CN102234476A - Waterborne acrylic polyurethane surface paint - Google Patents
Waterborne acrylic polyurethane surface paint Download PDFInfo
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- CN102234476A CN102234476A CN2010101639940A CN201010163994A CN102234476A CN 102234476 A CN102234476 A CN 102234476A CN 2010101639940 A CN2010101639940 A CN 2010101639940A CN 201010163994 A CN201010163994 A CN 201010163994A CN 102234476 A CN102234476 A CN 102234476A
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Abstract
The invention relates to a waterborne acrylic polyurethane surface paint. The paint is prepared from the raw materials of, by weight: 150 to 200 parts of waterborne acrylic resin, 200 to 300 parts of deionized water, 1 to 3 parts of an antifoaming agent, 180 to 200 parts of titanium pigment, 1 to 3 parts of a neutralizer, 2 to 6 parts of aluminum tripolyphosphate, 100 to 150 parts of precipitated barium sulfate, 10 to 20 parts of a rheological auxiliary agent, 2 to 4 parts of a flash corrosion inhibitor, 25 parts of saponite, 1 to 3 parts of a leveling agent, and 0.5 to 2 parts of a catalyst. The paint provided by the invention has the following advantages: 1. environment pollution is reduced, and energy is saved; 2. the paint has strong adhesive forces on various base materials, and the coating has high hardness, good water resistance, good weatherability, good chemical resistance, and relatively high wear resistance; 3. the paint can be used as terrace and floor paint, metal rust-resisting paint, ship paint, and can be applied on automobiles, light industrial products and drinking-water cylinder inner walls for preventing corrosion.
Description
Technical field:
The present invention relates to a kind of coating, particularly a kind of water soluble acrylic acid polyurethane finish.
Background technology:
Along with the continuous progress of society, various countries improve constantly the consciousness of environmental protection.And containing a large amount of volatilizable organic compound (VOC) in the present widely used solvent based coating, organic compound (VOC) is poisonous, inflammable, pollutes the atmosphere, and environment and human body are all worked the mischief.Therefore, in order to reduce the pollution of these organic solvents to environment, China has listed water-borne coatings in the developing direction of industrial coating from now on.But its water tolerance of aqueous industrial coating, chemical resistant properties, wear resistance and weathering resistance that China is applied on Floor paint, metal rust preventing lacquer and the marine finish at present are undesirable.
Summary of the invention:
Purpose of the present invention just is to overcome above-mentioned the deficiencies in the prior art, and a kind of pollution-free and water tolerance, chemical resistant properties, wear resistance and weathering resistance water soluble acrylic acid polyurethane finish preferably is provided.
As above design, technical scheme of the present invention is: a kind of water soluble acrylic acid polyurethane finish is characterized in that: made according to following weight proportion by following raw materials according: water-borne acrylic resin 150-200 part, deionized water 200-300 part, defoamer 1-3 part, titanium dioxide 180-200 part, neutralizing agent 1-3 part, aluminium triphosphate 2-6 part, process white 100-150 part, auxiliary rheological agents 10-20 part, sudden strain of a muscle corrosion inhibitor 2-4 part, 25 parts of talcum powder, flow agent 1-3 part, catalyzer 0.5-2 part.
Above-mentioned water-borne acrylic resin is made according to following weight proportion by following raw materials according: n-butyl acrylate BA 20-35 part, vinylbenzene ST 12-30 part, vinylformic acid AA 1-3 part, methacrylic acid MAA 1-3 part, methyl methacrylate MMA 1-4 part, N hydroxymethyl acrylamide NMA 5-10 part, Potassium Persulphate K2 S2 08 0.1-1 part, OP-10 and sodium alkyl sulfate 1-4 part, neutralizing agent 0.1-0.3 part, propylene glycol 0.1-0.3 part, deionized water 40-60 part.
Above-mentioned neutralizing agent is made according to following weight proportion by following raw materials according: butanols 50-80 part, trolamine 40-70 part, tributyl phosphate 40-60 part.
The present invention has following advantage and positively effect:
1, the present invention is dispersion medium with the deionized water, need not to add organic solvent, thereby has reduced the pollution to environment, and has saved resource.
2, the water soluble acrylic acid polyurethane finish of making according to combination formula of the present invention all has very strong sticking power to various base materials, and the hardness height of coating, has excellent water tolerance, weathering resistance and chemical resistant properties and higher wear resistance.
3, the present invention is of many uses.Can use as terrace, Floor paint, metal rust preventing lacquer, marine finish, automobile light industrial products and scuttle butt inner wall anti-corrosive.
Embodiment:
Embodiment 1: a kind of water soluble acrylic acid polyurethane finish, make according to following weight proportion by following raw materials according: water-borne acrylic resin 150Kg, deionized water 200Kg, defoamer 1Kg, titanium dioxide 180Kg, neutralizing agent 1Kg, aluminium triphosphate 2Kg, process white 100Kg, auxiliary rheological agents 10Kg, sudden strain of a muscle corrosion inhibitor 2Kg, talcum powder 25Kg, flow agent 1Kg, catalyzer 0.5Kg.
