CN102300635B - 用于通过将乙酸加氢生产乙醇的包含在含硅载体上的铂-锡的催化剂 - Google Patents

用于通过将乙酸加氢生产乙醇的包含在含硅载体上的铂-锡的催化剂 Download PDF

Info

Publication number
CN102300635B
CN102300635B CN201080006216.9A CN201080006216A CN102300635B CN 102300635 B CN102300635 B CN 102300635B CN 201080006216 A CN201080006216 A CN 201080006216A CN 102300635 B CN102300635 B CN 102300635B
Authority
CN
China
Prior art keywords
platinum
tin
acetic acid
catalyst
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080006216.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN102300635A (zh
Inventor
H·魏纳
V·J·约翰斯顿
J·L·波茨
R·耶夫蒂奇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese International Corp
Original Assignee
Celanese International Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/588,727 external-priority patent/US8309772B2/en
Application filed by Celanese International Corp filed Critical Celanese International Corp
Priority to CN201110452877.0A priority Critical patent/CN102557871B/zh
Publication of CN102300635A publication Critical patent/CN102300635A/zh
Application granted granted Critical
Publication of CN102300635B publication Critical patent/CN102300635B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201080006216.9A 2009-10-26 2010-10-26 用于通过将乙酸加氢生产乙醇的包含在含硅载体上的铂-锡的催化剂 Expired - Fee Related CN102300635B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110452877.0A CN102557871B (zh) 2009-10-26 2010-10-26 用于通过将乙酸加氢生产乙醇的包含在含硅载体上的铂-锡的催化剂

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/588,727 US8309772B2 (en) 2008-07-31 2009-10-26 Tunable catalyst gas phase hydrogenation of carboxylic acids
US12/588,727 2009-10-26
PCT/US2010/054134 WO2011056595A1 (en) 2009-10-26 2010-10-26 Catalyst for the production of ethanol by hydrogenation of acetic acid comprising platinum -tin on silicaceous support

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201110452877.0A Division CN102557871B (zh) 2009-10-26 2010-10-26 用于通过将乙酸加氢生产乙醇的包含在含硅载体上的铂-锡的催化剂

Publications (2)

Publication Number Publication Date
CN102300635A CN102300635A (zh) 2011-12-28
CN102300635B true CN102300635B (zh) 2014-10-29

Family

ID=46506679

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080006216.9A Expired - Fee Related CN102300635B (zh) 2009-10-26 2010-10-26 用于通过将乙酸加氢生产乙醇的包含在含硅载体上的铂-锡的催化剂

Country Status (11)

Country Link
EP (1) EP2493609A1 (enExample)
JP (1) JP5775087B2 (enExample)
CN (1) CN102300635B (enExample)
AU (1) AU2010315552B2 (enExample)
BR (1) BR112012009770A2 (enExample)
CA (1) CA2778957A1 (enExample)
IL (1) IL219400A0 (enExample)
MX (1) MX2012004841A (enExample)
RU (1) RU2549893C2 (enExample)
WO (1) WO2011056595A1 (enExample)
ZA (1) ZA201202847B (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
BR112014015080A8 (pt) * 2011-12-29 2017-06-13 Celanese Int Corp catalisador de cobalto e estanho para produzir etanol
US9333496B2 (en) 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
US8865609B2 (en) * 2012-01-06 2014-10-21 Celanese International Corporation Hydrogenation catalysts
US9079851B2 (en) * 2012-02-01 2015-07-14 Greenyug, Llc Ethyl acetate production
US8927786B2 (en) 2012-03-13 2015-01-06 Celanese International Corporation Ethanol manufacturing process over catalyst having improved radial crush strength
CN102658165B (zh) * 2012-04-06 2014-11-05 华东理工大学 乙酸气相加氢制备乙醇的催化剂及其制备方法
CN104107701B (zh) * 2013-04-16 2016-08-03 中国石油化工股份有限公司 高活性Pt基催化剂、制备方法及其用途
DE102013106787A1 (de) 2013-06-28 2014-12-31 Oxea Gmbh Verfahren zur Herstellung von n-Butanderivaten
DE102013106790A1 (de) 2013-06-28 2014-12-31 Oxea Gmbh Verfahren zur Herstellung von 1,3-Butandiol
CN103331158B (zh) * 2013-07-15 2017-08-25 上海华谊（集团）公司 一种醋酸加氢制乙醇的催化剂及制备方法
CN111359618B (zh) * 2020-04-23 2022-10-25 上海亚铂化工科技有限公司 催化剂及其制备方法和应用以及催化酯加氢反应的方法
EP4549622A1 (en) 2023-10-31 2025-05-07 Basf Se Hydrogenation of carbonyl compounds using hydrogen with low deuterium content

