CN102268657B - 聚碳酸酯工程塑料化学镀前表面粗化方法 - Google Patents
聚碳酸酯工程塑料化学镀前表面粗化方法 Download PDFInfo
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- CN102268657B CN102268657B CN2011102128788A CN201110212878A CN102268657B CN 102268657 B CN102268657 B CN 102268657B CN 2011102128788 A CN2011102128788 A CN 2011102128788A CN 201110212878 A CN201110212878 A CN 201110212878A CN 102268657 B CN102268657 B CN 102268657B
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- polycarbonate plate
- aqueous solution
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- 239000004417 polycarbonate Substances 0.000 title claims abstract description 95
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 95
- 238000000034 method Methods 0.000 title claims abstract description 29
- 229920006351 engineering plastic Polymers 0.000 title claims abstract description 14
- 238000007788 roughening Methods 0.000 title claims abstract description 10
- 239000000126 substance Substances 0.000 title abstract description 7
- 238000007747 plating Methods 0.000 title abstract description 6
- 230000008961 swelling Effects 0.000 claims abstract description 77
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000007864 aqueous solution Substances 0.000 claims abstract description 37
- 239000000243 solution Substances 0.000 claims abstract description 29
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 24
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000012360 testing method Methods 0.000 claims abstract description 18
- 239000012153 distilled water Substances 0.000 claims abstract description 6
- 206010042674 Swelling Diseases 0.000 claims description 74
- 230000003628 erosive effect Effects 0.000 claims description 56
- 239000007788 liquid Substances 0.000 claims description 36
- 238000005530 etching Methods 0.000 claims description 27
- 239000002994 raw material Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- 238000007772 electroless plating Methods 0.000 claims description 7
- 238000011010 flushing procedure Methods 0.000 claims description 4
- XEEVLJKYYUVTRC-UHFFFAOYSA-N oxomalonic acid Chemical compound OC(=O)C(=O)C(O)=O XEEVLJKYYUVTRC-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 34
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 abstract description 23
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 abstract description 7
- 238000012545 processing Methods 0.000 abstract description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract description 6
- 230000005855 radiation Effects 0.000 abstract description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 abstract 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 230000003746 surface roughness Effects 0.000 abstract 1
- 230000010148 water-pollination Effects 0.000 abstract 1
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 13
- 238000012876 topography Methods 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- -1 octyl phenyl Chemical group 0.000 description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 239000010410 layer Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000007704 wet chemistry method Methods 0.000 description 4
- 238000009713 electroplating Methods 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910001437 manganese ion Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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Abstract
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CN2011102128788A CN102268657B (zh) | 2011-07-28 | 2011-07-28 | 聚碳酸酯工程塑料化学镀前表面粗化方法 |
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CN2011102128788A CN102268657B (zh) | 2011-07-28 | 2011-07-28 | 聚碳酸酯工程塑料化学镀前表面粗化方法 |
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CN102268657A CN102268657A (zh) | 2011-12-07 |
CN102268657B true CN102268657B (zh) | 2012-11-07 |
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CN106191949A (zh) * | 2016-06-24 | 2016-12-07 | 镇江阿尔法特种镀膜科技有限公司 | 一种特种工程塑料表面粗化方法 |
CN110983306B (zh) * | 2019-11-21 | 2021-12-03 | 深圳市飞荣达科技股份有限公司 | 液晶聚合物塑料的镀前表面粗化方法及液晶聚合物塑料 |
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DE2022109C3 (de) * | 1970-05-06 | 1974-03-21 | Celfa Ag, Seewen (Schweiz) | Verfahren zur Herstellung von metallisierbaren Kunststofformkörpern |
JPS5811773A (ja) * | 1981-07-13 | 1983-01-22 | Sekisui Chem Co Ltd | 非導電部材のメッキ方法 |
JP3925724B2 (ja) * | 2003-11-13 | 2007-06-06 | 株式会社黒坂鍍金工業所 | 非導体材料への表面処理方法 |
CN101597782A (zh) * | 2009-06-30 | 2009-12-09 | 陕西师范大学 | 聚碳酸酯工程塑料表面微蚀方法 |
CN101892469B (zh) * | 2010-06-29 | 2011-09-07 | 陕西师范大学 | 超声微蚀体系对abs工程塑料零部件表面微蚀方法 |
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