CN102326591A - Common threewingnut root electro-thermal liquid mosquito incense and preparation method thereof - Google Patents
Common threewingnut root electro-thermal liquid mosquito incense and preparation method thereof Download PDFInfo
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- 238000002360 preparation method Methods 0.000 title claims abstract description 8
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- 239000012141 concentrate Substances 0.000 claims abstract description 30
- YCOZIPAWZNQLMR-UHFFFAOYSA-N pentadecane Chemical compound CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 240000001851 Artemisia dracunculus Species 0.000 claims abstract description 10
- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 claims abstract description 9
- 235000003097 Artemisia absinthium Nutrition 0.000 claims abstract description 9
- 235000017731 Artemisia dracunculus ssp. dracunculus Nutrition 0.000 claims abstract description 9
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- 239000001138 artemisia absinthium Substances 0.000 claims abstract description 9
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- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229960005235 piperonyl butoxide Drugs 0.000 claims abstract description 8
- 238000005303 weighing Methods 0.000 claims abstract description 8
- 241000205585 Aquilegia canadensis Species 0.000 claims abstract 3
- 239000003814 drug Substances 0.000 claims description 44
- 235000015398 thunder god vine Nutrition 0.000 claims description 22
- OEYQBKYISMRWQB-UHFFFAOYSA-N Santal Chemical compound C=1C(OC)=CC(O)=C(C2=O)C=1OC=C2C1=CC=C(O)C(O)=C1 OEYQBKYISMRWQB-UHFFFAOYSA-N 0.000 claims description 18
- 241000756943 Codonopsis Species 0.000 claims description 12
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- 235000003255 Carthamus tinctorius Nutrition 0.000 claims description 8
- 244000020518 Carthamus tinctorius Species 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 5
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- 230000002147 killing effect Effects 0.000 abstract description 5
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- 244000124209 Crocus sativus Species 0.000 abstract description 2
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- 241000206389 Helleborus Species 0.000 abstract 1
- 240000000513 Santalum album Species 0.000 abstract 1
- 235000008632 Santalum album Nutrition 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
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- 235000013974 saffron Nutrition 0.000 abstract 1
- 239000004248 saffron Substances 0.000 abstract 1
- 239000006200 vaporizer Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 241000125175 Angelica Species 0.000 description 7
- 241001570521 Lonicera periclymenum Species 0.000 description 7
- 239000000077 insect repellent Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 241000193830 Bacillus <bacterium> Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
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- 230000037213 diet Effects 0.000 description 2
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- 241000208365 Celastraceae Species 0.000 description 1
- 235000008495 Chrysanthemum leucanthemum Nutrition 0.000 description 1
- 244000192528 Chrysanthemum parthenium Species 0.000 description 1
- 235000000604 Chrysanthemum parthenium Nutrition 0.000 description 1
- 241000125183 Crithmum maritimum Species 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
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- 241000134102 Ferula fukanensis Species 0.000 description 1
- 241000134109 Ferula sinkiangensis Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000234280 Liliaceae Species 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- 241000221035 Santalaceae Species 0.000 description 1
- 241000607764 Shigella dysenteriae Species 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 244000236151 Tabebuia pallida Species 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 241001170744 Veratrum nigrum Species 0.000 description 1
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- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
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- 229940065181 bacillus anthracis Drugs 0.000 description 1
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- 231100000315 carcinogenic Toxicity 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 229930193529 cinerin Natural products 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
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- 239000007933 dermal patch Substances 0.000 description 1
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- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
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- 235000008384 feverfew Nutrition 0.000 description 1
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
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- 238000010438 heat treatment Methods 0.000 description 1
- 208000006454 hepatitis Diseases 0.000 description 1
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- 231100000037 inhalation toxicity test Toxicity 0.000 description 1
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- 230000007774 longterm Effects 0.000 description 1
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- 239000002304 perfume Substances 0.000 description 1
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- 239000002728 pyrethroid Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
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- 229940007046 shigella dysenteriae Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008492 tangshen Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
The invention discloses common threewingnut root electro-thermal liquid mosquito incense and a preparation method thereof. The common threewingnut root electro-thermal liquid mosquito incense is formed by mixing the following components in part by weight: 100 parts of pentadecane, 1 to 3 parts of Chinese medicinal composition concentrate, and 0.03 to 0.06 part of piperonyl butoxide, wherein the Chinese medicinal composition concentrate is prepared by the following steps of: weighing the following Chinese medicinal components in part by weight: 70 to 80 parts of common threewingnut root, 20 to 25 parts of virgate wormwood herb, 3 to 6 parts of angelica dahurica, 1 to 3 parts of Chinese asafetida, 15 to 25 parts of honeysuckle, 1 to 3 parts of sandalwood, 4 to 6 parts of agilawood, 1 to 3 parts of saffron, 2 to 4 parts of hellebore and 0.5 to 1.5 parts of pilose asiabell root; crushing the components, and mixing the powder uniformly to obtain a Chinese medicinal composition; and adding water into the Chinese medicinal composition, decocting for 0.5 to 2.5 hours at the temperature of between 70 and 90 DEG C, filtering, concentrating, and thus obtaining the Chinese medicinal composition concentrate. The common threewingnut root electro-thermal liquid mosquito incense has strong expelling and killing effects on mosquitoes, and does not produce harmful effect on the human body.
