CN102388010B - 生产1,6-己二醇和己内酯的方法 - Google Patents

生产1,6-己二醇和己内酯的方法 Download PDF

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Publication number
CN102388010B
CN102388010B CN201080015293.0A CN201080015293A CN102388010B CN 102388010 B CN102388010 B CN 102388010B CN 201080015293 A CN201080015293 A CN 201080015293A CN 102388010 B CN102388010 B CN 102388010B
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China
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acid
hydrogenation
cyclohexanediol
esterification
workshop section
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Expired - Fee Related
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English (en)
Chinese (zh)
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CN102388010A (zh
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R·平科斯
D·布罗伊宁格尔
G-D·特贝恩
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D313/00—Heterocyclic compounds containing rings of more than six members having one oxygen atom as the only ring hetero atom
    • C07D313/02—Seven-membered rings
    • C07D313/04—Seven-membered rings not condensed with other rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyrane Compounds (AREA)
  • Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
CN201080015293.0A 2009-04-07 2010-03-31 生产1,6-己二醇和己内酯的方法 Expired - Fee Related CN102388010B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09157503 2009-04-07
EP09157503.5 2009-04-07
PCT/EP2010/054285 WO2010115798A2 (de) 2009-04-07 2010-03-31 Verfahren zur herstellung von 1,6-hexandiol und caprolacton

Publications (2)

Publication Number Publication Date
CN102388010A CN102388010A (zh) 2012-03-21
CN102388010B true CN102388010B (zh) 2015-04-08

Family

ID=42667987

Family Applications (1)

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CN201080015293.0A Expired - Fee Related CN102388010B (zh) 2009-04-07 2010-03-31 生产1,6-己二醇和己内酯的方法

Country Status (9)

Country Link
US (1) US8471042B2 (enExample)
EP (1) EP2417089B1 (enExample)
JP (1) JP5566450B2 (enExample)
KR (1) KR20120004513A (enExample)
CN (1) CN102388010B (enExample)
CA (1) CA2755698A1 (enExample)
ES (1) ES2421150T3 (enExample)
SG (1) SG174394A1 (enExample)
WO (1) WO2010115798A2 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010115738A1 (de) * 2009-04-07 2010-10-14 Basf Se Verfahren zur herstellung von 1,6-hexandiol
DE102009047194A1 (de) 2009-11-26 2011-06-01 Basf Se Verfahren zur Herstellung von Kunststoffen mit 1,6-Hexandiol mit einem Aldehydanteil von kleiner 500ppm
WO2013101970A1 (en) 2011-12-30 2013-07-04 E. I. Du Pont De Nemours And Company Production of 5-hydroxymethyl-2-furfural from levoglucosenone
EP2797904A4 (en) 2011-12-30 2015-08-05 Du Pont PREPARATION OF TETRAHYDROFURAN-2, 5-DIMETHANOL FROM ISOSORBIDE
US8889912B2 (en) 2011-12-30 2014-11-18 E I Du Pont De Nemours And Company Process for preparing 1,6-hexanediol
US8865940B2 (en) 2011-12-30 2014-10-21 E I Du Pont De Nemours And Company Process for preparing 1,6-hexanediol
BR112014015996A2 (pt) 2011-12-30 2017-06-13 Du Pont processo
WO2013101968A1 (en) 2011-12-30 2013-07-04 E. I. Du Pont De Nemours And Company Process for the production of hexanediols
US8859826B2 (en) 2012-04-27 2014-10-14 E I Du Pont De Nemours And Company Production of alpha, omega-diols
US8846985B2 (en) 2012-04-27 2014-09-30 E I Du Pont De Nemours And Company Production of alpha, omega-diols
US9018423B2 (en) 2012-04-27 2015-04-28 E I Du Pont De Nemours And Company Production of alpha, omega-diols
CN102671695B (zh) * 2012-06-04 2014-10-08 湖南大学 一种六棱柱形貌的Co负载MFI分子筛及其制备方法
KR102048986B1 (ko) * 2018-03-22 2019-11-26 표상현 ε-카프로락톤의 제조 방법
CN111995612A (zh) * 2020-08-24 2020-11-27 青岛科技大学 一种己内酯的合成方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3933930A (en) * 1975-03-06 1976-01-20 Celanese Corporation Hexanediol from cyclohexane
CN1211969A (zh) * 1996-03-01 1999-03-24 巴斯福股份公司 制备1,6－己二醇和己内酯的方法
WO2008152001A1 (de) * 2007-06-14 2008-12-18 Basf Se VERFAHREN ZUR HERSTELLUNG ε-CAPROLACTON

