CN102283251B - Agricultural sterilization solution - Google Patents

Agricultural sterilization solution Download PDF

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Publication number
CN102283251B
CN102283251B CN 201110185105 CN201110185105A CN102283251B CN 102283251 B CN102283251 B CN 102283251B CN 201110185105 CN201110185105 CN 201110185105 CN 201110185105 A CN201110185105 A CN 201110185105A CN 102283251 B CN102283251 B CN 102283251B
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sterilization solution
agricultural
agricultural sterilization
weight percentage
triacontanol
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CN102283251A (en
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朱晓鸣
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Beijing Kang Hua star health biotechnology limited liability company
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朱晓鸣
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Abstract

The invention belongs to the technical field of agricultural sterilization, and discloses agricultural sterilization solution. The agricultural sterilization solution contains the following components in percentage by weight: 0.5 to 2 percent of polyhexamethylenebiguanidine hydrochloride, 0.05 to 0.5 percent of polyacrylic acid, and the balance of water. The agricultural sterilization solution has the characteristics of high efficiency, broad spectrum, safety, stability, no toxicity, no harm, no residue pollution, increment on crop yield and income, convenience for fresh keeping and storage of agricultural products and the like.

Description

A kind of agricultural sterilization solution
Technical field
The invention belongs to the agricultural bactericidal technical field, be specifically related to a kind of agricultural sterilization solution.
Background technology
Existing disinfectant use in agriculture kind is a lot, but bactericidal effect differs, such as early stage inorganic compound bactericide, and the disinfectant use in agriculture kinds such as organic sulfur afterwards, organochlorine, organic mercury, organo-arsenic, organic phosphor, farm antibiotics.The problems such as these bactericide ubiquity use cost height, poor stability, toxic, corrosivity and residual contamination environment are subject to very big limitation in agricultural production application.Therefore, modern agriculture needs the new type bactericide product that safety and stability, high-efficiency broad spectrum, noresidue are polluted.And at sterilization disease-resistant simultaneously, in time replenish the needed nutritional factors of plant growth and bioactie agent, satisfy the crop growth needs, to increase output, improve quality.Enlarge simultaneously the scope of application of disinfectant use in agriculture, be applied to the cleaning and sterilizing of vegetables, fruit, be convenient to fresh-keeping storage.
Summary of the invention
The agricultural sterilization solution that the object of the present invention is to provide a kind of safety and stability, high-efficiency broad spectrum, noresidue to pollute.
For achieving the above object, the technical scheme taked of the present invention is as follows:
A kind of agricultural sterilization solution, comprise the each component of following weight percent: polyhexamethylene guanide 0.5 ~ 2%, polyacrylic acid 0.05 ~ 0.5%, surplus are water.Polyhexamethylene guanide is as main bactericidal component, polyhexamethylene guanide is polyguanidine family macromolecule polymer, in the aqueous solution, can produce ionization, its hydrophilic group partly contains strong electropositive, absorption is electronegative each bacterioid usually, virus, fatty acid in cell membrane phospholipid is combined, puncture rapidly their cytoplasma membrane, break through the core of germ cell, make the endobacillary living matter outflow of disease, it is synthetic to suppress film lactones plastid, thereby the splitting function that has suppressed bacterium, make bacterium lose fecundity, cause the thalline apoptosis, reach best bactericidal effect.Polyacrylic acid is dispersant, and composite use has collaborative effect of increasing production effect.Polyhexamethylene guanide and polyacrylic acid all in the prior art may be used to the present invention.
Particularly, when spraying for crops, agricultural sterilization solution comprises the each component of following weight percent: polyhexamethylene guanide 0.5 ~ 2%, polyacrylic acid 0.05 ~ 0.5%, surplus are water; When being used for seed dressing, agricultural sterilization solution comprises the each component of following weight percent: polyhexamethylene guanide 0.75 ~ 2%, polyacrylic acid 0.06 ~ 0.45%, surplus are water; When being used for soil disinfection, agricultural sterilization solution comprises the each component of following weight percent: polyhexamethylene guanide 0.5 ~ 2%, polyacrylic acid 0.07 ~ 0.5%, surplus are water.