Description
Technical field
The present invention relates to a kind of vaporizer mosquito liquid and preparation method thereof, relate in particular to a kind of thunder godvine electric liquid device and preparation method thereof.
Background technology
Mosquito-repellent incense is a kind of mosquito repellent thing, and medicine is wherein lighted the cigarette that is sent the back can drive mosquito or smoked dead mosquito away.China's very long history that kindles mosquito repellent incense, traditional mosquito-repellent incense divides line spices, incense coil and vaporizer mosquito liquid.
Vaporizer mosquito liquid mainly be a kind of chemical composition that is called pyrethroid, cinerins can pass through digestive tract, respiratory tract and absorb, and certain toxicity is arranged, if long-term excessive contact has carcinogenic, teratogenesis.
Summary of the invention
To the above-mentioned deficiency that exists in the prior art, one of technical problem to be solved by this invention provides a kind of thunder godvine electric liquid device, and mosquito is had the stronger effect of killing, and can not produce harmful effect to human body.
Two of technical problem to be solved by this invention provides above-mentioned thunder godvine electric liquid device and preparation method thereof.
The present invention seeks to realize through following technical scheme:
A kind of thunder godvine electric liquid device is mixed by following component by weight: 100 parts of n-pentadecanes, and Chinese medicine composition concentrate 1-3 part, piperonyl butoxide 0.03-0.06 part,
Wherein, said Chinese medicine composition concentrate is prepared from following method:
(1) takes by weighing each traditional Chinese medicinal components of following weight parts: thunder godvine 70-80 part, oriental wormwood 20-25 part, root of Dahurain angelica 3-6 part, asafoetide 1-3 part, honeysuckle 15-25 part, santal 1-3 part, agalloch eaglewood 4-6 part, west safflower 1-3 part, black false hellebore 2-4 part and Radix Codonopsis 0.5-1.5 part; Pulverize; Mix, obtain Chinese medicine composition;
(2) water is added in the above-mentioned Chinese medicine composition, the addition of water is 6-8 a times of Chinese medicine composition gross weight, decocts 0.5-2.5 hour in 70-90 ℃; Filter; Concentrate, obtain the Chinese medicine composition concentrate, the weight of said Chinese medicine composition concentrate is 1-3 times of Chinese medicine composition gross weight.
Further, the present invention also provides a kind of preparation method of thunder godvine electric liquid device, is made up of following step:
(1) takes by weighing each traditional Chinese medicinal components of following weight parts: thunder godvine 70-80 part, oriental wormwood 20-25 part, root of Dahurain angelica 3-6 part, asafoetide 1-3 part, honeysuckle 15-25 part, santal 1-3 part, agalloch eaglewood 4-6 part, west safflower 1-3 part, black false hellebore 2-4 part and Radix Codonopsis 0.5-1.5 part; Pulverize; Mix, obtain Chinese medicine composition;
(2) water is added in the above-mentioned Chinese medicine composition, the addition of water is 6-8 a times of Chinese medicine composition gross weight, decocts 0.5-2.5 hour in 70-90 ℃; Filter; Concentrate, obtain the Chinese medicine composition concentrate, the weight of said Chinese medicine composition concentrate is 1-3 times of Chinese medicine composition gross weight;
(3) n-pentadecane of 100 weight portions, the above-mentioned Chinese medicine composition concentrate of 1-3 weight portion and the piperonyl butoxide of 0.03-0.06 weight portion are mixed, can make thunder godvine electric liquid device of the present invention.