Embodiment 2: a kind of water soluble acrylic acid polyurethane finish, make according to following weight proportion by following raw materials according: water-borne acrylic resin 200Kg, deionized water 300Kg, defoamer 3Kg, titanium dioxide 200Kg, neutralizing agent 3Kg, aluminium triphosphate 6Kg, process white 150Kg, auxiliary rheological agents 20Kg, sudden strain of a muscle corrosion inhibitor 4Kg, talcum powder 25Kg, flow agent 3Kg, catalyzer 2Kg.
Embodiment 3: a kind of water soluble acrylic acid polyurethane finish, make according to following weight proportion by following raw materials according: water-borne acrylic resin 170Kg, deionized water 250Kg, defoamer 2Kg, titanium dioxide 190Kg, neutralizing agent 2Kg, aluminium triphosphate 4Kg, process white 125Kg, auxiliary rheological agents 15Kg, sudden strain of a muscle corrosion inhibitor 3Kg, talcum powder 25Kg, flow agent 2Kg, catalyzer 1.5Kg.
Above-mentioned water-borne acrylic resin is made by following raw materials according: n-butyl acrylate (BA), vinylbenzene (ST), vinylformic acid (AA), methacrylic acid (MAA), methyl methacrylate (MMA), N hydroxymethyl acrylamide (NMA), Potassium Persulphate (K2 S2 08), OP-10 and sodium alkyl sulfate, neutralizing agent, propylene glycol and deionized water.
Above-mentioned neutralizing agent is mixed and made into by butanols, trolamine and tributyl phosphate.
Above-mentioned auxiliary rheological agents can adopt polyether-polyurethane association type auxiliary rheological agents.Above-mentioned sudden strain of a muscle corrosion inhibitor can adopt Sodium Nitrite, Sodium Benzoate and sodium tetraborate.
Should be noted that following item during construction of the present invention:
1, press finish paint before using: solidifying agent=dispose at 5: 1, leave standstill then and spray about 10min or brush.Solidifying agent adopts by there not being the aqueous polyurethane solidifying agent that free sub different acetic ester is made.
Note dustless, the no wet goods of body surface when 2, spraying or brushing.
3, the paint for preparing should use up in 4 hours, in order to avoid the gel waste.
4, store under the product condition up to specification, effective storage life 1 year still can continue to use through being up to the standards as surpassing 1 year.
Claims (3)
1. a water soluble acrylic acid polyurethane finish is characterized in that: made according to following weight proportion by following raw materials according: water-borne acrylic resin 150-200 part, deionized water 200-300 part, defoamer 1-3 part, titanium dioxide 180-200 part, neutralizing agent 1-3 part, aluminium triphosphate 2-6 part, process white 100-150 part, auxiliary rheological agents 10-20 part, sudden strain of a muscle corrosion inhibitor 2-4 part, 25 parts of talcum powder, flow agent 1-3 part, catalyzer 0.5-2 part.
2. water soluble acrylic acid polyurethane finish according to claim 1 is characterized in that: above-mentioned water-borne acrylic resin is made according to following weight proportion by following raw materials according: n-butyl acrylate BA 20-35 part, vinylbenzene ST 12-30 part, vinylformic acid AA 1-3 part, methacrylic acid MAA 1-3 part, methyl methacrylate MMA 1-4 part, N hydroxymethyl acrylamide NMA 5-10 part, Potassium Persulphate K2 S2 O8 0.1-1 part, OP-10 and sodium alkyl sulfate 1-4 part, neutralizing agent 0.1-0.3 part, propylene glycol 0.1-0.3 part, deionized water 40-60 part.