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1235879B (de) 1964-03-17 1967-03-09 Basf Ag Verfahren zur Herstellung von Alkoholen durch katalytische Hydrierung von Carbonsaeuren
DE1618143C3 (de) 1967-04-27 1975-08-21 Basf Ag, 6700 Ludwigshafen Verfahren zur Gewinnung von epsilon-Hydroxycapronsäurelacton und von Alkandicarbonsäuren
JPS4815314B1 (enExample) * 1969-08-18 1973-05-14
DE2060548C3 (de) 1970-12-09 1979-10-11 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von sehr reinem 1,6-Hexandiol durch Kristallisation
DE2321101C2 (de) 1973-04-26 1982-07-22 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung im wesentlichen trägerfreier Kobaltkatalysatoren
DE3823213A1 (de) 1988-07-08 1990-01-11 Basf Ag Verfahren zur herstellung von caprolacton
DE19607954A1 (de) 1996-03-01 1997-09-04 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol und Caprolacton
KR100465468B1 (ko) * 1996-03-01 2005-02-28 바스프 악티엔게젤샤프트 순도99%이상의1,6-헥산디올의제조방법
DE19730939A1 (de) 1997-07-18 1999-01-21 Basf Ag Verfahren zur Hydrierung von Carbonylverbindungen
DE19738464A1 (de) 1997-09-03 1999-03-04 Basf Ag Verwendung von Formkörpern als Katalysator zur Herstellung von Caprolactam
DE10128249A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Entfernung von Ameisensäure aus wässrigen Lösungen
DE10334489A1 (de) * 2003-07-29 2005-02-24 Basf Ag Verfahren zur hydrierenden Zersetzung von Ammoniumformiaten in polyolhaltigen Reaktionsgemischen
DE102004033557A1 (de) 2004-07-09 2006-02-16 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol in einer Reinheit von über 99,5%
DE102004054047A1 (de) 2004-11-05 2006-05-11 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol
US8247580B2 (en) 2007-11-05 2012-08-21 Basf Se Process for preparing ε-caprolactone
EP2225220B1 (de) 2007-12-21 2013-05-22 Basf Se Verfahren zur Herstellung von epsilon-Caprolacton
JP2011512339A (ja) 2008-02-15 2011-04-21 ビーエーエスエフ ソシエタス・ヨーロピア ６−ヒドロキシカプロン酸エステルの製造方法
DE102009047194A1 (de) 2009-11-26 2011-06-01 Basf Se Verfahren zur Herstellung von Kunststoffen mit 1,6-Hexandiol mit einem Aldehydanteil von kleiner 500ppm

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3933930A (en) * 1975-03-06 1976-01-20 Celanese Corporation Hexanediol from cyclohexane
CN1211969A (zh) * 1996-03-01 1999-03-24 巴斯福股份公司 制备1,6－己二醇和己内酯的方法
WO2008152001A1 (de) * 2007-06-14 2008-12-18 Basf Se VERFAHREN ZUR HERSTELLUNG ε-CAPROLACTON

Also Published As

Publication number Publication date
SG174394A1 (en) 2011-10-28
JP5566450B2 (ja) 2014-08-06
JP2012522823A (ja) 2012-09-27
CA2755698A1 (en) 2010-10-14
US20120010419A1 (en) 2012-01-12
KR20120004513A (ko) 2012-01-12
CN102388010A (zh) 2012-03-21
WO2010115798A3 (de) 2010-12-09
EP2417089A2 (de) 2012-02-15
EP2417089B1 (de) 2013-06-05
WO2010115798A2 (de) 2010-10-14
US8471042B2 (en) 2013-06-25
ES2421150T3 (es) 2013-08-29

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