CN102386333A - 一种叠层有机薄膜太阳能电池 - Google Patents
一种叠层有机薄膜太阳能电池 Download PDFInfo
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- CN102386333A CN102386333A CN2011103546894A CN201110354689A CN102386333A CN 102386333 A CN102386333 A CN 102386333A CN 2011103546894 A CN2011103546894 A CN 2011103546894A CN 201110354689 A CN201110354689 A CN 201110354689A CN 102386333 A CN102386333 A CN 102386333A
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- solar cell
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- tetramethyl
- quinacridone
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- 239000010409 thin film Substances 0.000 title claims abstract description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 14
- -1 poly(3,4-ethylenedioxythiophene) Polymers 0.000 claims abstract description 14
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims abstract description 11
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000031700 light absorption Effects 0.000 claims abstract description 6
- 229910003472 fullerene Inorganic materials 0.000 claims abstract description 4
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- 239000010408 film Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 230000031709 bromination Effects 0.000 claims description 10
- 238000005893 bromination reaction Methods 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000001704 evaporation Methods 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 229920000144 PEDOT:PSS Polymers 0.000 claims description 9
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- 238000003756 stirring Methods 0.000 claims description 8
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- 235000019441 ethanol Nutrition 0.000 claims description 7
- 239000011521 glass Substances 0.000 claims description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 238000004440 column chromatography Methods 0.000 claims description 6
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 238000000746 purification Methods 0.000 claims description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 5
- MKARNSWMMBGSHX-UHFFFAOYSA-N 3,5-dimethylaniline Chemical class CC1=CC(C)=CC(N)=C1 MKARNSWMMBGSHX-UHFFFAOYSA-N 0.000 claims description 4
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- GRPQBOKWXNIQMF-UHFFFAOYSA-N indium(3+) oxygen(2-) tin(4+) Chemical compound [Sn+4].[O-2].[In+3] GRPQBOKWXNIQMF-UHFFFAOYSA-N 0.000 claims description 4
- 238000007738 vacuum evaporation Methods 0.000 claims description 4
- JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 claims description 3
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 238000010276 construction Methods 0.000 claims description 3
- 239000012043 crude product Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 3
- 235000011118 potassium hydroxide Nutrition 0.000 claims description 3
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- 239000000243 solution Substances 0.000 claims description 3
- MPPPKRYCTPRNTB-UHFFFAOYSA-N 1-bromobutane Chemical compound CCCCBr MPPPKRYCTPRNTB-UHFFFAOYSA-N 0.000 claims description 2
- LSXKDWGTSHCFPP-UHFFFAOYSA-N 1-bromoheptane Chemical compound CCCCCCCBr LSXKDWGTSHCFPP-UHFFFAOYSA-N 0.000 claims description 2
- MNDIARAMWBIKFW-UHFFFAOYSA-N 1-bromohexane Chemical compound CCCCCCBr MNDIARAMWBIKFW-UHFFFAOYSA-N 0.000 claims description 2
- AYMUQTNXKPEMLM-UHFFFAOYSA-N 1-bromononane Chemical compound CCCCCCCCCBr AYMUQTNXKPEMLM-UHFFFAOYSA-N 0.000 claims description 2
- VMKOFRJSULQZRM-UHFFFAOYSA-N 1-bromooctane Chemical compound CCCCCCCCBr VMKOFRJSULQZRM-UHFFFAOYSA-N 0.000 claims description 2
- YZWKKMVJZFACSU-UHFFFAOYSA-N 1-bromopentane Chemical compound CCCCCBr YZWKKMVJZFACSU-UHFFFAOYSA-N 0.000 claims description 2
- CYNYIHKIEHGYOZ-UHFFFAOYSA-N 1-bromopropane Chemical compound CCCBr CYNYIHKIEHGYOZ-UHFFFAOYSA-N 0.000 claims description 2
- LUYOVJTWKZIFCT-UHFFFAOYSA-N 2-bromopropane silane Chemical compound [SiH4].C(C)(C)Br LUYOVJTWKZIFCT-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- QEPPHIJQCNEGDG-UHFFFAOYSA-N bromine;ethynylbenzene Chemical compound [Br].C#CC1=CC=CC=C1 QEPPHIJQCNEGDG-UHFFFAOYSA-N 0.000 claims description 2
- IYYIVELXUANFED-UHFFFAOYSA-N bromo(trimethyl)silane Chemical compound C[Si](C)(C)Br IYYIVELXUANFED-UHFFFAOYSA-N 0.000 claims description 2
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 claims description 2
- 125000005909 ethyl alcohol group Chemical group 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 229940102396 methyl bromide Drugs 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- 229910003087 TiOx Inorganic materials 0.000 abstract description 3
- 229920001467 poly(styrenesulfonates) Polymers 0.000 abstract description 3
- HLLICFJUWSZHRJ-UHFFFAOYSA-N tioxidazole Chemical compound CCCOC1=CC=C2N=C(NC(=O)OC)SC2=C1 HLLICFJUWSZHRJ-UHFFFAOYSA-N 0.000 abstract description 3
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 23
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 10
- 150000002576 ketones Chemical class 0.000 description 8
- 230000008020 evaporation Effects 0.000 description 7
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical class N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- 238000013519 translation Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