Concrete, in the present invention,
Thunder godvine is the root of plant Celastraceae thunder godvine.Originate in ground such as Zhejiang, Anhui, Jiangxi, Hunan, Guangdong, Guangxi, Fujian, Taiwan, Yunnan." Hunan medicine will ": " desinsection, anti-inflammatory, detoxifcation.”
Oriental wormwood, these article are the dry aerial parts of feverfew shore wormwood artemisia or Artemisia capillaris.Be recorded in an one-166 of Pharmacopoeia of the People's Republic of China version in 2005.
The root of Dahurain angelica is the dry root of the umbellate form section plant root of Dahurain angelica or Radix angelicae dahuricae.Be recorded in one one-69-70 of Pharmacopoeia of the People's Republic of China version in 2005.
Asafoetide is the resin of samphire Ferula sinkiangensis or Ferula fukanensis K.M.Shen.Be recorded in an one-131 of Pharmacopoeia of the People's Republic of China version in 2005.
Honeysuckle is caprifoliaceae plant dry flower or the first flower of opening of band of honeysuckle.Function with cure mainly: clearing heat and detoxicating, wind-heat dissipating.Be recorded in one one-152-153 of Pharmacopoeia of the People's Republic of China version in 2005.
Santal is the heartwood of Santalaceae plant santal trunk.Be recorded in an one-264 of Pharmacopoeia of the People's Republic of China version in 2005.
Agalloch eaglewood contains the timber of resin for Thymelaeceae plant whitewood perfume (or spice).Be recorded in an one-128 of Pharmacopoeia of the People's Republic of China version in 2005.
West safflower is the dry column cap of irides Crocus sativus.Be recorded in an one-86 of Pharmacopoeia of the People's Republic of China version in 2005.
Black false hellebore (formal name used at school: the plant of Liliaceae Veratrum Veratrum nigrum L.), perennial herb.Effect: clearing heat and detoxicating, desinsection.Also many places are on the books in one one of Pharmacopoeia of the People's Republic of China version in 2005.
Radix Codonopsis is the dry root of Campanulaceae plant Radix Codonopsis, plain flower Radix Codonopsis or radix codonpsis tangshen.Be recorded in an one-199 of Pharmacopoeia of the People's Republic of China version in 2005.
Mosquito repellent component of the present invention is processed by natural wild Chinese herbal medicine fully; The smell that in vaporizer mosquito liquid heating process, distributes can suppress, the kill virus germ; The prevention respiratory disease, enhances human body immunologic function, mosquito killer; Fresh air, more crucial is to use the present invention to produce harmful effect to human body for a long time.
Special, in one one of Pharmacopoeia of the People's Republic of China version in 2005, particularly point out: Radix Codonopsis should not with black false hellebore with using.Discovery after yet the process inventor tests is in a large number added Radix Codonopsis simultaneously in vaporizer mosquito liquid and black false hellebore not only can increase repelling effect, and can't produce harmful effect to human body.
The experiment proof; The present invention has certain inhibition, killing action to multiple germs such as gold look staphylococcus, shigella dysenteriae, tubercle bacillus, Pseudomonas aeruginosa, bacillus anthracis, hepatitis bacillus; Particularly the virus and bacteria for epidemic infection property disease has very strong insect killing effect, and mosquito is had the stronger effect of killing.
Embodiment
Embodiment 1:
(1) take by weighing following each traditional Chinese medicinal components: thunder godvine 70 grams, oriental wormwood 25 grams, the root of Dahurain angelica 3 grams, asafoetide 3 grams, honeysuckle 15 grams, santal 3 grams, agalloch eaglewood 4 grams, west safflower 3 grams, black false hellebore 2 grams and Radix Codonopsis 1.5 grams, pulverize, mix, obtain Chinese medicine composition;
(2) 780 gram water are added in the above-mentioned Chinese medicine composition in 90 ℃ decocted 0.5 hour, filter, concentrate, obtain 388 gram Chinese medicine composition concentrates;
(3) n-pentadecane of 100 grams, the above-mentioned Chinese medicine composition concentrate of 1 gram and the piperonyl butoxide of 0.06 gram are mixed, can make thunder godvine electric liquid device of the present invention.