3. according to claim 1 and 2 described water soluble acrylic acid polyurethane finishs, it is characterized in that: above-mentioned neutralizing agent is made according to following weight proportion by following raw materials according: butanols 50-80 part, trolamine 40-70 part, tributyl phosphate 40-60 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101639940A CN102234476A (en) | 2010-05-06 | 2010-05-06 | Waterborne acrylic polyurethane surface paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101639940A CN102234476A (en) | 2010-05-06 | 2010-05-06 | Waterborne acrylic polyurethane surface paint |
Publications (1)
| Publication Number | Publication Date |
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| CN102234476A true CN102234476A (en) | 2011-11-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN2010101639940A Pending CN102234476A (en) | 2010-05-06 | 2010-05-06 | Waterborne acrylic polyurethane surface paint |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865306A (en) * | 2014-03-14 | 2014-06-18 | 福州皇家地坪有限公司 | Self-cleaning flooring finishing material and preparation method thereof |
| CN103923546A (en) * | 2014-05-08 | 2014-07-16 | 铁岭永新涂料有限公司 | Matte black water-based plastic piece coating for automotive trim |
| CN105385269A (en) * | 2015-12-24 | 2016-03-09 | 常熟市福达金属制件有限公司 | Ton drum for industrial production |
| CN105385281A (en) * | 2015-12-30 | 2016-03-09 | 天恒涂料有限公司 | Water-based acrylic polyurethane top-coat |
| CN104497662B (en) * | 2014-12-30 | 2016-08-31 | 何革兴 | A kind of environment-friendlywater-based water-based paint and preparation method thereof |
| CN106189780A (en) * | 2016-08-05 | 2016-12-07 | 吴静 | The preparation method of the special-purpose aqueous acrylic polyurethane enamel of centrifuge |
| CN106189596A (en) * | 2016-08-05 | 2016-12-07 | 安庆市汇东机械有限责任公司 | A kind of extruder vinyl perchloride anti-corrosion paint |
| CN106833334A (en) * | 2017-02-15 | 2017-06-13 | 苏州凯康化工科技有限公司 | Aqueous double-component floor paint and preparation method thereof |
| CN106928801A (en) * | 2017-02-08 | 2017-07-07 | 佛山沛涂科技有限公司 | A kind of automobile coating of water resistant, acid-alkali-corrosive-resisting |
| CN106947352A (en) * | 2017-02-08 | 2017-07-14 | 佛山沛涂科技有限公司 | A kind of automobile coating for taking into account environmental resistance and glossiness |
| CN108084825A (en) * | 2017-12-25 | 2018-05-29 | 安徽科创美涂料科技股份有限公司 | A kind of antistatic floor coatings and the method for making the floor coatings |
| CN112778910A (en) * | 2020-12-30 | 2021-05-11 | 天恒涂料有限公司 | Water-based axle low-VOC special coating |
| CN113444431A (en) * | 2019-06-28 | 2021-09-28 | 河北晨阳工贸集团有限公司 | Water-based anti-sagging clear primer and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104765A (en) * | 2007-08-20 | 2008-01-16 | 维新环保涂料（深圳）有限公司 | Water-based acrylic acid top-coat |
| CN101619183A (en) * | 2009-08-05 | 2010-01-06 | 赵庆利 | Water-based anticorrosive finish paint |
| CN101698771A (en) * | 2009-09-24 | 2010-04-28 | 中国海洋石油总公司 | Water-based primer-topcoat braking paint and preparation method thereof |
-
2010
- 2010-05-06 CN CN2010101639940A patent/CN102234476A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104765A (en) * | 2007-08-20 | 2008-01-16 | 维新环保涂料（深圳）有限公司 | Water-based acrylic acid top-coat |
| CN101619183A (en) * | 2009-08-05 | 2010-01-06 | 赵庆利 | Water-based anticorrosive finish paint |
| CN101698771A (en) * | 2009-09-24 | 2010-04-28 | 中国海洋石油总公司 | Water-based primer-topcoat braking paint and preparation method thereof |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865306A (en) * | 2014-03-14 | 2014-06-18 | 福州皇家地坪有限公司 | Self-cleaning flooring finishing material and preparation method thereof |
| CN103865306B (en) * | 2014-03-14 | 2016-08-17 | 福州皇家地坪有限公司 | A kind of automatically cleaning terrace Lacquer finish material and preparation method thereof |
| CN103923546A (en) * | 2014-05-08 | 2014-07-16 | 铁岭永新涂料有限公司 | Matte black water-based plastic piece coating for automotive trim |
| CN104497662B (en) * | 2014-12-30 | 2016-08-31 | 何革兴 | A kind of environment-friendlywater-based water-based paint and preparation method thereof |
| CN105385269A (en) * | 2015-12-24 | 2016-03-09 | 常熟市福达金属制件有限公司 | Ton drum for industrial production |
| CN105385281A (en) * | 2015-12-30 | 2016-03-09 | 天恒涂料有限公司 | Water-based acrylic polyurethane top-coat |
| CN106189780A (en) * | 2016-08-05 | 2016-12-07 | 吴静 | The preparation method of the special-purpose aqueous acrylic polyurethane enamel of centrifuge |
| CN106189596A (en) * | 2016-08-05 | 2016-12-07 | 安庆市汇东机械有限责任公司 | A kind of extruder vinyl perchloride anti-corrosion paint |
| CN106928801A (en) * | 2017-02-08 | 2017-07-07 | 佛山沛涂科技有限公司 | A kind of automobile coating of water resistant, acid-alkali-corrosive-resisting |
| CN106947352A (en) * | 2017-02-08 | 2017-07-14 | 佛山沛涂科技有限公司 | A kind of automobile coating for taking into account environmental resistance and glossiness |
| CN106833334A (en) * | 2017-02-15 | 2017-06-13 | 苏州凯康化工科技有限公司 | Aqueous double-component floor paint and preparation method thereof |
| CN108084825A (en) * | 2017-12-25 | 2018-05-29 | 安徽科创美涂料科技股份有限公司 | A kind of antistatic floor coatings and the method for making the floor coatings |
| CN113444431A (en) * | 2019-06-28 | 2021-09-28 | 河北晨阳工贸集团有限公司 | Water-based anti-sagging clear primer and preparation method thereof |
| CN112778910A (en) * | 2020-12-30 | 2021-05-11 | 天恒涂料有限公司 | Water-based axle low-VOC special coating |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20111109 |