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- 238000002207 thermal evaporation Methods 0.000 description 3
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
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- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 description 2
- 238000001819 mass spectrum Methods 0.000 description 2
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 description 1
- PDWBGRKARJFJGI-UHFFFAOYSA-N 2-phenylcyclohexa-2,4-dien-1-one Chemical compound O=C1CC=CC=C1C1=CC=CC=C1 PDWBGRKARJFJGI-UHFFFAOYSA-N 0.000 description 1
- 0 CC*(C)C(C)NC Chemical compound CC*(C)C(C)NC 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000004847 absorption spectroscopy Methods 0.000 description 1
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- 229910052799 carbon Inorganic materials 0.000 description 1
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- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
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- 239000012860 organic pigment Substances 0.000 description 1
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- IKXKTLBKRBLWNN-UHFFFAOYSA-N pentacene Chemical compound C1=CC=CC2=CC3=CC4=CC5=CC=CC=C5C=C4C=C3C=C21.C1=CC=CC2=CC3=CC4=CC5=CC=CC=C5C=C4C=C3C=C21 IKXKTLBKRBLWNN-UHFFFAOYSA-N 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
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- 229960002796 polystyrene sulfonate Drugs 0.000 description 1
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- 229920000123 polythiophene Polymers 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
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- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
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- 229910000104 sodium hydride Inorganic materials 0.000 description 1
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- 239000012209 synthetic fiber Substances 0.000 description 1
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- 229930192474 thiophene Natural products 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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- Photovoltaic Devices (AREA)
Abstract
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Claims (4)
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CN102386333A true CN102386333A (zh) | 2012-03-21 |
CN102386333B CN102386333B (zh) | 2014-07-16 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103613121A (zh) * | 2013-11-12 | 2014-03-05 | 北京科技大学 | 一种油溶性氧化铟氧化锡纳米微粒及气敏薄膜的制备方法 |
CN103824944A (zh) * | 2012-11-19 | 2014-05-28 | 海洋王照明科技股份有限公司 | 太阳能电池器件及其制备方法 |
CN104716261A (zh) * | 2013-12-13 | 2015-06-17 | 中国科学院大连化学物理研究所 | 一种吸收光谱互补的硅薄膜/有机叠层薄膜太阳能电池 |
WO2017012162A1 (zh) * | 2015-07-20 | 2017-01-26 | 深圳市华星光电技术有限公司 | 富勒烯/pedot:pss混合溶液的制备方法及具有富勒烯/pedot:pss复合透明导电膜的基板的制备方法 |
Citations (3)
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JP2003007358A (ja) * | 2001-06-20 | 2003-01-10 | Nippon Kayaku Co Ltd | 色素増感光電変換素子 |
CN101432904A (zh) * | 2006-05-02 | 2009-05-13 | 三菱化学株式会社 | 有机光电转换元件的制造方法和有机光电转换元件 |
CN102060854A (zh) * | 2010-11-25 | 2011-05-18 | 吉林大学 | 腈取代喹吖啶酮类化合物及其在有机太阳能电池中的应用 |
-
2011
- 2011-11-10 CN CN201110354689.4A patent/CN102386333B/zh not_active Expired - Fee Related
Patent Citations (3)
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JP2003007358A (ja) * | 2001-06-20 | 2003-01-10 | Nippon Kayaku Co Ltd | 色素増感光電変換素子 |
CN101432904A (zh) * | 2006-05-02 | 2009-05-13 | 三菱化学株式会社 | 有机光电转换元件的制造方法和有机光电转换元件 |
CN102060854A (zh) * | 2010-11-25 | 2011-05-18 | 吉林大学 | 腈取代喹吖啶酮类化合物及其在有机太阳能电池中的应用 |
Non-Patent Citations (6)
Title |
---|
《APPLIED PHYSICS LETTERS》 20090922 Zong-Xiang Xu et al. Organic field-effect transistors fabricated with N,N-substituteddialkyl-1,3,8,10-tetramethylquinacridone compounds , * |
JIN YOUNG KIM ET AL.: "Efficient Tandem Polymer Solar Cells Fabricated by All-Solution Processing", 《SCIENCE》, vol. 317, 13 July 2007 (2007-07-13), XP055104067, DOI: doi:10.1126/science.1141711 * |
KAIQI YE ET AL.: "Supramolecular Structures and Assembly and Luminescent Properties of Quinacridone Derivatives", 《J. PHYS. CHEM. B》, vol. 109, no. 16, 30 March 2005 (2005-03-30) * |
UWE KELLER ET AL.: "Hydrogen-Bonding and Phase-Forming Behavior of a Soluble Quinacridone", 《ADVANCED MATERIALS》, vol. 8, no. 6, 31 December 1996 (1996-12-31) * |
ZONG-XIANG XU ET AL.: "Organic field-effect transistors fabricated with N,N-substituteddialkyl-1,3,8,10-tetramethylquinacridone compounds", 《APPLIED PHYSICS LETTERS》, 22 September 2009 (2009-09-22) * |
张磊: "聚合物叠层太阳能电池", 《中国优秀硕士学位论文全文数据库工程科技II辑》, 15 August 2008 (2008-08-15) * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103824944A (zh) * | 2012-11-19 | 2014-05-28 | 海洋王照明科技股份有限公司 | 太阳能电池器件及其制备方法 |
CN103613121A (zh) * | 2013-11-12 | 2014-03-05 | 北京科技大学 | 一种油溶性氧化铟氧化锡纳米微粒及气敏薄膜的制备方法 |
CN103613121B (zh) * | 2013-11-12 | 2015-04-15 | 北京科技大学 | 一种油溶性氧化铟氧化锡纳米微粒及气敏薄膜的制备方法 |
CN104716261A (zh) * | 2013-12-13 | 2015-06-17 | 中国科学院大连化学物理研究所 | 一种吸收光谱互补的硅薄膜/有机叠层薄膜太阳能电池 |
WO2017012162A1 (zh) * | 2015-07-20 | 2017-01-26 | 深圳市华星光电技术有限公司 | 富勒烯/pedot:pss混合溶液的制备方法及具有富勒烯/pedot:pss复合透明导电膜的基板的制备方法 |
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CN102386333B (zh) | 2014-07-16 |
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