Embodiment 2:
(1) take by weighing each traditional Chinese medicinal components of following gram: thunder godvine 80 grams, oriental wormwood 20 grams, the root of Dahurain angelica 6 grams, asafoetide 1 gram, honeysuckle 25 grams, santal 1 gram, agalloch eaglewood 6 grams, west safflower 1 gram, black false hellebore 4 grams and Radix Codonopsis 0.5 gram, pulverize, mix, obtain Chinese medicine composition;
(2) 1150 gram water are added in the above-mentioned Chinese medicine composition,, filter, concentrate, obtain 145 gram Chinese medicine composition concentrates in 70 ℃ of decoctions 2.5 hours;
(3) n-pentadecane of 100 grams, the above-mentioned Chinese medicine composition concentrate of 3 grams and the piperonyl butoxide of 0.03 gram are mixed, can make thunder godvine electric liquid device of the present invention.
Embodiment 3:
(1) take by weighing each traditional Chinese medicinal components of following gram: thunder godvine 75 grams, oriental wormwood 23 grams, the root of Dahurain angelica 4 grams, asafoetide 2 grams, honeysuckle 20 grams, santal 2 grams, agalloch eaglewood 5 grams, west safflower 2 grams, black false hellebore 3 grams and Radix Codonopsis 1 gram, pulverize, mix, obtain Chinese medicine composition;
(2) 960 gram water are added in the above-mentioned Chinese medicine composition,, filter, concentrate, obtain 270 gram Chinese medicine composition concentrates in 80 ℃ of decoctions 1.5 hours;
(3) n-pentadecane of 100 grams, the above-mentioned Chinese medicine composition concentrate of 2 grams and the piperonyl butoxide of 0.05 gram are mixed, can make thunder godvine electric liquid device of the present invention.
Test case 1: indoor harmacological effect
Adopt GB 18418-2001 domestic sanitary desinsection articles for use electric liquid device standard, test.In this standard, it is qualified that KT50 value (boxing method)≤10 minute can be judged to.
Table 1: vaporizer mosquito liquid indoor harmacological effect table (boxing method)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| The KT50 value | 8 minutes 25 seconds | 6 minutes 55 seconds | 7 minutes 39 seconds |
Test case 2: acute oral toxicity test
The vaporizer mosquito liquid of experiment material: embodiment 2.The back 5 minutes activities in rats of contaminating increase, and continue about 2 minutes, and activity transfers to normally, and diet is normal, and the observation period does not have death, and LD50 belongs to actual nontoxic greater than 5000 milligrams/kilogram.
Test case 3: acute toxicity on inhalation test
The vaporizer mosquito liquid of experiment material: embodiment 2.Contamination back rat diet activity no abnormality seen, the observation period does not have death, and LD50 belongs to actual nontoxic greater than 10 gram/cubic meters.
Test case 4: skin patch test
The vaporizer mosquito liquid of experiment material: embodiment 2.It is 0 that experimental group erythema and oedema form the scoring sum, explains skin is had no stimulation.
Test case 5: eye irritant test
The acute eye irritation score index of the vaporizer mosquito liquid of embodiment 2 is 0, explains mucous membrane is had no stimulation.
Claims (2)
1. a thunder godvine electric liquid device is characterized in that, is mixed by weight by following component: 100 parts of n-pentadecanes, and Chinese medicine composition concentrate 1-3 part, piperonyl butoxide 0.03-0.06 part,
Wherein, said Chinese medicine composition concentrate is prepared from following method:
(1) takes by weighing each traditional Chinese medicinal components of following weight parts: thunder godvine 70-80 part, oriental wormwood 20-25 part, root of Dahurain angelica 3-6 part, asafoetide 1-3 part, honeysuckle 15-25 part, santal 1-3 part, agalloch eaglewood 4-6 part, west safflower 1-3 part, black false hellebore 2-4 part and Radix Codonopsis 0.5-1.5 part; Pulverize; Mix, obtain Chinese medicine composition;
(2) water is added in the above-mentioned Chinese medicine composition, the addition of water is 6-8 a times of Chinese medicine composition gross weight, decocts 0.5-2.5 hour in 70-90 ℃; Filter; Concentrate, obtain the Chinese medicine composition concentrate, the weight of said Chinese medicine composition concentrate is 1-3 times of Chinese medicine composition gross weight.