Further, in sterilization, promoting crop growth, increase product and use function, also comprise the triacontanol milk powder of weight percentage 0.1 ~ 0.5%.Triacontanol milk powder is natural long-chain plant growth regulator, and Promoting plant growth increases dry-matter accumulation, improves cell leakage, improves photosynthetic intensity, strengthens enzymic activity.
Particularly, when spraying for crops, agricultural sterilization solution also comprises the triacontanol milk powder of weight percentage 0.1 ~ 0.5%; When being used for seed dressing, agricultural sterilization solution also comprises the triacontanol milk powder of weight percentage 0.2 ~ 0.5%; When being used for soil disinfection, agricultural sterilization solution also comprises the triacontanol milk powder of weight percentage 0.15 ~ 0.45%.
Further again, for increasing the trophic function of product, make it to become " Fungicidal nutritive liquid ", also comprise the trace element of weight percentage below 5%.Described trace element is trace element commonly used known in this field, preferably contains wherein a kind of or its combination of the salt of zinc, selenium, molybdenum, boron, manganese, copper, iron.According to applicable different crops, select concrete different trace element, its overall weight percentage consumption is controlled at below 5%.Trace element is the essential nutritive element of plant.Trace element effect in plant corpus has very strong selectivity, can not lack also and can not replace.Mostly be the constituent of plant corpus endoenzyme or coenzyme, participate in the metabolism redox process of candy and nitrogen, affect photosynthesis and the respiration of plant, improve simultaneously crop to the repellence of disease and poor environment.When micro-undersupply, plant often shows specific shortage symptom, and yield and quality is descended, when serious in addition particle do not receive.
Particularly, when spraying for crops, agricultural sterilization solution also comprises the trace element of weight percentage 1 ~ 5%; When being used for seed dressing, agricultural sterilization solution also comprises the trace element of weight percentage 2 ~ 4%; When being used for soil disinfection, agricultural sterilization solution also comprises the trace element of weight percentage 0.02 ~ 3.5%.
Further, for coordinating to enhance product performance, improve service efficiency, also comprise the humate of weight percentage below 5%.Described humate is humate commonly used known in this field, one of preferred potassium humate, sodium humate or both combinations.Humate can dissociate out in the aqueous solution and show weakly acidic humus.Humus is a kind of natural organic substance, is decomposition, the synthetic product of plant process natural microorganisms, has faintly acid, water imbibition, colloidality, adsorptivity, ion exchangeable, complexing, oxidation-reduction quality and physiologically active.Humus is as physiological activator, to crop grow and the body physiological metabolism has spread effect, Main Function: promote fertilizer efficiency, improve soil, improve quality, regulating crop growth, strengthen the resistance of crop and resistance against diseases etc.
Particularly, when spraying for crops, agricultural sterilization solution also comprises the humate of weight percentage 2 ~ 4.5%; When being used for seed dressing, agricultural sterilization solution also comprises the humate of weight percentage 3 ~ 5%; When being used for soil disinfection, agricultural sterilization solution also comprises the humate of weight percentage 0.01 ~ 3.5%.
The preparation method of agricultural sterilization solution of the present invention: directly mix in proportion.
The using method of agricultural sterilization solution of the present invention: the crop leaf surface is sprayed, also can dress seed or water in soil.
Agricultural sterilization solution of the present invention is applicable to various crops sterilization disease-resistants, improves quality, increases output and soil disinfection, also is applied to cleaning and sterilizing and the fresh-keeping storage of vegetables, fruit.
Agricultural sterilization solution of the present invention possesses high-efficiency broad spectrum, and safety and stability is nontoxic, and noresidue is polluted, and crop yield is increased income, and is convenient to the characteristics such as agricultural products fresh-keeping storage, and concrete manifestation is as follows:
