盐的分散剂
4g/l增稠剂(黄原胶)
1.0g/l含聚硅氧烷的消泡剂
用水配成1000ml
实施例2-对SC A的微生物计数试验
通过将100g悬浮浓缩物A与防腐剂以表1中详述的量(0.125g/l,0.25g/l,0.5g/l,1g/l和2g/l)和PDO(10,20和30g/l)混合而制备15个样品。为对照目的测试仅含悬浮浓缩物A的样品。
在每种情况下将10ml样品1-16用由各种细菌品种(如枯草杆菌(Bacillus subtilis)、大肠杆菌(Escherchia coli)、绿脓杆菌(Pseudomonasaeruginosa)、金黄色葡萄球菌(Staphylococcus auFeus))组成的微生物混合物接种,均化并在23℃下温育。立即并且也在24、48和72小时后测定每克样品的微生物计数(cfu/g)。为此,在每种情况下准确称重约1g被污染样品并在浓度为2%的麦芽提取琼脂上以合适的稀释度形成条纹。被污染样品通过用无菌水均化而稀释。为了检测细菌,将麦芽板在23℃下温育3天。没有防腐剂和没有PDO的对照表明显著大于50000cfu/g的非常高微生物计数。结果汇编在表1中。
表明防腐剂的活性可以通过将1,2-戊二醇混入农业化学配制剂中而提高。
表1:微生物计数[cfu/g]
防腐剂的量 | 1.0g PDO | 2.0g PDO | 3.0g PDO |
0.2g | 无 | 无 | 无 |
0.1g | >10000 | 212 | 21 |
0.05g | >10000 | 86 | 79 |
0.025g | >10000 | 1500 | 194 |
0.0125g | 类似于对照 | 类似于对照 | 627 |
实施例3-对SC B的微生物计数试验
如实施例2进行该试验,现在使用悬浮浓缩物B代替悬浮浓缩物A。结果汇编在表2中。表明防腐剂的活性可以通过将1,2-戊二醇混入农业化学配制剂中而提高。
表2:微生物计数[cfu/g]
防腐剂的量 | 1.0g PDO | 2.0g PDO | 3.0g PDO |
0.2g | 120 | 无 | 无 |
0.1g | 310 | 160 | 无 |
0.05g | >10000 | 300 | 无 |
0.025g | >50000 | 575 | 无 |
0.0125g | 类似于对照 | 890 | 无 |
Claims (8)
1.一种包含农药、小于0.5重量%的防腐剂和0.1-8重量%的具有5-10个碳原子的未支化1,2-链烷二醇的农业化学组合物,其中所述农药为杀真菌剂、杀虫剂、杀鼠剂或除草剂,所述链烷二醇为1,2-戊二醇,并且所述防腐剂选自烷基异噻唑啉酮类、苯并异噻唑啉酮类、2-甲基-4,5-三亚甲基-2H-异噻唑-3-酮以及它们的混合物。
2.根据权利要求1的组合物,其为液体且包含至少10重量%水。
3.根据权利要求1或2的组合物,其包含0.5-3重量%链烷二醇。
4.一种制备根据权利要求1-3中任一项的组合物的方法,其中混合农药、防腐剂和具有5-10个碳原子的未支化1,2-链烷二醇。
5.未支化1,2-戊二醇在用于包含农药和防腐剂的农业化学组合物中的用途,其中所述农药为杀真菌剂、杀虫剂、杀鼠剂或除草剂,并且所述防腐剂选自烷基异噻唑啉酮类、苯并异噻唑啉酮类、2-甲基-4,5-三亚甲基-2H-异噻唑-3-酮以及它们的混合物。
6.根据权利要求1-3中任一项的组合物在防治植物病原性真菌和/或不希望的植物生长和/或不希望的昆虫或螨虫侵袭和/或调节植物生长中的用途,其中使所述组合物作用于相应害虫、其环境或要防止相应害虫的植物、土壤和/或不希望的植物和/或有用植物和/或其环境。
7.根据权利要求1-3中任一项的组合物在植物上控制不希望的昆虫或螨虫侵袭和/或防治植物病原性真菌和/或防止不希望的植物生长的用途,其中用所述组合物处理有用植物的种子。
8.一种用根据权利要求1-3中任一项的组合物处理种子的方法,其中所述种子包含所述组合物。
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WO2017015273A1 (en) * | 2015-07-20 | 2017-01-26 | S.C. Johnson & Son, Inc. | Water-based fragrance composition, fragrance delivery device, and method of providing a long-lasting scent |
CN105439782B (zh) * | 2015-12-14 | 2019-02-19 | 中国科学院南京土壤研究所 | 癸二醇作为硝化抑制剂的应用 |
CN107736357A (zh) * | 2017-11-13 | 2018-02-27 | 江苏艾津农化有限责任公司 | 一种农药悬浮剂用防腐组合物及其使用方法 |
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CN112336706A (zh) * | 2020-04-21 | 2021-02-09 | 江苏南京农大动物药业有限公司 | 一种兽用双甲脒溶液增效剂及其制备方法 |
BE1029367B1 (fr) | 2021-05-03 | 2022-12-05 | Minagro Srl | Utilisation des 1,2-alcanediols comme adjuvant en agriculture |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0542721A2 (en) * | 1990-04-27 | 1993-05-19 | Imperial Chemical Industries Plc | Biocide composition and its use |
CN1235014A (zh) * | 1998-02-12 | 1999-11-17 | 莱雅公司 | 化妆品或皮肤病组合物以及1,2-戊二醇在其中的应用 |
CN1620248A (zh) * | 2002-02-19 | 2005-05-25 | 西姆莱斯有限责任两合公司 | 1,2-烷烃二醇的协同性混合物 |