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1549851A (zh) * 2001-07-18 2004-11-24 ���з����о���˾ 氢化反应和脱氢反应方法及用于该方法的催化剂

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8509530D0 (en) 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
GB8707595D0 (en) 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
DE19720657A1 (de) * 1997-05-16 1998-11-19 Basf Ag Verfahren zur Herstellung von aliphatischen Alkoholen
JP3780669B2 (ja) * 1997-11-17 2006-05-31 三菱化学株式会社 アルデヒド類及び、又はアルコール類の製造方法
JP3911955B2 (ja) * 1999-04-28 2007-05-09 三菱化学株式会社 ルテニウム−スズ系担持触媒の製造方法。
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
DE102004007498A1 (de) * 2004-02-13 2005-09-01 Basf Ag Hydrierverfahren zur Herstellung optisch aktiver Alkohole oder Carbonsäuren
KR100922998B1 (ko) * 2008-03-06 2009-10-22 한국화학연구원 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1549851A (zh) * 2001-07-18 2004-11-24 ���з����о���˾ 氢化反应和脱氢反应方法及用于该方法的催化剂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP特开平11-147845A 1999.06.02

Also Published As

Publication number Publication date
MX2012004841A (es) 2012-05-29
RU2549893C2 (ru) 2015-05-10
AU2010315552A1 (en) 2012-05-17
JP2013508423A (ja) 2013-03-07
JP5775087B2 (ja) 2015-09-09
AU2010315552B2 (en) 2016-05-12
BR112012009770A2 (pt) 2016-05-17
RU2012121807A (ru) 2013-12-10
CA2778957A1 (en) 2011-05-12
EP2493609A1 (en) 2012-09-05
ZA201202847B (en) 2013-06-26
CN102300635A (zh) 2011-12-28
WO2011056595A1 (en) 2011-05-12
IL219400A0 (en) 2012-06-28

Similar Documents

Publication Publication Date Title
CN102557871B (zh) 用于通过将乙酸加氢生产乙醇的包含在含硅载体上的铂-锡的催化剂
CN102300635B (zh) 用于通过将乙酸加氢生产乙醇的包含在含硅载体上的铂-锡的催化剂
CN102271805B (zh) 由乙酸制备乙醇的方法
US8501652B2 (en) Catalysts for making ethanol from acetic acid
US8471075B2 (en) Processes for making ethanol from acetic acid
CN102421521B (zh) 用于生产乙醇的包含结晶载体改性剂的催化剂的制备和用途
EP2493606A2 (en) Catalysts for making ethanol from acetic acid
HK1165362A (en) Catalyst for the production of ethanol by hydrogenation of acetic acid comprising platinum-tin on silicaceous support
HK1166623A (en) Catalysts for making ethanol from acetic acid
HK1166623B (en) Catalysts for making ethanol from acetic acid

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1165362

Country of ref document: HK

C14 Grant of patent or utility model
GR01 Patent grant
REG Reference to a national code

Ref country code: HK

Ref legal event code: WD

Ref document number: 1165362

Country of ref document: HK

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20141029

Termination date: 20181026