(1), plant seed is processed and crops have disease-resistant protective effect, effective kill harmful bacterium, wide spectrum, efficiently, and have long-term bacteriostasis, have good prevention, treat and increase income effect;
(2), have the characteristics of water-soluble and surface adhesion, do not need to add again surfactant and binder.Form a stable antimicrobial thin polymer film in the crops surface, it is lasting, nontoxic, harmless, pollution-free to keep rendeing a service, and is the ecological, environmental protective product, uses safety in agricultural;
(3), improve crop yield, improve quality of agricultural product, be applicable to the vegetative stage of various crops;
(4), be applied to soil disinfection, can dispel residual agricultural chemicals, weed killer herbicide to the infringement of plant, protect from infection;
(5), be applied to clean or spray vegetables and fruit, instant fresh-keeping storage;
(6), use valid density low, speed of action is fast, stable in properties can be used at normal temperatures.
Embodiment
The embodiment that corps leaf surface sprays
The bactericidal liquid of preparation 100kg, with measuring respective sets part, adding distil water complements to 100kg, stirs to get final product by table 1.
Figure 16857DEST_PATH_IMAGE001
Measure of merit
With distilled water the bactericidal liquid of 1 ~ 5 preparation of embodiment in the table 1 is carried out 200 times, 400 times, 800 times, 1000 times dilutions, then be divided into 4 concentration gradients, directly spray on the blade face, carry out the test determination of sterilization and nutrition effect of increasing production, general performance such as table 2 in multiple kinds of crops.
Figure 933998DEST_PATH_IMAGE002
The calculating of above bactericidal effect and effect of increasing production is all take clear water as contrast, below roughly the same.
As can be seen from the above table: bactericidal liquid is carried out the effect of foliage-spray to crops relevant with the concentration of dilution, but the concentration of dilution is less to the influential effect of medicine, and under 1000 times dilution for many times, bactericidal liquid still has the preferably effect of Fungicidal nutritive.
The embodiment that seed dressing is used
The bactericidal liquid of preparation 100kg, with measuring respective sets part, adding distil water complements to 100kg, stirs to get final product by table 3.
Measure of merit
With distilled water the bactericidal liquid of 1 ~ 5 preparation of embodiment in the table 3 is carried out 10 times, 100 times, 200,400 times dilutions, then be divided into 4 concentration gradients, soaking seed before the multiple kinds of crops seed germination (is as the criterion with the submergence seed, conventional 3 ~ 5 hours), carry out the test determination of sterilization and nutrition effect of increasing production in multiple kinds of crops, general performance such as table 4.
As can be seen from the above table: before seed germination, soak seed with seed dressing with bactericidal liquid, its effect is relevant with the concentration of dilution, but diluted concentration is less to the influential effect of medicine, and under 400 times dilution for many times, bactericidal liquid still has the preferably effect of Fungicidal nutritive.
The embodiment that soil disinfection is used
The bactericidal liquid of preparation 100kg, with measuring respective sets part, adding distil water complements to 100kg, stirs to get final product by table 5.
Figure DEST_PATH_IMAGE005
Measure of merit
With distilled water the bactericidal liquid of 1 ~ 5 preparation of embodiment in the table 5 is carried out 100 times, 200 times, 800 times, 1000 times dilutions, then be divided into 4 concentration gradients, directly punching is executed in soil, carries out the test determination of sterilization and nutrition effect of increasing production, general performance such as table 6 in multiple soil types.
Figure 107337DEST_PATH_IMAGE006
Interpretation of result and discussion
As can be seen from the above table: it is relevant with the concentration of dilution that the soil disinfection bactericidal liquid is directly rushed the effect of executing in soil, but diluted concentration is less to the influential effect of medicine, under 1000 times dilution for many times, soil disinfection Fungicidal nutritive liquid still has the preferably effect of Fungicidal nutritive.
Annotate: suitably adjust the content of each composition in table 1,3,5 prescription allowed bands, expression effect is basic identical.