CN101257795A (zh) * | 2005-07-08 | 2008-09-03 | Isp投资有限公司 | 杀微生物组合物 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3523121A (en) * | 1967-03-09 | 1970-08-04 | Rohm & Haas | Certain 2-carbamoyl-3-isothiazolenes |
JP3657395B2 (ja) * | 1996-05-27 | 2005-06-08 | 株式会社資生堂 | 外用組成物 |
CA2261362A1 (fr) * | 1998-02-12 | 1999-08-12 | L'oreal | Utilisation du 1,2-pentanediol dans une composition cosmetique ou dermatologique contenant une dispersion aqueuse de particules de polymere filmogene, et composition cosmetique oudermatologique comprenant ces constituants |
JP4418976B2 (ja) * | 1998-02-24 | 2010-02-24 | 株式会社マンダム | 防腐殺菌剤及び化粧料組成物 |
JP5062708B2 (ja) * | 1998-02-24 | 2012-10-31 | 株式会社マンダム | 防腐殺菌剤及び人体施用組成物 |
US6503904B2 (en) * | 1998-11-16 | 2003-01-07 | Syngenta Crop Protection, Inc. | Pesticidal composition for seed treatment |
JP3649619B2 (ja) * | 1999-03-30 | 2005-05-18 | 株式会社資生堂 | 外用組成物 |
TW592711B (en) | 1999-03-30 | 2004-06-21 | Shiseido Co Ltd | Antiseptic/antifungal agent and endermic liniment composition which contains the same |
GT200100026A (es) * | 2000-02-18 | 2002-02-21 | Composiciones fungicidas tolerantes a inoculos. | |
JP2003081761A (ja) | 2001-06-27 | 2003-03-19 | Mandom Corp | 乳化組成物 |
JP2004352688A (ja) * | 2003-05-30 | 2004-12-16 | Kao Corp | 防腐剤組成物 |
JP5179865B2 (ja) * | 2004-07-06 | 2013-04-10 | ビーエーエスエフ ソシエタス・ヨーロピア | 液体農薬組成物 |
WO2006045743A1 (en) * | 2004-10-22 | 2006-05-04 | Symrise Gmbh & Co. Kg | Synergistic mixtures of 1,2-hexanediol and 1,2-octanediol and also a further preservative |
US7468384B2 (en) * | 2004-11-16 | 2008-12-23 | Rohm And Haas Company | Microbicidal composition |
EP2000122A3 (en) * | 2005-07-11 | 2010-12-15 | Thor Specialities (UK) Limited | Microbiocidal composition |
EP1772055A1 (en) * | 2005-10-04 | 2007-04-11 | Rohm and Haas France SAS | Synergistic microbicidal compositions comprising a N-alkyl-1,2-benzoisothiazolin-3-one |
JP4999321B2 (ja) * | 2005-11-28 | 2012-08-15 | 株式会社マンダム | 防腐殺菌剤を配合した医薬品、及び防腐殺菌方法 |
UA106213C2 (ru) * | 2008-10-10 | 2014-08-11 | Басф Се | Жидкие препараты для защиты растений, содержащие пираклостробин |
-
2010
- 2010-04-21 CN CN201080018511.6A patent/CN102413684B/zh not_active Expired - Fee Related
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- 2010-04-21 JP JP2012506476A patent/JP2012525327A/ja active Pending
- 2010-04-21 US US13/266,262 patent/US20120046167A1/en not_active Abandoned
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0542721A2 (en) * | 1990-04-27 | 1993-05-19 | Imperial Chemical Industries Plc | Biocide composition and its use |
CN1235014A (zh) * | 1998-02-12 | 1999-11-17 | 莱雅公司 | 化妆品或皮肤病组合物以及1,2-戊二醇在其中的应用 |
CN1620248A (zh) * | 2002-02-19 | 2005-05-25 | 西姆莱斯有限责任两合公司 | 1,2-烷烃二醇的协同性混合物 |
CN101257795A (zh) * | 2005-07-08 | 2008-09-03 | Isp投资有限公司 | 杀微生物组合物 |
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