2. the preparation method of a thunder godvine electric liquid device is characterized in that, is made up of following step:
(1) takes by weighing each traditional Chinese medicinal components of following weight parts: thunder godvine 70-80 part, oriental wormwood 20-25 part, root of Dahurain angelica 3-6 part, asafoetide 1-3 part, honeysuckle 15-25 part, santal 1-3 part, agalloch eaglewood 4-6 part, west safflower 1-3 part, black false hellebore 2-4 part and Radix Codonopsis 0.5-1.5 part; Pulverize; Mix, obtain Chinese medicine composition;
(2) water is added in the above-mentioned Chinese medicine composition, the addition of water is 6-8 a times of Chinese medicine composition gross weight, decocts 0.5-2.5 hour in 70-90 ℃; Filter; Concentrate, obtain the Chinese medicine composition concentrate, the weight of said Chinese medicine composition concentrate is 1-3 times of Chinese medicine composition gross weight;
(3) n-pentadecane of 100 weight portions, the above-mentioned Chinese medicine composition concentrate of 1-3 weight portion and the piperonyl butoxide of 0.03-0.06 weight portion are mixed, can make thunder godvine electric liquid device of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103103010A CN102326591B (en) | 2011-09-28 | 2011-09-28 | Common threewingnut root electro-thermal liquid mosquito incense and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103103010A CN102326591B (en) | 2011-09-28 | 2011-09-28 | Common threewingnut root electro-thermal liquid mosquito incense and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102326591A true CN102326591A (en) | 2012-01-25 |
| CN102326591B CN102326591B (en) | 2013-05-08 |
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| CN2011103103010A Expired - Fee Related CN102326591B (en) | 2011-09-28 | 2011-09-28 | Common threewingnut root electro-thermal liquid mosquito incense and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105594754A (en) * | 2016-02-17 | 2016-05-25 | 广西大学 | Fructus toosendan electrothermal liquid mosquito-repellent incense and preparation method thereof |
| CN108514543A (en) * | 2018-06-25 | 2018-09-11 | 廖海湘 | A kind of Chinese medicine mosquito repellent liquid |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1209273A (en) * | 1997-08-21 | 1999-03-03 | 李德安 | Pollution-free plant mosquito-fly-killing agent |
| CN1282514A (en) * | 1999-07-30 | 2001-02-07 | 杨兵生 | Mosquito-repellent incense |
| CN1316185A (en) * | 2001-02-27 | 2001-10-10 | 中国科学院上海昆虫研究所 | Liquid mosquito-repellent incense soup |
| CN1692739A (en) * | 2005-04-22 | 2005-11-09 | 徐云 | Internal burning type electrically heated insect repellent piece |
| CN101015303A (en) * | 2006-12-25 | 2007-08-15 | 洪云飞 | Plant mosquito-fly pesticide |
-
2011
- 2011-09-28 CN CN2011103103010A patent/CN102326591B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1209273A (en) * | 1997-08-21 | 1999-03-03 | 李德安 | Pollution-free plant mosquito-fly-killing agent |
| CN1282514A (en) * | 1999-07-30 | 2001-02-07 | 杨兵生 | Mosquito-repellent incense |
| CN1316185A (en) * | 2001-02-27 | 2001-10-10 | 中国科学院上海昆虫研究所 | Liquid mosquito-repellent incense soup |
| CN1692739A (en) * | 2005-04-22 | 2005-11-09 | 徐云 | Internal burning type electrically heated insect repellent piece |
| CN101015303A (en) * | 2006-12-25 | 2007-08-15 | 洪云飞 | Plant mosquito-fly pesticide |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105594754A (en) * | 2016-02-17 | 2016-05-25 | 广西大学 | Fructus toosendan electrothermal liquid mosquito-repellent incense and preparation method thereof |
| CN108514543A (en) * | 2018-06-25 | 2018-09-11 | 廖海湘 | A kind of Chinese medicine mosquito repellent liquid |
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| Publication number | Publication date |
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| CN102326591B (en) | 2013-05-08 |
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