Claims (6)

1. agricultural sterilization solution, it is characterized in that comprising each component of following weight percent: polyhexamethylene guanide 0.5 ~ 2%, polyacrylic acid 0.05 ~ 0.5%, triacontanol milk powder 0.1 ~ 0.5%, surplus are water.
2. agricultural sterilization solution as claimed in claim 1 is characterized in that: when being used for crops and spraying, triacontanol milk powder weight percentage is 0.1 ~ 0.5% in the agricultural sterilization solution; When being used for seed dressing, triacontanol milk powder weight percentage is 0.2 ~ 0.5% in the agricultural sterilization solution; When being used for soil disinfection, triacontanol milk powder weight percentage is 0.15 ~ 0.45% in the agricultural sterilization solution.
3. agricultural sterilization solution, it is characterized in that comprising each component of following weight percent: polyhexamethylene guanide 0.5 ~ 2%, polyacrylic acid 0.05 ~ 0.5%, triacontanol milk powder 0.1 ~ 0.5%, trace element are below 5%, and surplus is water.
4. agricultural sterilization solution as claimed in claim 3 is characterized in that: when being used for crops and spraying, micro-weight percentage is 1 ~ 5% in the agricultural sterilization solution; When being used for seed dressing, micro-weight percentage is 2 ~ 4% in the agricultural sterilization solution; When being used for soil disinfection, micro-weight percentage is 0.02 ~ 3.5% in the agricultural sterilization solution.
5. agricultural sterilization solution, it is characterized in that comprising each component of following weight percent: polyhexamethylene guanide 0.5 ~ 2%, polyacrylic acid 0.05 ~ 0.5%, triacontanol milk powder 0.1 ~ 0.5%, trace element below 5%, humate are below 5%, and surplus is water.
6. agricultural sterilization solution as claimed in claim 5 is characterized in that: when being used for crops and spraying, the humate weight percentage is 2 ~ 4.5% in the agricultural sterilization solution; When being used for seed dressing, the humate weight percentage is 3 ~ 5% in the agricultural sterilization solution; When being used for soil disinfection, the humate weight percentage is 0.01 ~ 3.5% in the agricultural sterilization solution.
CN 201110185105 2011-07-04 2011-07-04 Agricultural sterilization solution Expired - Fee Related CN102283251B (en)

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Publication number Priority date Publication date Assignee Title
CN103975942B (en) * 2013-05-07 2015-08-26 江苏辉丰农化股份有限公司 There is the bactericidal composition of synergistic effect
JP2018529699A (en) * 2015-09-25 2018-10-11 フレクジッヒ パテント カンパニー エルエルシー Novel plant protection composition and use thereof
CN105541480A (en) * 2015-12-29 2016-05-04 辛集市远翔环保能源科技有限公司 Soil amendment
CN105494436A (en) * 2015-12-29 2016-04-20 辛集市远翔环保能源科技有限公司 Agricultural sterilizing agent
CN105859393A (en) * 2016-03-31 2016-08-17 太仓市东泾农场专业合作社 A trace element-rich sterilization liquid
US20190230929A1 (en) * 2018-01-30 2019-08-01 W.M. Barr & Company, Inc. Composition for residual sanitization

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1357235A (en) * 2000-12-08 2002-07-10 马渝强 Polyoxy alkene guanidine disinfectant
CN1451276A (en) * 2002-12-17 2003-10-29 苏州富美实植物保护剂有限公司 Aqueous carbosulfan emulsion and preparing method thereof
CN1542033A (en) * 2003-05-01 2004-11-03 上海黛龙生物工程科技有限公司 Macromolecule polymer and method for preparing the same
CN101028530A (en) * 2006-02-27 2007-09-05 权力敏 Air antiseptic cleaner
CN101027999A (en) * 2006-02-27 2007-09-05 权力敏 Agricultural bacteriocide

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1357235A (en) * 2000-12-08 2002-07-10 马渝强 Polyoxy alkene guanidine disinfectant
CN1451276A (en) * 2002-12-17 2003-10-29 苏州富美实植物保护剂有限公司 Aqueous carbosulfan emulsion and preparing method thereof
CN1542033A (en) * 2003-05-01 2004-11-03 上海黛龙生物工程科技有限公司 Macromolecule polymer and method for preparing the same
CN101028530A (en) * 2006-02-27 2007-09-05 权力敏 Air antiseptic cleaner
CN101027999A (en) * 2006-02-27 2007-09-05 权力敏 Agricultural bacteriocide

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Address before: 450000 34, 1 building, 69 agricultural road, Jinshui District, Zhengzhou, Henan.

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